In order to obtain data on tritium removal from the atmosphere of a room, which is needed for designing a reliable effective atmosphere detritiation system in a fusion reactor and for detailed analysis on its safety, intentional tritium release experiments have been carried out in a controlled space called Caisson under various atmosphere conditions at the Tritium Process Laboratory (TPL) in Japan Atomic Energy Research Institute (JAERI). In case there is no tritiated water vapor in the released tritium gas, tritium was ideally removed by constant ventilation in spite of atmospheric conditions and residence time. On the other hand, when tritiated water vapor existed in the released tritium, residual contamination on the wall of the Caisson was detected and it was found that it depended on the initial humidity in the Caisson. This tritium removal behavior was successfully analyzed by considering the adsorption and desorption reaction rates of tritiated water on the wall by the constant ventilation.