Total Organic Carbon δ13C Values Research Articles

Sulfur sources for ultramafic‐hosted sulfide mineralization in the Tianzuo hydrothermal field, 63.5° E, South‐west Indian Ridge: Insights from sulfur and carbon isotopes

To date, discovered ultramafic‐hosted seafloor massive sulfide (UM–SMS) deposits are rare, remain poorly understood in terms of their genesis, and typically form along slow‐ and ultraslow‐spreading mid‐oceanic ridges. The Tianzuo hydrothermal field (THF) is the only UM–SMS deposit identified so far along the ultraslow‐spreading South‐west Indian Ridge (SWIR). This study presents new detailed mineralogical and S–C isotopic data for serpentinized peridotite, gabbro, serpentinite, and sulfide ore samples from the THF and to provide new insights into the processes that formed the deposit. Chromium‐reduced sulfur (CRS) and sulfate–sulfur (SS) in samples of serpentinized peridotite have positive δ34S values (up to 10.22‰ and 20.67‰, respectively). The CRS formed through thermochemical reduction of seawater sulfate during reactions between seawater and ultramafic rocks, whereas the SS most likely occurred as dissolved sulfate phases in seawater occupying the pore space of serpentinized peridotite after exposure at the seafloor. The serpentinite samples contain SS with δ34S values of 19.21‰–20.9‰, indicating infiltration by seawater that led to the deposition of seawater sulfate. The sulfide ores have acid‐volatile sulfur (AVS), CRS, and SS δ34S values of 10.99‰–12.07‰, 2.34‰–10.98‰, and −4.13‰ to 2.76‰, respectively, indicating that the AVS and CRS within the samples are dominated by sulfur reduced from seawater sulfate (e.g., anhydrite) and leached from the surrounding wall rocks, although the re‐oxidization of microbial‐reduced sulfur most likely generated the sulfate with low and negative δ34S values. The total carbon and total organic carbon δ13C values of the THF samples are negative and range from −21.99‰ to −0.34‰ and −26.7‰ to −21.02‰, respectively, further suggesting that the samples record microbial activity. Gabbro samples have strongly negative AVS (−10.69‰) and CRS (−7.2‰) δ34S values, indicating that microbial‐reduced sulfur derived from shallow levels in the crust was incorporated into the hydrothermal system that circulated through the deeper‐seated gabbroic units. Our results suggest that the ultramafic and gabbroic rocks, seawater, and microbial activity all provided sulfur to the THF, with well‐developed fractures and local magma supply probably being the key factors controlling the formation of this field and similar UM–SMS deposits elsewhere.

Isotopic Records of Ancient Wildfires in C4 Grasses Preserved in the Sediment of the Ross Sea, Antarctica

AbstractWe report carbon isotopic values in total organic carbon (TOC) and pyrogenic carbon (PyC) preserved in two sediment cores from the Ross Sea, Antarctica. The δ13C values of PyC ranged from −10.9‰ to −17.2‰, with distinct differences from the δ13C values of TOC (−24.1‰ to −26.1‰) in the sediments. The radiocarbon ages of PyC were 9,128 and 8,410 years old on average in the two cores but were thousands of years younger than the ages of TOC at the same core depth. These isotopic records provide strong evidence indicating that the PyC was produced from ancient wildfires predominantly in C4 vegetation and transported to Antarctica in the atmosphere. We suggest that ancient wildfires in predominantly C4 grasslands likely frequently occurred on a large scale and at a high intensity in the Southern Hemisphere during the last deglaciation to mid‐Holocene period of 14,800–4,200 years ago.

High-resolution reconstruction of sedimentary organic matter variability during the Holocene in the mud area of the Yellow Sea using multiple organic geochemical proxies

As a result of terrestrial input and local circulation, an area containing continuously deposited mud with abundant organic matter (OM) has formed in the Yellow Sea (YS) off the Shandong Peninsula, China, during the Holocene. The understanding of temporal variations in sedimentary organic matter (SOM) from this mud area helps to evaluate the influences of Yellow River discharge and marine productivity on the burial of organic matter in the YS. In this study, multiple organic geochemical proxies were used to reconstruct Holocene changes in SOM in a sediment core (A02C) recovered from the mud area of the YS. Higher total organic carbon (TOC) and biomarker contents during the early Holocene relative to the middle and late Holocene are attributed to sea-level fluctuations. The δ13C values of TOC (δ13CTOC) range from −21.8‰ to −23.5‰, becoming more positive from the bottom to the top of the core. TMBR' (terrestrial and marine biomarker ratio) values vary from 0.43 to 0.80, with a decreasing trend during the Holocene. The decrease in TOM contribution was related to elevated sea-level, shifting of the mouth of the Yellow River, and weakening of the East Asian Winter Monsoon (EAWM) during the Holocene. A mixing model with three end-members, based on δ13CTOC and TMBR', reveals that the contribution of soil OM (average 42%) is higher than that of plant OM (average 17%). Simultaneous decreases in the plant OM fraction and the marine OM fraction occurred around 10.3, 8.2, 5.9, 4.2, and 2.8 kyr BP, corresponding to drift-ice events in the North Atlantic. Spectral analyses also reveal that all three OM fractions exhibit 1015-year periodicity and that the soil and plant OM fractions display 1420-year periodicity, consistent with the 1000-year cycle of solar activity and the 1500-year cycle of the Kuroshio Current (KC), respectively.

Multi-proxy evidence for decreased terrestrial contribution to sedimentary organic matter in coastal areas of the East China Sea during the past 100 years

Little is known about temporal changes in sedimentary organic matter (OM) in the East China Sea (ECS) due to the lack of continuous high-resolution records. In this study, we used a multi-proxy approach to reconstruct sedimentary OM variations over the past 100years from three sediment cores collected from the coastal areas of the ECS. For the three cores, total organic carbon (TOC) normalized concentrations of phytoplankton biomarkers (brassicasterol+dinosterol+alkenones) and a marine archaea biomarker (crenarchaeol) showed gradual increases over the past 100years with a greater increase after the 1980s. These increases are attributed to eutrophic conditions caused by monsoonal variation and intensified human activities in the Yangtze River Basin (YRB) over the past century. Conversely, TOC-normalized concentrations of higher plant biomarker long-chain n-alkanes (∑(C27+C29+C31n-alkanes)) showed no obvious trend over the past 100years. The δ13C values of TOC (δ13CTOC), the terrestrial and marine biomarker ratio (TMBR) index, and the branched and isoprenoid tetraether (BIT) index for the three cores record a gradual decrease in the contribution of terrestrial organic matter (TOM) since the 1960s. This decrease is likely linked to enhanced dam construction in the YRB from the 1960s onwards, leading to a reduction in TOM input to the ECS. A three end-member mixing model based on δ13CTOC values and the TMBR index was used to further divide sedimentary OM into three factions: marine organic matter (MOM), plant OM, and soil OM. The MOM contribution gradually increased over the past 100years, while the contribution of soil OM gradually decreased over the past 100years with a significant decline during the past 50years. This trend can also be related to intensify dam construction in the middle and upper reaches of the YR since the 1960s.

Provenances, distribution, and accumulation of organic matter in the southern Mariana Trench rim and slope: Implication for carbon cycle and burial in hadal trenches

It is generally accepted that organic matter content and accumulation rate at the seafloor attenuate with increasing water depth. However, hadal trenches, which represent the deepest portion of the hydrosphere on Earth, do not abide by this universal rule. It has been speculated that hadal trenches would serve as organic matter depocenters, where bacteria-mediated organic matter degradation intensifies. Here we examine the contents of total organic carbon (TOC) and total nitrogen (TN), as well as the δ13C values of TOC in three gravity cores, two box cores, and three grab samples with water depth from 4900 to 7118m, in order to reveal the provenances of organic matter, spatial distribution and accumulation rates of particulate organic carbon (POC) in the southern Mariana Trench rim and slope. Although the deepest area was not sampled, trench rim and slope is also of importance in terms of transportation and accumulation processes of organic matter. A vast majority of the sediment samples have bulk TOC/TN molar ratios and δ13C values of TOC ranging from 4.2 to 11 and from −21.8 to −18.9‰, respectively, implying that the organic matter was primarily sourced from marine algae. Two exceptions have been found at 101cm and 201cm depths of core GC05 with a possible input of terrestrial material suggested by an abrupt increase in TOC contents and TOC/TN molar ratios accompanied by marked decreases in δ13C values of TOC. Moreover, TOC contents in surface sediments basically increased with water depth. Based on the published excess 210Pb data and by assuming a simplified one-dimensional sediment loading despite of frequent occurrences of mass wasting transports in hadal trenches, the sedimentation rate in the southern Challenger Deep (6037m) was estimated to be 0.02cmyr−1. This much higher sedimentation rate compared to the globally averaged values in deep ocean sediments coupled with the trend of increasing in TOC contents with water depth may serve as evidence for the lateral transport of sediment particles induced by the funnel-like topography and localized current dynamics within the trench. The average POC accumulation rate within the southern Challenger Deep roughly amounts to 1.5×10−5gcm−2yr−1, equivalent to about a seventh of the globally averaged POC accumulation rate in deep-ocean seafloor. To our knowledge, POC accumulation in hadal trenches has been quantified for the first time, and we highlight that organic matter degradation in deep hadal trenches should not be neglected and may represent a significant component of the global carbon cycle.

A new approach for reconstruction of the Holocene climate in the Mongolian Altai: The high-resolution δ13C records of TOC and pollen complexes in Hoton-Nur Lake sediments

δ13C of total organic carbon (TOC) and pollen grain, TOC, C/N ratio, and δ15N of total organic nitrogen (TON) in a 2.57-m long core from Hoton-Nur Lake in Mongolian Altai have been measured for reconstruction of the Holocene climates. The δ13C values of TOC and pollen carbon have similar average values but different ranges. Pollen δ13C has negative correlation with %AP (arboreal taxa pollen) and positive correlation with %NAP (herbaceous pollen and spores) that are connected with conditions of humidity in the area. Taiga-biome has lighter δ13C than steppe-biome. Hence, pollen δ13C composition is more sensitive to changes of humidity in the analogous spectra than palynotaxonomical structure and δ13C of TOC. Based on our results, the Holocene climates in Mongolian Altai are: (1) dry conditions prior to 11.5kyr BP; (2) wet conditions between 11.5 and 6.0kyr BP; (3) a relatively dry/cool episode during 6–4kyr BP; (4) stable cool and semiarid conditions with moderately effective moisture during the past 4000years. Two abrupt climatic changes occurred at ∼7.45kyr BP and ∼11.5kyr BP might be related to glacial activities. The Holocene climatic trend in Mongolian Altai which is controlled by the Westerlies is similar to the trend of monsoonal climate shown by the Chinese speleothem records as well as the lake/sand dune evidence in the deserts of NW China. The contact of the two climatic systems and shift of the monsoonal boundary during the past need to be further studied.

A biogeochemical study of sediments from the eutrophic Lake Lugano and the oligotrophic Lake Brienz, Switzerland

The biomarker composition and stable isotope (C, O) ratio values of organic matter (OM) and carbonate from sediment cores from the oligotrophic Lake Brienz and the eutrophic Lake Lugano (both in Switzerland) are compared, in order to obtain information about OM sources and transformation processes. Eutrophic conditions at Lake Lugano are reflected in elevated total organic carbon (TOC) content and hydrogen index (HI) values, as well as higher lipid concentrations. Parallel down core trends in δ13C values of TOC and calcite in the Lake Lugano sediments reflect bioproductivity cycles. Variations in δ18O values of calcite are consistent with changes in mean summer temperature over the time interval covered by the core. In contrast, such a correlation does not exist for Lake Brienz and there the stable isotope composition of calcite reflects its allochthonous origin. In the sediments of both lakes, fatty acid (FA) distributions and the composition of n-alkanols and n-alkanes indicate highly variable proportions of autochthonous OM sources (algae, zooplankton, bacteria) and OM from land plants. Enhanced in situ microbial synthesis during sediment deposition in Lake Lugano is suggested by the higher TOC-normalised concentrations of branched chain FAs (C15–C17), hopanoic acids and triterpenoid alcohols (i.e. tetrahymanol, diplopterol). Variations in the concentrations of cholesterol are related to contributions from zooplankton and/or green algae, while sitosterol concentrations reflect the input of vascular plants. Periods of increased input of OM from diatoms are evidenced by high 24-methylcholesta-5,22-dien-3β-ol (either epibrassicasterol or brassicasterol) and/or highly branched isoprenoid (HBI) alkenes concentrations. High relative concentrations of diplopterol in Lake Lugano sediments are consistent with the predominance of cyanobacteria commonly observed in eutrophic lakes. The presence of archeol and hydroxyarcheol in very low concentrations in the Lugano sediments argues for the activity of methanogens and/or anaerobic methanotrophs.Differences in OM degradation processes are reflected in higher chlorin index values in the Brienz sediments but higher saturated vs. unsaturated n-FAs in the core from Lugano. Higher concentrations of branched chain FAs and 16:1ω7 n-FA, as well as enhanced 18:1ω7/18:1ω9 n-FA, are consistent with enhanced bacterial biomass in the Lugano water column or sediments. The preservation of phytol seems to be enhanced in sediments with a high relative contribution of land plant OM. Major factors affecting OM accumulation in the lakes are differences in OM sources (i.e. terrestrial OM vs. autochthonous production), extent of bacterial activity and most likely oxygen availability in the water column.

Transport of terrestrial organic matter to the deep North Atlantic Ocean by ice rafting

Abstract Total organic carbon (TOC), δ13C values of TOC (δ13Corg) and glycerol dialkyl glycerol tetraethers (GDGTs) were analysed for a sediment core from the North Atlantic covering the last 30 kyr to investigate organic matter deposition due to ice rafting. TOC content was low in sediments representing glacial times (0.2–0.4%) and even lower in Holocene sediments (

Organic-matter source variation and the expression of a late Middle Ordovician carbon isotope excursion

Research Article| November 01, 1999 Organic-matter source variation and the expression of a late Middle Ordovician carbon isotope excursion Richard D. Pancost; Richard D. Pancost 1Department of Geosciences, Pennsylvania State University, University Park, Pennsylvania 16802, USA Search for other works by this author on: GSW Google Scholar Katherine H. Freeman; Katherine H. Freeman 1Department of Geosciences, Pennsylvania State University, University Park, Pennsylvania 16802, USA Search for other works by this author on: GSW Google Scholar Mark E. Patzkowsky Mark E. Patzkowsky 1Department of Geosciences, Pennsylvania State University, University Park, Pennsylvania 16802, USA Search for other works by this author on: GSW Google Scholar Geology (1999) 27 (11): 1015–1018. https://doi.org/10.1130/0091-7613(1999)027<1015:OMSVAT>2.3.CO;2 Article history first online: 02 Jun 2017 Cite View This Citation Add to Citation Manager Share Icon Share MailTo Twitter LinkedIn Tools Icon Tools Get Permissions Search Site Citation Richard D. Pancost, Katherine H. Freeman, Mark E. Patzkowsky; Organic-matter source variation and the expression of a late Middle Ordovician carbon isotope excursion. Geology 1999;; 27 (11): 1015–1018. doi: https://doi.org/10.1130/0091-7613(1999)027<1015:OMSVAT>2.3.CO;2 Download citation file: Ris (Zotero) Refmanager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar search Search Dropdown Menu toolbar search search input Search input auto suggest filter your search All ContentBy SocietyGeology Search Advanced Search Abstract The carbon isotopic composition of organic matter is a powerful tool in the study of organic carbon burial and pCO2 through the geologic record. However, the organic-matter source can affect total organic carbon δ13C values and may complicate interpretation of environmental conditions. We examined the influence of organic-matter source variations on a late Middle Ordovician positive δ13C excursion in strata of the United States midcontinent. In a core from Iowa, the magnitude of the excursion recorded by carbonate carbon is ∼2.5‰, whereas the excursion recorded by total organic carbon is nearly 8‰. Although this difference could arise from a profound decrease in surface-water CO2 concentrations, association of the organic-walled microfossil Gloeocapsomorpha prisca with 13C-enriched total organic carbon (TOC) in this interval suggests that the excursion could also record a shift from normal-marine to G. prisca–dominated organic matter. Carbon isotope analyses of individual biomarkers indicate that both of these explanations are required to explain the data. Compounds inferred to be of G. prisca origin are enriched in 13C by 7‰ relative to compounds derived from other algal sources. Furthermore, compounds exclusively from either G. prisca or other sources exhibit a positive shift of only 3.5‰. Thus, the large excursion recorded by TOC reflects, in part, a change in the proportional contribution of G. prisca to TOC. That all compounds exhibit a positive carbon isotopic shift indicates that, independent of contributions from G. prisca, a positive organic δ13C excursion occurred and records a change in environmental conditions such as CO2(aq) concentrations. The 3.5‰ shift is similar in magnitude to that observed for TOC in correlative units from Pennsylvania, suggesting that this event has broad geographic significance. This work illustrates that organic-matter source variations as well as environmental conditions govern the TOC δ13C values and shows how compound-specific isotope analyses can resolve these multiple controls. This content is PDF only. Please click on the PDF icon to access. First Page Preview Close Modal You do not have access to this content, please speak to your institutional administrator if you feel you should have access.