Trenton Limestone Research Articles

Microfacies Analysis and Depositional Model for the Black River -Trenton Carbonates (Ordovician) of Southern Ontario, Canada

This study documents the detailed microfacies depositional environment of the Ordovician Black River and Trenton limestone Groups in Lake Simcoe area of southern Ontario, resting unconformably on Precambrian basement. Local Precambrian 'highs' complicate the overall facies pattern and lithofacies patterns define local shoal, intershoal and basinal environments. Detailed microfacies and facies analysis in large quarries in the Lake Simcoe area are used to infer various carbonate environments by comparison with analogous modern and ancient ramps. Fifteen microfacies are grouped into six microfacies associations based on composition, grain size and texture. Relative energy levels, and depositional environments for these are then inferred. These environments resemble the Recent Arabian Shelf of the Persian Gulf for the Black River Group, and the Recent West Florida Shelf for the Trenton, though other Recent ramps like South Australia are also comparable. The vertical arrangement of facie\s in the Lake Simcoe area forms repetitive cycles, which can then be traced laterally into adjacent areas, complicated by the effects of sea-floor topography and possibly by synsedimentary faulting.

Understanding controls on the geochemistry of hydrocarbon produced waters from different basins across the US.

The most massive waste stream generated by conventional and unconventional hydrocarbon exploration is the produced water (PW). The costs and environmental issues associated with the management and disposal of PW, which contains high concentrations of inorganic and organic pollutants, is one of the most challenging problems faced by the oil and gas industry. Many of the current strategies for the reuse and recycling of PW are inefficient because of varying water demand and the spatial and temporal variations in the chemical composition of PW. The chemical composition of PW is controlled by a multitude of factors and can vary significantly over time. This study aims to understand different parameters and processes that control the quality of PW generated from hydrocarbon-bearing formations by analyzing relationships between their major ion concentrations, O, H, and Sr isotopic composition. We selected PW data sets from three conventional (Trenton, Edwards, and Wilcox Formations) and four unconventional (Lance, Marcellus, Bakken, and Mesaverde Formations) oil and gas formations with varying lithology and depositional environment. Using comparative geochemical data analysis, we determined that the geochemical signature of PW is controlled by a complex interplay of several factors, including the original source of water (connate marine vs. non-marine), migration of the basinal fluids, the nature and degree of water-mineral-hydrocarbon interactions, water recharge, processes such as evaporation and ultrafiltration, and production techniques (conventional vs. unconventional). The development of efficient PW recycle and reuse strategies requires a holistic understanding of the geological and hydrological history of each formation to account for the temporal and spatial heterogeneities.

Integrated reservoir characterization of a Utica Shale field

We performed an integrated multidisciplinary study for reservoir characterization of a Utica Shale field in eastern Ohio covered by a multiclient 3D seismic data set acquired in 2015. Elastic seismic inversion was performed in-house for effective reservoir characterization of the Utica Shale, which covers the interval from the top of Upper Utica (UUTIC) to the top of Trenton Limestone. Accurate, high-fidelity inversion results were obtained, including acoustic impedance, shear impedance, density, and VP/VS. These consistent inversion results allow for the reliable calculation of geomechanical and petrophysical properties of the reservoir. The inverted density clearly divides the Point Pleasant (PPLS) interval as low density from the overlying UUTIC Shale interval. Both Poisson's ratio (PR) and brittleness unmistakably separate the underlying PPLS from the overlying Utica interval. The PPLS Formation is easier to hydraulically fracture due to its much lower PR. Sequence S4 is the best due to its higher Young's modulus to sustain the open fractures. The calculated petrophysical volumes indisputably delineate the traditional Utica Shale into two distinctive sections. The upper section, the UUTIC, can be described as having 1%–2% total organic carbon (TOC), 3.5%–4.8% porosity, 10%–24% water saturation, and 40%–58% clay content. The lower section, PPLS, can be described as having 3%–4.5% TOC, 5%–9% porosity, 2%–10% water saturation, and about 15%–35% clay content. Both sections exhibit spatial variation of the properties. Nevertheless, the underlying PPLS is obviously a significantly better reservoir and operationally easier to produce.

Seismic reservoir characterization of Utica-Point Pleasant Shale with efforts at quantitative interpretation — A case study: Part 1

The Utica Shale is one of the major source rocks in Ohio, and it extends across much of the eastern United States. Its organic richness, high content of calcite, and development of extensive organic porosity make it a perfect unconventional play, and it has gained the attention of the oil and gas industry. The primary target zone in the Utica Play includes the Utica Formation, Point Pleasant Formation, and Trenton Formation intervals. We attempt to identify the sweet spots within the Point Pleasant interval using 3D seismic data, available well data, and other relevant data. This has been done by way of organic richness and brittleness estimation in the rock intervals. The organic richness is determined by weight % of total organic carbon content, which is derived by transforming the inverted density volume. Core-log petrophysical modeling provides the necessary relationship for doing so. The brittleness is derived using rock-physics parameters such as the Young’s modulus and Poisson’s ratio. Deterministic simultaneous inversion along with a neural network approach are followed to compute the rock-physics parameters and density using seismic data. The correlation of sweet spots identified based on the seismic data with the available production data emphasizes the significance of integration of seismic data with all other relevant data.

Eustatic and far-field tectonic control on the development of an intra-platform carbonate-shoal complex: upper tongue of the Tanglewood Member, Upper Ordovician Lexington Limestone, central Kentucky, U.S.A.

The Lexington or Trenton Limestone is an Upper Ordovician (Chatfieldian–Edenian; upper Sandbian–lower Katian), temperate-water unit, averaging about 60-m thick, that was deposited in relatively shallow waters across the Lexington Platform in east-central United States during the Taconian Orogeny. Lexington/Trenton shallow-water deposition ended across most of the platform in late Chatfieldian time and from that point deepened upward into the more shale-rich Clays Ferry, Point Pleasant and Kope formations due to apparent sea-level rise. In central Kentucky, however, deposition of the Lexington Limestone continued into early Edenian time and includes up to 50m of additional coarse calcarenites and calcirudites at the top, which form the Tanglewood buildup and reflect locally regressive conditions, apparently related to local structural uplift. Consequently, in central Kentucky, the Lexington is more than 100-m thick, and Lexington deposition on the buildup continued into early Edenian time as an intra-platform shoal complex that tongues out into deeper-water units in all directions. In an attempt to understand how this shoal complex developed, we examined the last major body of coarse skeletal sands in the central Kentucky Lexington Limestone, the upper tongue of the Tanglewood Member, a 12-m-thick succession of fossiliferous calcarenite and calcirudite that occurs across an area of 5200km2 near the center of the Lexington Platform. Although relatively homogeneous, the upper Tanglewood is divisible into five, small-scale, fining-upward, sequence-like cycles, which contain prominent, widespread deformed horizons. Facies analysis indicates that four lithofacies, which reflect distinct depositional environments, comprise the sequences across the shoal complex. Lithofacies were correlated across the shoal complex by integrating cyclicity and widespread deformed horizons in order to delineate the locations of major depositional environments. Facies analysis shows that the thickest and coarsest parts of each sequence, and the shallowest depositional environments, coincide with basement fault blocks, which are known to have experienced uplift during earlier Lexington Limestone deposition. The occurrence of thick, coarse facies on the same blocks suggests that the blocks continued to experience uplift into shallow water, where tides and waves redistributed sediments during upper Tanglewood deposition. Although eustasy apparently controlled cyclicity, Taconian far-field forces generated by orogeny in the east seem to have influenced facies distribution in each cycle through reactivation of basement fault zones as synsedimentary growth faults. The example of the upper Tanglewood Member shows that tectonic far-field forces can exert important influences on the development of carbonate depositional environments, even in distal intracratonic settings like the Lexington Platform.

Deep gas well encounters ultramafic kimberlite-like material in the Sauk Sequence of southeastern Ohio, USA

The first indication of a potential deep-subsurface kimberlite-like material in the Appalachian Basin, without surface expression, has been discovered in oil and gas well drilling samples from a deep well drilled near Zanesville, Ohio, USA. The well was drilled into the Cambrian Sauk Sequence within a localized fault-bounded graben, where a zone of ultramafic rocks was encountered. The zone of ultramafic rocks is within Sauk carbonates at 1720 m below sea level and is not highly anomalous on geophysical wire-line well logs. Petrographic analyses of grain-mounted samples show a 20 m zone of ultramafic rock material near the top of the Conasauga Group. Well cuttings from the ultramafic zone include relatively fresh phenocrysts of phlogopite with calcite, apatite, and titaniferous magnetite, in a secondary matrix of amphibole, chlorite, Fe-oxides, and possibly serpentine. The rocks have undergone deuteric alteration and probably later hydrothermal alteration. A 20-m-thick, localized, natural gas–bearing sandstone unconformably overlies (Knox unconformity) the Sauk Sequence above the ultramafic zone. Structural mapping indicates that the localized sandstone is confined to a small seismic-defined graben originating in the faulted Precambrian Grenville basement complex. Mapping of newly acquired gravity and magnetic data does not indicate the presence of an anomaly coincident with the graben, suggesting that the ultramafic material must be a very small, localized intrusive body (pipe or diatreme). Alternative interpretations include a thin intrusive sill, extrusive tuff deposits, Grenville-aged tectonic fault slice, or eroded igneous deposits. Subsurface mapping of units above the Sauk Sequence (Ordovician Black River Group–Trenton Limestone) shows no significant variation in structural contours above the feature. Although the igneous material has not been isotopically dated, the stratigraphic position suggests that it was intruded prior to Middle Ordovician time.

Origin and reservoir characteristics of Upper Ordovician Trenton�Black River hydrothermal dolomite reservoirs in New York

In the past decade, more than 20 new natural gas fields have been discovered in laterally discontinuous dolomites of the Upper Ordovician Black River Group in south-central New York. The dolomites form around basement-rooted wrench faults that are detectable on seismic data. Most fields occur in and around elongate fault-bounded structural lows interpreted to be negative flower structures. Away from these faults, the formation is composed of impermeable limestone and forms the lateral seal for the reservoirs. In most cases, the faults die out within the overlying Trenton Limestone and Utica Shale. Most porosity occurs in saddle dolomite-coated vugs, breccias, and fractured zones. Matrix porosity is uncommon in the Black River cores described for this study. The patchy distribution around basement-rooted faults and geochemical and fluid-inclusion analyses supports a fault-related hydrothermal origin for the saddle and matrix dolomites. This play went for many years without detection because of its unconventional structural setting (i.e., structural lows versus highs). Using the appropriate integrated structural-stratigraphic-diagenetic model, more hydrothermal dolomite natural gas reservoirs are likely to be discovered in the Black River of New York and in carbonates around the world.

Late Paleozoic remagnetization of the Trenton Formation in Ordovician petroleum reservoirs of southwestern Ontario

A paleomagnetic study of subsurface core samples from dolomitized carbonates of two producing reservoirs in the Upper Ordovician Trenton Formation, collected from four wells in southwestern Ontario yielded a paleomagnetic direction of D = 152.3°, I = − 12.3° ( N = 49, α 95 = 8.7). This characteristic remanent magnetization (ChRM) direction was azimuth-corrected by aligning the viscous remanence magnetization (VRM) with the present Earth's magnetic field direction. A drilling-induced magnetization (VRMdi) was present in less than half the specimens sampled in this study. In addition, where the VRM correction could not be made, a paleolatitudinal arc calculated from the inclination-only mean of I = − 9.0° ( N = 34, α 95 = 3.0°) intersected the apparent polar wander path in the Late Permian–Early Triassic. These paleodirections are similar to the paleomagnetic directions observed in Ordovician Trenton carbonates from the Michigan Basin and New York State, U.S.A., suggesting a related regional late Paleozoic remagnetization.

Weird things from the Middle Ordovician of North America interpreted as conulariid fragments

Small phosphatic fossils recovered from acid residues of the Galena Group Middle (Ordovician) of Wisconsin were recently described by Clark et al. (1999) as weird things. Here, we report that specimens identified by those authors as Thing 3 and Thing 6 are fragments of conulariids belonging to two species that occur widely through Middle Ordovician strata of eastern North America. Similarly disintegrated, conspecific specimens from the Trenton Limestone of northwestern Indiana, and articulated, conspecific specimens from Ohio and New York, are introduced for comparison.

WEIRD THINGS FROM THE MIDDLE ORDOVICIAN OF NORTH AMERICA INTERPRETED AS CONULARIID FRAGMENTS

Small phosphatic fossils recovered from acid residues of the Galena Group Middle (Ordovician) of Wisconsin were recently described by Clark et al. (1999) as weird things. Here, we report that specimens identified by those authors as Thing 3 and Thing 6 are fragments of conulariids belonging to two species that occur widely through Middle Ordovician strata of eastern North America. Similarly disintegrated, conspecific specimens from the Trenton Limestone of northwestern Indiana, and articulated, conspecific specimens from Ohio and New York, are introduced for comparison.

Anomalous unblocking temperatures, viscosity and frequency-dependent susceptibility in the chemically-remagnetized Trenton limestone

Chemical remagnetization of many carbonate rock units occurred by diagenetic alteration of iron sulfide precursors and by authigenesis of fine-grained magnetite, which can commonly be recognized by a distinctive set of rock-magnetic attributes. These carbonates also typically exhibit anomalously high unblocking temperatures for recent thermoviscous components that have overprinted the characteristic chemical remanence. Recent work has shown that departures from Néel theory (as applied in the model of Pullaiah et al.) can generally be attributed to VRM carried by multidomain particles, to which the theory does not apply. In the remagnetized carbonates, however, rock-magnetic data all point to an overwhelming dominance of fine superparamagnetic and stable single-domain particles. Therefore we explore possible alternative causes for the anomalous unblocking temperatures, including maghemitization and magnetocrystalline rather than shape anisotropy. New blocking–unblocking models for these cases, however, fail to match the observed behavior, leading to the conclusion that the anomalous unblocking temperatures are indeed probably attributable to multidomain carriers. A possible alternative explanation is an increase in coercivity due to maghemitization of single-domain particles after acquisition of the viscous overprint, causing a significant increase in their unblocking temperatures. New frequency-dependent susceptibility measurements at low temperatures allow us to focus on the time–temperature behavior of the particles at the superparamagnetic-stable single-domain threshold, and we find that these do closely follow the predictions of Néel theory, as formulated in the models of Pullaiah et al. and Walton–Middleton–Schmidt.

The Ordovician Sebree Trough: An oceanic passage to the Midcontinent United States

The Sebree Trough is a relatively narrow, shale-filled sedimentary feature extending for several hundred kilometers across the Middle and Late Ordovician carbonate platform of the Midcontinent United States. The dark graptolitic shales within the trough stand in contrast to the coeval bryozoan-brachiopod-echinoderm– rich limestones on the flanking platforms. We infer from regional stratal patterns, thickness and facies trends, and temporal relations established by biostratigraphy and K-bentonite stratigraphy that the Sebree Trough initially began to develop during late Turinian to early Chatfieldian time (Mohawkian Series) as a linear bathymetric depression situated over the failed late Precambrian–Early Cambrian Reelfoot Rift. Rising sea level and positioning of a subtropical convergence zone along the southern margin of Laurentia caused the rift depression to descend into cool, oxygen-poor, phosphate-rich oceanic waters that entered the southern reaches of the rift from the Iapetus Ocean. The trough apparently formed in a system of epicontinental estuarine circulation marked by a density- stratified water column. Trough formation was accompanied by cessation of carbonate sedimentation, deposition of graptolitic shales, development of hardground omission surfaces, substrate erosion, and local phosphogenesis. The carbonate platforms on either side of the trough are dominated by bryozoan-brachiopod- echinoderm grainstones and packstones that were deposited in zones of mixing where cool, nutrient-rich waters encountered warmer shelf waters. Concurrently, lime mudstone and wackestone were deposited shoreward (northern Illinois, Wisconsin, Iowa, Minnesota, Michigan) in warmer, more tropical shallow seas. Coeval upward growth of the flanking carbonate platforms sustained and enhanced development of the trough shale facies. Five widespread diachronous late Mohawkian and Cincinnatian omission surfaces are present in the carbonate facies of the Midcontinent. These surfaces include sub-Deicke K-bentonite, DS1; top of Black River Limestone, DS2; base and top of the Guttenberg Limestone Member of the Decorah Formation, DS3 and DS4; and top of the Trenton Limestone, DS5. Some of the surfaces correspond to previously described depositional sequence boundaries. All five surfaces, which embody deepening phases on top of highstand-systems tracts, converge in the Sebree Trough, indicating that the trough was a long-lived feature and was the source of eutrophic waters that episodically spread across the adjacent platforms, terminating carbonate production. Late Turinian and early Chatfieldian incipient drowning episodes were followed by a final drowning event that began in the Sebree Trough during the late Chatfieldian ( Climacograptus spiniferus Zone) and reached southernmost Minnesota and other regions far within the platform interior by Richmondian time ( Amorphognathus ordovicicus Zone).

Dolomitization and Dolomite Neomorphism: Trenton and Black River Limestones (Middle Ordovician) Northern Indiana, U.S.A.

Dolomitization and Dolomite Neomorphism: Trenton and Black River Limestones (Middle Ordovician) Northern Indiana, U.S.A.

Dolomitization and Dolomite Neomorphism: Trenton and Black River Limestones (Middle Ordovician) Northern Indiana, U.S.A.

ABSTRACT The Trenton and Black River Limestones are dolomitized extensively along the axis of the Kankakee Arch in Indiana, with the proportion of dolomite decreasing to the south and southeast of the arch. Planar and nonplanar dolomite replacement textures and rhombic (type 1) and saddle (type 2) void-filling dolomite cements are present. Three stages of dolomitization, involving different fluids, are inferred on the basis of petrographic and geochemical characteristics of the dolomites. Nonferroan planar dolomite has relatively high 18O values (-1.8 to -6.1o/oo PDB) and has 87Sr/86Sr ratios (0.70833 to 0.70856) that overlap those of Middle Ordovician seawater. Petrography, geochemistry, and the geometry of the dolomitized body suggest that the planar dolomite was formed in Middle and Late Ordovician seawater during the deposition of the overlying Maquoketa Shale. Ferroan planar and nonplanar dolomite occurs in the upper few meters of the Trenton Limestone, confined to areas underlain by planar dolomite. This dolomite contains patches of nonferroan dolomite with cathodoluminescence (CL) characteristics similar to underlying planar dolomite. Ferroan dolomite has relatively low 18O values (-5.1 to -7.3o/oo PDB) and has slightly radiogenic 87Sr/86Sr ratios (0.70915 to 0.70969) similar to those obtained for the overlying Maquoketa Shale. These data indicate that ferroan dolomite formed by neomorphism of nonferroan planar dolomite as fluids were expelled from the overlying Maquoketa Shale during burial. The absence of ferroan dolomite at the Trenton-Maquoketa contact, in areas where the earlier-formed nonferroan planar dolomite also is absent, indicates that the fluid expelled from the overlying shale did not contain enough Mg2+ to dolomitize limestone. Type 1 dolomite cement has isotopic compositions similar to those of the ferroan dolomite, suggesting that it also formed from shale-derived burial fluids. CL growth zoning patterns in these cements suggest that diagenetic fluids moved stratigraphically downward and toward the southeast along the axis of the Kankakee Arch. Type 2 saddle dolomite cements precipitated late; their low 18O values (-6.0 to -7.0o/oo PDB) are similar to those of the type 1 dolomite cement. However, fluid-inclusion data indicate that the saddle dolomite was precipitated from more saline, basinal fluids and at higher temperatures (94° to 143°C) than the type 1 cements (80° to 104°C). A trend of decreasing fluid-inclusion homogenization temperatures and salinities from the Michigan Basin to the axis of Kankakee Arch suggests that these fluids emerged from the Michigan Basin after precipitation of type 1 cement.

Abstract: Faults control of facies patterns and reservoir rocks in temperate Middle Ordovician shelf carbonates (Black River and Trenton Limestone Groups) of South-Central Ontario, Canada

Abstract: Faults control of facies patterns and reservoir rocks in temperate Middle Ordovician shelf carbonates (Black River and Trenton Limestone Groups) of South-Central Ontario, Canada

ABSTRACT: Location of Dolomitized Grainstone Reservoirs in the Upper Ordovician Black River and Trenton Limestone Groups in Ontario

ABSTRACT: Location of Dolomitized Grainstone Reservoirs in the Upper Ordovician Black River and Trenton Limestone Groups in Ontario

ABSTRACT: K-Bentonite and Sequence Correlations of Upper Black River and Lower Trenton Limestones from Lake Simcoe, Southern Ontario Canada to Watertown, Northern New York State

ABSTRACT: K-Bentonite and Sequence Correlations of Upper Black River and Lower Trenton Limestones from Lake Simcoe, Southern Ontario Canada to Watertown, Northern New York State

Fluid inclusion and stable isotope analyses of veins from the central Appalachian Valley and Ridge province: Implications for regional synorogenic hydrologic structure and fluid migration

Fluid inclusion microthermometric analyses and O and C stable isotopic analyses of vein minerals are used to determine the chemistry and trapping conditions of fluids present in the central Appalachian fold-and-thrust belt during the late Paleozoic Alleghanian orogeny. The upper Paleozoic rock section contains three regional hydrostratigraphic systems based on fluid chemistry and temperature. The Ordovician Trenton Formation through the Devonian Helderberg Group was a regional aquitard and was dominated by high-salinity, CH 4 -saturated, in situ fluids. The Devonian Oriskany Formation through the lower portion of the Chemung Formation was a regional aquifer system and underwent an influx of warm migrating fluids. The upper portion of the Devonian Chemung through Pocono Formations was also a regional aquifer, but it was dominated by an influx of meteoric water that mixed with in situ fluids. The migrating fluid was a warm (160 to >220 °C) CH 4 -saturated NaCl-CaCl 2 brine that was stratigraphically restricted to the Oriskany Formation through the lower portion of the Chemung Formation, although there is evidence for infiltration into lower stratigraphic units. Two separate fluid migration events are recorded in the rocks. The first event is either late synfolding to postfolding, and the second event is postfolding. Approximately 2‐4 km of overburden were removed by erosion between the two migration events. The source of the warm migrating fluids is still unknown. However, the most likely source would be fluids that were tectonically driven through the fold-and-thrust belt by large-scale, out of sequence thrusting in the hinterland. The migrating fluids were transported far into the foreland where they may have been directly responsible for (1) flushing of hydrocarbons from the upper Paleozoic of the Valley and Ridge into the Plateau province and (2) elevated thermal maturation indicators in the Valley and Ridge and Plateau provinces.

Abstract: Implications for a Dolomite Fairway"in the Trenton Limestone in Southwestern Indiana"

Abstract: Implications for a Dolomite Fairway"in the Trenton Limestone in Southwestern Indiana"

Black Shale Source Rocks and Oil Generation in the Cambrian and Ordovician of the Central Appalachian Basin, USA

Nearly 600 million bbl of oil (MMBO) and 1 to 1.5 trillion ft3 (tcf) of gas have been produced from Cambrian and Ordovician reservoirs (carbonate and sandstone) in the Ohio part of the Appalachian basin and on adjoining arches in Ohio, Indiana, and Ontario, Canada. Most of the oil and gas is concentrated in the giant Lima-Indiana field on the Findlay and Kankakee arches and in small fields distributed along the Knox unconformity. Based on new geochemical analyses of oils, potential source rocks, bitumen extracts, and previously published geochemical data, we conclude that the oils in both groups of fields originated from Middle and Upper Ordovician black shale (Utica and Antes shales) in the Appalachian basin. Moreover, we suggest that approximately 300 MMBO and many trillions of cubic feet of gas in the Lower Silurian Clinton sands of eastern Ohio originated in these same source rocks. Oils from the Cambrian and Ordovician reservoirs have similar saturated hydrocarbon compositions, biomarker distributions, and carbon isotope signatures. Regional variations in the oils are attributed to differences in thermal maturation rather than to differences in source. Total organic carbon content, genetic potential, regional extent, and bitumen extract geochemistry identify the black shale of the Utica and Antes shales as the most plausible source of the oils. Other Cambrian and Ordovician shale and carbonate units, such as the Wells Creek formation, which rests on the Knox unconformity, and the Rome Formation and Conasauga Group in the Rome trough, are considered to be only local petroleum sources. Tmax, CAI, and pyrolysis yields from drill-hole cuttings and core indicate that the Utica Shale in eastern and central Ohio is mature with respect to oil generation. Burial, thermal, and hydrocarbon-generation history models suggest that much of the oil was generated from the Utica-Antes source in the late Paleozoic during the Alleghanian orogeny. A pervasive fracture network controlled by basement tectonics aided in the distribution of oil from the source to the trap. This fracture network permitted oil to move laterally and stratigraphically downsection through eastward-dipping, impermeable carbonate sequences to carrier zones such as the Middle Ordovician Knox unconformity, and to reservoirs such as porous dolomite in the Middle Ordovician Trenton Limestone in the Lima-Indiana field. Some of the oil and gas from the Utica-Antes source escaped vertically through a partially fractured, leaky Upper Ordovician shale seal into widespread Lower Silurian sandstone reservoirs.