The effect of ablation of absorbing dielectrics by single and two successive ultra short pulses from an excimer laser source is investigated. The numerical model is based on two photon absorption by the molecular chromophores followed by thermal degradation and diffusion, whereas ablation occurs through sublimation of the material from the surface. The numerical analysis involves solving a set of coupled three- or two-level chromophore rate equations, heat diffusion equation, and the transient radiative transport equation, using two techniques: a fully implicit iterative scheme and a predictor corrector technique (Fromm's scheme). Results for the temperature distribution and ablation depth are obtained for different laser parameters such as the delay time between two successive pulses, laser pulse width, laser fluence, and various material properties such as activation energy, relaxation time, thermal conductivity, and absorption cross section of molecules. The results obtained by consideration of the transient radiative transfer equation are compared with the steady-state formulation, and significant differences are observed in the temperature profiles and the ablation depth.