Annular Dark-field Transmission Electron Microscopy Research Articles

Dual-scale clusters enabling exceptional mechanical properties of a CoNiCr-based MP159 superalloy at 650 °C

Prior or early-stage precipitation products, e.g., GP zones and chemical short-range ordering, attract tons of interests recently due to their extremely small size and notable hardening effects. In this work in a commercial CoNiCr-based MP159 superalloy, we, for the first time, simultaneously introduced two kinds of these products, i.e., the atomic-scale L11 cluster, and the nano L12 cluster with 2.7 nm in size, by simply removing the standard annealing process and directly conducting the intermediate 650 °C tension. The ultra-dense co-existence of these dual-scale clusters generates over 200 MPa hardening effect at the specific 650 °C when compared to the standardly-annealed MP159 alloy that contains only larger (∼6.0 nm) L12 precipitates. High-angle annular dark field-transmission electron microscopy associated with atom probe tomography evidence that firstly, the atomic-scale cluster is of the L11 type, similar to the one observed in the NiCoV medium entropy alloy. And secondly, the composition of the nano L12 cluster is abnormally close to (Ni,Co)3Ti, whose equilibrium crystalline structure is otherwise D024. This likely leads to a high anti-phase boundary energy hence high shearing resistance for dislocations.

Phase and Composition Engineering of Self-Intercalated 2D Metallic Tantalum Sulfide for Second-Harmonic Generation.

Self-intercalation in two-dimensional (2D) materials is significant, as it offers a versatile approach to modify material properties, enabling the creation of interesting functional materials, which is essential in advancing applications across various fields. Here, we define ic-2D materials as covalently bonded compounds that result from the self-intercalation of a metal into layered 2D compounds. However, precisely growing ic-2D materials with controllable phases and self-intercalation concentrations to fully exploit the applications in the ic-2D family remains a great challenge. Herein, we demonstrated the controlled synthesis of self-intercalated H-phase and T-phase Ta1+xS2 via a temperature-driven chemical vapor deposition (CVD) approach with a viable intercalation concentration spanning from 10% to 58%. Atomic-resolution scanning transmission electron microscopy-annular dark field imaging demonstrated that the self-intercalated Ta atoms occupy the octahedral vacancies located at the van der Waals gap. The nonperiodic Ta atoms break the centrosymmetry structure and Fermi surface properties of intrinsic TaS2. Therefore, ic-2D T-phase Ta1+xS2 consistently exhibit a spontaneous nonlinear optical (NLO) effect regardless of the sample thickness and self-intercalation concentrations. Our results propose an approach to activate the NLO response of centrosymmetric 2D materials, achieving the modulation of a wide range of optoelectronic properties via nonperiodic self-intercalation in the ic-2D family.

Pd sub-nanolayer on Au core for enhanced catalytic hydrogenation reduction of oxyanions pollutants: Synergistic effect of Pd and Au

Oxyanion pollutants in industrial wasterwater, such as (Cr(VI)), BrO3− (Br(V)) and SeO32− (Se(IV)) have detrimental or toxic effects on individual health when their concentrations accumulated to a certain level. The conversion of these oxyanions into harmless/industrial-valuable products or removal from wastewater is of significance. Herein, we designed Pd sub-nanolayer on Au core catalysts supported on Al2O3 (sub-Pd-Au/Al2O3) for highly effective catalytic hydrogenation reduction of oxyanions under ambient conditions. The sub-Pd(0.049)-Au(0.927)/Al2O3 catalyst exhibited the highest catalytic activity and TOF value for Cr(VI), Br(V) and Se(IV) reduction, respectively, by optimizing the Pd loading amount. The synergistic effect between Pd sub-nanolayer and Au core enhanced catalytic activity by regulating the Pd dispersion and site property, according to thorough characterizations that included high-angle annular dark-field transmission electron microscopy (HAADF-TEM) image, in-situ CO-IR adsorption, CO chemisorption, and X-ray photoelectron spectroscopy (XPS). This work might provide some new lights on design of highly efficient catalysts for the elimination of oxyanion pollutants.

CO Methanation over NiO-CeO2 Mixed-Oxide Catalysts Prepared by a Modified Co-Precipitation Method: Effect of the Preparation pH on the Catalytic Performance.

In this study, a series of NiO-CeO2 mixed-oxide catalysts have been prepared by a modified co-precipitation method similar to the one used for the synthesis of hydrotalcites. The syntheses were carried out at different pH values (8, 9 and 10), in order to determine the influence of this synthetic variable on the properties of the obtained materials. These materials were characterized by using different techniques, such as TGA, XRD, ICP, N2 adsorption-desorption isotherms, H2 temperature-programmed reduction (H2-TPR), and electron microscopy, including high-angle annular dark-field transmission electron microscopy (HAADF-TEM) and EDS. The characterization results revealed the influence of the preparation method, in general, and of the pH value, in particular, on the textural properties of the oxides, as well as on the dispersion of the Ni species. The catalyst prepared at a higher pH value (pH = 10) was the one that exhibited better behavior in the CO methanation reaction (almost 100% CO conversion at 235 °C), which is attributed to the achievement, under these synthetic conditions, of a combination of properties (metal dispersion, specific surface area, porosity) more suitable for the reaction.

SPION nanoparticles for delivery of dopaminergic isoquinoline and benzazepine derivatives

Superparamagnetic iron nanoparticles (SPIONs) have become one of the most useful colloidal systems in nanomedicine. We report here the preparation of new hybrid core@shell systems based on SPION nanoparticles coated with a SiO2 shell (SPION@SiO2) and functionalized with carboxyl groups (SPION@SiO2-COOH). A series of new N-alkylamino- and N-alkylamido-terminated 1-phenyl- tetrahydroisoquinolines (THIQs) and 3-tetrahydrobenzazepines (THBs) derivatives presenting -SMe and -Cl groups, respectively, with potential dopaminergic activity, are synthesized and incorporated to the hybrid system. We include the synthetic details for THIQs and THBs derivatives preparation and investigate the influence of the terminal-functional group as well as the number of carbon atoms linked to THIQ and THB molecules during the coupling to the SPION@SiO2-COOH. Nuclear magnetic resonance (NMR) and electron ionization mass spectrometry (EI-MS) are used to characterize the synthesized THIQs and THBs. High-angle annular dark-field transmission electron microscopy (HAADF-TEM), energy dispersive X-ray transmission electron microscopy (EDX-TEM), and proton high-resolution magic angle spinning NMR spectroscopy1H HRMAS-NMR) are used to confirm the presence of THB and THIQ molecules onto the surface of the nanoparticles. The hybrid SPION@SiO2-THIQ and THB systems show significant activity toward the D2 receptor, reaching Ki values of about 20 nM, thus having potential application in the treatment of central nervous system (CNS) diseases.

Synthesis, physicochemical, and antimicrobial characteristics of novel poly(urethane-siloxane) network/silver ferrite nanocomposites

In situ polymerization was used to produce novel AgFeO2@PEG/polyurethane network nanocomposites (NP-PUs) with 30–60 wt% of soft poly(dimethylsiloxane) segments in polyurethane (PU), containing 1 wt% of PEG-coated AgFeO2 nanoparticles, AgFeO2@PEG. Physicochemical properties and in vitro biological activity of the NP-PUs were systematically evaluated in terms of AgFeO2@PEG (NP) addition and soft segment content. High-angle annular dark-field transmission electron microscopy showed that the nanoparticles were generally uniformly distributed in the PU matrix. Increased soft segment content caused significantly increased intensity of the broad, amorphous X-ray diffraction peaks of crystalline AgFeO2, probably because the chemical composition of PU affected the distribution of nanoparticles. The Young modulus, hardness, and plasticity of the NP-PUs were higher than for pure PU and increased with decreasing soft segment content. Decreased soft segment content induced higher microphase separation, increased hydrophilicity and swelling ability, but decreased cross-linking density. Additionally, NP-PUs had higher glass transition temperatures, improved thermal stability, and enhanced nanomechanical performance over pure PU. The NP-PUs demonstrated good selective inhibition of Candida albicans and Candida parapsilosis (30–55%) and no pronounced cytotoxicity to MRC5 human lung fibroblasts. Among the investigated AgFeO2@PEG/PUs, the best antifungal activity was shown by composites with 30 and 40 wt% soft segments. Consequently, the novel AgFeO2@PEG/polyurethane network nanocomposites could be further optimized to be used as biocompatible surfaces that also prevent formation of fungal biofilms.Graphical abstract

Anchoring Copper Single Atoms on Porous Boron Nitride Nanofiber to Boost Selective Reduction of Nitroaromatics.

Single-atom catalysts have received widespread attention for their fascinating performance in terms of metal atom efficiency as well as their special catalysis mechanisms compared to conventional catalysts. Here, we prepared a high-performance catalyst of single-Cu-atom-decorated boron nitride nanofibers (BNNF-Cu) via a facile calcination method. The as-prepared catalyst shows high catalytic activity and good stability for converting different nitro compounds into their corresponding amines both with and without photoexcitation. By combined studies of synchrotron radiation analysis, high-resolution high-angle annular dark-field transmission electron microscopy studies, and DFT calculations, dispersion and coordination of Cu atoms as well as their catalytic mechanisms are explored. The BNNF-Cu catalyst is found to have a record high turnover frequency compared to previously reported non-precious-metal-based catalysts. While the performance of the BNNF-Cu catalyst is only of the middle range level among the state-of-the-art precious-metal-based catalysts, due to the much lower cost of the BNNF-Cu catalyst, its cost efficiency is the highest among these catalysts. This work provides a choice of support material that can promote the development of single-atom catalysts.

Phase-Controlled Synthesis of Monolayer W1- x Rex S2 Alloy with Improved Photoresponse Performance.

Tuning bandgap and phases in the ternary 2D transition metal dichalcogenides (TMDs) alloys has opened up unexpected opportunities to engineer optoelectronic properties and explore potential applications. In this work, a salt-assisted chemical deposition vapor (CVD) growth strategy is reported for the creation of high-quality monolayer W1- x Rex S2 alloys to fulfill a readily phase control from 1H to DT by changing the ratio of Re and W precursors. The structures and chemical compositions of doping alloys are confirmed by combining atomic resolution scanning transmission electron microscopy-annular dark field imaging with energy dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy, matching well with the calculated results. The field-effect transistors (FETs) devices fabricated based on 1H-W0.9 Re0.1 S2 monolayer exhibit a n-type semiconducting behavior with the mobility of 0.4 cm2 V-1 s-1 . More importantly, the FETs show high-performance responsivity with a value of 17 µA W-1 in air, which is superior to that of monolayer CVD-grown WS2 . This work paves the way toward synthesizing monolayer ternary alloys with controlled phases for potential optoelectronic applications.

Interstitial Boron Atoms in the Palladium Lattice of an Industrial Type of Nanocatalyst: Properties and Structural Modifications.

It is well-established that the inclusion of small atomic species such as boron (B) in powder metal catalysts can subtly modify catalytic properties, and the associated changes in the metal lattice imply that the B atoms are located in the interstitial sites. However, there is no compelling evidence for the occurrence of interstitial B atoms, and there is a concomitant lack of detailed structural information describing the nature of this occupancy and its effects on the metal host. In this work, we use an innovative combination of high-resolution 11B magic-angle-spinning (MAS) and 105Pd static solid-state NMR nuclear magnetic resonance (NMR), synchrotron X-ray diffraction (SXRD), in situ X-ray pair distribution function (XPDF), scanning transmission electron microscopy-annular dark field imaging (STEM-ADF), electron ptychography, and electron energy loss spectroscopy (EELS) to investigate the B atom positions, properties, and structural modifications to the palladium lattice of an industrial type interstitial boron doped palladium nanoparticle catalyst system (Pd-intB/C NPs). In this study, we report that upon B incorporation into the Pd lattice, the overall face centered cubic (FCC) lattice is maintained; however, short-range disorder is introduced. The 105Pd static solid-state NMR illustrates how different types (and levels) of structural strain and disorder are introduced in the nanoparticle history. These structural distortions can lead to the appearance of small amounts of local hexagonal close packed (HCP) structured material in localized regions. The short-range lattice tailoring of the Pd framework to accommodate interstitial B dopants in the octahedral sites of the distorted FCC structure can be imaged by electron ptychography. This study describes new toolsets that enable the characterization of industrial metal nanocatalysts across length scales from macro- to microanalysis, which gives important guidance to the structure-activity relationship of the system.

Phase-Controlled Synthesis of Monolayer Ternary Telluride with a Random Local Displacement of Tellurium Atoms.

Alloying 2D transition metal dichalcogenides has opened up new opportunities for bandgap engineering and phase control. Developing a simple and scalable synthetic route is therefore essential to explore the full potential of these alloys with tunable optical and electrical properties. Here, the direct synthesis of monolayer WTe2 x S2(1- x ) alloys via one-step chemical vapor deposition (CVD) is demonstrated. The WTe2 x S2(1- x ) alloys exhibit two distinct phases (1H semiconducting and 1T ' metallic) under different chemical compositions, which can be controlled by the ratio of chalcogen precursors as well as the H2 flow rate. Atomic-resolution scanning transmission electron microscopy-annular dark field (STEM-ADF) imaging reveals the atomic structure of as-formed 1H and 1T ' alloys. Unlike the commonly observed displacement of metal atoms in the 1T ' phase, local displacement of Te atoms from original 1H lattice sites is discovered by combined STEM-ADF imaging and ab initio molecular dynamics calculations. The structure distortion provides new insights into the structure formation of alloys. This generic synthetic approach is also demonstrated for other telluride-based ternary monolayers such as WTe2 x Se2(1- x ) single crystals.

Spatially Resolved Chemical Analysis of Geobacter sulfurreducens Cell Surface.

Geobacter sulfurreducens is of interest for the highest efficiency of power generation and extremely long extracellular electron transfer (EET) between the bacterium and electrodes. Despite more than 15 years of intensive molecular biological research, there is still no clear answer which molecules are responsible for these processes. In the present work, we look at the problem from another (atomic) perspective and identify the location and shape of the compounds that are known to be conductive, particularly those containing Fe atoms. By using highly sophisticated energy dispersive X-ray spectroscopy combined with high-angle annular dark-field transmission electron microscopy enabling detection, identification, and localization of chemical compounds on the surface at nearly atomic spatial resolution, we analyze Fe spatial distribution within the G. sulfurreducens community. We discover the presence of small Fe-containing particles on the surface of the bacterium cells. The size of the particles (diameter 5.6 nm) is highly reproducible and comparable with the size of a single protein. The particles cover about 2% of the cell surface, which is similar to that expected for molecular conductors responsible for electron transfer through the bacterium cell wall. We find that G. sulfurreducens filaments ("bacterial molecular wires") also contain Fe atoms in their bundles. We observe that the bacterium enable changing the distance between the Fe-containing bundles in the filaments from separated to attached (the latter is needed for the efficient electron transfer between the Fe-containing particles), depending on the bacterium metabolic activity and attachment to extracellular substrates. These results are consistent with the recently published research about the role of Fe atoms in protein molecular conductance ( Phys. Chem. Chem. Phys. , 2018 , 20 , 14072 - 14081 ) and show what type of Fe-containing particles are involved in the bacterial extracellular communication. They can be used for the design and construction of artificial biomolecular wires and bioinorganic interfaces.

Synthesis of Ag-loaded Sb2WO6 microsphere with enhanced photocatalytic ability for organic dyes degradations under different light irradiations

In this study, the Ag-loaded Sb2WO6 photocatalysts have been successfully synthesized by a facile solvothermal method. The as-prepared Ag-loaded Sb2WO6 microspheres were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), high-resolution transmission electron microscopy (HRTEM), high angle annular dark-field transmission electron microscopy (HAADF-STEM), energy-dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), UV–Vis diffuse reflectance spectroscopy (UV-DRS) and the Brunauer–Emmett–Teller (BET) method. Results indicate that metallic Ag was successfully grown on Sb2WO6. The photocatalytic activities of the Ag-Sb2WO6 photocatalysts were evaluated by degradations of MO, RhB and MB under UV light and visible light. It is found that the photocatalytic activity is excellent and superior after the decoration of the metallic Ag nanoparticles. A possible photocatalytic mechanism was proposed.

Differentiating Polymorphs in Molybdenum Disulfide via Electron Microscopy.

The presence of rich polymorphs and stacking polytypes in molybdenum disulfide (MoS2 ) endows it with a diverse range of electrical, catalytic, optical, and magnetic properties. This has stimulated a lot of interest in the unique properties associated with each polymorph. Most techniques used for polymorph identification in MoS2 are macroscopic techniques that sample averaged properties due to their limited spatial resolution. A reliable way of differentiating the atomic structure of different polymorphs is needed in order to understand their growth dynamics and establish the correlation between structure and properties. Herein, the use of electron microscopy for identifying the atomic structures of several important polymorphs in MoS2 , some of which are the subjects of mistaken assignment in the literature, is discussed. In particular, scanning transmission electron microscopy-annular dark field imaging has emerged as the most effective and reliable approach for identifying the different phases in MoS2 and other 2D materials because its images can be directly correlated to the atomic structures. Examples of the identification of polymorphs grown under different conditions in molecular beam epitaxy or chemical vapor deposition, for example, 3R, 1T, 1T'-phases, and 1T'-edges, are presented, including their atomic structures, fascinating properties, growth methods, and corresponding thermodynamic stabilities.

Heterostructured palladium-platinum core-shell nanocubes for use in a nonenzymatic amperometric glucose sensor

Heterostructured Pd-Pt core-shell nanocubes (NCs) are shown to display catalytic activity in the glucose oxidation reaction (GOR), and were employed as non-enzymatic glucose sensors in 0.1 M NaOH(aq) solution. High-angle annular dark-field transmission electron microscopy and line-scanned energy-dispersive X-ray spectroscopy analyses show that the growth of the Pt shell initially occurs via a layer-by-layer mode, but then switches to the island mode. The voids formed between Pt islands contribute to an increase in the electrochemically active surface area. Based on the same catalyst loading mass, the results of Tafel measurements and cyclic voltammetry indicate that the heterostructured Pd-Pt core-shell NCs (typically 32.7 nm in size) display an exchange current density of 1.81 × 10−2 mA cm−2 for chemisorption and dehydrogenation of glucose at the onset of the GOR, and an activity of 0.322 mA in the subsequent reaction that causes the formation gluconolactone on the Pt-OH surface. These values are larger than those observed for 7.5-nm Pt nanoparticles (1.51 × 10−2 mA cm−2 and 0.187 mA cm-2, respectively). Additionally, the core-shell NCs exhibit a sensitivity of 170 μA∙mM−1∙cm−2 under GOR catalysis conditions, require a potential as low as −0.05 V (vs. Ag/AgCl) which favors selectivity, and have a linear response range that extends from 0.3 to 6.8 mM. The potential of these NCs for use in non-enzymatic sensing of glucose is further exemplified by a successful analysis of spiked calf serum. In our perception, this sensor also has a large potential in glucose fuel cells.

Synergy between Printex nano-carbons and silver nanoparticles for sensitive estimation of antioxidant activity

We report on the synthesis, characterization and applications of a Printex L6 carbon-silver hybrid nanomaterial (PC-Ag), which was obtained using a polyol method. In addition, we also highlight the use of Printex L6 nano-carbon as a much cheaper alternative to the use of carbon nanotubes and graphene. The silver nanoparticles (AgNP) were prepared directly on the surface of the Printex 6L carbon “nanocarbon” material using ethylene glycol as the reducing agent. The hybrid nanomaterial was characterized by High-angle annular dark-field transmission electron microscopy (HAADF-TEM), energy–dispersive X-ray spectroscopy (EDX), selected area electron diffraction (SAED), Raman spectroscopy and cyclic voltammetry. Optimized electrocatalytic activity on glassy carbon electrode was reached for the architecture GC/PC-Ag, the silver nanoparticles with size ranging between 1 and 2 nm were well–distributed throughout the hybrid material. The synergy between PC nano-carbons and AgNPs was verified by detection of gallic acid (GA) at a low applied potential (0.091 V vs. Ag/AgCl). GA detection was performed in a concentration range between 5.0 × 10−7 and 8.5 × 10−6 mol L−1, with a detection limit of 6.63 × 10−8 mol L−1 (66.3 nmol L−1), which is considerably lower than similar devices. The approach for fabricating the reproducible GC/PC-Ag electrodes is entirely generic and may be explored for other types of (bio)sensors and devices.

Fluidized bed coupled rotary reactor for nanoparticles coating via atomic layer deposition.

A fluidized bed coupled rotary reactor has been designed for coating on nanoparticles (NPs) via atomic layer deposition. It consists of five major parts: reaction chamber, dosing and fluidizing section, pumping section, rotary manipulator components, as well as a double-layer cartridge for the storage of particles. In the deposition procedure, continuous fluidization of particles enlarges and homogenizes the void fraction in the particle bed, while rotation enhances the gas-solid interactions to stabilize fluidization. The particle cartridge presented here enables both the fluidization and rotation acting on the particle bed, demonstrated by the analysis of pressure drop. Moreover, enlarged interstitials and intense gas-solid contact under sufficient fluidizing velocity and proper rotation speed facilitate the precursor delivery throughout the particle bed and consequently provide a fast coating process. The cartridge can ensure precursors flowing through the particle bed exclusively to achieve high utilization without static exposure operation. By optimizing superficial gas velocities and rotation speeds, minimum pulse time for complete coating has been shortened in experiment, and in situ mass spectrometry showed the precursor usage can reach 90%. Inductively coupled plasma-optical emission spectroscopy results suggested a saturated growth of nanoscale Al2O3 films on spherical SiO2 NPs. Finally, the uniformity and composition of the shells were characterized by high angle annular dark field-transmission electron microscopy and energy dispersive X-ray spectroscopy.

Randomly oriented twin domains in electrodeposited silver dendrites

Silver dendrites were prepared by electrochemical deposition. The structures of Ag dendrites, the type of twins and their distribution were investigated by scanning electron microscopy (SEM), Z-contrast high angle annular dark field transmission electron microscopy (HAADF), and crystallografically sensitive orientation imaging microscopy (OIM). The results revealed that silver dendrites are characterized by the presence of randomly distributed 180? rotational twin domains. The broad surface of dendrites was of the {111} type. Growth directions of the main dendrite stem and all branches were of <112> type.

Enhanced methanol oxidation activity of Au@Pd nanoparticles supported on MWCNTs functionalized by MB under ultraviolet irradiation

A successful approach to assemble Au core Pd shell (Au@Pd) nanoparticles on the surface of multi-walled carbon nanotubes functionalized by methylene blue (MB) (Au@Pd/fuv-MWCNTs) was reported. In this method, MWCNTs were functionalized under ultraviolet irradiation. UV–Vis analysis and high-angle annular dark-field transmission electron microscope (HAADF-TEM) image prove that core–shell structure of Au@Pd nanoparticles forms. TEM results indicate that Au@Pd nanoparticles (~5.2 nm) are well-dispersed on the surface of fuv-MWCNTs. X-ray photoelectron spectroscopy (XPS) reveals that ultraviolet irradiation can promote the interaction between Au@Pd nanoparticles and the functional groups on the surface of MWCNTs. Cyclic voltammograms (CV), chronoamperograms (CA), and electrochemical impedance spectroscopy (EIS) results demonstrate that the Au@Pd/fuv-MWCNTs catalysts show excellent electrocatalytic performance for methanol oxidation in alkaline media. The catalytic activity of the Au@Pd/fuv-MWCNTs is ~2 times higher than that of the commercial Pd/C catalysts. This is mostly attributed to that ultraviolet irradiation can make the moieties of MB provide a uniform surface with active and anchoring sites, and improves the functional effect of MB on the surface of MWCNTs. Especially, ultraviolet irradiation modifies electronic structure of Pd and is beneficial for the enhancement of catalytic activity.

Core/Shell Colloidal Semiconductor Nanoplatelets

We have recently synthesized atomically flat semiconductor colloidal nanoplatelets with quasi 2D geometry. Here, we show that core/shell nanoplatelets can be obtained with a 2D geometry that is conserved. The epitaxial growth of the shell semiconductor is performed at room temperature. We report the detailed synthesis of CdSe/CdS and CdSe/CdZnS structures with different shell thicknesses. The shell growth is characterized both spectroscopically and structurally. In particular, the core/shell structure appears very clearly on high-resolution, high-angle annular dark-field transmission electron microscope images, thanks to the difference of atomic density between the core and the shell. When the nanoplatelets stand on their edge, we can precisely count the number of atomic planes forming the core and the shell. This provides a direct measurement, with atomic precision, of the core nanoplatelets thickness. The constraints exerted by the shell growth on the core is analyzed using global phase analysis. The core/shell nanoplatelets we obtained have narrow emission spectra with full-width at half-maximum close to 20 nm, and quantum yield that can reach 60%.

The cis-bis(decanoate)tin phthalocyanine/DPPC film at the air/water interface

Films made of cis-bis-decanoate-tinIV phthalocyanine (PcSn10) and racemic dipalmitoylphosphatidylcholine (DPPC) are studied with compression isotherms and Brewster angle microscopy (BAM) at the air/water interface. Films enriched in PcSn10 present phase separation elliptical-shaped domains. These domains present optical anisotropy and molecular order. They are enriched in PcSn10, and the film outside these domains is enriched in DPPC, as shown in by high-angle annular dark-field transmission electron microscopy on Langmuir–Blodgett (LB) transferred films. Film collapse area and atomic force microscopy images of LB transferred films on mica indicate that the films are actually multilayers. A computational survey was performed to determine how the PcSn10 molecules prefer to self-assemble, in films basically made of PcSn10. The relative energetic stability for several dimeric assemblies was obtained, and a crystal model of the film was developed through packing and repeating the PcSn10 molecules, along the crystallographic directions of the unit cell. Our results contribute to understanding the strong interaction between PcSn10 and DPPC at the air/water interface, where even small quantities of DPPC (∼1–2%) can modify the film in an important way.