Tracer Gas Research Articles

Analysis of the airflow features and ventilation efficiency of an Ultra-Clean-Air operating theatre by qDNS simulations and experimental validation

Ultra-Clean-Air (UCA) operating theatres aim to minimise surgical instrument contamination and wound infection through high flow rates of ultra-clean air, reducing the presence of Microbe Carrying Particles (MCPs). This study investigates the airflow patterns and ventilation characteristics of a UCA operating theatre (OT) under standard ventilation system operating conditions, considering both empty and partially occupied scenarios. Utilising a precise computational model, quasi-Direct Numerical Simulations (qDNS) were conducted to delineate flow velocity profiles, energy spectra, distributions of turbulent kinetic energy, energy dissipation rate, local Kolmogorov scales, and pressure-based coherent structures. These results were also complemented by a tracer gas decay analysis following ASHRAE standard guidelines. Simulations showed that contrary to the intended laminar regime, the OT’s geometry inherently fosters a predominantly turbulent airflow, sustained until evacuation through the exhaust vents, and facilitating recirculation zones irrespective of occupancy level. Notably, the occupied scenario demonstrated superior ventilation efficiency, a phenomenon attributed to enhanced kinetic energy induced by the additional obstructions. The findings underscore the critical role of UCA-OT design in mitigating MCP dissemination, highlighting the potential to augment the design to optimise airflow across a broader theatre spectrum, thereby diminishing recirculation zones and consequently reducing the propensity for Surgical Site Infections (SSIs). The study advocates for design refinements to harness the turbulent dynamics beneficially, steering towards a safer surgical environment.

Archie's cementation factors for natural rocks: Measurements and insights from diagenetic perspectives

Archie's cementation factor, m, is a critical parameter for petrophysical studies, and the value is influenced by several factors such as the shape, type, and size of grains, degrees of diagenesis, and associated pore structure. Using integrated experimental and theoretical approaches, the goal of this study is to obtain the cementation factor of rocks (both reservoir rock and caprock) and assess the impact of diagenetic processes on the values of the cementation factor. Thirteen samples of geologically diverse rocks (six mudstones, four fossiliferous limestones, two marbles, and one sandstone) were selected to achieve these research objectives. Two approaches, the diffusion of gas tracers and the Bosanquet formula calculation using pore-throat sizes from mercury intrusion porosimetry analyses, were used to derive the cementation factors of these rock samples. These rocks were categorized into two groups based on the correlation between average pore-throat diameter and diffusivity, and an exponential-law relationship between the cementation factor and porosity was determined for these sample groups. In addition, thin-section petrography and field emission-scanning electron microscopy observations were utilized to investigate diagenetic processes, with four diagenetic patterns being established: (1) strong compaction, strong cementation, and weak dissolution-diagenesis pattern; (2) weak compaction, medium cementation, and weak dissolution-diagenesis pattern; (3) weak compaction, medium cementation, and strong dissolution-diagenesis pattern; and (4) fracture-matrix pattern. The results indicated that diagenetic processes and microfractures contribute to the variability in the cementation factors of these rock samples.

The influence of ventilation on airborne transmission between stacking toilets

Multiple COVID-19 outbreaks in high-rise residential buildings have been linked to the vertical spread of the virus along the building. This study aimed to provide empirical evidence and experimental results to evaluate the effects of toilet ventilation on the spread of bathroom aerosols in high-rise residential buildings. This study explored potential transmission pathways by conducting tracer gas experiments in a full-scale mock-up toilet facility and identified effective strategies to minimize tracer gas surge and overall exposure. A novel IoT-enabled tracer gas sensing network was used to evaluate tracer gas dispersion from a lower-floor toilet to an upper-floor toilet and the roof under 32 different ventilation conditions of windows, exhaust fans, and forward-facing wind. The findings confirmed the potential for vertical airborne transmission through toilet ventilation and suggested effective ventilation strategies for forward-facing wind and no-wind conditions. This study provided novel experimental results on vertical aerosol transmission, contributing to further analysis and validation in this field. Appropriate ventilation measures were also discussed to ensure clean, virus-free air intake, reducing the risk of airborne cross-infection via the vertical transmission pathway.

Unraveling microbial processes involved in carbon and nitrogen cycling and greenhouse gas emissions in rewetted peatlands by molecular biology

Restoration of drained peatlands through rewetting has recently emerged as a prevailing strategy to mitigate excessive greenhouse gas emissions and re-establish the vital carbon sequestration capacity of peatlands. Rewetting can help to restore vegetation communities and biodiversity, while still allowing for extensive agricultural management such as paludiculture. Belowground processes governing carbon fluxes and greenhouse gas dynamics are mediated by a complex network of microbial communities and processes. Our understanding of this complexity and its multi-factorial controls in rewetted peatlands is limited. Here, we summarize the research regarding the role of soil microbial communities and functions in driving carbon and nutrient cycling in rewetted peatlands including the use of molecular biology techniques in understanding biogeochemical processes linked to greenhouse gas fluxes. We emphasize that rapidly advancing molecular biology approaches, such as high-throughput sequencing, are powerful tools helping to elucidate the dynamics of key biogeochemical processes when combined with isotope tracing and greenhouse gas measuring techniques. Insights gained from the gathered studies can help inform efficient monitoring practices for rewetted peatlands and the development of climate-smart restoration and management strategies.

Numerical sensitivity analysis of the tracer gas decay method coupled with the Kalman filter in a two-zones dwelling

The measurement of a natural airflow-rate is already challenging. It is often realised thanks to the decay method. Dealing with multi-zone naturally ventilated buildings is even more challenging as multi-zone’s applications prevent from using single-tracer gas methods. A method has already shown its ability to measure the global airflow-rate of a multi-zone passive stack dwelling. It is based on the Kalman filter applied to decay methods implemented quasi-simultaneously in each outlet room of a dwelling. This paper presents a numerical sensitivity analysis of the so-called “Kalman decay method”. Formulations of the global uncertainty are drawn depending on parameters involved in the analysis. It allowed improving the accuracy, compared to the conventional 2-points method, from 8 to 48%. If the sensor is placed near the outlet, an accuracy between 8 and 20% can be achieved. The main influential parameter is occupation in living rooms of the dwelling during the test, but its effect on the global uncertainty of the Kalman decay method is 20% lower than on the conventional 2-points method.

Physical modelling and hydrodynamic characterization of an internally circulating fluidized bed for biomass fast pyrolysis

This study investigates the hydrodynamics of the cold flow model (CFM) of an internally circulating fluidized bed (ICFB) finalized to biomass fast pyrolysis. The ICFB, basically consisting of a bubbling fluidized bed interconnected with a moving bed, is designed aiming at high fuel particles heating rates, efficient solids mixing and low gas residence times. Experimental techniques such as basket collection, solids and gas tracing are adopted to determine solids circulation rates, gas bypassing and particles residence times, consequently a compartment model of the CFM is proposed. The influence of operating conditions such as bed inventory and superficial gas velocity is investigated together with the effect of the opening ratio between the two interconnected beds. Results highlight that different operation regimes can occur and an optimization of operating and design parameters allows high solids circulation rates, low gas bypass and residence times lower than 1 s, as pursued in fast pyrolysis.

New Methodology to Evaluate and Optimize Indoor Ventilation Based on Rapid Response Sensors.

The recent pandemic increased attention to the need for appropriated ventilation and good air quality as efficient measures to achieve safe and healthy indoor air. This work provides a novel methodology for continuously evaluating ventilation in public areas using modern rapid response sensors (RRS). This methodology innovatively assesses the ventilation of a space by combining a quantitative estimation of the real air exchange in the space-obtained from CO2 experimental RRS measurements and the characteristics of and activity in the space-and indoor and outdoor RRS measurements of other pollutants, with healthy recommendations from different organisations. The methodology allows space managers to easily evaluate, in a continuous form, the appropriateness of their ventilation strategy, thanks to modern RRS measurements and direct calculations (implemented here in a web app), even in situations of full activity. The methodology improves on the existing standards, which imply the release of tracer gases and expert intervention, and could also be used to set a control system that measures continuously and adapts the ventilation to changes in indoor occupancy and activity, guaranteeing safe and healthy air in an energy-efficient way. Sample public concurrence spaces with different conditions are used to illustrate the methodology.

JOYS: MIRI/MRS spectroscopy of gas-phase molecules from the high-mass star-forming region IRAS 23385+6053

Context. Space-based mid-infrared (IR) spectroscopy is a powerful tool for the characterization of important star formation tracers of warm gas which are unobservable from the ground. The previous mid-IR spectra of bright high-mass protostars with the Infrared Space Observatory (ISO) in the hot-core phase typically show strong absorption features from molecules such as CO2, C2H2, and HCN. However, little is known about their fainter counterparts at earlier stages. Aims. We aim to characterize the gas-phase molecular features in James Webb Space Telescope Mid-Infrared Instrument Medium Resolution Spectrometer (MIRI/MRS) spectra of the young and clustered high-mass star-forming region IRAS 23385+6053. Methods. Spectra were extracted from several locations in the MIRI/MRS field of view, targeting two mid-IR sources tracing embedded massive protostars as well as three H2 bright outflow knots at distances of >8000 au from the multiple. Molecular features in the spectra were fit with local thermodynamic equilibrium (LTE) slab models, with their caveats discussed in detail. Results. Rich molecular spectra with emission from CO, H2, HD, H2O, C2H2, HCN, CO2, and OH are detected towards the two mid-IR sources. However, only CO and OH are seen towards the brightest H2 knot positions, suggesting that the majority of the observed species are associated with disks or hot core regions rather than outflows or shocks. The LTE model fits to 12CO2, C2H2, HCN emission suggest warm 120–200 K emission arising from a disk surface around one or both protostars. The abundances of CO2 and C2H2 of ~10−7 are consistent with previous observations of high-mass protostars. Weak ~500 K H2O emission at ~6–7 µm is detected towards one mid-IR source, whereas 250–1050 K H2O absorption is found in the other. The H2O absorption may occur in the disk atmosphere due to strong accretion-heating of the midplane, or in a disk wind viewed at an ideal angle for absorption. CO emission may originate in the hot inner disk or outflow shocks, but NIRSpec data covering the 4.6 µm band head are required to determine the physical conditions of the CO gas, as the high temperatures seen in the MIRI data may be due to optical depth. OH emission is detected towards both mid-IR source positions and one of the shocks, and is likely excited by water photodissociation or chemical formation pumping in a highly non-LTE manner. Conclusions. The observed molecular spectra are consistent with disks having already formed around two protostars in the young IRAS 23385+6054 system. Molecular features mostly appear in emission from a variety of species, in contrast to the more evolved hot core phase protostars which typically show only absorption; however, further observations of young high-mass protostars are needed to disentangle geometry and viewing angle effects from evolution.

The ALMaQUEST Survey. XII. Dense Molecular Gas as Traced by HCN and HCO+ in Green Valley Galaxies

Abstract We present Atacama Large Millimeter/submillimeter Array (ALMA) observations of two dense gas tracers, HCN (1−0) and HCO+ (1-0) for three galaxies in the green valley and two galaxies on the star-forming main sequence with comparable molecular gas fractions as traced by the CO (1−0) emissions, selected from the ALMaQUEST survey. We investigate whether the deficit of molecular gas star formation efficiency (SFEmol) that leads to the low specific star formation rate (sSFR) in these green valley galaxies is due to a lack of dense gas (characterized by the dense gas fraction f dense) or the low star formation efficiency of dense gas (SFEdense). We find that SFEmol as traced by the CO emissions, when considering both star-forming and retired spaxels together, is tightly correlated with SFEdense and depends only weakly on f dense. The sSFR on kiloparsec scales is primarily driven by SFEmol and SFEdense, followed by the dependence on f mol, and is least correlated with f dense or the dense-gas-to-stellar mass ratio (R dense). When compared with other works in the literature, we find that our green valley sample shows lower global SFEmol and lower SFEdense while exhibiting similar dense gas fractions when compared to star-forming and starburst galaxies. We conclude that the star formation of the three green valley galaxies with a normal abundance of molecular gas is suppressed, mainly due to the reduced SFEdense rather than the lack of dense gas.

Quantifying heterogeneity in an animal model of acute respiratory distress syndrome, a comparison of inspired sinewave technique to computed tomography

The inspired sinewave technique (IST) is a non-invasive method to measure lung heterogeneity indices (including both uneven ventilation and perfusion or heterogeneity), which reveal multiple conditions of the lung and lung injury. To evaluate the reproducibility and predicted clinical outcomes of IST heterogeneity values, a comparison with a quantitative lung computed tomography (CT) scan is performed. Six anaesthetised pigs were studied after surfactant depletion by saline-lavage. Paired measurements of lung heterogeneity were then taken with both the IST and CT. Lung heterogeneity measured by the IST was calculated by (a) the ratio of tracer gas outputs measured at oscillation periods of 180 s and 60 s, and (b) by the standard deviation of the modelled log-normal distribution of ventilations and perfusions in the simulation lung. In the CT images, lungs were manually segmented and divided into different regions according to voxel density. A quantitative CT method to calculate the heterogeneity (the Cressoni method) was applied. The IST and CT show good Pearson correlation coefficients in lung heterogeneity measurements (ventilation: 0.71, and perfusion, 0.60, p < 0.001). Within individual animals, the coefficients of determination average ventilation (R2 = 0.53) and perfusion (R2 = 0.68) heterogeneity. Strong concordance rates of 98% in ventilation and 89% when the heterogeneity changes were reported in pairs measured by CT scanning and IST methods. This quantitative method to identify heterogeneity has the potential to replicate CT lung heterogeneity, and to aid individualised care in ARDS.

Statistical assessment of the concentration fluctuations in street canyons via time-resolved wind tunnel experiments

Time-resolved wind tunnel experiments are performed for three periodic street canyon configurations: one of uniform (H/W = 1) and two of variable building height (consisting of 0.5H and 1.5H tall towers in aligned and staggered arrangements) for perpendicular wind direction. The velocity field is mapped using Laser Doppler Anemometry (LDA), and the tracer gas concentration is sampled using Fast Flame Ionization Detection (FFID). The concentration field is characterized by the mean concentration and the characteristic percentiles of the concentration-time series, such as the median and the peak, represented by the 99th percentile, in a total of 1138 sampling points. The probability distribution of the concentration in each point is modeled using the gamma distribution, which is fitted based on the mean and the variance of the measured time series. The results show that the mean pedestrian exposure to air pollutants is significantly lower in the case of heterogeneous roof height, although the mean concentration at the leeward corner of the source canyon can locally exceed those of the uniform street canyons for both tower arrangements of variable building height. Moreover, it is shown that the concentration peaks for both tower configurations can significantly exceed those of the uniform canyons case, especially near the sources.

Multizone representation of time-varying airflows in naturally ventilated dwellings: Occupant-generated CO2 approach

Accurate measurement of air exchange-rates (AERs) is crucial in naturally ventilated dwellings. AER calculations must take into account the multizone and time-varying aspects to avoid significant deviations from reality. To address the issues of invasiveness, high cost, and inability to track real-time changes in airflow and to represent real airflow patterns associated with the multiple tracer gas methods, this study proposes a practical and feasible approach, belonging to the occupant-generated CO2 methods, for the multizone representation of time-varying airflow in naturally ventilated dwellings. In this approach, the idea of state traversal is introduced to account for all possible airflow patterns. For each airflow pattern, the transient indoor CO2 mass balance equation associated with Kalman filter, and the dynamic simulation of indoor temperature are applied to successively determine the airflow pattern that is closest to the actual pattern. The approach's reliability for multizone representation of airflow is validated in controlled multizone environments, and its applicability to natural ventilation of real residential situations is also evaluated. This study further examines the zoning criterion and the approach's correction capability, while also providing a detailed analysis of its strengths and weaknesses.

Efficient injection of gas tracers into rivers: A tool to study Surface water–Groundwater interactions

Surface water (SW) - groundwater (GW) interactions exhibit complex spatial and temporal patterns often studied using tracers. However, most natural and artificial tracers have limitations in studying SW–GW interactions, particularly if no significant contrasts in concentrations between SW and GW exist or can be maintained for long durations. In such context, (noble) gases have emerged as promising alternatives to add to the available tracer methods, especially with the recent development of portable mass spectrometers, which enable continuous monitoring of dissolved gas concentrations directly in the field. However, long-duration gas injection into river water presents logistical challenges. To overcome this limitation, we present an efficient and robust diffusion-injection apparatus for labeling large amounts of river water. Our setup allows fine, real-time control of the gas injection rate, and is suitable for extended injection durations and different gas species. To illustrate the effectiveness of our approach, we present a case study where helium (He) is used as an artificial tracer to study river water infiltration into an alluvial aquifer. Our injection of He as a tracer increased the dissolved He concentration of the river water by one order of magnitude compared to air-saturated water concentration for 35 days. This experiment yields valuable information on travel times from the river to a pumping well and on the mixing ratios between freshly infiltrated river water and regional groundwater.

Identification of exhaust stack sampling location of a research reactor considering ANSI/HPS N13.1-2011 mixing criteria using computational fluid dynamics

ABSTRACT Research Reactors have exhaust stacks that emit filtered radioactive gaseous waste into the atmosphere. In this research work, to check whether the radioactive gaseous waste met the requirements of ANSI/HPS N13.1–2011 mixing criteria, computational fluid dynamics (CFD) analysis was performed. According to ANSI criteria, Coefficient of Variance (COV) of velocity uniformity, flow angle, tracer gas, and aerosol particles concentration should be less than 20%. Therefore, the COV of the four parameters at different sampling positions along the stack height, with eight tracer gas and eight particles injection cases, were analyzed. The COV of velocity at 6 m height is 17.5% and flow cyclone is 9.8 degree. The results indicated that the 6 m height of the stack is enough for cyclone angle and COV of velocity to fulfill the ANSI mixing criteria. The COV of tracer gas concentration in one to eight injection cases is 10%, 4.8%, 7.5%, 17%, 2.5%, 6%, 13%, and 5% at 14 m stack height so the tracer gas also satisfied the standard mixing criteria in a concise length of 14 m because of the minimal difference in densities of tracer gas and air. However, due to their much higher density, aerosol particles took much longer to mix into the air. At 60 m stack height, the COV of aerosol particle concentration in one to eight injection cases is 14.8%, 18%, 8%, 12%, 11%, 15%, 15.5%, and 2%, respectively. As a result, when the stack height is set to 60 m, the COV of velocity, cyclone flow angle, tracer gas concentration, and aerosol particle concentration are found to meet the ANSI mixing criteria. Therefore, the minimum recommended height of the stack is proposed to be 60 m for the case under consideration.

Compatibility of integrated physical barriers and personal exhaust ventilation with air distribution systems to mitigate airborne infection risk

This study investigated the effectiveness of integrating desk partitions and personal exhaust ventilation to mitigate airborne infection risks in areas where people sit closely together. Experiments were conducted in a test chamber equipped with different air distribution systems, including two different mixing and one displacement ventilation. N2O tracer gas was utilized to study airborne transmission between occupants. Results showed effectiveness of preventive measures varied depending on air distributions. In the absence of preventive measures, mixing ventilation systems exhibited higher infection risk compared to displacement ventilation. After the introduction of physical barriers, N2O concentration increased at two measurement points in presence of one of the mixing ventilation systems. In contrast, the other mixing ventilation and displacement ventilation showed a reduction in N2O concentration, up to 63 % and 43 %, respectively, depending on measurement points. Combination of physical barriers and personal exhaust ventilation consistently reduced N2O concentration by 34 % to 83 %, depending on measurement point's location and type of air distribution. Furthermore, higher airflow rates of personal exhaust increased efficiency of proposed strategy in limiting infection risk. This study supports employing physical barriers and personal exhaust ventilation to reduce airborne infection risks. Tailoring preventive measures to specific air distribution system is crucial.

Wind-induced ventilation rate of single-sided ventilation in a building with internal partition

Wind-induced single-sided ventilation is a prevalent form of natural ventilation extensively used in buildings. Nevertheless, prior experimental investigations predominantly focused on single-zone buildings, neglecting the multizone buildings with internal partitions which is representative of more common scenarios. This study addresses this gap by investigating the impact of internal partitions on single-sided ventilation, employing a combination of wind tunnel experiment and numerical analysis. Airflow rate (AFR) was measured with a split-fibre probe and purging flow rate (PFR) was assessed by the tracer gas methodology. The PFR exhibits greater sensitivity to internal partitions in unidirectional airflow compared to bidirectional flow. Large Eddy Simulation (LES) was conducted to elucidate the intricate airflow characteristics in single-sided ventilation. The ventilation efficiency (ratio of PFR and AFR) derived from LES ranges between 0.74 and 0.79, which means that <80% of the AFR actively contributes to the removal of contaminants. Notably, the investigation discerned that the AFR of a single room approximates that of the entire room, whereas the PFR of a single room is smaller than that of the whole room. The disparities in AFR and PFR were caused by the recirculating flow, which was elaborated by the theoretical analysis.

Effectiveness of respiratory protective equipment on source control of exhaled pollutants

Respiratory protective equipment (RPE) is used either to protect the wearer (protection effect during inhalation) or to protect others from potential transmission of pathogens from the wearer (source control effect during exhalation). Inhalation and exhalation are two processes that generate microenvironments with different characteristics inside the RPE. In order to quantitatively evaluate the source control effectiveness (SCE) of RPE, the gap size between the RPE and the face was measured using volunteers, and the tracer-gas-based method and aerosol-based method were applied to visualize and quantify the dispersion of exhaled pollutants through the face mask and the gap using a manikin. The tracer-gas-based method (using CO2) largely overestimated the concentration of exhaled pollutants in front of the RPE. The SCE of RPE was 76–99% for aerosols and 79–92% for tracer gas. The top gap of the face mask was the dominant leakage route of exhaled pollutants. When the size of the top gap increased from 8 mm to 20 mm, the SCE for aerosols smaller than 1 μm decreased by about 15%. The SCE of the combined RPE with an N95 mask and a face shield was about 7% higher than that for an N95 mask alone. Increasing the pulmonary ventilation rate from 6 to 13 L/min and the respiratory cycle from 3 to 5 s decreased the SCE of RPE by 16% and 9%, respectively, indicating the importance of considering the activity level. The data obtained provides a basis for evaluating and improving the performance of RPE.

Infiltration Models in EnergyPlus: Empirical Assessment for a Case Study in a Seven-Story Building

The current decarbonization transition to be achieved by 2050 according to the European Council has given great prominence to the use of Digital Twins as tools for energy management. For their correct operation, it is essential to control the uncertainties of the energy models, which lead to differences between the measured and predicted data. One of the key parameters that is most difficult to assess numerically is air leakage. The existent infiltration models available in EnergyPlus were developed to be applied in low-rise residential buildings with fewer than three stories. Therefore, it is common to rely on air leakage equations employing predefined coefficients. This research presents an empirical assessment of the performance of two EnergyPlus air leakage models, the “Effective Leakage Area” and the “Flow Coefficient”, in predicting dynamic infiltration within the attic of a seven-story building. Blower door tests, along with the application of CO2 tracer gas, were conducted to establish coefficients for the models. Then, they were evaluated in three independent periods according to the criteria established in the American Society for Testing Material D5157 Standard. Those models that only used in situ coefficients consistently met the standard across all three periods, demonstrating for both equations their accurate performance and reliability. For the best model derived from tracer gas data, the R2 and NMSE values are 0.94 and 0.019, respectively. In contrast, the model developed using blower door test data and EnergyPlus default values presented a 64% reduction in accuracy compared to the best one. This discrepancy could potentially lead to misleading energy estimates. Although other software options exist for estimating infiltration, this study specifically targets EnergyPlus users. Therefore, these findings offer valuable insights to make more informed decisions when implementing the infiltration models into energy simulations for high-rise buildings using EnergyPlus.

Airborne pathogens diffusion: A comparison between tracer gas and pigmented aerosols for indoor environment analysis

The evaluation of airborne pathogens diffusion is a crucial practice in preventing airborne diseases like COVID-19, especially in indoor environments. Through this transmission route, pathogens can be carried by droplets, droplet nuclei and aerosols and be conveyed over long distances. Therefore, understanding their diffusion is vital for prevention and curbing disease transmission. There are different techniques used for this purpose, and one of the most common is the utilization of tracer gas, however, it has limitations such as the difference in size between the gas molecules and the respiratory droplets, as well as its incapability to take into account evaporation. For this reason, a new method for evaluating the diffusion of respiratory droplets has been developed. This approach involves the use of an ultrasonic emitter to release and disperse pigmented aerosols, and a colorimeter for the following quantitative evaluation. A comparison with the tracer gas technique has been carried out, showing for the pigmented aerosols methodology a response that is dependent on different relative humidity conditions, while there is no clear difference in the dispersion of tracer gas at high or low humidity.

Implementation of an On-Line Reactive Source Apportionment (ORSA) Algorithm in the FARM Chemical-Transport Model and Application over Multiple Domains in Italy

A source apportionment scheme based on gas and aerosol phase reactive tracers has been implemented in the chemical-transport model FARM, to efficiently estimate contributions of different sources to ambient concentrations. The on-line scheme deals with all the main processes that the chemical species undergo in the model, to enhance consistency with the calculation of bulk concentrations. The fate of precursors through gas-phase chemical reactions is followed by an efficient solver that determines their incremental reactivity, while the contributions to the secondary particulate species from their gaseous precursors is determined by assuming the thermodynamic equilibrium between the two phases. The paper details the new employed methodologies and illustrates the application of the apportionment scheme (based on 6 source sectors) to PM10 and O3, simulated on three domains of different dimensions in Italy, all sharing the same horizontal resolution and a common region (Lombardy). Spatial patterns of results show, on average, a relevant contribution of heating on PM10 concentration in January, with local hotspots dominated by road traffic. Contributions appear consistent in the three simulated domains, apart from the boundary conditions, influenced by the dimension of the domain. Hourly series of contributions to O3 concentrations in July at three selected sites show the dominance of boundary conditions, underlining the large scale of O3 formation. Finally, for PM10 components, the resulting sectorial contributions are compared with the impacts computed via the brute force method, showing that results are similar for elemental carbon and sulfate, while they are different for nitrate and ammonium, due to a different allocation of contributions and impacts between the methods. Each approach responds in principle to a different purpose, and their combined use provides possibly a wide set of information useful for addressing the different air quality management needs.