Transition Layer Research Articles

Numerical investigation on effect of non-parallelism on natural transition in boundary layers around underwater axisymmetric bodies

For both fluid mechanics and practical engineering problems, it is important to study the effect of non-parallelism on the natural transition in boundary layers around underwater axisymmetric bodies. This paper develops the method of harmonic linearized Navier–Stokes (HLNS) equations for such boundary layers. The method can be used to study the evolution of small disturbances considering the non-parallelism of the basic flow. Based on the results of the HLNS equations, the transition positions of the boundary layers are predicted by the eN method. Because traditional linear stability theory (LST) neglects non-parallelism, the difference between the results using the HLNS method and those given by LST represents the effects of non-parallelism. Numerical calculations are performed for five classical forebody shapes, and the effect of non-parallelism is identified. (i) At each streamwise location, non-parallelism suppresses low-frequency disturbances while promoting high-frequency ones. The influence on high-frequency disturbances is more obvious. (ii) The effect of non-parallelism on the neutral curve focuses on the region near the critical instability position. Non-parallelism slightly delays the critical instability position for most forebody shapes and pushes the unstable zone toward the high-frequency direction while broadening its frequency bandwidth. (iii) The streamwise range at each growth-rate level is widened, implying that non-parallelism destabilizes the boundary layers. (iv) The transition occurs earlier, indicating that non-parallelism promotes the transition. (v) Non-parallelism shifts the dangerous frequency band toward the high-frequency direction. (vi) Non-parallelism enhances the wall pressure fluctuations (WPF) in the unstable laminar zone.

A novel PDA/POSS transition layer on the surface of UHMWPE fibers by co-depositing to improve the mechanical properties of composites

A novel PDA/POSS transition layer on the surface of UHMWPE fibers by co-depositing to improve the mechanical properties of composites

Using contrasts in horizontal P-wave reflectivity to map the base of the continental lithosphere: Results for the central and eastern U.S.

Vertical-incidence seismic reflection profiles generated from global phases for 16 earthquakes recorded by stations of the Transportable Array (TA) show distinctive patterns of P-wave reflectivity in the uppermost mantle beneath the central and eastern United States. The overall distribution of reflections identified objectively using the sign test statistic applied to bootstrapped stacks is consistent with a westward increase in depth of the lithosphere-asthenosphere boundary (LAB) from roughly 110 to 250 km that is marked within the lower lithosphere by piecewise continuous segments of elevated horizontal P-wave reflectivity. For some profiles, the onsets of zones of increased reflectivity closely match depths corresponding to the maximum negative S-wave velocity gradients found by surface-wave tomography, suggesting that P-wave reflectivity can be used to help characterize properties of the lower lithosphere. We suggest that the vertical change in horizontal reflectivity straddles the lithosphere-asthenosphere transition, encompassing a broad zone of layering caused by increased strain in the lower lithosphere as well as drag-induced flow in the asthenosphere. Some of the lines also show waveforms that fall within the depth range of arrivals identified as midlithospheric discontinuities (MLDs) in overlapping Sp receiver-function profiles. The reflection waveforms observed in the TA lines are mostly multicyclic with a mix of polarities indicating a layered transition, consistent with previous observations and model studies that show the breakup of single Sp waveforms into a series of less prominent, shorter-period P-wave reflections as the dominant frequency of incident energy is increased.

P(MMA-GMA-AM-St) as transition layer for constructing GO@pPTFE core-shell nanoparticles as hydro-based lubricant additives towards excellent friction reduction and wear resistance

P(MMA-GMA-AM-St) as transition layer for constructing GO@pPTFE core-shell nanoparticles as hydro-based lubricant additives towards excellent friction reduction and wear resistance

Enhanced plasticization resistance of hollow fiber membranes via metal ion coordination for advanced helium recovery

Plasticization can significantly impair the gas separation performance of gas separation membranes, especially for hollow fiber membranes (HFMs) with ultrathin skin layer. While conventional thermal crosslinking is an effective method to address this issue, it often leads to the transition layer collapse in HFMs, resulting in a significant decrease in gas permeance. Herein, we fabricate polyimide-cerium (PI-Ce) complex HFMs using a carboxylic group-containing 6FDA-mPDA0.65-DABA0.3-TFMB0.05 copolyimide through metal ion coordination to achieve plasticization-resistance helium recovery from natural gas. We optimized dope compositions and spinning conditions to produce defect-free hollow fiber membranes with a skin layer as thin as 300 nm. The coordination between carboxyl groups and cerium ions was characterized using Fourier Transform Infrared Spectroscopy (FTIR) and Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy. The polymer-metal coordinated membranes exhibited enhanced gas selectivities compared to the pristine HFMs due to the tailored microporosity achieved through polymer-metal coordination. Furthermore, the PI-Ce HFMs demonstrated only a 10.8% decline in mixed-gas He/CH4 selectivity, which is significantly lower than the 55.4% decline observed in pristine HFMs when exposed to CO2-containing feed pressures below 400 PSIA. Molecular dynamics simulations confirmed that coordination confined molecular chain swelling, thereby suppressing plasticization caused by CO2. The exceptional plasticization resistance of the PI-Ce complex HFMs provides a novel strategy for recovering helium from aggressive natural gas environments.

Numerical investigation of turbulent flow over a randomly packed sediment bed using a variable porosity continuum model

A large eddy simulation (LES) is performed for a turbulent open channel flow over a porous sediment bed at permeability Reynolds number of ReK∼2.56 (Reτ = 270) representative of aquatic systems. A continuum approach based on the upscaled, volume-averaged Navier−Stokes (VaNS) equations is used by defining smoothly varying porosity across the sediment water interface (SWI) and modeling the drag force in the porous bed using a modified Ergun equation with Forchheimer corrections for inertial terms. The results from the continuum approach are compared with a pore-resolved direct numerical simulation (PR-DNS) in which turbulent flow over a randomly packed sediment bed of monodispersed particles is investigated [Karra et al.,J. Fluid Mech. 971, A23 (2023)] A spatially varying porosity profile generated from the pore-resolved DNS is used in the continuum approach. Mean flow, Reynolds stress statistics, and net momentum exchange between the freestream and the porous bed are compared between the two studies, showing reasonably good agreement. Small deviations within the transitional region between the sediment bed and the freestream as compared to the PR-DNS results are attributed to the local protrusions of particles in a randomly packed bed that are absent in the continuum approach but are present in the PR-DNS. A better representation of the effective permeability in the top transition layer that accounts for roughness effect of exposed particles is necessary. The continuum approach significantly reduces the computational cost, thereby making it suitable to study hyporheic exchange of mass and momentum in large scale aquatic domains with combined influence of bedform and bed roughness.

Enhancing strength and ductility synergy through heterogeneous laminated structure design in high-entropy alloys

Heterogeneous laminated structure (HLS) design offers new opportunities to enhance the mechanical performance of high-entropy alloys (HEAs) through synergistic effects from heterogeneity. However, it remains challenging to introduce the HLS into HEAs via severe plastic deformation due to their strong work-hardening capacity. In this study, a specially designed multi-level HLS, characterized by alternatively stacked micro-grained soft CoCrFeNi layers and nanostructured ultra-hard Al0.3CoCrFeNi layers containing a three-phase microstructure (composed of nanograined face-centered cubic matrix, (Al, Ni)-rich B2 precipitates, and Cr-rich σ precipitates), is controllably introduced into FCC HEAs via a conventional thermo–mechanical processing involving hot-pressing, cold-rolling, and annealing. Meanwhile, thermo–mechanical processing induces Al element diffusion across the layer interface, resulting in the formation of an interfacial transition layer and the establishment of a strong interface bonding between the neighboring CoCrFeNi and Al0.3CoCrFeNi layers. As a result, the multi-level HLSed CoCrFeNi/Al0.3CoCrFeNi composite exhibits a yield strength as high as 1127±25.4 MPa while maintaining a large fracture elongation (up to (26.3±2.4)%). Such an excellent strength–ductility synergy surpasses that of most previously reported high-performance monolithic bulk CoCrFeNi and Al0.3CoCrFeNi HEAs prepared through careful chemical composition optimization and/or thermo–mechanical processing. Strong hetero-deformation induced strengthening benefited from the apparent microstructural/microhardness difference and the strong interface bonding between the neighbouring CoCrFeNi and Al0.3CoCrFeNi layers, together with simultaneous activation of multiple strain hardening mechanisms containing mechanical twinning, stacking faults and precipitation strengthening, is responsible for the excellent strength–ductility combination. This multi-level HLS and its fabrication strategy provide an enlightening way to develop strong and ductile HEAs and can also be applied to high-performance designs of other metallic materials.

Study on Acoustic Variability Affected by Upper Ocean Dynamics in South Eastern Arabian Sea

AbstractThe influence of upper ocean dynamics on the acoustic field in the South Eastern Arabian Sea (SEAS) is studied using in situ oceanographic/acoustic measurements from a moored buoy, along with satellite‐derived and climatological data sets. Upper‐ocean variability at the site is quantified using Mixed Layer Depth (MLD), Isothermal Layer Depth (ILD), Barrier Layer Thickness (BLT), Maximum Spice Depth (MSD), and Sonic Layer Depth (SLD), along with surface variability factors such as Sea Surface Temperature, Sea Surface Salinity, Spice, and Sea Level Anomaly. The mixed layer acoustic duct (MLAD) varies from 2 to 100 m, with BLT varying from 5 to 99 m, and a mean SLD of 43 m. A thick transition layer connects the mixed layer with the thermocline during winter. The observations reveal that maximum SLD, MSD, and BLT occurred during January–March. Unlike other seasons when SLD follows MLD, winter SLD is influenced by BLT, suggesting strong salinity stratification due to low‐salinity water intrusion from the Bay of Bengal by East India Coastal Current. During these months, the SLD varies from 80 to 100 m, with the corresponding minimum cut‐off frequency varying from 300 to 200 Hz. Results are correlated with estimated Sound Pressure Level (SPL) from Ambient Noise Measurements during November 2018 to November 2019. SPL variation follows SLD for low and mid‐frequencies, with the highest SPL noted during January‐February. Acoustic propagation simulations at 250 and 1,000 Hz revealed features like acoustic duct leakage and channeling, indicating energy transfers between the surface acoustic duct and deeper layers.

Effect of heat input on the microstructure and performance of dissimilar welded joint between Q345B low-alloy steel and 2205 duplex stainless steel

Q345B/2205 dissimilar steel multi-layer multi-pass welded joints were prepared using gas metal arc welding (GMAW). The effects of heat inputs on the microstructures and properties of welded joints were studied. The morphology and composition distribution of Q345B base metal near the fusion line were investigated. The results showed that the welded joints under different heat inputs were all present “carbon depleted zone” and “carburized zones” on both sides of the Q345B base metal and transition layer interface. The microstructure of the “carburized zones” was composed of martensite phase and granular bainite phase. It was found that only the welded joints with heat inputs of 1.765 kJ/mm and 2.860 kJ/mm met the usage requirements. The corrosion behavior and characteristics of the welded joint with a heat input of 1.765 kJ/mm in a 3.5 wt % NaCl solution were investigated intensively. During the soaked process of 14 days, the total impedance value of the welded joint showed first increasing and then decreasing. The maximum value of 8.7 kΩ cm2 was obtained on the 5th day. As the soaked time increased, the corrosion products of the welded joint underwent the formation, thickening, cracking and detachment, which was the main reason of the change in the corrosion resistance. The research results of this article have significant implications for the application of low-alloy steel and stainless steel welded joints in engineering.

Achieving strength-ductility synergy of ODS-FeCrAl alloys via heterostructured strategy

Oxide dispersion strengthened (ODS)-FeCrAl alloys are candidate structural materials for advanced nuclear reactor applications, which have excellent strength and radiation tolerance but low ductility. In this study, a novel ODS-FeCrAl heterostructured composite, reinforced with FCC-structured ODS-CoCrFeNiMn high-entropy particles, was prepared by using mechanical alloying and spark plasma sintering to achieve the strength-ductility synergy. The effect of different reinforcement contents (0, 10, 15 and 20 wt.%, designated as RC-0, RC-10, RC-15, and RC-20, respectively) on the microstructure and mechanical properties of the composites was investigated. The results showed that the unreinforced reference alloy, RC-0, consists of BCC-structured ODS-FeCrAl matrix and high-density oxides. In the RC-10, RC-15, and RC-20 composites, in addition to the ODS-FeCrAl matrix and nanoscale oxides, FCC-structured ODS-CoCrFeNiMn high-entropy reinforcement with ultrafine grain size and FCC transition layer with gradient grain size are observed. As the reinforcement content increases, the thickness of transition region increases. The composites show an increase in ultimate compressive strength and compressive strain with increasing reinforcement content in the following order: 2951 MPa/33.6%, 3169 MPa/40.0%, 3290 MPa/43.2%, and 3489 MPa/48.8%. And the compressive yield strength exhibits an initial increase and subsequent decrease, i.e. 1523 MPa (RC-0), 1680 MPa (RC-10), 1635 MPa (RC-15), and 1355 MPa (RC-20), respectively. The increase in yield strength is mainly attributed to hetero-deformation induced (HDI) strengthening and reinforcement hardening. The improvement in ductility is mainly attributed to the HDI work hardening and the suppression of microcrack formation and propagation at prior powder boundaries.

Breaking boundaries in O3-type NaNi1/3Fe1/3Mn1/3O2 cathode materials for sodium-ion batteries: An industrially scalable reheating strategy for superior electrochemical performance

To address the challenges of air stability and slurry processability in layered transition metal oxide O3-type NaNi1/3Fe1/3Mn1/3O2 (NFM) for sodium-ion batteries (SIBs), we have designed an innovative 500 °C reheating strategy. This method improves the surface properties of NFM without the need for additional coating layers, making it more efficient and suitable for large-scale applications. Pristine NFM (NFM-P) was first synthesized through a high-temperature solid-state method and then modified using this reheating approach (NFM-HT). This strategy significantly enhances air stability and electrochemical performance, yielding an initial discharge specific capacity of 151.46 mAh/g at 0.1 C, with a remarkable capacity retention of 95.04% after 100 cycles at 0.5 C. Additionally, a 1.7 Ah NFM||HC (hard carbon) pouch cell demonstrates excellent long-term cycling stability (94.64% retention after 500 cycles at 1 C), superior rate capability (86.48% retention at 9 C), and strong low-temperature performance (77% retention at −25 °C, continuing power supply at −40 °C). Notably, even when overcharged to 8.29 V, the pouch cell remained safe without combustion or explosion. This reheating strategy, which eliminates the need for a coating layer, offers a simpler, more scalable solution for industrial production while maintaining outstanding electrochemical performance. These results pave the way for broader commercial adoption of NFM materials.

Oxidation behavior and mechanical properties of a directionally solidified high Nb TiAl based alloy between 800 °C and 900 °C

The high temperature oxidation behavior and mechanical property response of a directionally solidified Ti-46Al-7Nb-0.4W-0.6Cr-0.1B alloy were investigated. The ultimate tensile strength of the alloy at 800 °C, 850 °C and 900 °C are 647 MPa, 590 MPa and 508 MPa, respectively, and the tensile fracture mode changed from brittle cleavage fracture to micro-void accumulation ductile fracture. At lower temperatures Al2O3 forms first, growing along the γ lamellae to form oxide bands aligned with the lamellar orientation. The oxidation mass gain of the alloy after 900 °C/100 h isothermal oxidation is only 0.91 mg/cm2. The oxidation kinetics results show the microalloyed high Nb TiAl alloy has excellent oxidation resistance, which is due to the formation of a TiO2 layer containing Nb, Cr and W, the AlNb2 phase and an Al/Cr rich transition layer above the directionally solidified lamellar matrix.

The Role and Substitution of Cobalt in the Cobalt‐Lean/Free Nickel‐Based Layered Transition Metal Oxides for Lithium Ion Batteries

AbstractThe Nickel‐based layered transition metal oxide cathode represented by NCM (LiNixCoyMnzO2, x+y+z=1) and NCA (LiNixCoyAlzO2, x+y+z=1) is widely used in the electric vehicle market due to its specific capacity and high working potential, in which Cobalt (Co) plays a huge role in improving the structural stability during the cycle. However, the limited supply of Co, due to its scarcity and the influence of geopolitics, poses a significant constraint on the further advancement of the Nickel‐based layered transition metal oxide cathode in the field of energy storage. In this paper, the mechanism of Co in the Nickel‐based layered transition metal oxides is reviewed, including its critical role for structural stability such as the inhibition of cationic mixing and the release of lattice oxygen et al. Subsequently, it outlines various strategies to enhance the performance of Co‐lean/free materials, such as ion doping, including single‐ion doping and multi‐ion co‐doping, and various surface coating strategies, so as to eliminate the adverse effects of Co loss on materials. Ultimately, this paper offers a glimpse into the promising future of Cobalt‐free strategies for high performance of Nickel‐based layered transition metal oxides.

Multiple Upward Residual Gravity and Magnetic Maps to Estimate the Deep Crustal Layers and Moho Discontinuity in Eastern Iraq

The upward continuation technique was applied to the gravity and magnetic data to obtain the residual anomalies maps in eastern Iraq. A new processing method is introduced to calculate the crustal layers depending on the relation between the total range of the residual anomalies of gravity, magnetic data and the upward continuation, with multi-elevations. The significant relationship shows slope variations, which may reflect the maximum contrast in the physical properties (density and/or susceptibility) and the intersection point representing the depth of layer contacts. This method was applied to the eastern central part of Iraq, adjacent to the Iranian borders. It is found that the average depth range to the Jurassic formations, top basement rocks, transition layer (Curie point), and Moho discontinuity are 3.1- 4.8 km, 8-12.9 km, 20.9-22.4 km and 43.6 km, respectively. The Sedimentary cover in the study area ranges from 8 to 13 km. The maximum depth to the Moho discontinuity obtained by gravity data in the study area is 43.6 km. The radially average power spectrum technique was applied in the study area to calculate the gravity depth and magnetic sources' depth. Three depth levels of sources from gravity and magnetic data were obtained. These depths are shallow sources, average basement rock and deep sources (Moho) at 3km, 13.2-12.1 km, and 32.2-34km, respectively. The obtained results concerning the main layers in the crust were compared between the two methods, and the new method shows more reliable results. The detected depth levels refer to top Jurassic, basement rocks, and Moho discontinuity. The new method is believed to be used to detect the crustal layers depth with good results.

Evolution of nonmetallic inclusions in high Mn–high Al steel during heat treatment

In order to reveal the evolution behaviours of the inclusions in a high Mn–high Al steel ( w(Mn) = 18 wt% and w(Al) = 1.5 wt%) at 1200 °C, heat treatment experiments were carried out in laboratory for different hours (0–10 h). It was found that, CaO-Al2O3-MnO-MgO system oxides (Type I), CaO-Al2O3-MnO-MgO + (Ca, Mn)S complex oxysulphides (Type II) and (Ca, Mn)S sulphides (Type III, w(MnS) > 95 wt%) were detected before and after heat treatment. During heat treatment, the dominant inclusions changed from Type I (oxides) into Type II (oxysulphides), and the size of the inclusions increased slightly. With heating time, the Al2O3 content increased in the oxide part of Type I and Type II inclusions, while the content of CaO decreased. MnS was quite stable in the steel, and it can precipitate on the oxides, thus forming a (Ca, Mn)S transition layer in between the MnS outer layer and the oxides. The MnS outer layer might be helpful to reduce the stress concentration during rolling.

Examining the Role of Surface Temperature on Boundary Layer Stability and Transition to Turbulence

This study investigates the influence of varying surface temperature on the critical Reynolds number to understand the onset of turbulence in the boundary layer of a flat plate. Computational Fluid Dynamics (CFD) simulations in ANSYS Fluent have been utilized for the purpose of this study. The study systematically varies surface temperature to measure its impact on flow stability. The research demonstrates that an increase in surface temperature results in a lower critical Reynolds number (leading to an earlier transition from laminar to turbulent flow) by modeling air as the working fluid and applying the k-ω SST turbulence model. The results align with theoretical predictions which highlight the destabilizing effect of temperature-induced viscosity changes. This finding has practical implications for aerospace engineering, HVAC systems, and environmental modeling where controlling turbulence can optimize performance and energy efficiency. The study acknowledges limitations due to the use of a 2D model and suggests future work using 3D simulations and other flow conditions to expand the applicability of the findings.

Effect of Heat Input on Tin Bronze-Induced Intergranular Cracks During Arc Cladding Process

This work aimed to figure out the effect of heat input on the characteristics, formation, and elimination of liquid tin bronze-induced intergranular cracks in steel sheets with a thickness of 2 mm. Tin bronze cladding layers were prepared using an arc cladding technique on the steel. A statistical method was adopted to analyze the severity of intergranular cracks. Microstructures and intergranular cracks were characterized by SEM and TEM. The tensile experiments were carried out using an electronic universal testing machine. For the bare steel sheets, the intergranular cracks originated from the cladding layer and propagated into the interior of the steel along the grain boundaries. The intergranular cracks could evolve into macrocracks and lead to the failure of steel. With the increase in heat input, the maximum temperature, maximum stress, and contact time between steel and liquid tin bronze increased. The severity of intergranular cracks was also increased, and the longest crack reached 520 μm. The mechanical properties of the steel sheets decreased with the increase in heat input. For nickel-plated steel sheets, intergranular cracks were eliminated under low heat input, and a transition layer with a nickel content of 12.32 wt.% was generated. The intergranular cracks generated under high heat input and nickel content in the transition layer were only 1.34 wt.%. The strength of the nickel-plated steel also decreased drastically, and the ductility was almost zero.

Probing enhanced superconductivity in van der Waals polytypes of VxTaS2

Layered transition metal dichalcogenides (TMDs) stabilize in multiple structural forms with profoundly distinct and exotic electronic phases. Interfacing different layer types is a promising route to manipulate TMDs' properties, not only as a means to engineer quantum devices but also as a route to explore fundamental physics in complex matter. Here we use angle-resolved photoemission (ARPES) to investigate a strong layering-dependent enhancement of superconductivity in TaS2, in which the superconducting transition temperature, Tc, of its 2H structural phase is nearly tripled when insulating 1T layers are inserted into the system. The study is facilitated by a vanadium-intercalation approach to synthesizing various TaS2 polytypes, which improves the quality of the ARPES data while leaving key aspects of the electronic structure and properties intact. The spectra show the clear opening of the charge density wave gap in the pure 2H phase and its suppression when 1T layers are introduced to the system. Moreover, in the mixed-layer 4Hb system, we observe a strongly momentum-anisotropic increase in electron-phonon coupling near the Fermi level relative to the 2H phase. Both phenomena help to account for the increased Tc in mixed 2H/1T layer structures. Published by the American Physical Society 2024

Development of laser felling modes of gas-thermal coating

The use of copper and its alloys to create parts for metallurgical equipment is associated with an increase in abrasive wear and high-temperature corrosion. In this regard, there is a need to apply a protective coating. In particular, to prevent wear and premature chipping of the metal of copper tuyeres, the surface is hardened with a coating of zirconium dioxide stabilized with yttria oxide by thermal spraying in an air atmosphere. Due to the difference in the coefficient of thermal expansion of copper (at T = 300 K: 16.7 µm/m оС and at T = 750 K: 19.7 µm/m оС) and its low resistance to gas corrosion, the application of zirconium oxide (produced by a preapplied intermediate layer that plays a role in matching the coefficient of thermal expansion (CTE) between the copper base and the ceramic coating. In addition, the intermediate layer protects copper from gas corrosion. In this case, The use of copper and its alloys to create parts for metallurgical equipment is associated with an increase in abrasive wear and high-temperature corrosion. In this regard, there is a need to apply a protective coating. In particular, to prevent wear and premature chipping of the metal of copper tuyeres, the surface is hardened with a coating of zirconium dioxide stabilized with yttria oxide by thermal spraying in an air atmosphere. Due to the difference in the coefficient of thermal expansion of copper (at T = 300 K: 16.7 pm/m °G and at T = 750 K: 19.7 pm/m оG) and its low resistance to gas corrosion, the application of zirconium oxide (produced by a pre-applied intermediate layer that plays a role in matching the coefficient of thermal expansion (CTE) between the copper base and the ceramic coating. In addition, the intermediate layer protects copper from gas corrosion. In this case, nickel-based alloys were used as intermediate layers. The use of nickel as the basis of intermediate layers is due to the fact that copper and nickel form a continuous series of solid solutions, such as cupronickel or monel metal-like structures. This, in turn, assumes a smooth transition of thermophysical properties from copper to nickel alloy. To ensure increased adhesion of the transition layer to copper by increasing the area of mutual contact between copper and the sublayer (dagger penetration) and significantly increasing the homogeneity of the material of the intermediate layer made of a nickel alloy, laser melting of the intermediate sublayer (Ni–B–Si system) was used on a laser complex based on laser LS-5 with a power of 5 kW with a KUKA KR-60HA robot in an argon atmosphere. To test the modes, experiments were carried out on copper samples of a flat shape and a body of rotation. The optimal parameters for the process of melting flat samples were: processing speed 33 mm/s, power from 400 to 3900 W, focal length from 200 to 230 mm, pitch between tracks: 0.25, 0.5 and 1 mm. The optimal parameters for the process of melting rotating samples were: laser radiation power 400–450 W, processing step 0.125; 0.5, focal length from 200 to 210 mm.

Geochemical characterization of trace fossil assemblages in spotted marls and limestones of the Lower Jurassic of the Western Carpathians: environmental implications

AbstractThe trace fossils of the spotted limestones and marls from upper Pliensbachian of the Skladaná Skala section, Western Carpathians (Slovakia), are characteristic of Zoophycos ichnofacies preserved in outer shelf deposits. The ichnoassociation is dominated by Lamellaeichnus and Chondrites, while Palaeophycus, Planolites, Teichichnus, Thalassinoides, Trichichnus, and Zoophycos, are less abundant. The presence of relatively large sized traces (reaching a decimetre in horizontal dimension for Thalassinoides and Zoophycos) and continuously well bioturbated deposits point to well oxygenated shallow zone (mixed layer) and deeper part of stiffed substrate of the transitional layer of bottom substrate up to the first tens of centimetres to depth. A first tier (tier I) corresponds to the shallowest sediment occupied by Bathysiphon tests and other epifaunal body fossils. The tier II is characterized by shallow infaunal burrows of deposit feeders (Planolites) and permanent dwelling, open burrows (Palaeophycus, Thalassinoides) located in a Ca-rich sediment (corresponding to CaCO3). The tier III is dominated by deposit feeders (Lamellaeichnus, Teichichnus) that burrowed stiff Ca-rich sediment below the redox boundary. Trace fossils of tier III are rich in fine siliciclastics (high content in Si, Al, K mainly associated to clays) and pyrite framboids (enrichment in Fe, S and Co). The deposit-feeders of tier III maintain connection to the sediment-water interface. Tier IV (Zoophycos, Teichichnus and large Chondrites), and deepest infaunal forms of the tier V. (Trichichnus, Pilichnus and tiny forms of Chondrites) comprises trace fossils commonly rich in pyrite framboids with relatively high content of Fe, S, and Co, congruent with chemosymbiotic behaviour commonly inferred for Chondrites, Trichichnus, and the organic-matter storage of Zoophycos.