Trace Element Geochemical Data Research Articles

A machine learning approach to tracking crustal thickness variations in the eastern North China Craton

The variation of crustal thickness is a critical index to reveal how the continental crust evolved over its four billion years. Generally, ratios of whole-rock trace elements, such as Sr/Y, (La/Yb)n and Ce/Y, are used to characterize crustal thicknesses. However, sometimes confusing results are obtained since there is no enough filtered data. Here, a state-of-the-art approach, based on a machine-learning algorithm, is proposed to predict crustal thickness using global major- and trace-element geochemical data of intermediate arc rocks and intraplate basalts, and their corresponding crustal thicknesses. After the validation processes, the root-mean-square error (RMSE) and the coefficient of determination (R2) score were used to evaluate the performance of the machine learning algorithm based on the learning dataset which has never been used during the training phase. The results demonstrate that the machine learning algorithm is more reliable in predicting crustal thickness than the conventional methods. The trained model predicts that the crustal thickness of the eastern North China Craton (ENCC) was ~45 km from the Late Triassic to the Early Cretaceous, but ~35 km from the Early Cretaceous, which corresponds to the paleo-elevation of 3.0 ± 1.5 km at Early Mesozoic, and decease to the present-day elevation in the ENCC. The estimates are generally consistent with the previous studies on xenoliths from the lower crust and on the paleoenvironment of the coastal mountain of the ENCC, which indicates that the lower crust of the ENCC was delaminated abruptly at the Early Cretaceous.

Identifying geochemical anomalies and spatial distribution of gold and associated elements in the Zuru Schist Belt, northwest Nigeria

The Zuru Schist Belt is one of the gold-bearing schist belts in northwestern Nigeria. The gold mineralisation is mainly associated with NE-trending shear zones and is hosted in veins of quartz, quartz-tourmaline and quartz-feldspar. In this study, the spatial pattern of gold and associated elements was identified and delineated through statistical analysis of trace element geochemical data. Statistical analyses including spearman correlation, principal component analysis and hierarchical cluster analysis were applied on the geochemical data to decipher and interpret multi-element association related with gold mineralisation. Spearman correlation revealed significant positive correlation amongst Co, Mn, Fe, V, Ni and Zn (>0.70), while Au has moderate correlation with Ag, Bi and Cu (>0.30). Based on principal component analysis and hierarchical cluster analysis, three element associations can be recognised: (a) Zn-Ni-Co-Mn-Fe-V, (b) Au-Ag-Bi-Pb and (c) Zn-U-Th-Sr-La-Ba. The first two multi-element associations are related to gold mineralisation. The multi-element association of Zn-Ni-Co-Mn-Fe-V signifies lithogenic factor and associated hydrothermal alteration, while Au-Ag-Bi-Pb is indicative of gold mineralisation. The combination of Au and associated elements (Ag, Bi and Pb), which was achieved through the use of uni-element thresholds (median+2 median absolute deviation) in multi-element halo technique, enabled the mapping of multi-element geochemical anomaly. The uni- and multi-element geochemical anomaly maps show geochemical anomalies in the northern, central and southern parts of the area. These anomalies, largely restricted to metasedimentary rocks notably foliated quartzite, schist, and phyllite, represent where further exploration should be focused with more attention particularly in the northern part where higher concentration than previously reported was observed.

Geology and geochronology of the Jurassic magmatic arc in the Magdalena quadrangle, north-central Sonora, Mexico

This work reports on the geology and U–Pb LA-ICPMS zircon geochronology of a crustal section that is part of the Jurassic magmatic arc in the Magdalena quadrangle of north-central Sonora, Mexico. This rock succession is variably metamorphosed and strained as it was affected by Late Cretaceous shortening, intruded by early Tertiary granitoids, and further exhumed in the lower plate of the early Miocene Magdalena metamorphic core complex. The older and more extensively exposed Jurassic unit is the >3.5 km thick Sierra Guacomea rhyolite that is composed of massive to poorly bedded rhyolite, bedded quartz-phyric rhyolitic ignimbrite and interbedded ash-fall tuffs and quartz-rich sandstone beds. Three rhyolite samples collected at different localities of its outcrops yielded concordia ages of 175.2 ± 0.9, 171.7 ± 0.6, and 171.4 ± 0.7 Ma. The quartz-phyric Rancho La Víbora, Los Vallecitos, and the Agua Caliente rhyolitic domes that are associated with the Sierra Guacomea rhyolite yield concordia ages of 176 ± 0.8, 174.4 ± 0.9 and 173.1 ± 0.8 Ma, respectively. The Rancho Los Pozos unit composed of interbedded rhyolitic ash-fall tuff and flows, sandstone, siltstone and subordinate limestone beds has an estimated thickness of 600 m and yielded a crystallization concordia age of 170.7 ± 0.6 Ma from a rhyolite bed. The porphyritic El Rincón granite that intrudes into the Sierra Guacomea rhyolite yields crystallization ages of 167.43 ± 0.42 and 164.4 ± 0.7 in samples from different localities. The La Jojoba metasandstone that consists of foliated, quartz-rich to arkosic strata of fluvial origin is at least 900 m thick; detrital zircon grains dated from three sandstone samples yielded dominantly Jurassic ages with peaks at 172, 170, and 163.7 Ma, and a combined maximum depositional age of ca. 163 Ma.The younger plutons are the porphyritic El Nopalito granite that has an interpreted crystallization age of 160.8 ± 0.6 Ma, and the leucocratic, two-mica, garnet-bearing La Cebolla granite that yielded a concordia age of 158.1 ± 1 Ma. These granitic intrusions record the waning magmatic pulses of the arc, in the study quadrangle, but their volcanic equivalents were not identified. Inherited zircon grains in the reported volcanic and plutonic units are only of Jurassic age, except by two Proterozoic zircon grains yielded by the El Nopalito granite. The El Salto granite augen gneiss is a xenolith dated at 1071.9 ± 5 Ma that indicates the presence of Grenvillian basement in the study area.Major- and trace-element geochemical data indicate that the volcanic and plutonic units are silica-rich, mostly high K calc-alkaline to shoshonitic rocks associated with a continental margin arc setting. The plutons are mostly peraluminous, and in conjunction with trace element geochemistry data, they suggest crustal assimilation of magmas emplaced in a probably thickened continental crust. Chondrite-normalized REE patterns and primitive mantle-normalized trace element diagrams also suggest partial melting and fractional crystallization processes.The ages obtained indicate that the arc in the study area developed from ca. 176 to 158 Ma, encompassing a 17 m.y. interval of magmatism and associated sedimentation. Regional correlation and geochronologic published data indicate that the arc crustal section of the Magdalena quadrangle is part of the Jurassic magmatic arc that regionally lasted from ca. 190 to 158 Ma.

The Peltetec ophiolitic belt (Ecuador): a window to the tectonic evolution of the Triassic margin of western Gondwana

ABSTRACT New field and petrographic observations, whole-rock major- and trace-element geochemical data, Nd and Sr isotope systematics and U-Pb SHRIMP zircon ages of the Peltetec metaophiolite and related rocks (Ecuador) allow the characterization of the igneous and sedimentary protoliths and the evaluation of the geodynamic evolution of the active western margin of Gondwana during the Mesozoic. The Peltetec ophiolitic belt, exposed along the western margin of the Cordillera Real (Ecuador) and previously considered of Cretaceous age, comprises slices of metamorphosed (greenschist facies) and variably deformed peridotites, gabbros (locally cumulate), basaltic lavas and dykes, hydrothermal breccias and sedimentary rocks. The geochemical characteristics of the tholeiitic basaltic rocks indicate a Sr-Nd isotope depleted mantle source with variable imprint of subduction zone-derived or continental crust-assimilated components, as indicated by enrichment in Th, negative anomaly of Nb and relative depletion in high field strength elements (HFSE). Geochemical diversity allows defining different groups of noncumulate igneous rocks with oceanic island arc and NMORB-like back-arc affinities. U-Pb zircon ages from a metabasite yielded 228.1 ± 1.7 Ma, interpreted as the crystallization age of the magma. These data allow proposing the generation of the Peltetec ophiolite in a back-arc setting as a consequence of late Triassic extension of the western continental margin of Gondwana. Granites located at the western margin of the Peltetec Unit with S-type affinity and equal Triassic age (U-Pb age of 228.2 ± 0.8 Ma) document coeval anatexis of the continental crust as a consequence of heating associated with the same extensional event that originated the ophiolite. Geologic correlation allows enlarging such tectonic scenario to include ophiolitic units of similar age in Colombia.

Petrogenesis and Tectonic Setting of the Highly Fractionated Junye Granitic Intrusion in the Yiliu Tungsten Polymetallic Deposit, Guangdong Province, South China: Constraints from Geochemistry and Sr-Nd-Pb-Hf Isotopes

The Yiliu tungsten polymetallic deposit, located in the south central portion of the Nanling nonferrous metal metallogenic province in South China, is an area with common Yanshanian tectonothermal events. Early Yanshanian magmatism leads to the emplacement of voluminous tungsten-bearing granite intrusions, such as the Baoshan, Benggangling and Junye plutons, which are considered temporally and spatially associated with W-polymetallic mineralization in the Yiliu region. Here, we investigate the basic geological and petrological characteristics of the Junye granites, and present major and trace element geochemical data and bulk-rock Sr-Nd-Pb-Hf isotopic data to gain insight into the petrogenesis and tectonic setting of granitic intrusions in the region. The Junye granites are high-K calc-alkaline and metaluminous to weakly peraluminous [A/CNK = molar ratios of Al2O3/(CaO + Na2O + K2O) = 0.97–1.02] with enrichment in SiO2 (75.68–76.44 wt.%), relatively high total alkalis (K2O + Na2O = 8.06–8.45 wt.%) with K2O/Na2O ratios ranging from 1.12 to 1.42, and moderate Al2O3 (12.62–13.00 wt.%), but low in P2O5 (<0.01 wt.%), MgO (0.02–0.04 wt.%), CaO (0.78–0.95 wt.%) and Fe2O3T (0.93–1.07 wt.%). They show spectacular tetrad effect REE (rare earth element) patterns with low ΣREE content (53.2–145.3 ppm), negative Eu anomalies (δEu = 0.09–0.17) and slight enrichment of LREEs (light rare earth elements) relative to HREEs (heavy rare earth elements). The granites are enriched in Rb (481–860 ppm), Th (16.2–46.1 ppm) and U (25.4–40.8 ppm) but depleted in Ba (1.0–5.8 ppm), Sr (11.1–23.4 ppm), P (9.5–26.7 ppm) and Ti (241–393 ppm). All geochemical features lead us to interpret the Junye granites as highly fractionated I-type granites. These granites underwent intense interaction between highly evolved magma and volatile-rich hydrothermal fluids during the late stage of formation, and accompanied fractional crystallization of biotite, plagioclase and accessory minerals, such as apatite, monazite and allanite. Additionally, the granites show uniform Nd isotopic ratios with calculated εNd (152 Ma) values of −8.28 to −8.91 and Nd model age (TDM2) of 1645 to 1698 Ma, stable age-corrected initial Pb isotopic compositions with (206Pb/204Pb)i of 18.646–19.010, (207Pb/204Pb)i of 15.767–15.786 and (208Pb/204Pb)i of 39.113–39.159, respectively, and homogeneous Hf isotopic values yielding εHf (152 Ma) values from −6.9 to −9.5 with TDM2 ages of 1680 to 2214 Ma, collectively suggesting that the granitic magma was probably derived from the remelting of ancient infracrustal materials in the basement of the Nanling region. Consequently, we consider that the Junye granites are the products of partial melting of Paleoproterozoic infracrustal medium- to high-K metamorphic basaltic rocks in the Cathaysia Block, which was caused by the underplating of coeval mantle basaltic magmas that provided abundant heat energy for melting in a tectonic setting, with lithospheric extension and thinning during the late Jurassic period.

Detrital record of the late Oligocene – early Miocene mafic volcanic arc in the southern Patagonian Andes (∼51°S) from single-clast geochronology and trace element geochemistry

Retroarc foreland basins are important archives of continental arc magmatism and upper plate deformational processes that control the evolution of continental lithosphere. However, resolving source areas in foreland basin infill dominated from mixed mafic and recycled sediment using conventional methods such as detrital zircon geochronology poses a challenge to thorough analysis due to lower zircon fertility and the higher susceptibility to weathering of mafic lithologies. Here, we integrate whole rock 40Ar/39Ar geochronology and major and trace element geochemistry data from volcanic clasts from the lower Miocene infill of the Magallanes-Austral Basin and local Sierra Baguales intrusive rocks to understand the distribution of mafic sources and Neogene changes in arc magmatism in between multiple ridge subduction events in the southern Patagonian Andes. Potential source areas for the coarse-grained mafic detritus include the Eocene plateau lavas, the Late Jurassic-Miocene Southern Patagonian batholith, and the Late Jurassic Sarmiento Ophiolitic Complex. Published detrital zircon U-Pb age spectra suggest that all three sources are viable contributors to the basin, though the paucity of Jurassic and Eocene zircons preclude these as major sources. Here, new 40Ar/39Ar dating of the volcanic clasts from the early Miocene Río Guillermo Formation reveals latest Oligocene to early Miocene eruptive ages (∼25-22 Ma), indicating syndepositional eruption with the ancestral Río Guillermo fluvial sedimentation. A single dated clast yields a Late Cretaceous age (∼102 Ma). The clasts are dominantly basaltic andesite with Ba/Ta ∼500-1000, La/Ta >20, and Ba/La >15, indicating an arc-derived melt source. We propose that the clasts record a Miocene mafic continental arc source area in the Patagonian Andes, which has since been removed by erosion and is thus sparsely represented in the batholith. Furthermore, we suggest that this early Miocene phase of arc volcanism, which postdates Eocene and Oligocene backarc magmatism and pre-dates middle Miocene to recent Chile Ridge backarc magmatism, reflects a return to normal arc volcanism along the Patagonian margin following a cessation due to ridge subduction and subsequent slab window migration. New geochemistry and 40Ar/39Ar data from a basaltic dike in the Sierra Baguales, which crosscuts the Cenozoic stratigraphic section, records plateau magmatism ∼16 Ma associated with incipient Chile Ridge slab window volcanism.

Volcanic record of the arc-to-rift transition onshore of the Guaymas basin in the Santa Rosalía area, Gulf of California, Baja California

AbstractThe Gulf of California is an archetype of continental rupture through transtensional rifting, and exploitation of a thermally weakened arc to produce a rift. Volcanic rocks of central Baja California record the transition from calcalkaline arc magmatism, due to subduction of the Farallon plate (ca. 24–12 Ma), to rift magmatism, related to the opening of the Gulf of California (<12 Ma). In addition, a suite of postsubduction rocks (<12 Ma), referred to as “bajaites,” are enriched in light rare-earth and other incompatible elements (e.g., Ba and Sr). These are further subdivided into high-magnesian andesite (with 50%–58% SiO2 and MgO >4%) and adakite (>56% SiO2 and MgO <3%). The bajaites correlate spatially with a fossil slab imaged under central Baja and are inferred to record postsubduction melting of the slab and subduction-modified mantle by asthenospheric upwelling associated with rifting or slab breakoff. We report on volcanic rocks of all three suites, which surround and underlie the Santa Rosalía sedimentary rift basin. This area represents the western margin of the Guaymas basin, the most magmatically robust segment of the Gulf of California rift, where seafloor spreading occurred in isolation for 3–4 m.y. (starting at 6 Ma) before transtensional pull-apart basins to the north and south ruptured the continental crust. Outcrops of the Santa Rosalía area thus offer the opportunity to understand the magmatic evolution of the Guaymas rift, which has been the focus of numerous oceanographic expeditions.We describe 21 distinct volcanic and hypabyssal map units in the Santa Rosalía area, using field characteristics, petrographic data, and major- and trace-element geochemical data, as well as zircon isotopic data and ten new 40Ar-39Ar ages. Lithofacies include lavas and lava domes, block-and-ash-flow tuffs, ignimbrites, and hypabyssal intrusions (plugs, dikes, and peperites). Calcalkaline volcanic rocks (13.81–10.11 Ma) pass conformably upsection, with no time gap, into volcanic rocks with rift transitional chemistry (9.69–8.84 Ma). The onset of rifting was marked by explosive eruption of silicic ignimbrite (tuff of El Morro), possibly from a caldera, similar to the onset of rifting or accelerated rifting in other parts of the Gulf of California. Epsilon Hf zircon data are consistent with a rift transitional setting for the tuff of El Morro. Arc and rift volcanic rocks were then juxtaposed by normal faults and tilted eastward toward a north-south fault that lay offshore, likely related to the north-south normal faults documented for the early history of the Guaymas basin, prior to the onset of northwest-southeast transtenional faulting. Magmatism in the Santa Rosalía area resumed with emplacement of high-magnesian andesite lavas and intrusions, at 6.06 Ma ± 0.27 Ma, coeval with the onset of seafloor spreading in the Guaymas basin at ca. 6 Ma.The 9.69–8.84 Ma rift transitional volcanic rocks underlying the Santa Rosalía sedimentary basin provide a maximum age on its basal fill. Evaporites in the Santa Rosalía sedimentary basin formed on the margin of the Guaymas basin, where thicker evaporites formed. Overlying coarse-grained clastic sedimentary fill of the Santa Rosalía basin and its stratiform Cu-Co-Zn-Mn sulfides may have accumulated rapidly, coeval with emplacement of 6.06 Ma high-magnesian andesite intrusions and the ca. 6 Ma onset of seafloor spreading in the Guaymas basin.

Contemporaneously emplaced submarine volcaniclastic deposits and pillow lavas from multiple sources in the island arc Brook Street Terrane, Southland, New Zealand

ABSTRACT Volcaniclastic and coherent volcanic rocks of the Permian island arc Brook Street Terrane crop out along the Southland coast, New Zealand, near Riverton. Extensive along-strike exposures reveal lateral variations in these submarine deposits and provide a rare opportunity to examine deposits of an arc environment within a thin slice of time. We describe pillow lavas, dikes, hydroclastic breccias, tuffs, lapilli tuffs and argillites, all hydrothermally altered and metamorphosed to prehnite-pumpellyite facies. Trace element geochemical data indicate multiple primitive island arc to MORB-like magma sources. Two separate volcanic centres apparently tapped different mantle domains in a source region transitional between the arc and back-arc. The centres’ proximity and inferred small sizes suggest they were satellite vents of a larger arc volcano. Tuff and lapilli tuff were formed as hyaloclastite during eruption of pillow lava, and redeposited by subaqueous mass flows. Peperitic contacts indicate that the lavas intruded unconsolidated volcaniclastic deposits. We infer that hydroclastic fragmentation associated with pillow emplacement produced debris that was then intruded by later pillows, with local peperite formation, as eruption persisted. The hydroclastic debris from these satellite vents was resedimented in turbidite fans with channels, and periodic turbidity currents delivered fine-grained material from the volcano’s main vent.

Constraints on the Genesis of the Qixiashan Pb-Zn Deposit, Nanjing: Evidence from Sulfide Trace Element Geochemistry

The large-scale Qixiashan Pb-Zn Deposit in the eastern Middle-Lower Yangtze metallogenic belt is hosted in carbonate rocks. Based on a detailed mineral paragenesis study, in-situ LA-ICP-MS (laser ablation inductively coupled plasma mass spectrometer) trace element geochemistry data for pyrite and sphalerite from different stages in the Qixiashan Deposit are reported, the Pb-Zn mineralization processes are reconstructed, and a genetic model is constructed. Four paragenetic stages of Pb-Zn ore deposition are identified: the biogenic pyrite mineralization stage (Stage 1), the early stage of hydrothermal Pb-Zn mineralization (Stage 2), the late stage of hydrothermal Pb-Zn mineralization (Stage 3), and the carbonate stage (Stage 4). Stages 2 and 3 are the main ore stages. The trace element characteristics of the sulfide in stages 2 and 3, such as the higher Co/Ni and lower trace element contents of the pyrite and the Fe, Mn, and Ge contents of the sphalerite, indicate that they were generated by magmatic-hydrothermal processes. Furthermore, the lower Cu, Ag, Sb, and Pb contents of the pyrite and sphalerite of Stage 3 compared to Stage 2 suggest an increase in magmatic-hydrothermal activity from Stage 2 to Stage 3. The hydrothermal fluids leached trace elements (e.g., Cu, Ag, Sb, and Pb) from the previously deposited primary pyrite and sphalerite, which were precipitated in the later hydrothermal stage Cu, Au, Ag, Sb, and Pb bearing minerals and secondary pyrite and sphalerite with lower trace element contents (e.g., Cu, Au, Ag, Sb, and Pb). Compared with the pyrite from stages 2 and 3, the Stage 1 pyrite has relatively higher trace elements contents (Sb, Cu, Zn, Au, Ag, Pb, As, and Ni). However, their lower Co/Ni ratio suggests a syngenetic sedimentary origin. Based on the petrographic features and trace element data, a multi-stage mineralization model is proposed. The Stage 1 biogenic pyrite formed stratiform pyrite layers, which provided reducing conditions and a base for the subsequent Pb-Zn mineralization. During Stage 2, subsequent hydrothermal fluid interacted with the stratiform pyrite layers, which resulted in sulfide precipitation and the formation of stratiform Pb-Zn orebodies. In Stage 3, the hydrothermal fluid replaced the limestone along the fractures, which triggered the formation of Pb-Zn vein orebodies.

Adakitic rocks and A‐type felsic dykes in the Changlingzi area, NE China: Constraints on multistage tectonism in the southern Great Xing'an Range

New LA–ICP–MS zircon U–Pb geochronology, whole‐rock major and trace element geochemistry data, and petrographic observations are presented for three granitic dykes in the Changlingzi area of NE China. These data provide precise age and petrogenesis information with respect to the late Palaeozoic–Mesozoic intrusions in the area, which further constrain the geodynamic evolution of the southern Great Xing'an Range. Our zircon U–Pb data denote that the felsic dykes were emplaced during the Late Permian (~254 Ma) and Late Jurassic (143–142 Ma). Geochemically, the Late Permian monzonite porphyries are characterized by high Al2O3 (16.52–16.92 wt%) and Sr (490–579 ppm) contents and low Yb (0.52–0.57 ppm), Y (5.7–6.3 ppm), and heavy rare earth element (HREE) contents, which indicate an adakitic affinity. The Late Jurassic felsic dykes are characterized by high FeOt/MgO (8.2–11.9) and Ga/Al (3.3–3.8) ratios, high zircon saturation temperatures (888–929°C), and remarkable negative Eu (Eu/Eu* = 0.25–0.42) anomalies, indicating they are akin to A‐type granites. The Late Permian adakitic magma resulted from the partial melting of thickened lower crust, and was formed during collisional orogenesis related to subduction of Palaeo‐Asian Ocean crust. The Late Jurassic A‐type magmas were probably generated by the partial melting of amphibolite‐facies lower crustal materials. The melting occurred in response to the upwelling of asthenospheric material caused by collapse of thickened crust, due to gravitational instability during closure of the Mongol–Okhotsk Ocean. Subsequently, the latest stage of magmatic activity in this area and elsewhere in NE China was controlled mainly by subduction of Palaeo‐Pacific Ocean crust.

Seasonal geochemical heterogeneity of sediments from a subtropical mountainous river in SE China

The Zhe-Min mountainous rivers in SE China are characterized by stable tectonics, small–mesoscale drainage basins, relatively homogenous bedrocks, dense vegetation cover and high rainfall conditions. These rivers deliver loads of sediments and nutrients to the oceans and always indicate considerably high variability of sediment flux on short-term timescales. However, short-term sediment compositional variations and transport mechanism by these mountainous rivers remain poorly understood. Here we target the Minjiang River, use mineralogical and trace element geochemical data of suspended particulate matters (SPMs) within a one-year hydrological cycle (from October 2016 to October 2017), riverbed sediments (<0.063 mm fractions) and SPMs from the mainstream and major tributaries, to investigate their provenance and transport process. The results indicate that the SPMs in different seasons have strong seasonal geochemical heterogeneity, with highly positive correlations between several trace element ratios (e.g. La(CN)/Yb(CN) and Th/Sc) and runoff of the river. Riverbed sediments and SPMs collected in pairs have distinct geochemical compositions. The riverbed sediments have relatively low La(CN)/Yb(CN) (ca. 10–15) and Th/Sc (ca. 2–5) ratios, whereas the SPMs have La(CN)/Yb(CN) and Th/Sc ratio ranges of ca. 14–17 and ca. 4–7, respectively. These findings suggest a predominant hydrologic control on the Minjiang River sediment transport and geochemical compositions on a seasonal timescale. We conclude that exposed riverbed sediments are probably selectively recycled in dry-season sediment transport, whereas the flood-season SPMs are less mixed with riverbed sediments and are likely dominated by particulates directly from those tributaries and the upper mainstream. We favor that the Zhe-Min mountainous rivers are featured by rapid sediment delivery in response to hydroclimatic changes and have similar sediment transport behaviors with those small mountainous rivers in tectonically active regions of the subtropical East Asia (e.g. Taiwan). This case study also highlights the importance of multi-spatio-temporal scale, heterogeneous river input of chemical elements to the oceans.

Permian felsic volcanic rocks in the Pannonian Basin (Hungary): new petrographic, geochemical, and geochronological results

Two distinct Permian volcanic epochs were revealed in the Pannonian Basin (eastern Central Europe) by U–Pb zircon geochronology: an older one (~ 281 Ma, Cisuralian) in the ALCAPA Mega-unit (Central Transdanubia, Hungary) and a younger volcanic episode (~ 267–260 Ma, Guadalupian) in the Tisza Mega-unit (Southern Transdanubia and the eastern Pannonian Basin, Hungary). The former is represented by dacitic subvolcanic rocks (dykes) and lavas, while the latter is dominantly by crystal-rich rhyolitic–rhyodacitic/dacitic ignimbrites and subordinate rhyodacitic/dacitic lavas. Whole-rock (major and trace element) geochemical data and zircon U–Pb ages suggest close relationship between the samples of Central Transdanubia and volcanic rocks of the Northern Veporic Unit (Western Carpathians, Slovakia), both being part of the ALCAPA Mega-unit. Such correlation was also revealed between the Permian felsic volcanic rocks of the Apuseni Mts (Romania) and the observed samples of Southern Transdanubia and the eastern Pannonian Basin that are parts of the Tisza Mega-unit. The older volcanic rocks (~ 281–265 Ma) could be linked to post-orogenic tectonic movements, however, the youngest samples (~ 260 Ma, eastern Pannonian Basin, Tisza Mega-unit) could be formed in the extensional setting succeeding the post-collisional environment. On the whole, the observed Permian magmatic rocks show significant similarity with those of the Western Carpathians.

Was Permian magmatism in the eastern Songnen and western Jiamusi massifs, NE China, related to the subduction of the Mudanjiang oceanic plate?

This paper presents new zircon U–Pb ages and Hf isotope data, and whole‐rock major and trace element geochemical data of Permian igneous rocks from the eastern Songnen Massif (SM) and the western Jiamusi Massif (JM), NE China, to constrain their tectonic evolution. Zircon U–Pb dating indicates that Permian magmatism within the eastern SM can be subdivided into two stages: early Permian (ca. 293 Ma) and middle to late Permian (272–257 Ma). The early Permian igneous rocks comprise a bimodal association of rhyolites, basaltic andesites, and gabbros. The middle to late Permian igneous rocks are dominated by gabbro–diorites, monzodiorites, quartz diorites, monzonites, quartz monzonites, granodiorites, monzogranites, syenogranites, and alkali feldspar granites, along with minor bodies of A‐type quartz trachytes. The Permian felsic magmas originated mainly from partial melting of a relatively juvenile lower crust, whereas the coeval mafic rocks were probably derived from partial melting of a relatively depleted lithospheric mantle that was modified by fossil subduction‐related fluids. The igneous rock associations and their geochemical features, together with data from coeval sedimentary and volcanosedimentary successions, indicate that Permian magmatism within the eastern Songnen and western Jiamusi massifs formed in an extensional environment, similar to a back‐arc setting, related to westward subduction of a Palaeo‐oceanic plate beneath the eastern margin of the Jiamusi Massif. We find no evidence for double‐sided subduction of the Mudanjiang oceanic plate during the Permian.

Formation of lower to middle crust of the Wyoming Craton, Montana (USA), using evidence from zircon Hf-O isotopic and trace element compositions

Coupled oxygen-hafnium isotope and trace element geochemical data were obtained using thirty eight previously dated zircon grains extracted from five mafic to intermediate crustal xenoliths of the Wyoming Craton (Montana, USA). Xenoliths include mid to lower crustal (642–817 °C and 3.5–9.4 kbar) mafic granulites and amphibolites with dominantly Mesoproterozoic (1772–1874 Ma) and minor Paleoproterozoic to Late Archean (2004–2534 Ma) 207Pb/206Pb zircon ages. Zircon oxygen isotope data indicate derivation from melts in equilibrium with a mantle source that interacted with limited supracrustal material (δ18O = 4.4–5.7‰), as well as the incorporation of supracrustal fluids or melts into mantle source regions (δ18O = 6.0–8.1‰). The small within-sample isotopic variability suggests that primary zircon did not exchange with isotopically distinct fluids or melts after initial formation. Initial zircon Hf isotopic values are highly variable across all xenoliths (εHf = +3.7 to −17.6), consistent with protolith derivation from mantle sources that incorporated evolved, unradiogenic material or were modified by subduction-related fluids. Within a single granulite xenolith, two zircon types are recognized based on CL imagery, Hf isotopes and U-Pb ages (Type I and Type II). Type I magmatic zircons show dispersed ages (ca. 1700–2534 Ma) and unradiogenic initial Hf (εHf = −17.6 to −1.5, 176Hf/177Hf = 0.281074–0.281232). The spread in ages and initial εHf, but narrow range in initial 176Hf/177Hf, points to variable Pb loss in response to dissolution-recrystallization of pre-existing zircon. Type II metamorphic zircon yields a younger Proterozoic population (ca. 1700–2155 Ma) with more radiogenic initial Hf relative to Type I zircon (εHf = −7.9 to +1.4, 176Hf/177Hf = 0.281427–0.281578); this type represents newly grown metamorphic zircon that formed in the solid-state and incorporated Zr and Hf from pre-existing zircon and silicate matrix/metamorphic phases. REE patterns from all xenoliths are steep and positively sloping without discernible HREE depletion relative to LREE, implying zircon crystallization/recrystallization in the absence of garnet. Negative Eu anomalies signify simultaneous zircon and feldspar crystallization. Solid-state recrystallization may have lead to variations in LREE, Eu and Ce in certain xenoliths. Xenoliths containing magmatic zircon (1834 ± 19 Ma) with mantle-like δ18O (4.4–5.5‰) and radiogenic initial εHf (−2.3 to +3.7) likely formed through crystallization of melts derived from a mantle source that incorporated minor amounts of subducted sedimentary/supracrustal material. Proterozoic (1874 ± 8 Ma) xenoliths with elevated δ18O (6.0–7.0‰) and unradiogenic initial εHf (−8.2 to −9.6) within magmatic zircon represent melt products of subduction-induced melting and metasomatism of the overlying mantle wedge in the vicinity of the northern GFTZ. Older (ca. 2534 Ma) xenoliths containing zircons with elevated δ18O (6.4–7.2‰) and unradiogenic εHf (up to −17.6) represent crystallization of protolith magmas extracted from a mantle source metasomatized by subduction-derived fluids and melts in the Late Archean or earlier. Zircon geochronology and isotope systematics within Mesoproterozoic xenoliths support a model of ocean-closure and subsequent continental collision between the Medicine Hat Block and Wyoming Craton, resulting in the formation of subduction-related melts at ca. 1834–1874 Ma, followed by ca. 1770 Ma collision-related metamorphism thereafter.

Thickening and partial melting of the Northern Qinling Orogen, China: insights from zircon U–Pb geochronology and Hf isotopic composition of migmatites

The widespread migmatites in the Precambrian basement of the North Qinling Belt are products of partial melting of the Earth's crust and record the tectono-thermal response to Late Paleozoic collision along the Shangdan suture. The morphology and trace element geochemistry of zircons from the migmatites suggest a metamorphic origin related to partial melting. The zircons from leucosome, melanosome and banded migmatites yield U–Pb weighted mean ages of 408 ± 2, 403 ± 2 and 400 ± 2 Ma, respectively, constraining the timing of migmatization. The granitic dyke intruded into the migmatites gives a zircon U–Pb weighted mean age of 396 ± 2 Ma, constraining the minimum time of migmatization. Zircons from the melanosome and banded migmatite yield upper intercept ages of 1088–1061 Ma, representing the protolith ages of the basement of the North Qinling Belt. The zircon rims of the melanosome and banded migmatite predominantly display negative and positive ε Hf ( t ) values, respectively, suggesting the variable input of mantle material. Together with the regional geology and previous geochronological data, we propose that the thickening and partial melting in the North Qinling Belt was induced by the collision along the Shangdan suture between the North and South China Blocks from c. 408 to 400 Ma. Supplementary material: LA-ICP-MS U–Pb data, Lu–Hf isotopic compositions and trace element geochemistry data of the zircons and Ti-in-zircon thermometry are available at https://doi.org/10.6084/m9.figshare.c.4521389

Spatial distribution and trace element geochemistry of laterites in Kunche area: Implication for gold exploration targets in NW, Ghana

Kunche area is located in NW Ghana within the Wa-Lawra greenstone Birimian belt and is composed mainly of volcaniclastics, metasediments and some intrusive granitoids. The area is covered with laterites making it difficult to identify exploration targets. In this study, we describe a new methodology based on statistical tools and trace element geochemistry to map the pathfinder elements of gold deposits in lateritic context. However, the results of this study are specific to a particular context and cannot be extrapolated without supplementary studies to all the lateritic areas. In this respect, a total of 67 lateritic samples were collected from residually weathered materials and their spatial distribution was determined by means of the GIS-based kriging interpolation method. The samples collected vary from detrital to residual laterites/duricrusts and are hosted in volcaniclastic rocks. ICP-MS and XRF techniques were used to determine the element concentrations of the samples. The trace element geochemical data were analyzed using bivariate and multivariate geostatistical analysis to establish relationships among elements. Fe-oxides such as goethite and hematite and clay minerals like kaolinite are the main secondary minerals of the concretionary reddish lateritic samples. All the analyzed elements showed asymmetrical distribution rather than normal distribution. Spearman correlation shows that Cu, Pb, S, As, and Ag have moderate to strong positive correlation with Au. From the multivariate geostatistical analysis, three element associations; a) Fe, Pb, S, Co, Cr; b) Ni, Y, Rb, Sr, Zn, and c) Ca, Cu, Mn, Ti, Zr, As, Au, Ag were observed. Threshold values of selected elements were determined using the median absolute deviation (MAD) method, which indicates possible anomalous concentrations in the laterites for Pb (≥48 ppm), Cu (≥46 ppm), As (≥134.2 ppm), and Ag (≥0.42 ppm). Multi-element mapping indicates that Pb + Cu + As + Ag is the most ideal association in the exploration of gold deposits. It reveals ellipsoidal anomalies comparable to the Au distribution map that suggest dispersion and accumulation of the pathfinder elements in the area. The geochemical anomalies are mainly restricted to the environment of the residual laterites in the Kunche area and we recommend that exploration programs should be focused in such areas.

The geochemistry of glacial deposits in Taylor Valley, Antarctica: Comparison to upper continental crustal abundances

Wet-based glacial deposits have been used traditionally as an analog for upper continental crust (UCC) abundances. To provide more information on the validity of using glacial deposits from wet-based glaciers, samples deposited by the dry-based polar glaciers located in Taylor Valley, Antarctica, were collected. Stream channel sediments, comprised of igneous, metamorphic, and sedimentary rocks initially deposited as glacial tills by polar glaciers, were analyzed by XRF, ICP-MS, and SEM. Based on the Chemical Index of Alteration values and A–CN–K ternary diagram, there are low levels of chemical weathering in these tills. Additionally, major and trace element geochemical data are compared to the average UCC values. The observed discrepancies between the mean UCC and Antarctic samples develop from the existence of mafic components, most likely the McMurdo Volcanic Group and Ferrar Dolerite, being present in the Taylor Valley tills. Even though the mafic material typically comprises 3–7% of the till, the volcanic rocks have a significant influence on the tills’ bulk geochemistry. The existence of this mafic fraction in the dry-based glacial tills results from the reduced rate of weathering, as compared to wet-based glaciers. Geochemical analyses of the dry-based glacial tills in polar deserts, such as those found in Taylor Valley, may provide a better representative composition of the original material than wet-based glaciers and need to be incorporated into upper continental crust calculations.

Neoarchaean magmatism through arc and lithosphere melting: Evidence from eastern Dharwar Craton

The Neoarchaean era is characterized by rapid crustal growth corresponding to some fundamental global changes in geodynamic processes. However, the nature of crustal growth including the mechanism and tectonic setting of the Neoarchaean are controversial issues. The eastern Dharwar Craton (EDC) exposes widespread Neoarchaean granite‐greenstone belts, which provide an opportunity to evaluate the various models proposed for Neoarchaean crustal growth. In this study, we present field, petrographic, and geochemical data and discuss the petrogenesis and significance for crustal evolution for a suite of previously undescribed banded gneisses, TTG (tonalite–trondhjemite–granodiorite), biotite granites, alkali feldspar granite and gabbro. These rocks are associated with Neoarchaean metavolcanic and metapelites rocks of the Tsundupalle greenstone belt, in the eastern fringe of the EDC. Whole‐rock major and trace element geochemical data are consistent with diverse sources, including both crust and enriched mantle in an evolving subduction zone. A convergent orogenic setting is proposed for interpreting the association of various granitoids in the Tsundupalle area. Finally, intrusion of crustally derived, highly silicic, alkali‐rich granite, and mantle‐derived gabbro emplaced in a post‐subduction regime is proposed. Lithospheric delamination and attendant mantle melting are suggested as possible mechanisms for generation of these rocks. The understanding of generation of the different granitoid types along with gabbro provides significant insights into the mechanism of Neoarchaean crustal growth.

Nitrogen isotope constraints on the early Ediacaran ocean redox structure

Nitrogen (N) is a macronutrient essential to all living organisms and its availability in Precambrian oceans may have played an important role in the early evolution and diversification of eukaryotes. It has been hypothesized that the billion-year evolutionary stasis of eukaryotes during the mid-Proterozoic (ca. 1.8–0.8 Ga) was linked with N limitation. As a corollary, the rapid diversification of eukaryotes during the Ediacaran implies the lift of this barrier. Indeed, recent nitrogen isotope (δ15N) studies suggested a stable oceanic nitrate (NO3-) pool and perhaps oxygenated mid-depth oceans since ca. 750 Ma. This inference, however, contrasts with the iron, sulfur, and trace element geochemical data that suggested much later ocean oxygenation during the Ediacaran or Paleozoic. To better understand the relationship between nitrogen isotope and other redox proxy data, we have conducted a nitrogen isotope study on the organic-rich black shales of the basal Doushantuo Formation (ca. 635–632 Ma) in multiple sections across a shelf-to-basin transect, from which iron, sulfur and trace element geochemical data are available. The results show exclusively positive δ15N values in all sections across the basin, with most values within the range of +3‰ to +12‰ and a modal value of +5 ± 1‰. The positive δ15N values from the basal Doushantuo black shales are comparable with those of the modern ocean (+3‰ to +14‰; modal value of +5‰) and most likely resulted from an aerobic nitrogen cycle with partial water column denitrification in the presence of a stable nitrate pool. In general, it is difficult to maintain a stable oceanic NO3- reservoir in strongly stratified oceans. Therefore, the new δ15N data, in combination with other geochemical data, provide evidence for an oxygenated mid-depth ocean during the early Ediacaran. The co-occurrence of aerobic N isotope signal and euxinia in some samples implies that the early Ediacaran ocean in South China could be periodically stratified well below the photic zone, with a chemocline at least down to the mid-depth (e.g., >1000 m) or close to the water column/sediment interface.

Garnet-Pyroxenite-Derived End-Member Magma Type in Kamchatka: Evidence from Composition of Olivine and Olivine-Hosted Melt Inclusions in Holocene Rocks of Kekuknaisky Volcano

Late Quaternary volcanoes of Sredinny Range (Kamchatka) attract geoscientists’ attention by their unusual geochemical features and geodynamic setting. They produced volcanic rocks that are enriched relative to N-MORB in most of incompatible trace elements (except HREE), including strong enrichment in large-ion lithophile elements, and show a negative Nb–Ta anomaly, which is typical for rocks formed in supra-subduction settings. However, modern subduction of the Pacific Plate does not reach the most part of Sredinny Range, as inferred by mapping of Wadati–Benioff zone or seismic tomography. We constrain the source of parental magmas for Sredinny Range volcanic rocks by combining major and trace element geochemical data for olivine and naturally quenched olivine-hosed melt inclusions for Holocene tephra layers of the Kekuknaisky field. Composition of the most magnesian olivine (Ni > 2000 ppm, Fe/Mn ≈ 75 at Mg# ~ 84–85 mol %) and geochemical characteristics of the most primitive melts (FC3MS = 0.61 ± 0.04 (2s)) are consistent with their derivation from a pyroxenite source, while elevated LREE/HREE ratios in lavas indicate that it contained garnet. This garnet-bearing pyroxenite likely originated from the lower crust or lithospheric mantle. Its melting could have occurred due to delamination and sinking into the hotter mantle.