This study investigates the impact of BaO as an additive on various radiation shielding parameters for recycled waste soda-lime silica glass (WSLSG) composites. Experimental gamma-ray attenuation measurements were performed using 137Cs and 60Co sources and BaO(x) [0.2Bi2O3-0.3ZnO-0.2B2O3-0.3SLS](1-x) glass composites (x = 0, 0.01, 0.02, 0.03, 0.04, and 0.05 mole%) with a NaI(Tl) detector. Additionally, theoretical validation of gamma-ray shielding effectiveness was carried out using the EpiXS and Phy-X/PSD programs over a wide gamma-ray energy range (0.015 – 15 MeV). Key parameters such as mass attenuation coefficient (MAC), half-value layer (HVL), tenth-value layer (TVL), effective atomic number (Zeff), effective electron density (Neff), transmission factor (TF), and gamma-ray dose rate (Dr) were calculated. For a fixed sample thickness and incident gamma-ray energy, the descending order of TF for the glass samples was determined as: . Furthermore, the fast neutron removal cross section (FNRCS) at 4.5 MeV and the macroscopic removal cross section (MRCS) for fast neutrons were evaluated using Phy-X/PSD and MRCScal software, respectively. The total macroscopic cross section for thermal neutrons (Σth) and TF for fast/thermal neutrons (4 MeV/25.4 meV) were also computed using NGcal and transmission/scatter power software. Results indicated that both FNRCS and MRCS increased with BaO mole %. Additionally, the range (R) and total stopping power (TSP) for selected ions were simulated using SRIM Monte Carlo software over a broad energy range (0.01 - 20 MeV). The TSP and continuous slowing down approximation (CSDA) range for electron interactions were deduced using the ESTAR NIST program across an electron energy range of 0.01 - 1000 MeV.
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