Trapping Efficiency Research Articles

Photo-Thermal Conversion and Raman Sensing Properties of Three-Dimensional Gold Nanostructure.

Three-dimensional plasma nanostructures with high light-thermal conversion efficiency show the prospect of industrialization in various fields and have become a research hotspot in areas of light-heat utilization, solar energy capture, and so on. In this paper, a simple chemical synthesis method is proposed to prepare gold nanoparticles, and the electrophoretic deposition method is used to assemble large-area three-dimensional gold nanostructures (3D-GNSs). The light-thermal water evaporation monitoring and surface-enhanced Raman scattering (SERS) measurements of 3D-GNSs were performed via theoretical simulation and experiments. We reveal the physical processes of local electric field optical enhancement and the light-thermal conversion of 3D-GNSs. The results show that with the help of the efficient optical trapping and super-hydrophilic surface properties of 3D-GNSs, they have a significant effect in accelerating water evaporation, which was increased by nearly eight times. At the same time, the three-dimensional SERS substrates based on gold nanosphere particles (GNSPs) and gold nanostar particles (GNSTs) had limited sensitivities of 10-10 M and 10-12 M to R6G molecules, respectively. Therefore, 3D-GNSs show strong competitiveness in the fields of solar-energy-induced water purification and the Raman trace detection of organic molecules.

A‐D‐A‐type Molecule with Dual Functions of Efficient Charge Extraction and Trap Passivation for n‐i‐p Perovskite Solar Cells

AbstractInterfacial defects and energy level mismatches between the perovskite and 2,2′,7,7′‐tetrakis[N,N‐di(4‐methoxyphenyl)amino]‐9,9′‐spirobifluorene (Spiro‐OMeTAD) layers heavily hinder charge transfer, limiting the efficiency and stability of n‐i‐p perovskite solar cells (PSCs). Herein, D‐type TPA, D‐A‐type TPA‐CN, and A‐D‐A‐type DTPA‐CN with triphenylamine units and different interfacial dipoles are designed as multifunctional interfacial layers for n‐i‐p PSCs. Among the three molecules, A‐D‐A‐type DTPA‐CN has the largest dipole moment, hole transporting capability, and hydrophobicity, and therefore the strongest passivation of interfacial defects and the best carrier extraction efficiency can be observed. As a result, the DTPA‐CN‐treated device achieves a champion power conversion efficiency (PCE) of 25.00%, as compared to the control device (22.78%). Moreover, the long‐term stability of the unencapsulated device is significantly improved. After 2,040 h of storage in a nitrogen glove box, the device maintains over 90% of its initial efficiency, while only 61% for the control device. The work indicates that simultaneous improvement of trap passivation and hole extraction is critical for achieving highly efficient and stable n‐i‐p PSCs.

CO2 trapping dynamics in tight sandstone: Insights into trapping mechanisms in Mae Moh's reservoir

The reliance on fossil fuels is a major contributor to increased anthropogenic CO2 emissions, driving global challenges such as climate change through the greenhouse effect. Carbon capture and storage (CCS) is a promising interdisciplinary technology aimed at mitigating these emissions by securely sequestering gigatons of CO2. This study focuses on the feasibility of storing point-source CO2 emissions in saline formations, with a particular emphasis on the Mae Moh coal-fired power plant in Lampang, Thailand, which is located near its associated coal mine. The region presents challenges due to tight sandstone reservoirs buried over 2000 m deep. With reservoir simulation, this study evaluates the impact of various factors on CO2 containment and trapping in these geological settings. Results show that elevated temperatures decrease structural trapping of 43.0%–28.9% and increase solubility trapping of 28.55%–46.5%, at 40 °C and 80 °C respectively. Hysteresis is found to enhance residual trapping by immobilizing up to 31.1% of CO2 within pore spaces at 0.5. Permeability heterogeneity has a minimal impact on overall trapping efficiency due to the less heterogeneity of the tight sandstone. However, the kV/kH ratio significantly influences vertical CO2 migration which resulted in residual trapping at its highest at the ratio of 0.1, while lower ratios support lateral dispersion. Moderate rock compressibility values are identified as optimal for structural and residual trapping, while extreme compressibility enhances solubility trapping by up to 30%. These findings emphasize the complexity of CO2 trapping mechanisms in tight sandstone formations, emphasizing the need for careful consideration of key factors in CCS projects.

A Study of CO2 Storage in Bimodal Carbonate Aquifer Rocks: Challenges and Enhancement through Foaming

Summary In carbonate rock reservoirs, the presence of dual-pore systems, characterized by two distinct pore size distributions, plays a crucial role in gas storage in saline aquifers. However, comprehensive research on the impact of bimodal porosity on CO2 storage in such reservoirs is lacking. This study explores CO2 storage efficiency in carbonate aquifer rocks with bimodal porosity. Petrographic examination, capillary pressure measurements, and nuclear magnetic resonance (NMR) T2 profiling revealed two distinct and interconnected pore systems with equal effective porosity proportions. While both systems facilitated fluid flow, the micropores had a high capillary entry pressure (>100 psi). Coreflood experiments showed gas displacement efficiencies below 50%, primarily in larger pores, with only 49–58% of these large pores (20–28% of total pores) storing injected gas through residual trapping after water imbibition. To address this challenge, CO2 was foamed using a foaming agent to enhance viscous forces and overcome capillary forces. This resulted in significant improvements, including a 31% increase in displacement efficiency and a 28% increase in residual gas. NMR analysis revealed effective redirection of CO2 into smaller pores when foam was applied. In another experiment on a sample with a different pore geometry, the use of nanoparticles to strengthen foam increased sweep efficiency by up to 117%, with a corresponding increase of up to 169% in residual trapping. While the use of foam entails additional operational expenses, we contend that the economic viability of foam technology for CO2 storage hinges on a rigorous cost-benefit analysis that weighs increased storage capacity/security against chemical costs. Such analysis should also consider the time, cost, and uncertainty associated with developing additional storage sites. Furthermore, improved site selection criteria in carbonate rocks are needed, including a predictive model for T2 cutoff to identify aquifers with excessive micropores and avoid them during site selection. While fractured porosity is not within the scope of this study, it is expected that foam can equally improve sweep and trapping efficiencies in naturally fractured carbonate rocks.

A numerical feasibility study of CO2 foam for carbon utilization and storage in a depleted, high salinity, carbonate oil reservoir

Carbon Capture, Utilization, and Storage (CCUS) offers a viable solution to reduce the carbon footprint in the petroleum industry, and foam injection presents a promising method to achieve this while simultaneously increasing oil recovery. In this work, we studied the feasibility of CO2 foam for co-optimizing enhanced oil recovery and CO2 storage in a high-salinity carbonate formation. The simulated hydrodynamic model is a depleted formation containing 30% residual oil, with three mechanisms for CO2 storage: solubility, residual, and mineralization trapping mechanisms. The results showed that after 20 years, oil recovery during foam injection was 2.7 times higher than CO2 injection, and the CO2 stored during foam flooding was 38% higher than CO2 injection. Notably, foam injection also increased CO2 storage capacity by 2.6 times, indicating the potential to store around 2 gigatons of CO2 in the simulated model. This was attributed to the ability of foam to significantly reduce gas mobility and thus form isolated bubbles through its Jamin effect. Residual trapping was the dominant trapping mechanism, contributing to over 70% of the total CO2 trapped, attributed to the reduction in the dissolution of CO2 in brine due to the high salinity of the aqueous medium. CO2 mineralization was also studied, showing the least trapping efficiency and the dissolution trend of all the carbonate minerals. This study illustrates a novel CO2 utilization and storage technique in which CO2 is concurrently sequestered while enhancing oil recovery in a depleted oil reservoir by injecting CO2 as foam. The relevance of this study lies in its potential to provide a dual benefit of reducing greenhouse gas emissions and boosting oil production, offering a sustainable approach for the petroleum industry.

An insight into hydrogen and carbon dioxide displacement and trapping efficiencies in carbonate formations through NMR and core flooding

The complex pore structure of carbonates can influence gas storage process to different extents, depending on stored gas type. Hence, investigating gas displacement and residual trapping in such formations is crucial. Here, several CO2 and H2 core flooding experiments were performed using three carbonate samples. The drainage process is followed by brine imbibition to test gas residual trapping. Additionally, nuclear magnetic resonance (NMR) T2 spectra measurements were conducted at different stages. The results show that H2 had less displacement efficiency in carbonates compared to CO2. The pore structure has a noticeable impact on CO2 displacement efficiency. However, H2 displacement efficiency is less sensitive to rock properties. The NMR-T2 measurements show that CO2 partially saturated medium-sized pores and almost filled all macropores during drainage. After imbibition, large pores are slightly re-saturated with brine with varying degrees compared to their initial brine saturations. H2 shows lower residual trapping efficiency compared to CO2.

Broadband light trapping in perovskite solar cells: Optimization and enhancement through exploiting multi-resonant Mie resonators

We present multi-resonant Mie resonators comprising dielectric nanopyramid arrays (DNPAs) for efficient broadband light trapping (LT) in perovskite solar cells (PSCs). Absorption in a 100 nm-thick active layer is significantly enhanced over a broad range of wavelengths through the simultaneous resonant excitation of electric and magnetic moments. Through optimization, a PSC integrated with a front-located DNPA LT structure having a base edge of 320 nm and a spacing of 180 nm at an aspect ratio of 1.5 yields a short-circuit current density (Jsc) of 18.13 mA/cm2, which is about 29 % higher than that of a planar PSC. Multipole resonance contributions and radiation patterns of DNPs are also investigated. The spectral overlap of the multipole resonances of the DNPAs can be easily tuned, thereby providing performance enhancements in diverse applications, such as nanoantennas, metasurfaces, photodiodes, and other solar cells.

Iron and Manganese concentrations in leaf tissues of Rhizophora mangle (Rhizophoraceae): implications for energetic metabolism

Introduction: Iron (Fe) and manganese (Mn) are bioessential micronutrients for plants but can impair the energetic metabolism when present at high levels. Objective: To assess the photosynthetic performance and oxidative damages in Rhizophora mangle L. leaf tissues at low and high concentrations of Fe (74 and 195 mg kg-1; Feleaf) and Mn (65 and 414 mg kg-1; Mnleaf). Methods: Photosynthetic pigments, chlorophyll a fluorescence, leaf CO2 assimilation and gas exchange and DPPH• radical scavenging capacity were sampled in R. mangle growing in estuarine forests in the North region of Espírito Santo State and the extreme South of Bahia State (Brazil) showing low and high Feleaf and Mnleaf. Results: Effects of high Fe and Mn were not identified on pigment levels. The increase in Feleaf and Mnleaf at the levels observed in this assessment had a positive effect on the number of reaction centers and on the efficiency of the oxygen-evolving complex, evaluated as K-band, while no changes were found in the parameters related to the excitation trapping efficiency at the active center of photosystem II. Distinct interference patterns of Fe and Mn on the functional processes of photosynthesis were identified, especially on CO2 assimilation and reactive oxygen species metabolism, with major effects on CO2 assimilation and carboxylation efficiency of Rubisco at high Mnleaf. Conclusion: These findings demonstrate the efficiency of R. mangle in positively regulating the electron transport chain in response to high Fe and Mn, at least in terms of the preservation of structure and functionality of the plant photosynthetic apparatus. Moreover, interference of high Mnleaf in R. mangle occurs at non-stomatal and biochemical levels. There is an antagonistic interference of these trace elements with the physiology of R. mangle, which is a dominant species in Brazilian mangroves.

Photocatalytic Synergy Between α-Bi2O3 Nanosphere and Spindle MIL-88A for Gas-Phase CO2 Reduction.

Visible light-active photocatalysts play a crucial role in gas-phase photocatalytic CO2 reduction, offering significant potential for sustainable energy conversion. Herein, we present the synthesis of spindle-shaped Iron (Fe)-based metal-organic framework (MOF) MIL-88 A, coupled with distinct α-Bi2O3 nanospheres. The α-Bi2O3/MIL88A heterostructure is formed by interacting opposite surface charges, enhancing visible-light absorption and efficient interfacial charge-carrier separation. Such low-cost photocatalysts have a 1.75 eV band gap and demonstrate enhanced efficacy in converting CO2 to CO, CH4, and H2 in water without using any sacrificial agents or noble metals compared to pristine MIL88A. In addition, in-situ Electron Spin Resonance (ESR) analyses revealed that these unique catalysts combination promoted enhanced interfacial charge dynamics, creating efficient trapping sites for photogenerated carriers. Further, in-situ Diffuse Reflectance Infrared Fourier Transfer Spectroscopy (DRIFTS) investigation elucidates the plausible reaction mechanism and provides an effective methodology for catalyst screening for CO2 photoreduction. This study offers an effective approach for synthesizing the earth-abundant heterostructure from metal oxide and low-cost MOFs, enhancing photocatalytic activity for sustainable carbon dioxide conversion into invaluable chemicals.

ExpoNano: A Strategy Based on Hyper-Cross-Linked Polymers Achieves Urinary Exposome Assessment for Biomonitoring.

Urinary analysis of exogenous and endogenous molecules constitutes an efficient, noninvasive approach to evaluate human health status. However, the exposome characterization of urinary molecules remains extremely challenging with current techniques. Herein, we develop an ExpoNano strategy based on hyper-cross-linked polymers (HCPs) to achieve ultrahigh-throughput measurement of exo/endogenous molecules in urine. The strategy includes a simple trapping-detrapping procedure (15 min) with HCPs in enzymatically treated urine, followed by mass spectrometer determination. Molecules that can be determined by ExpoNano have a wide range of molecular weight (75-837 Da) and Log Kow (octanol-water partition coefficient; -9.86 to 10.56). The HCPs can be repeatedly used five times without decreasing the trapping efficiency. Application of ExpoNano in a biomonitoring study revealed a total of 63 environmental chemicals detected in >50% of the urine pools collected from Chinese adults living in 13 cities, with a median concentration of 0.026-47 ng/mL, while nontargeted analysis detected an additional 243 exogenous molecules. Targeted and nontargeted analysis also detected 926 endogenous molecules in pooled urine. Collectively, the ExpoNano strategy demonstrates unique advantages over traditional urine analysis approaches, including a wide range of analytes, satisfactory trapping efficiency, high simplicity and reusability, and extremely reduced time demand and financial cost.

Exploring the inhibitory effect of WTaVCr high-entropy alloys on hydrogen retention: From dissolution, diffusion to desorption

Due to the excellent resistance to radiation damage, high-entropy alloys (HEAs) have been considered as important candidates for nuclear materials. However, to realize the great potential of HEAs in fusion energy, it is important to consider the hydrogen (H) behaviors, which remain to be elucidated. Here, we systematically investigate the dissolution, diffusion and desorption of H in equiatomic WTaVCr using the first-principles calculations. It is found that the H solution energy in WTaVCr is lower than that in pure W, which can be clarified by the H affinity of metallic elements and the available volume of interstitial sites. Accordingly, a possible diffusion path of interstitial H is selected, containing 26 metastable sites, and the corresponding energy barrier is 0.46 eV. Besides, the maximum trapping energy and accommodation number of H at a mono-vacancy in WTaVCr is only 0.30 eV and 3 ∼ 5 H, respectively, which is much lower than that in pure W (1.28 eV and 12 H). More importantly, because of the low trapping energy and moderate diffusion energy barrier, the desorption temperature of H from a mono-vacancy is lower than the room temperature, implying that vacancies are not efficient trapping centers for interstitial H atoms in WTaVCr. Therefore, although the equilibrium interstitial H concentration in WTaVCr is higher than that in pure W, H retention at high temperatures and H-induced blistering are suppressed due to the weak H-defect interactions. Our results will provide a good reference for understanding the H behaviors in HEAs.

Quantitatively Evaluating Interactions between Patient-Derived Organoids and Autologous Immune Cells by Microfluidic Chip.

The coculture of patient-derived tumor organoids (PDOs) and autologous immune cells has been considered as a useful ex vivo surrogate of in vivo tumor-immune environment. However, the immune interactions between PDOs and autologous immune cells, including immune-mediated killing behaviors and immune-related cytokine variations, have yet to be quantitatively evaluated. This study presents a microfluidic chip for quantifying interactions between PDOs and autologous immune cells (IOI-Chip). A baffle-well structure is designed to ensure efficient trapping, long-term coculturing, and in situ fluorescent observation of a limited amount of precious PDOS and autologous immune cells, while a microbeads-based immunofluorescence assay is designed to simultaneously quantify multiple kinds of immune-related cytokines in situ. The PDO apoptosis and 2 main immune-related cytokines, TNF-α and IFN-γ, are simultaneously quantified using samples from a lung cancer patient. This study provides, for the first time, a capability to quantify interactions between PDOs and autologous immune cells at 2 levels, the immune-mediated killing behavior, and multiple immune-related cytokines, laying the technical foundation of ex vivo assessment of patient immune response.

Biomimetic Fog Collector with Hybrid and Gradient Wettabilities.

Water scarcity is a global problem and collecting water from the air is a viable solution to this crisis. Inspired by Namib Desert beetle, leaf venation and spider silk, we designed an integrated biomimetic system with hybrid wettability and wettability gradient. The hybrid hydrophilic-hydrophobic wettability design that bionomics desert beetle's back can construct a three-dimensional topography with a water layer on the surface, expanding the contact area with the fog flow and thus improving the droplet trapping efficiency. The venation-like structure with wettability gradient not only provides a planned path for water transportation, but also accelerates water removal under the synergistic effect of gravity and wettability driving force, thus further improving the surface regeneration rate. The collector combines droplet capture, coalescence, transportation, separation, and storage capabilities, which provides new ideas for the design of future high-efficiency fog collectors.

Numerical simulation and in vitro experimental study of the hemodynamic performance of vena cava filters with helical forms

Inferior vena cava filter (IVCF) implantation is a common method of thrombus capture. By implanting a filter in the inferior vena cava (IVC), microemboli can be effectively blocked from entering the pulmonary circulation, thereby avoiding acute pulmonary embolism (PE). Inspired by the helical flow effect in the human arterial system, we propose a helical retrievable IVCF, which, due to the presence of a helical structure inducing a helical flow pattern of blood in the region near the IVCF, can effectively avoid the deposition of microemboli in the vicinity of the IVCF while promoting the cleavage of the captured thrombus clot. It also reduces the risk of IVCF dislodging and slipping in the vessel because its shape expands in the radial direction, allowing its distal end to fit closely to the IVC wall, and because its contact structure with the inner IVC wall is curved, increasing the contact area and reducing the risk of the vessel wall being punctured by the IVCF support structure. We used ANSYS 2023 software to conduct unidirectional fluid–structure coupling simulation of four different forms of IVCF, combined with microthrombus capture experiments in vitro, to explore the impact of these four forms of IVCF on blood flow patterns and to evaluate the risk of IVCF perforation and IVCF dislocation. It can be seen from the numerical simulation results that the helical structure does have the function of inducing blood flow to undergo helical flow dynamics, and the increase in wall shear stress (WSS) brought about by this function can improve the situation of thrombosis accumulation to a certain extent. Meanwhile, the placement of IVCF will change the flow state of blood flow and lead to the deformation of blood vessels. In in vitro experiments, we found that the density of the helical support rod is a key factor affecting the thrombus trapping efficiency, and in addition, the contact area between the IVCF and the vessel wall has a major influence on the risk of IVCF displacement.

Research on data analysis method of oscillating water column wave energy converters

Abstract Taking the floating oscillating water column central tube wave energy converters (OWC WECs) as the research goal, the Fourier transform (FFT), and the ensemble empirical mode decomposition method (EEMD) were used to statistically analyze the wave height, motion acceleration, velocity and displacement of the device in the physical model test from the perspective of a frequency domain. Through the Fourier transform, the energy spectrum of the incident wave and the motion of the WEC is obtained, and it is found that the peak frequency of the two is the same, that is, the period is 1.138s, but the peak energy of the former is slightly greater than that of the latter. Through the ensemble empirical mode decomposition method, the 1-8 intrinsic mode functions of the incident wave and the displacement of the device are obtained, which shows that the device efficiently captures the dominant frequency wave in the incident wave, that is, the wave height is 0.0628m, the period is 1.1s, and the motion displacement of the vertical direction obtained by the device is 0.0585mm, and the period is 1.1119s. At the same time, it absorbs low-frequency, long-period reflected waves in the pool. The analysis results of the two methods are highly consistent, and the OWC WEC shows good hydrodynamic performance, with efficient wave trapping ability and fast wave responsability. This paper’s research methods and results provide a basis for the later optimization of the device and a new idea for the data processing method of the WECs.

Perfect Off-Axis Optical Vortex Lattice

Optical vortex lattices (OVLs) with diverse modes show potential for a wide range of applications, such as high-capacity optical communications, optical tweezers, and optical measurements. However, vortices in typical regulated OVLs often exhibit irregular shapes, such as being narrow and elongated. The resulting increase in asymmetry negatively impacts the efficiency of particle trapping. Additionally, the vortex radii expand with an increase in topological charge (TC), limiting the TC value of the vortices and hindering their ability to fully utilize orbital angular momentum (OAM). Herein, we propose an alternative approach to custom OVLs using off-axis techniques combined with amplitude modulation. Amplitude modulation enables the precise generation of an OVL with perfect vortex properties, known as a perfect off-axis OVL. Further, the number of vortices in the perfect off-axis OVL, the off-axis distances, and the TC can be freely modulated while maintaining a circular mode. This unique OVL will promote new applications, such as the complex manipulation of multi-particle systems and optical communication based on OAM.

PCN-222/H3PW12O40/graphene oxide@cotton cloth with improved photocatalytic/photothermal properties for water decontamination

In this study, a novel visible-light-driven PCN-222/H3PW12O40/graphene oxide@cotton cloth (PCN-222/HPW/GO@Cot) photocatalytic platform was developed for efficient water sterilization and purification. PCN-222/HPW/GO ternary photocatalyst was prepared via one-pot solvothermal method, and anchored onto cotton cloth though catechol-amine reaction. By introducing HPW as the quasi-semiconductor co-catalyst and efficient electron trap, the photocatalytic activity of PCN-222 was boosted. Besides, the addition of GO further enhanced electron transfer capability and photothermal properties. PCN-222/HPW/GO@Cot exhibited significantly improved organic dye photodegradation and sterilization efficiencies compared to PCN-222 and PCN-222/HPW coated cotton cloths. It also maintained consistent organic dye removal efficiency over reuse cycles and retained high sterilization activity after repeated washings, indicating its remarkable durability and coating stability. The band positions and the enhanced photocatalytic/photothermal mechanisms were investigated in depth. This research suggests the great potential of PCN-222/HPW/GO@Cot photocatalytic platform for practical water purification and sterilization applications, and the potential to become multifunctional textiles.

Adjustable focusing property of circular Airyprime beam through Fourier space modulation.

Airyprime beams are known for their powerful autofocusing property, which are further enhanced by the introduction of a circular structure-circular Airyprime beam (CAPB). We derive an asymptotic expression of the CAPB in Fourier space (FS) and verify its accuracy by the numerical Fourier transform (FT) method. Through FS modulation on it, adjustable control of autofocusing property of the FS-modulated CAPB can be achieved, whose lower and upper limits can reach 8.7% reduction and 2.6 times enhancement compared to the unmodulated one. The experimental results agree well with the numerical analyses. Our findings offer promising possibilities for efficient particle trapping and enhancing free-space optical communication capabilities.

Maneuvering magic-sized transition metal chalcogenides nanoclusters for Solar-to-Hydrogen conversion

Magic-sized nanoclusters (MSCs) have recently deemed as a novel and crucial sector of nanomaterials on account of their large absorption coefficient for light harvesting, peculiar quantum confinement effect, and abundant active. Nevertheless, precise control of photoinduced charge carriers over MSCs has so far not yet been reported because of the ultra-short carrier lifetime and intrinsic instability of MSCs, which renders the complexity of MSCs photosystems with photoredox mechanism remaining blank. Herein, we for the first time conceptually demonstrate the grafting of amino-containing organic molecular onto the L-cysteine (L-Cys) ligand of CdSe@L-Cys MSCs as charge transport mediator, and the amino functional group acts as an efficient electron-withdrawing trap, which markedly boosts the charge separation and prolongs the charge lifetime of CdSe@L-Cys MSCs, resulting in the significantly improved photocatalytic hydrogen generation performances under visible light irradiation along with favorable stability. Our work will provide sparking ideas for fine tuning of photoinduced charge separation and transfer over transition metal chalcogenides MSCs photosystems for solar-to-hydrogen energy conversion.

Tailoring of bulk oxygen vacancies in BiVO4 photoanodes via crystallization dynamics engineering for boosted photoelectrochemical water oxidation

Oxygen vacancies (Ov) in metal oxides is of critical importance in photoelectrochemical water splitting due to its unique capability on modulating the carrier density and charge separation. A challenge remains however currently on generating bulk Ov in metal oxides since surface Ov faces awkward photochemical instability. We herein demonstrate a facile way of creating the bulk Ov in Mo:BiVO4 (MBVO) photoanodes simply from altering Bi/V in MBVO with non-stoichiometric ratio, which significantly modifies the crystallization dynamics of MBVO and tailors the amount of bulk Ov in MBVO. It is proposed that the bulk OV significantly increase the majority carrier density due to the additional photoexcitation of OV, and reduce the recombination constant (krec) due to the efficient trapping of excess holes in the stable deep-level inter-band Ov2+ states. It is further demonstrated that the tailored bulk OV leads to a 1.6-fold increased photocurrent density and 50 h operational stability at 1.23 VRHE, indicating the potentials for tailoring bulk Ov in photoanodes via crystallization dynamics engineering for viable photoelectrochemical water splitting.