The paper comprehensively explores the development, characteristics, and antenna applications of lithium titanium (LiTi) ferrite. Utilising a solid-state reaction technique, the study examines the substrate’s electrical, magnetic, and structural properties in detail. Additionally, it assesses the far-field radiation patterns of a magnetically-biased LiTi ferrite-based antenna. Key findings point to a noticeable reduction in mutual coupling and radiated power, along with an isotropic redistribution of minor side lobes. Comparative analysis with RT-duroid substrates in X band frequency spectrum highlights the LiTi ferrite-based antenna’s remarkable 62.85 % miniaturization and consistent directivity, along with a superior quality factor. These findings emphasise LiTi ferrite’s potential for compact, high-performance applications in demanding environments. LiTi ferrite’s advantages in miniaturisation and stability position it for specific applications, despite trade-offs in bandwidth, gain, and impedance compared to RT-duroid substrates.