In recent years, ozone (O3) pollution in many Chinese cities has worsened. Several cities have also experienced incidents where nocturnal O3 concentrations did not decrease as expected, and instead remained at high levels (above 50 ppb). However, there have been few detailed studies on the causes of these events. The present study used air quality and meteorological monitoring data, along with the Hybrid Single-Particle Lagrangian Integrated Trajectory model, to investigate the causes contributing to nocturnal O3 remaining at high values (NORHV) in Linfen City, a typical basin city in the Fenhe River Basin, characterized by severe O3 pollution. These events are influenced by the individual or combined impacts of mountain-valley breezes, along with vertical and horizontal transport of O3-rich air masses. In addition, the influencing mechanisms of three NORHV events were identified as: 1) the alternating effect of the descent of upper-level air masses enriched with O3, CO, and SO2 and downslope mountain breezes carrying the O3-rich air mass; 2) the interaction between the transport of polluted air masses across mountains and downslope mountain breezes on both sides of the two mountains in urban areas; and 3) the O3-rich air mass from high-altitude regions descended into the urban area following two LLJ events. These conclusions were supported by vertical distributions of O3 concentrations in the three cases simulated using the WRF-CMAQ model. In addition, the NORHV events resulted in higher initial O3 concentrations on the following day compared to normal days, exacerbating O3 pollution. The results of this study demonstrate the significant contributions of complex synergistic effects, such as mountain-valley breezes and vertical transport, to the occurrence of NORHV events in basin cities. These findings may be applicable to other basin cities around the world.
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