Troll Station Research Articles

Brominated Flame Retardants in Antarctic Air in the Vicinity of Two All-Year Research Stations

Continuous atmospheric sampling was conducted between 2010–2015 at Casey station in Wilkes Land, Antarctica, and throughout 2013 at Troll Station in Dronning Maud Land, Antarctica. Sample extracts were analyzed for polybrominated diphenyl ethers (PBDEs), and the naturally converted brominated compound, 2,4,6-Tribromoanisole, to explore regional profiles. This represents the first report of seasonal resolution of PBDEs in the Antarctic atmosphere, and we describe conspicuous differences in the ambient atmospheric concentrations of brominated compounds observed between the two stations. Notably, levels of BDE-47 detected at Troll station were higher than those previously detected in the Antarctic or Southern Ocean region, with a maximum concentration of 7800 fg/m3. Elevated levels of penta-formulation PBDE congeners at Troll coincided with local building activities and subsided in the months following completion of activities. The latter provides important information for managers of National Antarctic Programs for preventing the release of persistent, bioaccumulative, and toxic substances in Antarctica.

Atmospheric ozone above Troll station, Antarctica observed by a ground based microwave radiometer

Abstract. This paper describes the stratospheric and mesospheric ozone profiles retrieved from spectral measurements of the 249.96 GHz O3 line, using the British Antarctic Survey's ground-based Microwave Radiometer at Troll (BAS-MRT), Antarctica (72°01' S, 02°32' E, 62° Mlat). The instrument operated at Troll from February 2008 through January 2010, and hourly averaged spectra were used to retrieve approximately 20 ozone profiles per day. The ozone profiles cover the pressure range from 3 hPa to 0.02 hPa (approximately 38 to 72 km) which includes the topside of the stratospheric ozone layer and the peak of the tertiary maximum. Comparing the retrieved ozone volume mixing ratio (vmr) values to Aura/MLS and SD-WACCM shows no significant bias to within the instrumental uncertainties. The long-term variations (>20 days) between MLS and SD-WACCM agree well with BAS-MRT at all altitudes with significant correlation coefficients of at least 0.9 (0.7 with SD-WACCM) in the upper stratosphere and middle mesosphere. A weaker correlation is found for the long-term variations in summer when most of the vmr values are below the random noise level of Aura/MLS. The correlation of short-term variations (<20 days) between MLS and BAS-MRT agree well at all altitudes with significant correlation coefficients of at least 0.7 in the upper stratosphere and middle mesosphere. The ozone profiles retrieved at Troll, Antarctica extend the sparse data coverage of middle atmospheric ozone above Antarctica, where, due to the dynamic nature of the ozone concentrations, systematic observations with a high temporal resolution are desirable. The O3 profiles presented here are stored at the UK's Polar Data Centre (http://doi.org/nc3) and are available for public scientific use.

Observations of nitric oxide in the Antarctic middle atmosphere during recurrent geomagnetic storms

AbstractWe report ground‐based measurements of the polar middle atmosphere made using a 230–250 GHz passive microwave radiometer deployed at Troll station (72°01′S 02°32′E, L shell of L = 4.8), Antarctica. Our observations show enhanced mesospheric nitric oxide (NO) volume mixing ratio (VMR) during a series of small recurrent geomagnetic storms in the 2008 austral winter, reaching 1.2 ppmv on day 200 (18 July). The Lomb normalized periodogram of the NO VMR time series averaged over 65‐80 km for days 130 to 220 of 2008 (9 May to 7 August) shows a peak exceeding the 95% confidence limit at 25.8 days, close to the synodic rotation period for low‐latitude solar coronal holes. The highest correlations between the radiometer NO VMR data and trapped and quasi‐trapped electron count rates for L = 3.5‐5.5 from the Polar Orbiting Environment Satellites 90° telescope are for the >30 keV (90e1) channel (rmax = 0.56, lag time of 5.1 days) and >100 keV (90e2) channel (rmax = 0.57, lag time of 4.4 days). Maximum correlation between NO VMR and the >700 keV (90P6) channel data is lower but lag times are close to zero. Superposed epoch analyses for the eight most significant geomagnetic storm periods and three Carrington rotations (2070‐2072) within the 90 day observation period indicate that significant NO abundance observed at 65‐80 km in the Antarctic mesosphere may be produced directly by >200 keV electron precipitation or originate from a source at higher altitudes, e.g., production by >30 keV electrons followed by downward transport.

Planetary wave oscillations observed in ozone and PMSE data from Antarctica

The effect of temperature variations caused by planetary waves on the occurrence of Polar Mesospheric Summer Echoes (PMSE) has been a subject of recent research. These same temperature fluctuations have also been shown to modulate the ozone volume mixing ratio above 30km. In this study, ground-based radiometer measurements of ozone mixing ratio profiles at Troll station (72°S, 2°E), Antarctica are compared with PMSE extracted from the near-range measurements of the Sanae (72°S, 2°W) Super Dual Auroral Radar (SuperDARN) over the radiometer field of view. We show here that the resulting quasi-periodic fluctuations in PMSE correlate with the variations seen in the ozone. The ozone mixing-ratio variations may then be used to trace the phase variation of planetary waves with height to demonstrate that they extend from the stratosphere up to the mesopause. The results indicate that the modulation of PMSE occurrence frequency during the summer of 2009/10 is the result of two planetary waves with similar zonal structure and period, but with different vertical phase structures.

Quasi-16-day period oscillations observed in middle atmospheric ozone and temperature in Antarctica

Abstract. Nightly averaged mesospheric temperature derived from the hydroxyl nightglow at Rothera station (67°34' S, 68°08' W) and nightly midnight measurements of ozone mixing ratio obtained from Troll station (72°01' S, 2°32' E) in Antarctica have been used to investigate the presence and vertical profile of the quasi-16-day planetary wave in the stratosphere and mesosphere during the Antarctic winter of 2009. The variations caused by planetary waves on the ozone mixing ratio and temperature are discussed, and spectral and cross-correlation analyses are performed to extract the wave amplitudes and to examine the vertical structure of the wave from 34 to 80 km. The results show that while planetary-wave signatures with periods 3–12 days are strong below the stratopause, the oscillations associated with the 16-day wave are the strongest and present in both the mesosphere and stratosphere. The period of the wave is found to increase below 42 km due to the Doppler shifting by the strong eastward zonal wind. The 16-day oscillation in the temperature is found to be correlated and phase coherent with the corresponding oscillation observed in O3 volume mixing ratio at all levels, and the wave is found to have vertical phase fronts consistent with a normal mode structure.

Long-term monitoring of persistent organic pollutants (POPs) at the Norwegian Troll station in Dronning Maud Land, Antarctica

Abstract. A first long-term monitoring of selected persistent organic pollutants (POPs) in Antarctic air has been conducted at the Norwegian research station Troll (Dronning Maud Land). As target contaminants 32 PCB congeners, α- and γ-hexachlorocyclohexane (HCH), trans- and cis-chlordane, trans- and cis-nonachlor, p,p'- and o,p-DDT, DDD, DDE as well as hexachlorobenzene (HCB) were selected. The monitoring program with weekly samples taken during the period 2007–2010 was coordinated with the parallel program at the Norwegian Arctic monitoring site (Zeppelin mountain, Ny-Ålesund, Svalbard) in terms of priority compounds, sampling schedule as well as analytical methods. The POP concentration levels found in Antarctica were considerably lower than Arctic atmospheric background concentrations. Similar to observations for Arctic samples, HCB is the predominant POP compound, with levels of around 22 pg m−3 throughout the entire monitoring period. In general, the following concentration distribution was found for the Troll samples analyzed: HCB > Sum HCH > Sum PCB > Sum DDT > Sum chlordanes. Atmospheric long-range transport was identified as a major contamination source for POPs in Antarctic environments. Several long-range transport events with elevated levels of pesticides and/or compounds with industrial sources were identified based on retroplume calculations with a Lagrangian particle dispersion model (FLEXPART).

Mesospheric CO above Troll station, Antarctica observed by a ground based microwave radiometer

Abstract. This paper presents mesospheric carbon monoxide (CO) data acquired by the ground-based microwave radiometer of the British Antarctic Survey (BAS radiometer) stationed at Troll station in Antarctica (72° S, 2.5° E, 1270 m a.s.l.). The dataset covers the period from February 2008 to January 2010, however, due to very low CO concentrations below approximately 80 km altitude in summer, profiles are only presented during the Antarctic winter. CO is measured for approximately 2 h each day and profiles are retrieved approximately every half hour. The retrieved profiles, covering the pressure range from 1 to 0.01 hPa (approximately 48 to 80 km), are compared to measurements from Microwave Limb Sounder on the Aura satellite (Aura/MLS) and Whole Atmosphere Community Climate Model with Specified Dynamics (SD-WACCM). This intercomparison reveals a low bias of 0.5 to 1 ppmv at 0.1 hPa (approximately 64 km) and 2.5 to 3.5 ppmv at 0.01 hPa (approximately 80 km) of the BAS microwave radiometer compared to both reference datasets. One explanation for this low bias could be the known high bias of MLS which is on the same order of magnitude. The ground based radiometer shows high and significant correlation (coefficients higher than 0.9/0.7 compared to MLS/SD-WACCM) at all altitudes compared with both reference datasets. The dataset can be accessed under http://dx.doi.org/10/mhq.

The effect of energetic electron precipitation on middle mesospheric night‐time ozone during and after a moderate geomagnetic storm

Using a ground‐based microwave radiometer at Troll Station, Antarctica (72°S, 2.5°E,L = 4.76), we have observed a decrease of 20–70% in the mesospheric ozone, coincident with increased nitric oxide, between 60 km and 75 km altitude associated with energetic electron precipitation (E > 30 keV) during a moderate geomagnetic storm (minimum Dst of −79 nT) in late July 2009. NOAA satellite data were used to identify the precipitating particles and to characterize their energy, spatial distribution and temporal variation over Antarctica during this isolated storm. Both the ozone decrease and nitric oxide increase initiate with the onset of the storm, and persist for several days after the precipitation ends, descending in the downward flow of the polar vortex. These combined data present a unique case study of the temporal and spatial morphology of chemical changes induced by electron precipitation during moderate geomagnetic storms, indicating that these commonplace events can cause significant effects on the middle mesospheric ozone distribution.

Direct observations of nitric oxide produced by energetic electron precipitation into the Antarctic middle atmosphere

[1] We report the first ground-based passive microwave observations made from Troll station, Antarctica, which show enhanced mesospheric nitric oxide (NO) volume mixing ratio reaching levels of 1.2 ppmv, or 2–3 orders of magnitude above background, at 70–80 km during small, relatively isolated geomagnetic storms in 2008. The mesospheric NO peaked 2 days after enhanced NO at higher altitudes (110–150 km) measured by the SABER satellite, and 2 days after peaks in the >30 keV and >300 keV electron flux measured by POES, although the 300 keV electron flux remained high. High time resolution data shows that mesospheric NO was enhanced at night and decayed during the day and built up to high levels over a period of 3–4 days. The altitude profile of mesospheric NO suggests direct production by ∼300 keV electron precipitation. Simulations using the Sodankyla Ion and Neutral Chemistry model show that the delay between thermospheric and mesospheric NO enhancements was primarily a result of the weaker production rate at lower altitudes by ∼300 keV electrons competing against strong day-time losses.