Tropical Weathering Research Articles

Nd and Sr Isotopes and REE Investigation in Tropical Weathering Profiles of Amazon Region

The exceptional development of lateritic profiles make the Amazon one of the best places to conduct a refined study on the effects of long-term tropical climate on the Earth's surface rocks. Concentrations of Nd and Sr isotopes, as well as rare earth elements (REE), Sr, and other trace elements were determined in six profiles in order to shed new light into element behavior and into the processes controlling the geochemistry and the transfer of these elements among the different compartments of the critical zone. Our investigation indicates natural isotope regional pulse transformations in the Oxisol at the top of all profiles. The ƐNd(t=0) values of the parent rock, mottled horizon, and lateritic duricrust are radiogenic similar to the Amazon craton signature. The thick Oxisol has ƐNd(t=0) values which are much more radiogenic and less variable, whereas it has Zr, Th, Y, and REE in higher concentrations. These issues highlight a complex process for the Nd system, and the following possibilities are proposed to explain this behavior: formation of authigenic cerianite and/or kaolinite, penetration of low-temperature weathering solutions along zircon fractures, and some vegetation uptake. These possibilities allow keeping the more radiogenic Nd isotopes, whereas the less radiogenic Nd is released especially in the Oxisol after REE mineral(s) weathering. The Sr system contrary to that of Nd became less radiogenic along the profiles and relatively to the parent rocks content, because nearly all Sr was removed after K-Rb feldspar and mica weathering. However, a mixture return of less radiogenic Sr from plant, biogenic aerosol, and rainwater may have helped let the weathering profiles become less radiogenic. These characteristics let the Oxisol even less Sr radiogenic but still permitting to identify the general parent rocks signature. In contrast, Nd is highly fractionated in the Oxisol relative to the parent rock. Thus, the REE and Sr behavior, similar in the six profiles, does not necessarily reflect only the parent rock geochemistry, but it also depends on the multiple surficial processes typical of the critical zone: weathering, pedogenesis, plant root activity, and rainwater composition which change the inherited primary minerals isotope signatures.

Resource Assessment and Possible Industrial Applications of Bauxite Occurrences in Parts of the Mambila Plateau, NE Nigeria

Bauxites are normally formed from underlying aluminosilicate rocks as a result of tropical weathering. In our previous 2 papers, we presented the Geology, possible host, mineralogy, and geochemistry of the bauxites of Mambila Plateau, NE Nigeria. The bauxite was formed from residual chemical weathering of trachyte and occurs as a blanket cover over saprolite. XRD results showed gibbsite as the major mineral with small amounts of hematite, kaolinite, and quartz. Geochemistry of the bauxite ore is characterized by enriched Al2O3 (39.50-78.20.0%), erratic amounts of SiO2 (2.89-5.13%) and Fe2O3 (5.98-21.96%). In this study, the resources of Mambilla Bauxite Deposits (Block I and Block II) have been estimated to be 7,529,312.5 metric tons using block method of vertical geological cross-section bearing in mind that the Mambilla Bauxite Deposits have been explored by pitting on a regular grid pattern of 100 m×100 m. The bauxite deposit in Block II has met the requirement for metallurgical grade bauxite as standard specification (IS: 5953-1985, Reaffirmed [1]). While, Block I deposit has not met such specifications. Sustained investment in bauxite exploration is required to upgrade the ore reserves for sustainable development of a mining enterprise.

Reading the climate signals hidden in bauxite

The dynamics of tropical weathering through time with the formation and long-term evolution of laterite associated with climatic and geodynamic forcing is still a poorly explored issue. To better access this, we focused on lateritic-bauxitic duricrusts from the well-explored, 300 m high Kaw mountain in northeastern French Guiana. Macroscopically homogeneous Fe (oxyhydr)oxides-rich subsamples were separated from 10 bulk samples. Bulk- and subsamples were investigated by mineralogical and geochemical analyses and (U-Th)/He geochronology. The samples show a large heterogeneity on the macro- and microscopic scale reflecting different stages of duricrust formation and evolution through processes of dissolution and (re)precipitation of Fe (oxyhydr)oxides. The 284 (U-Th)/He ages obtained for goethite α-(Fe, Al)OOH and hematite α-Fe2O3 range from 30.5 ± 3.1 to < 0.8 Ma and show large variability within a sample. The oldest hematite and Al-poor goethite subsamples precipitated since 30 Ma and formed while kaolinite was stable. Precipitation of Fe-minerals increased since ∼ 14–12 Ma but still happened under ferruginous lateritic, non-bauxitic conditions. The dissolution and (re)precipitation of Fe minerals, Al-substitution in goethite, and the overall enrichment in Th, as well as gibbsite precipitation indicate an intensification of weathering and a shift towards bauxitic conditions since the end of the Miocene. The Th-, U-, and Al-rich Fe phases formed in this late episode of intense weathering partially replace the oldest, often Th- and U-poor phases leading to a considerable age spread. We claim that this episode of intensified weathering, which had its peak at ca. 6–2 Ma, corresponds to the bauxitization of the lateritic cover of Kaw mountain.Our proposed model of lateritization since at least 30 Ma and bauxitization since the late Miocene provides new constraints on the timescale and intensity of weathering at Kaw mountain. The onset of lateritization in French Guiana (Kaw region) is potentially older than ca. 30 Ma and was possibly synchronous with the development of bauxites in neighboring countries, and differences in the Paleogene weathering intensity might be due to different drainage capacities of the parental material. Late Neogene bauxitization suggests a regional increase in precipitations and drainage potentially linked to increased incision owing to local uplift.Finally, we confirm that a detailed combination of geochronological results coupled to mineralogical and geochemical analyses improves our understanding of tropical weathering processes and duricrust formation by placing mineralogical and geochemical processes into a temporal framework.

Secondary Minerals Drive Extreme Lithium Isotope Fractionation During Tropical Weathering

AbstractLithium isotopes are used to trace weathering intensity, but little is known about the processes that fractionate them in highly weathered settings, where secondary minerals play a dominant role in weathering reactions. To help fill this gap in our knowledge of Li isotope systematics, we investigated Li isotope fractionation at an andesitic catchment in Puerto Rico, where the highest rates of silicate weathering on Earth have been documented. We found the lowest δ7Li values published to date for porewater (−27‰) and bulk regolith (−38‰), representing apparent fractionations relative to parent rock of −31‰ and −42‰, respectively. We also found δ7Li values that are lower in the exchangeable fraction than in the bulk regolith or porewater, the opposite than expected from secondary mineral precipitation. We interpret these large isotopic offsets and the unusual relationships between Li pools as resulting from two distinct weathering processes at different depths in the regolith. At the bedrock‐regolith transition (9.3–8.5 m depth), secondary mineral precipitation preferentially retains the lighter 6Li isotope. These minerals then dissolve further up the profile, leaching 6Li from the bulk solid, with a total variation of about +50‰ within the profile, attributable primarily to clay dissolution. Importantly, streamwater δ7Li (about +35‰) is divorced entirely from these regolith weathering processes, instead reflecting deeper weathering reactions (&gt;9.3 m). Our work thus shows that the δ7Li of waters draining highly weathered catchments may reflect bedrock mineralogy and hydrology, rather than weathering intensity in the regolith covering the catchment.

Geochemistry of a spheroidal weathering profile in a tropical mountainous landscape, Rio de Janeiro, Brazil

Boulders are an important material in debris flow and their source is coupled with spheroidal weathering profiles that produce corestones. The goal of this work was to establish the geochemical transformations that produced corestones and distinguished them from the surrounding grus in two tropical granite weathering profiles (P1 and P2). Sampling was not performed in a vertical profile; instead, we gathered 13 (P1) to 16 (P2) samples displaying different weathering degrees (corestone and saprolite) and spatial positions in the profiles. We conducted the geochemistry (EDXRF/EDX and INAA) and mineralogy (petrography and XRD) of the samples. The CIA values ranged from 46 (corestones) to 93 (saprolite). Granite spheroidal weathering under a tropical mountainous slope develops mostly due to feldspar weathering (foremost plagioclase) in the following sequence: porosity growth, kaolinite, and gibbsite crystallization. Zircon weathering stability and its probable mobility as grain along the weathering profile play an important role in REE concentration. Spheroidal weathering is mainly a lixiviation process, yet specific locations (below the individualized corestones) presented REE enrichment due to translocation. They are hosted mainly by clay minerals and, to some extent, by amorphous Fe oxyhydroxide. The evolution of spheroidal weathering results in a vertical patchy weathering profile.

Alteration of high alkaline and alkaline basaltic rocks: parent rocks in the Lava Durian orchard, Sisaket Province, NE Thailand

Lava Durian Sisaket is the first geographically identified (GI) fruit related to the volcano in Thailand and distributed in three districts of Sisaket Province, the southernmost edge of the Khorat Plateau. The parent rocks of orchards are important for the description of soil and rock relation with respect to mineralogical and geochemical characteristics. This work aims to study lithology, mineralogy, and geochemistry of basaltic rocks, parent rocks of in situ soil in these orchards, and delineate the existing basaltic soil models. The several orchards are covered by reddish-brown to brown in situ soils, weathered from mafic volcanic rocks: porphyritic olivine basalt, vesicular olivine basalt, and nephelinite. The microscopic image analysis, XRD, and MiniSEM-EDS are used to classify mineralogy, while XRF and analysis of large and rare elements in ICP-MS/ICP-OES were used to determine parental rocks geochemistry and alteration. The olivine basalts comprise forsterite microphenocrysts associated with bytownite, diopside, augite, pigeonite, and ilmenite groundmass, while nephelinite is composed of nepheline groundmass and bytownite-labradorite, diopside, augite, pigeonite, and ilmenite crystals. In addition, these basalts display high alteration rates, especially olivine highly altered to iddingsite. According to the geochemical data, Sisaket's basalts were identified as alkali basalt and nepheline basanite with high LILEs and LREEs (La, Nd, Pr, Gd, Eu). The kaolinite, smectite, and illite are altered from felsic minerals, while the chlorite and iddingsite are from mafic minerals. The mineralogical analyses classified secondary phyllosilicates related to low-moderate temperature hydrothermal fluid, very high cation exchange capacity (H+, K+, Ca2+, Mg2+), and tropical weathering. The alkaline and high alkaline basalts, presenting as parent rocks, are one of the parameters that produced good nitisal soil of Sisaket's agricultural areas.

Influence of particle size selection methods on asphalt mixtures produced with lateritic aggregates

The aggregates of asphalt mixtures provide resistance to most of the load applied to the pavement, so it is important to evaluate the physical and mechanical properties of the aggregates. In some regions of Brazil, the availability of traditional aggregates (granitic) is becoming scarce due to the rapid increase in infrastructure projects and the longer distance of deposit to the paving works. To address the above issues, we tried to find substitutes for granitic aggregates in asphalt mixtures. Laterite is a tropical or sub-tropical weathering product, abundant material in the North and Northeast of Brazil. The study aimed to evaluate the performance of asphalt mixtures produced with lateritic and granitic aggregates and verify the influence of National Department of Transport Infrastructure (DNIT), Bailey, and French particle size selection methods in the mixtures, through mechanical tests. The Dominant Aggregates Range (DAR) technique was used to evaluate the behavior of the mixtures in terms of permanent deformation. The asphalt mixtures were analyzed through dynamic modulus, flow number, fatigue test, resilience modulus, and Modified Lottman test. The analysis of the mixtures by the DAR method showed results that did not corroborate the results of the mechanical tests. However, all the analyzed mixtures showed good performance regarding permanent deformation, especially the mixtures with lateritic aggregates. The asphalt mixtures produced with lateritic aggregates present better mechanical performance, enabling their use mainly in countries with a tropical climate and low rainfall, such as the northeast region of Brazil. The French method showed equivalent mechanical performance and even superior to the DNIT method, commonly used in Brazil.

Soil Related Factors Controlling Erosion And Landslides In Malaysia

The high temperature and rainfall in Malaysia results in intensive tropical weathering and depending on the parent material, the resultant soil can have deep or shallow soil profiles. Thus, a variety of soils can form with different textures (clay content), structure and porosity. With the high rainfall, soils in steep terrain are subjected to surface erosion when exposed or landslides if the rainwater percolates into the soil profile. Key soil-related factors controlling soil erosion and landslides include local climate, parent material of soils and depth of the weathered profile. Slope and geomorphology, vegetation and land use as well as land management practices also influence erosion and landslides. Measures used to control soil erosion and stabilize slopes require improved understanding of soil weathering, erosion, landslide and their linkages in steep terrain.

Mechanical properties of dense mycelium-bound composites under accelerated tropical weathering conditions

Mycelium, as the root of fungi, is composed of filamentous strands of fine hyphae that bind discrete substrate particles into a block material. With advanced processing, dense mycelium-bound composites (DMCs) resembling commercial particleboards can be formed. However, their mechanical properties and performance under the working conditions of particleboards are unknown. Here, we show how weathering conditions affect the DMC stress and elastic modulus. DMC was made using Ganoderma lucidum mycelium grown on a substrate of sawdust and empty fruit bunch. The DMC was then subjected to weathering under tropical conditions over 35 days and tested under flexural, tensile, and compressive loading with reference to international standards. After exposure to specified weathering conditions, the maximum stress in flexure, tension, and compression decreased substantially. The addition of a protective coating improved the resistance of DMC to weathering conditions; however, the difference between coated and uncoated samples was only found to be statistically significant in tensile strength.

Holocene sedimentary evolution of a subaqueous delta off a typical tropical river, Hainan Island, South China

High-resolution seismic surveys were conducted off the eastern coast of Hainan Island to study the distribution and mass budget of Holocene subaqueous clinoform sediments. The Holocene subaqueous clinoform extends 45 km seaward across the shelf and more than 80 km northeastward along the shore. It covers an area of over 3,000 km2, which is almost equivalent to the expansion of large river systems. Overlying the transgressive surface, the deltaic sequence can be divided into a transgressive unit and a highstand unit separated by a downlap maximum flooding surface. The volume of sediments within the Holocene subaqueous clinoform is estimated to be 33.12×109 m3, equivalent to an annual accumulation of 3.61–3.31 Mt/yr, which is substantially higher than the global average. The high sediment yield presumably resulted from strong tropical weathering and active tectonics. The sediment flux during the transgression and sea-level highstand were 3.85–3.08 and 3.47 Mt/yr, respectively, suggesting no substantial changes in sedimentation. Compared to river systems originating from high mountain glaciers, the sedimentation variation of small tropical rivers throughout the Holocene is relatively minor. However, the sediment discharge of the Wanquan River has drastically decreased in recent decades because of increased human activity.

Tropical Weathering History Recorded in the Silicon Isotopes of Lateritic Weathering Profiles

AbstractUnder tropical climates, mineral assemblages composing lateritic weathering profiles offer precious records of past weathering conditions. Silicon (Si) isotope signatures in the clay fractions of a deep lateritic profile in central Amazonia, Brazil, in combination with previously determined kaolinite ages, suggest that the surrounding region underwent two major weathering episodes, distinct in their intensity. The first episode (ca. 35–20 Ma) of moderate intensity produced well‐crystallized kaolinites from the parent sediment with limited Si isotope fractionation. A more recent (8–6 Ma) and shorter phase caused the replacement, from top to bottom of the profile, of the first kaolinite generation by a new population characterized by higher crystallographic disorder and stronger Si isotope fractionation, suggesting weathering under conditions of rapid water percolation. These inferences are supported by results from an isotope‐enabled reactive transport model, and they are consistent with paleoclimatic and paleogeographic evidences recorded over the Amazon Basin.

Metabarcoding Reveals Changes in Benthic Eukaryote and Prokaryote Community Composition along a Tropical Marine Sediment Nickel Gradient.

The Southeast Asia and Melanesia region has extensive nickel (Ni)-rich lateritic regoliths formed from the tropical weathering of ultramafic rocks. As the global demand for Ni continues to rise, these lateritic regoliths are increasingly being exploited for their economic benefit. Mining of these regoliths contributes to the enrichment of coastal sediments in trace metals, especially Ni. The present study used high-throughput sequencing (metabarcoding) to determine changes in eukaryote (18s v7 recombinant DNA [rDNA] and diatom-specific subregion of the 18s v4 rDNA) and prokaryote (16s v4 rDNA) community compositions along a sediment Ni concentration gradient offshore from a large lateritized ultramafic regolith in New Caledonia (Vavouto Bay). Significant changes in the eukaryote, diatom, and prokaryote community compositions were found along the Ni concentration gradient. These changes correlated most with the dilute-acid extractable concentration of Ni in the sediments, which explained 26, 23, and 19% of the variation for eukaryote, diatom, and prokaryote community compositions, respectively. Univariate analyses showed that there was no consistent change in indices of biodiversity, evenness, or richness. Diatom richness and diversity did, however, decrease as sediment acid extractable-Ni concentrations increased. Threshold indicator taxa analysis was conducted separately for each of the 3 targeted genes to detect changes in taxa whose occurrences decreased or increased along the acid extractable-Ni concentration gradient. Based on these data, 46 mg acid extractable-Ni/kg was determined as a threshold value where sensitive species began to disappear. In the case of the estuarine sediments offshore from lateritized ultramafic regolith in New Caledonia, this is recommended as an interim threshold value until further lines of evidence can contribute to a region-specific Ni sediment quality guideline value. Environ Toxicol Chem 2021;40:1894-1907. © 2021 SETAC.

Gold dispersion in tropical weathering profiles at the Belikombone gold anomaly (Bétaré Oya gold district), east Cameroon

The distribution of gold in the weathering blanket at the Belikombone gold prospect in east Cameroon provides insights into gold mobility in the secondary environment and in tropical terrains worldwide. Both gridline-controlled sampling of topsoil (surface samples) and sampling of various layers in pits are used and the gold assay for each sample determined by NiS fire assay with ICP-AES finish. One hundred and thirty-two (132) surface samples and a total of 206 samples from 19 exploration pits were analyzed. The results from the topsoil samples show an anomaly with the highest Au concentration at 5.9 mgkg−1. The mineralization corridor follows a NE-SW trend. The horizons within the pits range from sap rock at the base, through saprolite, rubble layer rich in relict quartz material to a ferruginous loose layer at the top although some horizons are missing in some pits. All the layers contain gold and the highest concentration in the sap rock horizon is 3.4 mgkg−1 while the rubble layer has a gold high of 6.1 mgkg−1. The individual soil horizons show no systematic gold trends and given the presence of gold in all layers, the patterns point towards supergene dissolution and redistribution of gold. Gold enrichment within the upper horizons in the weathering blanket is attributed to sequestration by Fe oxides of chemically remobilized gold. However, the high gold content within the sap rock and saprolite layers suggests that migration of gold in the particulate form supersedes chemical gold redistribution. Particulate gold obtained by panning samples from the pits varies in shape from euhedral, elongated to irregular. Electron microprobe analysis on the grains record high contents of gold in the rim zones (90.0 to 99.8 wt%). The cores are relatively rich in Ag (12.6 to 14.2 wt%) while the rims are poor in Ag. The low Ag content in the rims is attributed to the preferential leaching of Ag. The soil pH value in this area varies between 3.6 and 7.3. Under such acidic to near neutral conditions, bisulfide and thiosulfate ions can dissolve and transport Au and Ag to be precipitated under surficial conditions creating authigenic Au haloes especially in the saprolite and sap rock layers. Such pH values together with oxidizing Eh conditions explain the solubility of gold in the area. These results are important for geochemical exploration of gold in tropical terrains, and confirm previous studies.

Reconnaissance Of Kenny Hill Formation Outcrops In The Rawang Area, Northern Selangor, Malaysia

New outcrops of Paleozoic meta-sediments northwest of Kuala Lumpur expose the deformational effects of the Late Paleozoic-Mesozoic collisions between various Gondwana-derived continental fragments as they amalgamated to form the core of SE Asia. Over a duration of 6 months, beginning in August 2020, we conducted field trips within northern Selangor to new laterally extensive outcrops for field observations, structural mapping and to measure and log the stratigraphic section. This paper focuses on Upper Paleozoic Kenny Hill Formation outcrops in northern Selangor. The most studied is the heavily weathered Jalan Rawang-Bestari Jaya (JRBJ) outcrop, which is characterised by a steeply dipping (southwest), upward-coarsening succession of sandstones and shales interpreted as a system of ephemeral fluvial channels possibly related to Gondwana glaciation. Concretions within bedding planes and fractures were possibly formed around organic material. Less than 4 km to the east, the Scientex development has excavated fresher outcrops of the same rocks dipping to the NE. Metamorphic lineation is not present in either outcrop location. In addition, a monocline is exposed at outcrop location number 3 nearby. Finally, at Bukit Botak, 14 km to the southwest, a system of westward verging thrust faults, back thrusts and normal faults can be viewed and an angular unconformity or decollement marks the contact between the Upper and Lower Paleozoic. These laterally extensive outcrops are rare and are quickly subject to intense tropical weathering, the encroachment of jungle vegetation and urban development. Historic mapping and prior stratigraphic, structural, and petrographic studies have been conducted in the area, but these relied on poor exposures. As suburban development escalates in the area, we hope that new outcrops, featuring multi-dimensional views of these formations, such as the four described in this paper, will complement the earlier work.

Oxygen isotopic compositions of end-members in a multicomponent mixture: Ediacaran weathering material from the East European Craton

The aim of the present study was to investigate the oxygen isotopic composition of the Ediacaran weathering material from the western margin of the East European Craton. This area presents a unique opportunity to investigate the Ediacaran strata with a minimum diagenetic overprint. Paleosol intervals, containing material formed during the most advanced weathering stages, rich in kaolinite and iron (hydr)oxides, and corresponding sedimentary rocks were investigated. Bulk material and separated clay fractions were subjected to reactions with hot dithionite-citrate-bicarbonate solution in order to remove free iron (hydr)oxides. The obtained material was characterized by X-ray diffraction, chemical analysis, thermogravimetric analysis, and the measurement of oxygen isotope composition. Comparison of the isotopic compositions of iron (hydr)oxides and phyllosilicates, extracted from the natural and dithionite-citrate-bicarbonate treated samples, bulk, and clay fractions, leads to the conclusion that these compounds are in isotopic disequilibrium in the investigated samples. Disequilibrium is caused by the presence of diagenetic illite, originating from the Caledonian and Variscan hydrothermal pulses. The average isotopic composition of kaolinite was extracted from the phyllosilicate data by extrapolation. The temperature estimate, based on the average isotopic composition of iron (hydr)oxide and kaolinite, depends strongly on the hematite-water fractionation factor used in the calculation but qualitatively agrees with the expected tropical weathering conditions. The complex approach needed to extract these data from multicomponent mineral mixtures results in large analytical error if precise error propagation analysis is applied.

Cenozoic to modern-day source to sink systems of Senegal: A record of provenance, transport, recycling and climate controls

This study presents an integrated mineralogical assessment for the provenance of sediments derived from modern-day rivers and Cenozoic deposits in Senegal and Gambia. Two distinct populations are identified from discrimination of the heavy mineral assemblages; the Senegal River sediment, sourced from the West African Craton and Mauritanides and Meso-Cenozoic sediment sourced from the onshore Senegal Basin, demonstrating prevalent recycling of Senegal Basin sediments by the Ferlo, Saloum, Gambia and Casamance Rivers throughout the Quaternary.The Senegal River records the occurrence of amphibole, epidote, garnet and pyroxene, which indicates denudation of Neo to Paleo-Proterozoic granites, low-medium grade meta-sediments and a skarn-type lithology. Meso-Cenozoic recycled sediments within the onshore Senegal Basin exhibit a heavy mineral component which has been modified through the chemical-weathering and diagenesis of less-stable amphibole, pyroxene and garnet. U/Pb dating of zircons from the Casamance and Gambia provinces indicates that, at least in part, the Mesozoic sediments of the onshore Senegal basin may have been ultimately derived from the Leo-Man Shield.Kaolin occurrence is associated with tropical weathering of laterites. The occurrence of terrigenous-smectite sourced from high altitude regions of the Mauritanides and West African Craton is interpreted to have formed under hyper-arid conditions prior to erosion and transportation, during the African humid periods of the Holocene.This integrated mineralogical study of modern-day and Cenozoic sediments has established prevalent recycling of Senegal Basin-sediments by the Ferlo, Saloum, Gambia and Casamance Rivers and continued erosion and recycling of hinterland-sediments via the modern-day Senegal River. This identification of two distinct provenance groups and the strong climatic signal provides the important framework for future studies assessing the source to sink systems during the Meso-Cenozoic.

A combined geophysical and lithological study on eruptive history and Quaternary lacustrine stratigraphy of a maar in Leizhou Peninsula, China

As the second common type of volcanic vent on Earth, maar-diatreme volcanoes and their post-eruptive lacustrine sediments are a main focus of volcanology, palaeolimnology, palaeoclimatology and palaeontology. A number of maar-type volcanoes have been found in Leizhou Peninsula, South China, but little is known about their eruption processes and detailed stratigraphy of the post-eruptive sediments. We present a combined geophysical and geological analysis to study the eruptive history and post-eruptive sediment stratigraphy of a large maar, the elliptical (1.8 × 3.0 km2) Jiudouyang (JDY) maar. The lacustrine stratigraphy revealed by drilling cores shows that the JDY maar lake has three major stages of evolution: (i) deep-lake sedimentary environment characterized by high autochthonous diatom productivity; (ii) shallow lake to swamp with very low water levels, characterized by a high total organic carbon (TOC) and abundant wood fragments; and, (iii) intermittent shallow lake and alluvial deposits composed of clay minerals and sand. The electrical resistivity tomography (ERT) values and lithological features are highly consistent, which clearly reveal the presence of ca. 50 m thick lacustrine sediments, directly underlain by a ca. 70 m thick basaltic lava rather than diatreme breccia in the crater. This infill sequence implies an alternation of eruption style from phreatomagmatic to Strombolian and/or lava flow, due to high magma flux and ascent rate of the Hainan Plume during the middle Pleistocene. The ERT data also reveal the initial phreatomagmatic crater floor at ca. 120 m depth. The initial crater had a large diameter/depth ratio (ca. 17), with an elongated shape (major axis to minor axis = 0.6), implying possible lateral vent migration during the eruption. A significant erosion under tropical weathering condition during the last few hundred thousand years, accounted for the large size of the maar crater. The study provides insights into the eruptive history and post-eruptive evolution of a large maar, as well as the spatial distribution of the lacustrine sediments.

Advances in geochemical footprint, iron speciation, and Pb isotopes in the tropical regolith of north-northwestern Amazonia, Brazil

A dataset with information on samples of gabbro, charnockite, gneiss, granite, basalt, and sandstone-derived iron lateritic duricrusts, concretions, nodules, and soils was analyzed to address the multi-element chemical composition, background values, scavenger trace elements in Fe oxyhydroxides, parent rock inheritance, and weathering effect on Pb isotopes. Tropical weathering causes high mass loss of SiO2, Ba, Rb, and Sr assigned to the mineral rock framework (quartz, feldspar, and mica). The aqua regia leaching indicates that part of these elements was probably accumulated in authigenic Al-phosphates minerals affecting their mobility in the lateritic terrains. There is a generally Sc and V high accumulation in the lateritic duricrusts with Fe oxyhydroxide mineral framework (goethite, hematite, and amorphous). Th, U, and Pb are also accumulated on the gabbro and granite-derived lateritic duricrusts, Cr on the basalt-derived ones, REE on the gabbro-derived ones, as well as Th and U low to high loss on gneiss-derived ones, thus allowing to track inheritance of parent rocks. The more refined geochemical information obtained from the Pb isotopes related to the Fe oxyhydroxides of the lateritic duricrusts, concretions and soils indicated changes according to the parent rocks since the gabbro-derived lateritic duricrust samples are more radiogenic while the gneiss and granite-derived ones are less radiogenic. The basalt and sandstone-derived lateritic duricrust samples maintain the radiogenic signature of the respective parent rocks. Although homogenization was expected, the mineral, the main and trace elements, and Pb isotope compositions produced by leaching and accumulation in the tropical regolith highlight the parent rock signature and a complex weathering process.

Ge and Si Isotope Behavior During Intense Tropical Weathering and Ecosystem Cycling

AbstractChemical weathering of volcanic rocks in warm and humid climates contributes disproportionately to global solute fluxes. Geochemical signatures of solutes and solids formed during this process can help quantify and reconstruct weathering intensity in the past. Here, we measured silicon (Si) and germanium (Ge) isotope ratios of the soils, clays, and fluids from a tropical lowland rainforest in Costa Rica. The bulk topsoil is intensely weathered and isotopically light (mean ± 1σ: δ30Si = −2.1 ± 0.3‰, δ74Ge = −0.13 ± 0.12‰) compared to the parent rock (δ30Si = −0.11 ± 0.05‰, δ74Ge = 0.59 ± 0.07‰). Neoforming clays have even lower values (δ30Si = −2.5 ± 0.2‰, δ74Ge = −0.16 ± 0.09‰), demonstrating a whole‐system isotopic shift in extremely weathered systems. The lowland streams represent mixing of dilute local fluids (δ30Si = 0.2 − 0.6‰, δ74Ge = 2.2 − 2.6‰) with solute‐rich interbasin groundwater (δ30Si = 1.0 ± 0.2‰, δ74Ge = 4.0‰). Using a Ge‐Si isotope mass balance model, we calculate that 91 ± 9% of Ge released via weathering of lowland soils is sequestered by neoforming clays, 9 ± 9% by vegetation, and only 0.2 ± 0.2% remains dissolved. Vegetation plays an important role in the Si cycle, directly sequestering 39 ± 14% of released Si and enhancing clay neoformation in surface soils via the addition of amorphous phytolith silica. Globally, volcanic soil δ74Ge closely tracks the depletion of Ge by chemical weathering (τGe), whereas δ30Si and Ge/Si both reflect the loss of Si (τSi). Because of the different chemical mobilities of Ge and Si, a δ74Ge‐δ30Si multiproxy system is sensitive to a wider range of weathering intensities than each isotopic system in isolation.

Gossan mineralogy, textures, and gold enrichment over the Au (As, Bi, Ag) deposit in the Buracão Area (Brasília Fold Belt, Brazil): Implications for gold prospecting in weathering profiles

The orogenic pyrite–rich Au (As, Bi, Ag) mineralization (up to 31 g/t) of the Buracão area is one of several orogenic deposits in the Brasilia Fold Belt (BFB; Central Brazil), exposed to tropical weathering that shows extensive oxidized profiles. The distribution and thickness of these gossan profiles lead to variable gold enrichments and uncertainties to gold prospecting in this region. In order to investigate physicochemical processes related to the evolution of the gossan cover and the supergene gold enrichment, we present mineralogical, textural and geochemical data from each zone of twenty gossan profiles in the Buracão area. These results show that the mineralogy and textures along the gossan profile reflect oxidation, hydrolysis, dissolution and precipitation processes controlled by different Eh–pH conditions, which are controlled by supergene conditions and hypogene ore composition. The geometry, distribution, and thickness of gossan profiles, as well as the style of gold occurrence, reflects textures of the hypogene orebodies, while the weathering has an important role in the gold chemical refining (i.e., increasing ca. 25% in gold fineness) and the distribution of gold grades along the profile.These points allowed us to identify that the leached spongy hematite–rich zone in the upper indigenous profile contains the higher fineness gold grades (i.e., the “bonanza level”), and Bi–minerals such as waylandite and bismutite that may be important pathfinders for high gold grades in these gossan profiles. Our results demonstrate that ore prospection in gossans over Au–As–Bi–Ag deposits should be done focusing on leached zones, different to that traditionally conducted in gossans related to base metal sulfide deposits that have focused on precipitation zones. The similarities between the hypogene mineralization of the Buracão area and many deposits in the BFB and worldwide encourage the application of this approach elsewhere, which improve gold prospecting in weathering profiles over orogenic deposits.