Trinuclear Platinum Complex Research Articles

Scope and mechanism of oxidative addition of carbon-sulfur double bonds to trinuclear platinum and palladium complexes

Scope and mechanism of oxidative addition of carbon-sulfur double bonds to trinuclear platinum and palladium complexes

Mononuclear and trinuclear platinum(II) complexes of bis(diphenylphosphinomethyl)phenylphosphine

Mononuclear and trinuclear platinum(II) complexes of bis(diphenylphosphinomethyl)phenylphosphine

ChemInform Abstract: PHOSPHORUS‐PHOSPHORUS BOND CLEAVAGE IN THE CAGE MOLECULE P4S3: SYNTHESIS AND CRYSTAL STRUCTURE OF THE TRINUCLEAR PLATINUM COMPLEX TRIS(2,6,7‐TRITHIA‐1,3,4,5‐TETRAPHOSPHABICYCLO(2.2.1)HEPTANE‐3,5‐DIYL‐P5,μ‐P# 3)TRIS(TRIPHENYLPHOSPHINEPLATINUM)‐BENZENE(1/1)

Chemischer InformationsdienstVolume 16, Issue 23 Organoelement Compounds ChemInform Abstract: PHOSPHORUS-PHOSPHORUS BOND CLEAVAGE IN THE CAGE MOLECULE P4S3: SYNTHESIS AND CRYSTAL STRUCTURE OF THE TRINUCLEAR PLATINUM COMPLEX TRIS(2,6,7-TRITHIA-1,3,4,5-TETRAPHOSPHABICYCLO(2.2.1)HEPTANE-3,5-DIYL-P5,μ-P# 3)TRIS(TRIPHENYLPHOSPHINEPLATINUM)-BENZENE(1/1) M. DI VAIRA, M. DI VAIRASearch for more papers by this authorM. PERUZZINI, M. PERUZZINISearch for more papers by this authorP. STOPPIONI, P. STOPPIONISearch for more papers by this author M. DI VAIRA, M. DI VAIRASearch for more papers by this authorM. PERUZZINI, M. PERUZZINISearch for more papers by this authorP. STOPPIONI, P. STOPPIONISearch for more papers by this author First published: June 11, 1985 https://doi.org/10.1002/chin.198523305Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat No abstract is available for this article. Volume16, Issue23June 11, 1985 RelatedInformation

Phosphorus–phosphorus bond cleavage in the cage molecule P4S3: synthesis and crystal structure of the trinuclear platinum complex [{Pt(µ-P4S3)(PPh3)}3]·C6H6

The reaction of [Pt(C2H4)(PPh3)2] with P4S3 yielded the trinuclear platinum complex [{Pt(µ-P4S3)(PPh3)}3]·C6H6 whose structure has been determined by X-ray diffraction. Crystals are triclinic, space group P, with Z= 2 in a unit cell of dimensions a= 21.414(12), b= 15.450(9), c= 15.670(9)A, α= 121.71(9), β= 94.22(8), and γ= 107.50(9)°. The final R factor was 0.069 for 3 990 independent observed reflections. Insertion of a metal–ligand moiety into a P–P bond of the cage molecule occurs and a trinuclear structure is formed by sharing one P atom from such a bond between two Pt atoms. The Pt ⋯ Pt separations range from 4.05 to 4.22 A and the mean P ⋯ P distance after cleavage is 3.03(3)A.