Transfer Mode Research Articles

How do industrial land transfer modes impact carbon emissions? An intermediation perspective based on industrial structure.

Industrial land is currently the main carrier and important source of global carbon emissions, and as the world's largest developing country, China's large-scale and diversified industrial land supply has made it the world's largest carbon emitter. Therefore, researching the impact of different supply methods of industrial land on carbon emissions and its impact paths in China can help provide a reference for other countries to reduce carbon emissions from the perspective of urban industrial land management, which is of great significance for effectively promoting global carbon reduction. Based on this, this paper analyses the impact of different supply methods of industrial land on carbon emissions and its urban heterogeneity using the SYS-GMM and chain-mediated effects models for 285 cities in China from 2008 to 2020. The study found that, in general, the impact of different industrial land transfer modes on carbon emission has hysteresis and persistence. Agreement and listing transfer with government intervention can significantly exacerbate carbon emissions, while more market-based bidding and auction transfer can dampen carbon emissions. In terms of intermediary effects, the transfer of industrial land by agreement and listing will inhibit the rationalization and advancement of industrial structure, thus aggravating carbon emissions. The transfer of industrial land by bidding and auction will create barriers to entry and a crowding-out effect, promote the rationalization of industrial structure and the transformation and upgrading of industrial structure and moderate carbon emissions. In terms of city heterogeneity, there is urban heterogeneity in the impact of industrial land transfer on carbon emissions in cities with different economic types. Bidding and auction transfer for industrial land in both economically developed and less developed cities can promote carbon pollution. While the more developed urban economy makes the intermediary effect of industrial structure not significant. In the future, it is necessary to strictly control the scale of industrial land supply; the whole process supervision mechanism of industrial land allocation and differentiated industrial land supply strategies will provide useful experience for many developing countries in allocating industrial land to mitigate carbon emissions, generating effective contributions to global carbon emission reduction.

Laser Parallel Nanofabrication of Dual‐Au‐Nanoholes on Microsphere‐Lens‐Array for Polarization‐Dependent SERS

AbstractHigh‐efficient fabrication of well‐ordered nanostructures on flexible substrates is a challenge to surface‐enhanced Raman spectroscopy (SERS) for analytical fingerprinting trace‐detection. In this work, a laser parallel nanofabrication method is reported via incident‐angle‐dependent photonic nanojet ablating Au film on the bottom surface of microsphere‐lens‐array (MLA), for combination with formed dual Au‐nanoholes (MLA/2‐AuNHs) as the flexible SERS substrates. The process parameters, i.e., pulsed laser energy, MLA diameter, Au film thickness, and laser incident angle, are optimized for high finish‐quality of dual‐AuNHs with a diameter of ≈875 nm and a tip gap of ≈90 nm. The SERS substrate demonstrates the limit of detection down to 10−11 M for 4‐nitrobenzenethiol molecules by the multiple optical regulations, including self‐aligned focusing to the hotspots and directional antenna, the strongly localized surface plasmon resonances, and optical whispering‐gallery modes for resonance energy transfer. The flexible PDMS film supporting the rigid MLA holds the SERS performance of MLA/2‐AuNHs with high flexibility. Moreover, the MLA/2‐AuNHs SERS substrate exhibits differential responses to orthogonally polarized excitation, by which the background noises can be eliminated to improve the Raman spectrum. The present work opens new opportunities to fabricate dielectric‐metal flexible SERS substrates by laser parallel nanofabrication via MLA for Raman trace detection.

Hybrid joints consisting of pre-tensioned bolts and a bonded connection—The influence of adhesives on the load-bearing capacity

This study explores the intricate mechanics of hybrid joints, which combine prestressed bolts and adhesive bonding, with a focus on increasing the joint capacity of steel structures. Despite their potential, the fundamental behaviour of these joints is not fully understood. The research focuses on unravelling the load-bearing capacity of these hybrid joints, emphasising the influence of the adhesive properties. The unique manufacturing process, involving the pre-tensioning of bolts while the adhesive is uncured, introduces additional dependencies not present in conventional adhesive joints. Analysis of the mechanical and physical properties of five adhesives provides key insights into the mechanics of load transfer and failure modes in hybrid joints, providing a comprehensive understanding. The study shows that load transfer occurs through micron-thin adhesive layers, highlighting the significant influence of adhesive properties on joint performance. Epoxies emerge as the top performers, with 2.5 times the average friction joint and more than five times the average bonded joint capacity, indicating their superiority in hybrid joint applications. Hybrid joints show significantly less variation than adhesive and friction joints, underlining their consistency and reliability in structural applications. When comparing hybrid and bonded joints with the same adhesive (SW7240), the variance was suppressed to one seventh by the application of preloaded bolts, with practical implications for design values based on quantiles. The study establishes correlations between joint strength and adhesive properties, emphasising the critical role of Young's modulus and tensile strength. It also finds that the elongation of hybrid joints at break is almost entirely dependent on load capacity, with viscosity having a lesser effect. Fracture surface investigations provide insight into the failure modes of hybrid joints, highlighting differences from those observed in frictional or purely bonded joints. This comprehensive study, combining experimental campaigns and in-depth analysis, provides valuable insights into the intricate relationships between joint capacity and adhesive properties in hybrid joints. The findings guide the selection of appropriate adhesives and provide the basis for the development of accurate load prediction methods, unlocking the full potential of hybrid joints and overcoming the limitations of conventional joining techniques in steel structures. Further research is encouraged to investigate the influence of adhesive class, post-tensioning stability and the nuanced mechanics of load transfer in these innovative joints.

Designed synthesized step-scheme heterojunction of Bi2WO6 nanosheet supported on CuBi2O4 nanorod with remarkable photo-assisted gas sensing for N-butyl alcohol

Photo-assisted gas sensors for n-butyl alcohol detection have attracted considerable attention due to their great potential in safety production and human health. However, the sensitivity, selectivity and stability should be further improved for practical application. Herein, Bi2WO6 nanosheet supported on CuBi2O4 nanorod sensor was realized by the two-step hydrothermal method, and it exhibited excellent sensitivity and stability for n-butyl alcohol detection under blue LED light illumination at the operating work temperature of 110 °C with gas concentration from 0.5 to 800 ppm. Meanwhile, the gas concentration of n-butyl alcohol obtained from the sensor was comparable to that of GC analysis. Furthermore, the sensor showed lower responses to other 25 kinds of common organic gases including alcohols, aldehydes, benzenes and ketones compared with that of n-butyl alcohol. More attractively, the Bi2WO6/CuBi2O4 sensor maintained its stable photo-assisted sensing activity over 3 months. The excellent gas-sensing property was caused by light illumination and formation of Bi2WO6/CuBi2O4 heterojunction, leading to abundant active electrons and superoxide radicals. The S-scheme mode of charge transfer at the Bi2WO6/CuBi2O4 heterojunction was revealed by the in-situ XPS and in-situ ESR analyses. The results gained herein may be useful for rational design of S-scheme heterojunction in photo-assisted gas sensor for n-butyl alcohol analysis.

DIMENSONAREA ȘI CONSTRUCȚIA TRADUCTOARELOR PIEZOELECTRICE DE VIBRAȚII

The paper presents the construction of piezoelectric accelerometers, the mechano-electrical transfer mode, typical constructions, basic characteristics, and theoretical approaches to the vibration phenomenon appearing in accelerometry and calculation possibilities of the various characteristics of the transducers. In the second part of the paper, the functional testing of such a transducer is also presented, piezoelectric vibration transducers being useful for vibration determination and dynamic balancing of electric machines. In general, vibration transducers provide, through mechano-electrical conversion according to different principles, an electrical signal directly proportional to a vibration parameter (acceleration, travel speed, amplitude); depending on the principle, they can be piezoelectric, electrodynamic, inductive, capacitive, resistive or based on the Hall effect, with magnetic fluids, interferometric, laser, servo-accelerometers, etc. Since there is no universal accelerometer, each one is intended to encompass the characteristics of a concrete application best, the way of stressing the photosensitive medium in the first place, the design,, as well as the other characteristics, vary from one construction to another.

Regulate drain‐shield relative positioning and contact for mitigating radiated emission from USB cables

AbstractThis letter delves into the influence of drain wire design on electromagnetic radiated emission (RE) from a commercial universal serial bus (USB) cable operating in a high‐speed data transfer mode. The investigation involves an experimental comparison of measured RE across various retrofitted cables. Notably, it is demonstrated that the distribution of contact points on the drain‐shield has negligible effects on RE. Conversely, relocating the drain wire externally to the shields and minimizing the distance with respect to the grounding connector leads to a significant reduction in RE, particularly within the sub‐MHz frequency range. Consequently, regulatory proposals are put forth to diminish overall RE and enhance the RE compliance of USB cables.

Kinetics of zinc leaching from intermediate feedstocks

The aim of the work was to study the leaching kinetics of zinc from the compound CaO. ZnO, formed during the sintering of dust from electric arc furnaces with limestone, as well as to identify the mechanisms by means which such chemical interactions occur. The object of the study was the dust sinter of electric arc furnaces with limestone obtained at the Chelyabinsk Zinc Plant. It was found that zinc is contained in sinter in the form of readily soluble CaO. ZnO. The elemental composition of the initial dusts and sinter was determined by the spectral atomic emission method using inductively coupled plasma on a Spectroblue optical emission device and spark spectrometry. The phase composition of the materials was studied on a Bruker D8 Advance X-ray diffractometer. The initial sinter was milled to apowder state having a particle size of ~0.04 mm and with a yield of ~97% of the composition, %: 11.9 Zn; 28.5 Ca; 16.6 Fe; 0.38 Mg; 0.14 Pb; 0.05 Cl. Experiments on the leaching of Zn with NaOH solution were carried out at the following parameters: the initial concentration of zinc in the pulp was 0.202 g-ion/dm3 ; alkali concentration – 5‒9 mol/dm3 NaOH; L:S = 9:1; pulp mixing rate – 10‒20 rad. c-1; temperature – 333‒363 K; duration – 0.5–2.5 hours. It has been shown that zinc from sinter passes into solution as sodium tetrahydroxozincate Na2[Zn(OH)4], while calcium remains in the cake, mainly as insoluble Ca(OH)2, which reacts with carbon dioxide to form insoluble calcium carbonate CaCO3. The process of dissolving zinc from the sinter corresponds to the external diffusion mode of mutual transfer of the initial reagents and reaction products through the surface layer of the liquid at the interface of the “liquid–solid” phases with an activation energy value equal to 12.44 kJ/mol. Thus, with the studied parameters of zinc leaching with NaOH solution, the process proceeds in an external diffusion mode. The results are of interest when identifying conditions corresponding to the intradiffusion and kinetic modes of zinc leaching.

A Study of Thermal Runaway Mechanisms in Lithium-Ion Batteries and Predictive Numerical Modeling Techniques

While thermal runaway characterization and prediction is an important aspect of lithium-ion battery engineering and development, it is a requirement to ensure that a battery system can be safe under normal operations and during failure events. This study investigated the current existing literature regarding lithium-ion battery thermal runaway characterization and predictive modeling methods. A thermal model for thermal runaway prediction was adapted from the literature and is presented in this paper along with a comparison of empirical data and predicted data using the model. Empirical data were collected from a Samsung 30Q 18650 cylindrical cell and from a large 20 Ah pouch cell format using accelerated rate calorimetry. The predictive model was executed in a macro-enabled Microsoft Excel workbook for simplicity and accessibility for the public. The primary purpose of using more primitive modeling software was to provide an accurate model that was generally accessible without the purchase of or training in a specific modeling software package. The modes of heat transfer during the thermal runaway event were studied and are reported in this work, along with insights on thermal management during a thermal runaway failure event.

Method of settlement calculation for underlying layer of soft soil composite foundation based on load transfer mechanism

The mechanical properties of soil in soft soil area are poor, and the settlement of the underlying layer in the composite foundation accounts for a large proportion of the total settlement. At present, most of the research focuses on the settlement of the reinforced area, and the research on the settlement of the underlying layer is of great significance for the settlement of soft soil composite foundation. The differences in load transfer modes of soil and pile are analyzed, and based on the Boussinesq solution and Mindlin solution, a calculation method for the stress and settlement of the underlying layer in flexible and rigid pile composite foundation is proposed. The relative displacement of soil and pile in flexible pile composite foundation is small, and the negative friction can be ignored, but the influence of effective pile length should be considered. The relative displacement of soil and pile in rigid pile composite foundation is large, so the negative friction should be considered. Part of soil top stress is transmitted to the pile via negative friction, and then the pile axial force is transmitted back to the soil via positive friction. In addition to effective pile length, the change of stress transfer path caused by negative friction should also be considered in settlement calculation.

Factors associated with the delay in informed consent procedures of patients with ST-segment elevation myocardial infarction and its influence on door-to-balloon time: a nationwide retrospective cohort study.

ST-segment elevation myocardial infarction (STEMI) is the deadliest and most time-sensitive acute cardiac event. However, failure to achieve timely informed consent is an important contributor to in-hospital delay in STEMI care in China. We investigated the factors associated with informed consent delay in patients with STEMI undergoing percutaneous coronary intervention (PCI) and the association between the delay and door-to-balloon time. We conducted a nationally representative retrospective cohort study using patient data reported by hospital-based chest pain centers from 1 January 2016 to 31 December 2020. We applied generalized linear mixed models and negative binomial regression to estimate factors independently predicting informed consent delay time. Logistic regressions were fitted to investigate the association of the informed consent delay time and door-to-balloon time, adjusting for patient characteristics. In total, 257, 510 patients were enrolled in the analysis. Mean informed consent delay time was 22.4 min (SD = 24.0), accounting for 39.3% in door-to-balloon time. Older age (≥65 years) was significantly correlated with informed consent delay time (RR: 1.034, P = 0.001). Compared with ethnic Han patients, the minority (RR: 1.146, P < 0.001) had more likelihood to extend consent giving; compared with patients who were single, longer informed consent time was found in married patients (RR: 1.054, P = 0.006). Patients with intermittent chest pain (RR: 1.034, P = 0.011), and chest pain relief (RR: 1.085, P = 0.005) were more likely to delay informed consent. As for transfer modes, EMS (RR: 1.063, P < 0.001), transfer-in (RR: 1.820, P < 0.001), and in-hospital onset (RR: 1.099, P = 0.002) all had positive correlations with informed consent delay time compared to walk-in. Informed consent delay was significantly associated with prolonged door-to-balloon time (OR: 1.002, P < 0.001). Informed consent delay is significantly associated with the door-to-balloon time which plays a crucial role in achieving better outcomes for patients with STEMI. It is essential to shorten the delay time by identifying and intervening modifiable factors that are associated with shortening the informed consent procedure in China and other countries.

Open-circuit fault diagnosis of rectifiers fed GMAW process under different transfer modes

Open-circuit fault diagnosis of rectifiers fed GMAW process under different transfer modes

Mechanics and Stability of Force Chain Arch in Excavated Granular Material

Rock and soil masses in geotechnical engineering projects, such as tunnels, mines and slopes, undergo relative motion, exhibiting mechanical characteristics of solid–fluid transition under critical conditions. This work analyzes the characteristics of the solid–fluid transition interface and the mode of load transfer through biaxial compression particle flow photoelastic experiments on granular materials. The study documents that this interface forms an arch shape, marked by a force chain arch. The granular material exhibits two distinct states depending on its position: below the arch, the granular material is in a solid–fluid transitional state, with bearing capacity reduced, while above the arch, it is in a stable solid state, capable of bearing the overlying rock layer’s load. The presence of the force chain arch alters the direction of the originally downward-transferring load, redirecting it along the trajectory of the arch. Analysis of the force and stability of the force chain arch revealed that the arch shape parameters and boundary loads control the instability of the arch. Changes in the overlying and lateral loads lead to different types of instability of the force chain arch. The findings of the study are crucial for underground engineering construction and for the prevention of geological disasters related to granular material.

Unraveling a Concerted Proton-Coupled Electron Transfer Pathway in Atomically Precise Gold Nanoclusters.

Metal nanoclusters (MNCs) represent a promising class of materials for catalytic carbon dioxide and proton reduction as well as dihydrogen oxidation. In such reactions, multiple proton-coupled electron transfer (PCET) processes are typically involved, and the current understanding of PCET mechanisms in MNCs has primarily focused on the sequential transfer mode. However, a concerted transfer pathway, i.e., concerted electron-proton transfer (CEPT), despite its potential for a higher catalytic rate and lower reaction barrier, still lacks comprehensive elucidation. Herein, we introduce an experimental paradigm to test the feasibility of the CEPT process in MNCs, by employing Au18(SR)14 (SR denotes thiolate ligand), Au22(SR)18, and Au25(SR)18- as model clusters. Detailed investigations indicate that the photoinduced PCET reactions in the designed system proceed via an CEPT pathway. Furthermore, the rate constants of gold nanoclusters (AuNCs) have been found to be correlated with both the size of the cluster and the flexibility of the Au-S framework. This newly identified PCET behavior in AuNCs is prominently different from that observed in semiconductor quantum dots and plasmonic metal nanoparticles. Our findings are of crucial importance for unveiling the catalytic mechanisms of quantum-confined metal nanomaterials and for the future rational design of more efficient catalysts.

Estimation of Heat Production Rate using Thermal Data During Exercise in Indoor Environments: A Study of Heat Storage Rate in Male Athletes.

The increasing preference for indoor exercise spaces highlights the relationship between indoor thermal environments and physiological responses, particularly concerning thermal comfort during physical activity. Determining the metabolic heat production rate during exercise is essential for optimizing the thermal comfort, well-being, and performance of individuals engaged in physical activities. This value can be determined during the activity using several methods, including direct calorimetry measurement, indirect calorimetry that uses analysis of respiratory gases, or approximations using collected data such as speed, body mass, and heart rate. The study aimed to calculate the metabolic heat production rate by infrared thermal evaluation (ITE) based on the body's thermal balance approach and compare it with the values determined by indirect calorimetry (IC). Fourteen participants volunteered for the study, using a cycling ergometer in a controlled climatic chamber. After the familiarization sessions, maximal O2 intake levels (VO2max) were determined through maximal graded exercise tests. Subsequently, constant work rate exercise tests were performed at 60% of VO2max for 20min. The metabolic heat production rates were calculated by IC and ITE for each athlete individually. Respiratory gases were used to determine IC, while body skin and core temperatures, along with physical environmental data, were applied to calculate ITE using the human body thermal balance approximation of ASHRAE. According to the results, heat storage rates were misleading among the body's heat transfer modes, particularly during the first 8min of the exercise. ITE showed a moderate level of correlation with IC (r: 0.03-0.86) with a higher level of dispersion relative to the mean (CV%: 12-84%). Therefore, a new equation (ITEnew) for the heat storage rates was proposed using the experimental data from this study. The results showed that ITEnew provided more precise estimations for the entire exercise period (p > 0.05). Correlations between ITEnew and IC values were consistently strong throughout the exercise period (r: 0.62-0.85). It can be suggested that ITEnew values can predict IC during the constant work rate steady-state exercise.

Fabrication of low thermal expansion Fe–Ni alloys by in-situ alloying using twin-wire arc additive manufacturing

The binary Fe–Ni system offers alloys with notably low linear coefficients of thermal expansion (CTE), contingent upon their Ni content. In this respect twin-wire arc additive manufacturing (T-WAAM) presents the opportunity of in-situ alloying through the simultaneous feeding of two metal wires into a weld pool to obtain desired alloy compositions. This study aims to deposit a graded wall with Ni contents targeted at 42, 46, and 52 wt% in the building direction of the wall, along with a block comprising of 46 wt% Ni, employing the T-WAAM approach. The results show effective incorporation of additional Ni into the weld pool and geometrically stable weld beads in the continuous metal transfer mode during the T-WAAM process. This mode led to the defect-free and chemically stable deposition of the graded wall and the block with average Ni contents of 42.3 ± 1.1, 45.8 ± 1.4, 52.6 ± 0.8 wt%, and 46.4 ± 0.9 wt%, respectively. The measured Curie temperatures of the as-deposited alloys and the mean CTE values of alloy 46 were found to be comparable to the commercial alloys. In summary, this study validates the feasibility of in-situ deposition of low thermal expansion alloy compositions, thereby enabling the possibility of on-demand thermal expansion properties.

Spectral effects of radiating gases and soot on an experimental aero-engine combustion chamber using full-spectrum k-distribution method

Radiative heat transfer is the main mode of heat transfer and has been proven to be important in the aero-engine combustion. Those radiating gases and soot resulted from combustion may display very strong spectral, or “nongray” behavior, which is difficult to both characterize and evaluate. In this work, the full-spectrum k-distribution (FSK) method is employed to resolve the spectral behavior of both radiating gases and soot during combustion in an experimental aero-engine. Different FSK-based spectral treatments are combined to illustrate how the spectral behavior affects the aero-engine combustion. Those weighted-sum-of-gray-gases (WSGG) results previously done by the authors (Wang, et al. 2024) are also partially compared to the FSK results in this work. Results show that different FSK-based spectral treatments result in small differences for temperature distribution of the flow field. However, since different spectral models are found to impose a considerable effect on radiative heat transfer rate, it is inferred that spectral behavior may be deeply coupled with the generation of pollutants. Results also show that the wall temperature of the combustor liner is highly affected by the spectral model: ignoration of soot radiation underestimates the wall temperature while assuming soot to be gray overestimates the wall temperature. Therefore, high-fidelity spectral models are recommended during the modelling of aero-engine combustion.

A correlation to calculate time constant of thermocouples

A time constant is the dynamic response time of a thermocouple measuring unsteady flow fields. The measured temperature of a thermocouple is the bead temperature, which is determined by the energy conservation of the bead. Heat transfer of the bead includes convective and radiative heat exchange with the flow, heat conduction with the wires, and surface radiation with the environment. These heat transfer modes affect both the bead temperature and its time constant. The novelty of the paper is to derive a correlation for calculating the time constant of a thermocouple based on the bead energy conservation, covering a wide range of conditions and explicitly reflecting the contribution of surface radiation and conduction. The correlation involves the parameter β related to surface radiation and the parameter cl related to conduction. The correlation for β is obtained by fitting the time constant of small beads in the flows with step change parameters using CFD simulations, while the parameter cl is obtained by fitting the time constant of thermocouples under varying flow conditions using CFD simulations. The relative errors between the calculated time constants with the correlation and those of the CFD simulations are less than 19%. The CFD simulations indicate that the time constants considering radiation and conduction are 33–49% of those considering only the effect of convection for the tested cases. The S type and K type thermocouples were used to measure the standard Hencken flames. By applying current loads and then removing them, the dynamic response curves and the time constants of the thermocouples are obtained. The maximum errors between the calculated time constants with the correlation and the experimental values are less than 10%.

Ethnoveterinary medicinal plants and their utilization by indigenous and local communities of Dugda District, Central Rift Valley, Ethiopia

BackgroundEthnoveterinary medicinal plants have been used by the people of Dugda District in the primary health care system to treat various livestock ailments for generations, particularly, in underserved rural areas. However, these ethnoveterinary practices and medicinal plants are dwindling without proper documentation, due to undergoing socio-cultural and environmental changes. Hence, this study aimed at inventory and analysis of ethnoveterinary medicinal plants and the associated indigenous and local knowledge used in the treatment of livestock health problems in Dugda District.MethodsData were collected from 378 local inhabitants through semi-structured interviews, 18 focus group discussions with 6 to 8 participants in each couple with participant field observations. Informant consensus factor (ICF), fidelity-level (FL) and relative importance value (RI) were used to evaluate the agreement of informants on ethnoveterinary practices, healing potential of medicinal plants and the most multipurpose species. Using standard taxonomic procedures, voucher specimens were collected, identified and deposited at the National Herbarium of Addis Ababa University.ResultsIn total, 64 medicinal plants of ethnoveterinary uses, belonging to 33 families were reported to treat 37 livestock health problems. Anthrax, inappetence and diarrhoea were said to be the most prevalent veterinary health problems treated by traditional medicinal plants. Family Fabaceae was the most widely reported (7 spp.), followed by Apocynaceae, Cucurbitaceae and Solanaceae (5 spp. each). Herbs were the dominant life forms (21spp.), followed by shrubs (20 spp.). The most commonly sought plant parts were leaves (55.25%), followed by roots (23.44%). The principal method of preparation was pounding remedial parts (46.85%) and mixing with cold water. The main route of administration was via oral application (72.67%), drenching diseased livestock. Withania somnifera and Kedrostis foetidissima were the most cited medicinal plants with 53 and 43 use reports (URs), respectively. ICF showed that respiratory diseases scored the highest value (0.94), while most of the reported medicinal plants were gastrointestinal agents. RI value analysis revealed that Croton macrostachyus had highest diversity of uses, followed by K. foetidissima and W. somnifera. Ethnoveterinary uses of some medicinal plants such as Phytolacca dodecandra, Calpurnia aurea, Cyphostemma cyphopetalum and Verbascum sinaiticum as prophylaxis against rabies were a new input for ethnoveterinary database.ConclusionThe study revealed that the people of the Dugda District are endowed with rich ethnoveterinary knowledge and medicinal plants. However, ethnoveterinary knowledge associated with medicinal plant species significantly differ (P < 0.05) between general and key informants, young and matured age groups and informants’ educational level. This infers the impact of mode of ethnoveterinary knowledge transfer, literacy, modern education and globalization on ethnoveterinary uses of medicinal plant species. And also most of the medicinal plants are found in wild habitats with nearly no conservation attention. Therefore, it is imperative to implement participatory conservation actions for medicinal plants in collaboration with traditional institutions (Gada system). The disparity of ethnoveterinary knowledge could be also minimized through awareness creation among local communities about the knowledge and its revitalization. Furthermore, medicinal plants, which are widely utilized and multipurpose, should be screened for their phytochemicals, pharmacological and toxicological activities to confirm ethnoveterinary uses and for future development of veterinary pharmaceuticals.

A novel array current collector design enabling high energy efficiency liquid metal batteries

Liquid metal battery (LMB) is one of the most competitive large-scale energy storage technologies due to its low-cost, long-lifespan, and high-safety. However, the low energy efficiency of the battery is currently one of the major challenges hindering its application process. The problem of poor wettability of the cathode liquid alloy is exacerbated by the design of the conventional planar structure of the positive collector. And the resulting interfacial mass transfer modes are inefficient. These lead to slow electrode reaction kinetics and large internal polarization. To address this issue, a novel array current collector suitable for LMB was designed here for the first time. The unique structure of the collector greatly increases the effective reaction area at the electrolyte/cathode and the contact area of the cathode/collector, providing more efficient nucleation and growth modes of the products as well as richer ionic mass-transfer channels, thus accelerating the electrode reaction kinetics. Benefiting from the application of the array current collector, the voltage efficiency of Li||Sb-Sn LMBs with a capacity of 20 Ah at 0.5C rate is increased by 4.8 %. Meanwhile, an average voltage efficiency of ∼ 94.7 % and an average energy efficiency of ∼ 92.2 % are achieved at 0.1C, which is the highest efficiency among the most promising LMB systems known to date. These encouraging results provide new directions for the design of high-performance LMBs and further promote the practical process of LMBs.

Internal stress transfer characteristics of coal–rock medium under concentrated force based on particle flow method

To solve the problem that the macroscopic deformation and failure of coal–rock medium under external loads are easy to be observed while the internal stress transfer mode and path are unclear. Based on the discrete element idea, the numerical models for pure coal or rock samples and coal–rock combination samples with different lithologies and combination methods under concentrated force are established by PFC2D software. Then the influence of coal or rock strength and combination methods on the internal stress transfer law and distribution evolution characteristics of coal–rock medium are discussed from the perspectives of macroscopic stress and mesoscopic force chain, respectively. The results showed that under concentrated load, the macroscopic stress transfer paths within pure coal or rock samples and coal–rock combination samples are primarily in the form of ‘point source radiation’. However, when transferring between coal–rock interfaces, there is a certain interface effect. For pure coal or rock samples, differences in lithology does not change the transfer rules and macro distribution patterns of internal stress, but it can cause changes in internal unit transfer stress value and local area transfer direction. For coal–rock combination samples, the greater the difference in lithology between the two sides of the interface, the more likely the interface effect will occur. In addition, the internal stress transfer is also influenced by the relative stratigraphic relationships of coal and rock. When the stress is transferred from a higher-strength rock to a lower-strength coal mass, the interface effect will be more significant. However, regardless of the combination pattern, the locations where significant stress surges occur are always within the higher strength rock mass near the interface. The findings are helpful to understand the mechanical properties and failure mechanism of mining coal and rock mass, and provide a theoretical basis for the study of the mining-induced mechanical behavior of the floor under the action of the coal pillar.