Based on semi-direct sums of Lie suhalgehra , a higher-dimensional 6 × 6 matrix Lie algebra sμ(6) is constructed. A hierarchy of integrable coupling KdV equation with three potentials is proposed, which is derived from a new discrete six-by-six matrix spectral problem. Moreover, the Hamiltonian forms is deduced for lattice equation in the resulting hierarchy by means of the discrete variational identity — a generalized trace identity. A strong symmetry operator of the resulting hierarchy is given. Finally, we prove that the hierarchy of the resulting Hamiltonian equations is Liouville integrable discrete Hamiltonian systems.