Geostatistical methods are one of the advanced techniques to interpolate groundwater quality data. Geostatistical interpolation techniques employ both the mathematical and the statistical properties of the measured points. Compiling the data distribution on spatial and temporal domain is of crucial importance in order to evaluate its quality and safety. The main purpose of this paper is to assess groundwater quality of Arak plain, Iran, by an unbiased interpolated method so called Kriging. Therefore, seven quality variables of Arak plain aquifer including TDS, SAR, EC, Na+, TH, Cl−, and SO42− have been analyzed, studied, and interpreted statistically and geostatistically. Utilized data in this study were collected from 97 water well samples in Arak plain, in 2012. After normalizing data, variogram as a geostatistical tool for defining spatial regression was calculated and experimental variograms have been plotted by GS+ software, then the best theoretical model was fitted to each variogram based on minimum RSS error. Cross validation was used to determine the accuracy of the estimated data. The uncertainty of the method could be well assessed via this method since the method not only gave the average error (around 0 in this study) but also gave the standard deviation of the estimations. Therefore, more than 3800 points were estimated by ordinary Kriging algorithm in places which have not been sampled. Finally, estimation maps of groundwater quality were prepared and map of estimation variance, EV, has been presented to assess the quality of estimation in each estimated point. Results showed that the Kriging method is more accurate than the traditional interpolation algorithms not honoring the spatial properties of the database.
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