The goal of this study is to show that trajectory hunting is an effective technique for comparison of multiplatform measurements. In order to achieve this goal, we (1) describe in detail the trajectory hunting technique (THT), (2) perform several consistency tests for THT (self‐hunting and reversibility), (3) estimate uncertainties of this technique, and (4) validate THT results against those obtained by the traditional correlative analysis (TCA). THT launches backward and forward trajectories from the locations of measurements and finds air parcels sampled at least twice within a prescribed match criterion during the course of several days. TCA finds matched profiles for a chosen match criterion, averages them for each instrument separately, and compares the averaged profiles. As an example, we consider the 22 October to 30 November 1996 period in the Southern Hemisphere and compare the latest versions of relevant measurements made by the following five instruments: Microwave Limb Sounder (MLS, version 5 (v.5)), Halogen Occultation Experiment (HALOE, v.19), Polar Ozone and Aerosol Measurement II (POAM‐II, v.6), Stratospheric Aerosol and Gas Experiment II (SAGE‐II, v.6.1), and Improved Limb Atmospheric Spectrometer (ILAS, v.5.20). We present results for O3, H2O, CH4, HNO3, and NO2, which show that (1) ozone measurements from all five instruments agree to better than 0.4 (0.2) ppmv below (above) 30 km; (2) water vapor measurements agree within ±5–10% above 22 km; (3) methane measurements by HALOE and ILAS agree to better than 10% above 30 km with a possible positive offset of up to 10–15% by ILAS in the lower stratosphere; (4) MLS HNO3 data corrected to account for some excited vibrational lines omitted in the v.5 HNO3 retrieval agree with ILAS HNO3 measurements to within ∼0.5 ppbv (∼10–20%) over the range ∼450–750 K; (5) ILAS sunset NO2 measurements are larger than both POAM‐II and SAGE‐II values by up to 10–15% below 30 km. The self‐hunting tests show that the THT RMS noise is of the order of 1–2% for O3, CH4, and H2O and 4% for NO2 and HNO3 measurements in the stratosphere. Total THT‐related uncertainties may be 3–5% for O3 measurements when photochemical effects and sensitivities of the results to duration of trajectories and match criteria are taken into account. Good agreement is found between the THT and TCA results for each of these products and for each possible pair of instruments, with considerably better statistics (typically by at least an order of magnitude) in the THT case. This agreement validates the THT results.
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