Triboelectric Nanogenerator Research Articles

Application of Biomass-Based Triboelectrification for Particulate Matter Removal

Electrostatic fields are crucial for achieving the highly efficient filtration of airborne pollutants. However, the dissipation of static charges over time, especially under humid conditions, limits their practical application. In this study, we present a self-charging air filter (SAF) powered by a triboelectric nanogenerator (TENG). This SAF is integrated into a commercial mask, termed SAFM, which can effectively capture and degrade airborne pollutants without requiring an external power source. By leveraging the triboelectric effect during breathing, the TENG within the SAFM continuously replenishes static charges, maintaining the triboelectric field. The system employs a cellulose aerogel/Ti3C2Tx composite as the electron donor and an esterified cellulose-based electrospun nanofiber as the electron acceptor. Remarkably, the triboelectric field significantly enhances filtration performance, with the SAF achieving up to 95.7% filtration efficiency for particulate matter as small as 0.3 μm. This work underscores the potential of TENG-powered triboelectric fields in the development of multifunctional, human-machine interactive facemasks.

Manufacturing strategies for highly sensitive and self-powered piezoelectric and triboelectric tactile sensors

Abstract Piezoelectric and triboelectric effects are of growing interest for facilitating high-sensitivity and self-powered tactile sensor applications. The working principles of piezoelectric and triboelectric nanogenerators provide strategies for enhancing output voltage signals to achieve high sensitivity. Increasing the piezoelectric constant and surface triboelectric charge density are key factors in this enhancement. Methods such as annealing processes, doping techniques, grain orientation controls, crystallinity controls, and composite structures can effectively enhance the piezoelectric constant. For increasing triboelectric output, surface plasma treatment, charge injection, microstructuring, control of dielectric constant, and structural modification are effective methods. The fabrication methods present significant opportunities in tactile sensor applications. This review article summarizes the overall piezoelectric and triboelectric fabrication processes from materials to device aspects. It highlights applications in pressure, touch, bending, texture, distance, and material recognition sensors. The conclusion section addresses challenges and research opportunities, such as limited flexibility, stretchability, decoupling from multi-stimuli, multifunctional sensors, and data processing.

Robust conductive hydrogel advances self-powered intelligent sports monitoring and fair judging

Currently, combining multimodal perceptual ability with mechanical robustness poses a significant challenge for developing hydrogel-based flexible electronics. Herein, a robust conductive hydrogel was successfully synthesized by introducing cellulose nanocrystals (CNC) as nanofillers and lithium chloride (LiCl) as the conductive component into the copolymer network through a one-pot crosslinking procedure in a water-dimethyl sulfoxide binary solvent. Besides excellent stretchable, self-adhesive, anti-freezing, self-healing, and anti-swelling properties, tunable and reversible optical property was realized due to the polarity-induced microphase separation of the hydrophilic and hydrophobic group in the zwitterionic sulfobetaine chains, enabling cyclic information encryption and decryption. An all-weather wearable sensor array was thus developed for multi-modal sensing of various environmental stimuli, including mechanical, and thermal variations. Specifically, the intensity and spatial distribution of strain can be detected almost in real time within a broad strain range, thus realizing speech recognation, text-to-speech and human electrocardiogram signal acquisition and underwater non-contact sensing functions. Notably, the CPAMD-based triboelectric nanogenerator demonstrates impressive temperature tolerance (−40 °C and 60 °C), and remarkable material identification capability. A non-contact proximity sensing sensor and a foul detection system were thus developed by coupling the piezoresistive, triboelectric and capacitive sensing metrics to serve as an electronic referee for identifying foul in curling. This work provides a valuable reference toward combining excellent mechanical robustness with balanced electrical performance for tactile perception and intelligent sports monitoring.

Constructing High-Performance and Versatile Liquid-Solid Triboelectric Nanogenerator with Inflatable Columnar Units

Abstract The use of water resources for energy generation has become increasingly prevalent, encompassing the conversion of kinetic energy from streams, tides, and waves into renewable electrical power. Water energy sources offer numerous benefits, including widespread availability, stability, and the absence of carbon dioxide and other greenhouse gas emissions, making them a clean and environmentally friendly form of energy. In this work, we develop a droplet-based liquid-solid triboelectric nanogenerator (LS-TENG) using sophisticatedly designed inflatable columnar structures with inner and outer dual-electrode. This device can be utilized to harvest both the internal droplet-rolling mechanical energy and the external droplet-falling mechanical energy, capable of assembling into various structures for versatile applications. The design incorporates a combined structure of both internal and external TENG to optimize output performance via multiple energy harvesting strategies. The internal structure features a dual-electrode columnar-shaped LS-TENG, designed to harvest fluid kinetic energy from water droplet flowing. By leveraging the back-and-forth motion of a small amount of water within the air column, mechanical energy can be collected, achieving a maximum mass power density of 9.02 W/Kg and an energy conversion efficiency of 10.358%. The external component is a droplet-based LS-TENG, which utilizes a double-layer capacitor switch effect elucidated with an equivalent circuit model. Remarkably, without the need for pre-charging, a single droplet can generate over 140 V of high voltage, achieving a maximum power density of 7.35 W·m² and an energy conversion efficiency of 22.058%. The combined LS-TENG with sophisticated inflatable columnar structure can simultaneously collect multiple types of energy in high efficacy, exhibiting great significance in potential applications such as TENG aeration rings, inflatable lifejacket, wind energy harvesting, gas-column TENG tents, and green houses.

Biomedical device powered by triboelectric nanogenerator

Biomedical devices play vital roles in health monitoring. Operability of these devices is hindered by their limited battery life. In vivo monitoring, diagnosis, and treatment have become challenging. The proposed Triboelectric Nanogenerator helps in overcoming the shackles of battery life. This article describes the process involved in the development of a healthcare device powered by triboelectric effect. In this work a contact-separation mode based triboelectric nanogenerator (TENG) has been used to power the device. TENG uses triboelectric phenomenon to transform mechanical energy into electrical energy. A contact-separation mode TENG operates through the interaction of two triboelectric materials. These materials act as an anode and a cathode, respectively, and develop opposite charges when brought into contact. Upon separation, the charged surfaces retain their individual charges, creating a potential difference between the materials. This difference generates an electrostatic field that drives the flow of electrons from one electrode to the other. As the electrons return, the field collapses, and the materials come back into contact, repeating the cycle. The device has been used to power a heart rate monitoring system. Experimental results demonstrate the output performance and long-term durability of the TENG device. Furthermore, future research, challenges and opportunities have been elaborated.

Highly stretchable carbon-based triboelectric nanogenerator textiles woven using coaxial fibres via direct ink writing

In recent years, triboelectric nanogenerators have seen great progress in the Internet of Things, wearable electronics, virtual reality and artificial intelligence technologies. However, current triboelectric nanogenerator devices generally face challenges of complex preparation processes and structures, hindering their application in large-area wearable textiles. In this study, we develop highly stretchable triboelectric fibres using direct ink writing as building blocks for further woven textiles. This consists of a conductive core and insulating sheath, namely composites of multi-wall carbon nanotube and fluorinated ethylene propylene particles, both doped in silicone rubber. The fibre enjoys outstanding electrical performance, as well as excellent mechanical stretchability. Particularly, a single-centimetre-long fibre, upon slight patting, can surprisingly produce an open-circuit voltage of 8 V, a short-circuit current of 110 nA and 2.5 nC short-circuit transferred charges, or equivalent lighting of four to five commercial light-emitting diodes alone, greatly outperforming current wearable devices. These fibres also can endure an extraordinary strain of up to ∼874 %. The fibres are then woven into wearable gloves and socks using traditional weaving techniques, which can realise motion pattern identification and recognition with classification accuracy as high as ∼96 % using convolutional neural networks. This creates application prospects in wearable electronics, providing a scalable and affordable method for weaving daily wearable textiles and favouring large-area, wearable, self-powered sensors and artificial intelligence technologies.

Real-time in-situ coatings corrosion monitoring using machine learning-enhanced triboelectric nanogenerator

Current methods for monitoring coating corrosion are limited by their inability to provide real-time data and dependence on external power sources. This study presents a novel in-situ corrosion monitoring system using a solid-liquid triboelectric nanogenerator (TENG) that converts mechanical energy into electrical signals for self-powered sensing. TENG signals and electrochemical impedance spectra were measured on a dopamine-modified lignin-polydimethylsiloxane coating on steel in 1 M NaCl solution under no corrosion, indentation, pitting, and broken conditions, respectively. We extract time-frequency features from the TENG signals to predict the coating’s corrosion condition by applying a customised convolutional neural network (CNN). By extracting time-frequency features from the TENG signals and applying a custom CNN, a prediction accuracy of 99 % for corrosion classification was achieved. Furthermore, the CNN regression model predicted coating impedance values with a high coefficient of determination (R² = 0.98), demonstrating its effectiveness in tracking corrosion progression. The developed TENG also facilitates defect localisation via a matrix electrode beneath the coating. Our approach introduces a promising real-time technology for in-situ corrosion monitoring.

Exploring Wettability: A Key to Optimizing Liquid-Solid Triboelectric Nanogenerators.

Nowadays, the liquid-solid triboelectric nanogenerator (L-S TENG) has gained much attention among researchers because of its ability to be a part of self-powering technology by harvesting ultra-low-frequency vibration in the environment. The L-S TENG works with the principle of contact electrification (CE) and electrostatic induction, in which CE takes place between the solid and liquid. The exact mechanism behind the CE at the L-S interface is still a debatable topic because many physical parameters of both solid and liquid triboelectric layers contribute to this process. In the L-S TENG device, water or solvents are commonly used as liquid triboelectric layers, for which their wettability over the solid triboelectric layer plays a significant role. Hence, this review is extensively focused on the influence of the wettability of solid surfaces on the CE and the corresponding impact on the output performance of L-S TENGs. The present review starts with introducing the L-S TENG, a mechanism that contributes to CE at the L-S interface, the significance of hydrophobic materials/surfaces in TENG devices, and their fabrication methods. Further, the impact of the contact angle over the electron/ion transfer over various surfaces has been extensively analyzed. Finally, the challenges and future prospects of the fabrication and utilization of superhydrophobic surfaces in the context of L-S TENGs have been included. This review serves as a foundation for future research aimed at optimizing the L-S TENG performance and inspiring new approaches in material design and multifunctional energy-harvesting systems.

Copper selenide as a facile nanomaterial for triboelectric nanogenerator: Self-powered Braille code keyboard

The development of triboelectric nanogenerators (TENGs) for sustainable energy harvesting has garnered significant interest, especially in integrating advanced materials to enhance device performance and exploring applications. Herein, the present study investigates the use of copper selenide (Cu2Se) as a robust material for TENGs fabrication. Cu2Se nanorods are synthesized using a facile hydrothermal method and subsequently embedded in a polyvinyl alcohol (PVA) matrix to form a nanocomposite, which is then utilized as tribopositive film. The procured Cu2Se and nanocomposites with varying filler quantities (0.1, 0.2, 0.4, and 0.8 wt%) are analyzed using powder X-ray diffraction, scanning electron microscopy, dielectric measurements, Fourier transform infrared spectroscopy, and ultraviolet–visible spectroscopy to evaluate their structural, morphological, dielectric, and optical properties, and their impact on TENG performance. Interestingly, the device with 0.2 wt% Cu2Se generated peak-to-peak voltage and current of 394.35 V and 83.45 µA respectively, which is about 2.5- and 41-times higher output compared to pristine PVA-TENG. Integrating Cu2Se as filler enhances charge generation, transfer, and retention, due to increased surface roughness, and ability to facilitate better charge separation within the polymer matrix leading to more efficient energy conversion in TENGs. In practical demonstration, the optimized PVA@ Cu2Se-TENG is employed as a self-powered Braille keyboard to generate electrical signals from mechanical interactions, offering a promising solution for energy-efficient, user-friendly Braille technology. Thus, the current study highlights the synergistic effects of integrating Cu2Se with polymer, resulting in enhanced triboelectric performance for innovative energy harvesting applications and self-powered sensory devices.

Hybrid Wind‐Solar Self‐Powered Detector System Using a Triboelectric‐Photovoltaic Generator for Smart Agriculture

The growth of crops is affected by factors such as temperature, humidity, and salinity, so it is critical to monitor these indicators through detectors in smart agriculture. Collecting renewable energy in the farmland environment to power the detector will provide a feasible approach. Therefore, a triboelectric‐photovoltaic hybrid generator (WS‐TPHG) is proposed to collect solar and wind energy efficiently. The generator structure includes a photovoltaic panel (PV) and a wind‐driven triboelectric nanogenerator (W‐TENG). The switching function of the power supply can be realized through the power management circuit. In the case of sufficient light, the detector is powered by PV steadily, and in the case of insufficient light, the detector is powered by W‐TENG via the switching function. The PV can supply a stable voltage of 8.1 V, and the open‐circuit voltage (VOC) of W‐TENG can reach 478.6 V at 180 rpm. The results verify that the detection of temperature, humidity, and salinity can be successfully achieved through the detector which is powered by WS‐TPHG. In this article, the potential application of WS‐TPHG is demonstrated in farmland to provide a solution for the sustainable development of agriculture.

Evolution of Tribotronics: From Fundamental Concepts to Potential Uses.

The intelligent sensing network is one of the key components in the construction of the Internet of Things, and the power supply technology of sensor communication nodes needs to be solved urgently. As a new field combining tribo-potential with semiconductor devices, tribotronics, based on the contact electrification (CE) effect, realizes direct interaction between the external environment and semiconductor devices by combining triboelectric nanogenerator (TENG) and field-effect transistor (FET), further expanding the application prospects of micro/nano energy. In this paper, the research progress of tribotronics is systematically reviewed. Firstly, the mechanism of the CE effect and the working principles of TENG are introduced. Secondly, the regulation theory of tribo-potential on carrier transportation in semiconductor devices and the research status of tribotronic transistors are summarized. Subsequently, the applications of tribotronics in logic circuits and memory devices, smart sensors, and artificial synapses in recent years are demonstrated. Finally, the challenges and development prospects of tribotronics in the future are projected.

High-performance biodegradable triboelectric nanogenerators using CoFe2O4 filled poly (butylene adipate-co-terephthalate)

The hunt for sustainable and efficient energy harvesting and storage devices has driven significant interest in triboelectric nanogenerators (TENGs) as potential alternatives to traditional batteries for powering electronic devices. However, the development of biodegradable TENGs remains a formidable challenge. This study presents the preparation of a tribopositive material entirely composed of biodegradable poly(butylene adipate-co-terephthalate) (PBAT) polymer enhanced with CoFe2O4 (CF) nanoparticles. The CF nanoparticles, synthesized via the combustion method, were incorporated into the PBAT matrix through solvent casting to form films with varied filler content (0.2, 0.4, 0.6, 0.8, and 1 g). The CF nanoparticles structural, surface, and electrical properties were characterized using XRD and FTIR spectroscopy. At the same time, the morphology of the nanomaterials and their composites was analyzed by scanning electron microscopy. Specifically, the 0.8 g PBAT-CF TENG demonstrated superior performance, achieving an output voltage of 45.45 V and a current of 4.5 µA. Subsequent electrical studies, including charging commercial capacitors (1.0 to 47 μF) and powering LEDs and calculators, underscored the device’s efficiency. The PBAT-CF TENG also effectively generated voltage and current signals from physical activities like walking and jumping. This innovative approach highlights the potential for biodegradable, high-performing, self-powered flexible electronics, and wearable devices, paving the way for sustainable technological advancements.

Submerged and completely open solid–liquid triboelectric nanogenerator for water wave energy harvesting

AbstractTriboelectric nanogenerator (TENG) is an emerging wave energy harvesting technology with excellent potential. However, due to issues with sealing, anchoring, and difficult deployment over large areas, TENG still cannot achieve large‐scale wave energy capture. Here, a submerged and completely open solid–liquid TENG (SOSL‐TENG) is developed for ocean wave energy harvesting. The SOSL‐TENG is adapted to various water environments. Due to its simple structure, it is easy to deploy into various marine engineering facilities in service. Importantly, this not only solves the problem of difficult construction of TENG networks at present, but also effectively utilizes high‐quality wave energy resources. The working mechanism and output performance of the SOSL‐TENG are systematically investigated. With optimal triggering conditions, the transferred charge (Qtr) and short‐circuit current (Isc) of SOSL‐TENG are 2.58 μC and 85.9 μA, respectively. The wave tank experiment is taken for fully demonstrating the superiority of the SOSL‐TENG network in large‐scale collection and conversion of wave energy. Due to the excellent output performance, TENG can harvest wave energy to provide power for various commercial electronic devices such as LED beads, hygrothermograph, and warning lights. Importantly, the SOSL‐TENG networks realizes self‐powered for electrochemical systems, which provides a direction for energy cleanliness in industrial systems. This work provides a prospective strategy for large‐scale deployment of TENG applications, especially for harvesting wave energy in spray splash zones or at the surface of the water.image

A Kelp Inspired High‐Power Density Triboelectric Nanogenerator with Stacking Structure for Multiple Directional Ocean Wave Energy Harvesting

AbstractOcean wave energy is one of the most promising green energies in the wild. However, it is still challenging to effectively collect wave energy due to its randomness and irregularity. In this work, a kelp inspired high‐power density triboelectric nanogenerator (K‐TENG) is presented for harvesting wave energy with characteristics in multiple directions. The proposed K‐TENG consists of a series of stacked leaf‐like units. The influence of configuration parameters, including pellet diameters, pellet numbers, unit sizes, oscillation frequency, swing amplitude, and wave directions on output performances of leaf‐like units, are extensively investigated. Experimental data indicates that a single leaf‐like unit can achieve a maximum output voltage of 623.14 V as well as a maximum current of 1.48 µA and realize energy harvesting from different wave directions. A K‐TENG composed of 15 leaf‐like units demonstrates a high‐power density of 18.77 W m−3 at a wave frequency of 2.5 Hz, which successfully powers a digital watch and 414 light‐emitting diodes (LEDs). This work is hoped to provide a simple and reliable route to effectively harvest ocean wave energy.

Multi-energy harvesting: Integrating contact-mode and slide-mode triboelectric nanogenerators, and solar technologies for efficient power generation in small electronic

Harvesting energy from the environment is getting more attention daily to drive small electronics. This paper presents a hybrid energy harvesting module that uses contact-mode triboelectric nanogenerator, slide-mode nanogenerator, and solar energy to generate electrical power. The fabricated module has three parts, i.e., the base part operating in triboelectric contact mode, the rotary part employing lateral sliding triboelectricity, and solar cells for harnessing sunlight. The 3D designed module parts have been fabricated using 3D printer and laser cutting machine. Subsequently, the parts were assembled by applying triboelectric (Aluminum and Kapton) material onto them. The triboelectric contact mode generated 0.57 µW of electric power achieving power density achieved 57 µWm−2 at the contact area of 100 cm2. Electric power delivered by triboelectrification of the rotary part was 117 µW, whereas the power density was recorded as 232.6 µWm−2 at the contact area 503.36 cm2, and power delivered by solar cells was 66.64 mW. The designed module successfully delivered power to small electronic devices such as electronic thermometers, digital calculators, digital clocks, and 25 green-coloured LEDs. The implications of these findings suggest that such a hybrid module can significantly extend the operational life and independence of small-scale electronics, making it a promising solution for remote sensing, wearable technology, and IoT devices.

Harvesting multidirectional wind energy based on flow-induced vibration triboelectric nanogenerator with directional tuning mechanism

Wind-induced vibration (WIV), as low-velocity wind energy utilization technology in agricultural environment, has significant advantages. Nevertheless, there is a mismatch between the variability of wind direction and the work mode of triboelectric nanogenerator (TENG), which leads to a sharp decline in the performance of triboelectric power generation. This work proposes a TENG based on multidirectional WIV (TENG-WIV), which mainly contains triboelectric power generation unit, guide-wing and triboelectric direction sensor. By introducing the directional tuning mechanism based on guide-wing, the TENG-WIV aims to break the constraints of single wind direction response and effectively respond to the wind direction within 360° range, thereby realizing multidirectional wind energy harvesting and sensor power supply. The empirical findings indicate that the output voltage and current of triboelectric power generation unit are in the ranges of 62–241 V and 0.25–1.21 μA, respectively, at the wind velocities of 1.23–5.13 m/s. At a wind velocity of 3.18 m/s, the unit achieves an out-power peak of 0.09 mW. Furthermore, the triboelectric direction sensor can respond to changes in 8 directions and has wind direction monitoring potentiality. The directional tuning mechanism endows flow-induced vibration energy harvesters with an all-around multidirectional sensitivity.

In-situ cured gel polymer/ecoflex hierarchical structure-based stretchable and robust TENG for intelligent touch perception and biometric recognition

Gel-based sensors for next generation touch panels have been acknowledged for their exceptional sensitivity and flexibility. However, these sensors typically depend on a metal grid connection, which is susceptible to structural deformation under heavy stress applications and necessitates external power. Here, we report a novel in-situ cured gel polymer electrode-based triboelectric nanogenerator (GPE-TENG) that is stretchable, semi-transparent, and durable, designed to enable a self-powered touch panel for intelligent touch perception. The in-situ curing of the hierarchical structure of the ionic polymer gel encapsulated within the ecoflex ensures robust adhesion of the ionic conductive polymer gel (PEO/LiTFSI) to the ecoflex layers, addressing the issue of delamination in TENG components under mechanical stress. As a result, the GPE-TENG demonstrates high durability, enduring under stretching of approximately 375 % and sustaining heavy mechanical deformations (under folding, twisting, and rolling) over a long period (approximately 2 months) without loss of functionality. Remarkably, the GPE-TENG exhibits outstanding energy harvesting capabilities with a peak power density of 0.36 W m-2. Notably, the GPE-TENG generates electrical signals through simple device stretching, thus serving as a self-powered wearable sensor for human activity monitoring. Moreover, a 9-digital arrayed (3 × 3) flexible, semi-transparent, and self-powered touch panel based on the GPE-TENG shows multifunctionality, including touch track/pattern recognition (i.e. touch and sliding mode) and a highly accurate (∼98 %) deep learning assisted smart biometric system for user identification.

Self-healable and stretchable perovskite-elastomer gas-solid triboelectric nanogenerator for gesture recognition and gripper sensing

Gas-solid triboelectric nanogenerators (GS-TENGs) based on porous elastomers provide a promising avenue for the design of self-powered sensors. However, the intrinsic limitation of low electric output in GS-TENGs could affect the accuracy and sensitivity of sensing systems. Here, we develop a porous composite by integrating an adhesive poly(siloxane-diphenylglyoxime-urethane) (PSDU) elastomer with ferroelectric (3,3-difluorocyclobutylammonium) 2 CuCl 4 [(DF-CBA) 2 CuCl 4 ] fillers. PSDU, an intrinsically triboelectric negative material with alternating hard-soft segments and supramolecular bonds, imparts excellent compressibility, adhesion, and self-healing properties to the composite. Simultaneously, the incorporation of (DF-CBA) 2 CuCl 4 as functional fillers leverages the formation of a hydrogen bonding network to enhance charge transfer processes. These fillers facilitate charge accumulation through an electric poling process, resulting in a power output improvement that surpasses 1400 times higher than that of a dense PSDU-based GS-TENG. Tapping onto the versatile properties of porous poly(siloxane-diphenylglyoxime-urethane)-perovskite (PSDU-PK) GS-TENGs, applications such as hand gesture/food recognition and dual-mode sensing system have been demonstrated, suggesting their promising potential in wearable electronics and smart agriculture.

Biocompatible triboelectric energy generators (BT-TENGs) for energy harvesting and healthcare applications.

Electronic waste (e-waste) has become a significant environmental and societal challenge, necessitating the development of sustainable alternatives. Biocompatible and biodegradable electronic devices offer a promising solution to mitigate e-waste and provide viable alternatives for various applications, including triboelectric nanogenerators (TENGs). This review provides a comprehensive overview of recent advancements in biocompatible, biodegradable, and implantable TENGs, emphasizing their potential as energy scavengers for healthcare devices. The review delves into the fabrication processes of self-powered TENGs using natural biopolymers, highlighting their biodegradability and compatibility with biological tissues. It further explores the biomedical applications of ultrasound-based TENGs, including their roles in wound healing and energy generation. Notably, the review presents the novel application of TENGs for vagus nerve stimulation, demonstrating their potential in neurotherapeutic interventions. Key findings include the identification of optimal biopolymer materials for TENG fabrication, the effectiveness of TENGs in energy harvesting from physiological movements, and the potential of these devices in regenerative medicine. Finally, the review discusses the challenges in scaling up the production of implantable TENGs from biomaterials, addressing issues such as mechanical stability, long-term biocompatibility, and integration with existing medical devices, outlining future research opportunities to enhance their performance and broaden their applications in the biomedical field.

Cellulose Nanocrystal-in-Solvent Processing for Efficient One-Pot Upcycling of Commercial Polymeric PFAS.

Upcoming regulations aim to ban per- and polyfluoroalkyl substances (PFAS), including commercial polymeric PFAS, or fluoropolymers, such as poly(tetrafluoroethylene) (PTFE) and poly(vinylidene fluoride) (PVDF), due to their environmental and toxicological impacts. However, fluoropolymers also provide crucial properties for clean energy transitions, and their regulation may hinder further technological advancements. Therefore, a facile one-pot recycling-upcycling strategy for fluoropolymers using inexpensive biomass, such as cellulose nanocrystals (CNCs), as absorbents and cocomponents for fluoro-functionalized composites could align with global sustainability goals and technological demands. Herein, we present a closed-loop CNC-in-solvent (CiS) processing system, which involves stirring fluoropolymers and CNCs in only low-polarity solvents like toluene (CiS-T). Our study reveals that CiS-T is a two-step process where the CNC-solvent interaction exposes CNCs' reducing end aldehyde protons due to solvent polarity and promotes H-F bond formation. The solvent used was recollected and reused. Additionally, we demonstrate the practical application of PTFE- and PVDF-CNC hybrids, byproducts of the CiS-T process, as performance-enhancing agents in green-energy-harvesting devices such as triboelectric nanogenerators. Our findings not only offer a sustainable method to overcome challenges from regulations against commercial fluoropolymers but also offer insights into developing an efficient, solvent-mediated CNC functionalization process that addresses forthcoming challenges in key industries.