A series of rectificat on tests on the methanol-water, ethanol-water, benzene-toluene, and carbontetrachloride-toluene mixtures were performed in a wetted-wall tower.The wetted-wall tower used was a glass tube, 22mm in inside diameter and 1010mm in length. Vapor from the electrically heated kettle rose up through the tower, and mass transfer took place between vapor and reflux, which flowed in layer form down the inner wall of the tower. Part of the vapor from the tower was condensed in the partial condenser directly coupled to the tower, and admitted to the tower as reflux at its boiling point. The remainder of the vapor was condensed in the total condenser and fed back to the kettle. The equipment was operated as a closed system. The tower and the lower part of the partial condenser were enclosed in heater jackets to minimize heat losses.Vapor flow was varied considerably by adjustment of the power input to the kettle, and reflux rates were controlled by cooling water supply to the partial condenser. Rates of vapor flow were determined by direct measurement of reflux liquid from the tower and distillate for a 30-second period. The compositions of liquid and vapor were varied over wide range. Analyses were made on the distillate and the reflux at the top and bottom. Vapor compositions were obtained by calculation.The experimental results in turbulent flow showed that the overall coefficient of mass transfer Ky [kg-mol/m2. hr. Δy], based on the vapor compesition differences as driving forces, was affected mainly by the velocity of vapor, and was independent of the rate and compesition of reflux or the slope of equilibrium curve. For a given system, Ky was proportional to the 0.8 power of the mass velocity G or Reynolds number Re of vapor; and at the same value of G, Ky was proportional approximately to the 3/4 power of the molal vapor diffusivity Dm of the mixture.The data could be correlated by the following equation:where d=inside diameter of tower;X=effective total vapor film thickness;ky=vapor film coefficient of mass transfer;Dm=in the brackets in kg-mol/m. hr.For vapor mixtures, whose viscosity was in the vicinity of 0.01 centipoiscs, the following approximate equation could also be used:where, ky in kg-mol/m2. hr. Δy, G in kg/m2. hr, Dm in kg-mol/m. hr, and d in m.The experimental data were w thin ±15% of these equations.
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