Total Metal Research Articles

Radial gradients of CO absorptions and abundance ratios in the bulge of M31

We present new H- and K-band spectroscopy for the bulge of M31, taken with the LUCI spectrograph at the Large Binocular Telescope (LBT). We studied radial trends of CO absorption features (namely and ) in the bulge of M31, out to a galactocentric distance of $ 380$ pc). We find that most COs do not exhibit a strong radial gradient, despite the strong metallicity gradient inferred from the optical spectral range, except for showing a steep increase in the center. We compared the observed line strengths to predictions of different state-of-the-art stellar population models, including an updated version of EMILES models, which also uses the extended IRTF spectral library. The observed COs are close to models' predictions, but in some models they turn out to be underestimated. We find that the lack of radial gradients is due to the combination of increasing CO strength with metallicity and C abundance, and decreasing CO strength with IMF slope and O abundance. We speculate that the steep gradient of might be due to Na overabundance. Remarkably, we were able to fit, at the same time, optical indices and all the NIR COs (except for CO1.68) leaving abundance ratios (i.e. and ) as free-fitting parameters, imposing age and metallicity constraints from the optical spectral range with no significant contribution from intermediate-age populations ($ 1$ Gyr-old). For the majority of the bulge, we find 0.15$ dex larger than (by $ 0.1$ dex), and C abundance consistent with that of Mg. In the central (few arcsec) region, we still find an enhancement of O and Mg, but significantly lower . We find that the COs' line strengths of the bulge are significantly lower than those of massive galaxies, possibly because of a difference in carbon abundance, as well as, to some extent, total metallicity.

Performance of vertical flow constructed wetland for the treatment of effluent from a brassware industry in city of Fez, Morocco: a laboratory scale study

Brassware industry constitutes the second most polluting industrial sector in Fez city, Morocco, owing to its high heavy metal load. The aim of this study is to examine and evaluate the performance of vertical flow constructed wetlands in treating brassware effluents using various plant species. Ten treatment systems were planted with four types of plants: Chrysopogon zizanioides, Typha latifolia, Phragmites australis, and Vitex agnus-castus, while another system remained unplanted. These systems underwent evaluation by measuring various parameters, including pH, electrical conductivity, suspended solids, chemical oxygen demand, biological oxygen demand, sulfates, orthophosphates, total Kjeldhal nitrogen, ammonium, nitrates, nitrites, and heavy metals such as silver, copper, and nickel, using standard methods over of ten weeks. The results obtained demonstrate effectiveness of these systems. When planted with Ch. zizanioides, the systems achieved elimination rates of 83.64%, 98.55%, 91.48%, 86.82%, 80.31%, 96.54%, 98%, and 98.82% for suspended solids, ammonium, nitrites, BOD5, sulfates, orthophosphates, silver, and nickel, respectively. System with V. agnus-castus showed significant reductions in nitrate and copper, with rates of 84.48% and 99.10%, respectively. Considerable decrease in pH and electrical conductivity values was observed in all systems, with a notable difference between planted and control systems regarding effectiveness of treatment for other parameters.

Unlocking critical nutritional potential: A comprehensive analysis of small indigenous fishes in Bangladesh and the development of ready-to-use fish products as balanced food

The study aimed to develop fish powder as a promising dietary supplement to combat inadequate nutrition. To achieve this goal, the study assessed the nutritional aspects, including proximate composition, mineral content, amino acid profile, and fatty acid profile, as well as the microbiological quality and heavy metal contents, of six small indigenous fish species. The protein content ranged from 57.73 % to 65.26 %, with G. chapra exhibiting the highest protein content (p < 0.001). In all fish powders, the mineral composition was found in the following order: Na > P > Ca > K> Mg > Fe > Mn > Zn. The results revealed significantly elevated levels of total essential amino acids in A. mola (227.20 mg/g, p < 0.001). The PUFA/SFA ratio (> 0.45) and ω-6/ω-3 fatty acids ratio (< 4.00) were generally optimal. The quality and safety of the fish products for human consumption were confirmed, as both the total colony count and heavy metal concentrations remained below the recommended threshold. All ready-to-use fish products, except A. mola, meet over 20 % of the daily nutritional needs for PLW, infants, and adults. Hence, these findings advocate the utilization of the studied fish species as a dietary supplement to address malnutrition.

Appraisal of Bioavailability and Immobilization of Constituent Metals in Tannery Solid Waste Biochar in Soil Amendments Using Sunflower

ABSTRACT The huge volume of tannery solid waste (TSW) can be reduced through conversion into tannery solid waste biochar (TSWB). Here, it was used as soil amendment at seven levels and the total metals and their soil bound or exchangeable fractions were determined through sequential extraction. The fate of metals was observed using sunflower as a test plant in a greenhouse trial using field soil amended with six concentrations (0.45–2.7%) of TSWB. The amendment rate of 1.8% proved to be the best for the growth of sunflower. Sequential extraction of metals indicated that 40% or more Cd, Cr and Pb remained in the exchangeable fraction, compared to less than 20% of Cu, Fe and Ni. Copper was mainly bound in the Fe-Mn and organic fractions, while Fe and Ni were mainly bound in the residual fraction. Copper, Fe and Ni were therefore immobilized in TSWB, while Cd, Cr, Pb, Mg and Zn were available as indicated by differential uptake in sunflower. All metals, except Cd, remained within the permissible limit in tissues of sunflower, while all were in permissible limits in the seeds. As a result, TSWB can be used as amendment below 1.8% to grow energy crops like sunflower.

Enrichment Characteristics and Ecological Risk Assessment of Heavy Metals in a Farmland System with High Geochemical Background in the Black Shale Region of Zhejiang, China

Soils derived from black shale enriched in heavy metals pose risks to the environment and human health. Eighty sets of soil–rice samples were collected in northwest Zhejiang, China. The results showed significant enrichment of As, Cd, Pb, and Zn in the studied soil. Sequential extraction data indicated that Cd had relatively high bioavailability. Thirty-four percent of the rice samples exceeded the heavy metal pollution thresholds of national food safety standards. A comprehensive evaluation of soil heavy metals using the potential ecological risk index (RI) revealed low-to-moderate-grade risk. Risk assessment code (RAC) levels decreased as follows: Cd &gt; Ni &gt; Zn &gt; Cr &gt; Cu &gt; Pb &gt; As &gt; Hg. The RAC of Cd was high and very high risk, whereas those of others were no or low risk. Cd was the major contributor to the environmental risk based on the total heavy metal concentration, toxicity, and chemical fractions. The health risk to the local populace was assessed using the method recommended by the USEPA. Local people may experience both non-carcinogenic and carcinogenic health risks, and children face greater health risks than adults. As, Cd, and Pb are the most significant contributors to non-carcinogenic health risks, and Cd is the main carcinogenic risk. In conclusion, special attention should be given to heavy metal pollution in black shale-derived soils.

Characteristics, sources, and health risks of PM2.5-bound trace metals in northern Zhejiang Province: The effects of meteorological variables based on machine learning

Atmospheric metals have recently attracted the attention of governments recently due to their significant health risks. In retrospect, a five-year (2017–2021) continuous measurement of airborne metals (13 elements) was conducted in northern Zhejiang Province. A declining trend of total metals (22%) was found from 2017 to 2021, with K, Fe, Zn, Ca, and Mn being its predominant compositions (95.3%). The Random Forest model simulation demonstrated the important roles of meteorological conditions in the trace metal reduction, such as Ca, As, K, Cr, and Zn. In addition, the emission controls contributed more than 50% to most of the remaining metals, especially for Cu (92.6%) and V (85.9%), which demonstrated the effectiveness of the government policies. The relative humidity, wind speed and wind direction were found to be the most important variables affecting the ambient concentration of trace metals. Meteorology was demonstrated to be the worst for trace metal diffusion in 2018. The primary noncarcinogenic metal was Mn (85.9%), while the major carcinogenic metal was Cd (63.4%). Six sources were resolved by positive matrix factorization (PMF). Anthropogenic source emission was largest in winter, followed by spring, summer, and autumn. The reduction of ferrous metal smelting and coal combustion emissions might be the major goal for reducing the public health risk of trace metals in the future.

DYNAMICS OF HEAVY METAL ACCUMULATION IN TROPHIC LEVELS OF FOREST ECOSYSTEMS

The aim of the study is to examine the accumulation of heavy metals (HMs) in trophic levels (soil, wood, tree leaves and fungi of various evolutionary origin) of forest ecosystems.&#x0D; Materials and Methods. The authors examined soil, wood, leaves and fungi in forests with different anthropogenic load intensity. The collecting grounds were selected according to forest management materials. In total, 26 grounds were examined. Sampling of soil and fungi of various trophic levels was carried out on different substrates, in different forest conditions and under different levels of technogenic impact. Leaf and wood samples were taken from phytopathogen-affected and healthy trees. Chemical sample analysis was carried out using a Kvant atomic absorption spectrophotometer.&#x0D; Results. The total heavy metal content in fungi is higher than in wood, but lower than in soil. The total heavy metal content in leaves of Norway maple affected by Rhytisma acerinum is higher compared to the leaves from heathy trees. Iron predominates among the heavy metals found in the fungi under consideration; cadmium content is minimal.&#x0D; Conclusion. The largest amount of accumulated heavy metals was found in the fruiting bodies of the facultative saprotroph, and the smallest amount was in the bodies of the facultative parasite. The forest type and growing conditions affect the heavy metal content in ecosystems.

Modelling Time-dependent Convective Penetration in 1D Stellar Evolution

One-dimensional stellar evolution calculations produce uncertain predictions for quantities like the age, core mass, core compactness, and nucleosynthetic yields; a key source of uncertainty is the modeling of interfaces between regions that are convectively stable and those that are not. Theoretical and numerical work has demonstrated that there should be numerous processes adjacent to the convective boundary that induce chemical and angular momentum transport, as well as modify the thermal structure of the star. One such process is called convective penetration, wherein vigorous convection extends beyond the nominal convective boundary and alters both the composition and thermal structure. In this work, we incorporate the process of convective penetration in stellar evolution calculations using the stellar evolution software instrument mesa. We implement convective penetration according to the description presented by Anders et al. to to calculate a grid of models from the pre-main sequence to helium core depletion. The extent of the convective penetration zone is self-consistently calculated at each time step without introducing new free parameters. We find both a substantial penetration zone in all models with a convective core and observable differences to global stellar properties such as the luminosity and radius. We present how the predicted radial extent of the penetration zone scales with the total stellar mass, age, and metallicity of the star. We discuss our results in the context of existing numerical and observational studies.

Occurrence of heavy metals in sanitary napkins from seven countries: Implication for risk management of female hygiene products

Chemicals in sanitary napkins are easy to enter women's bodies, as these products are in contact with the skin of vagina and vulva directly, which has strong absorption capacity. However, available information regarding the occurrence of metals in sanitary napkins and their potential hazards, remains very limited. This study measured the concentrations of As, Co, Cu, Pb, Cd, Zn, Ni and Cr in sanitary napkins collected from seven countries. Moderate levels of Pb, Cd, Zn and Cr and lower levels of other metals were found, in comparison to the metal concentrations reported for other products previously. Metal concentrations differed by producer, price and fragrance. These metals were originated mainly from the introduction of raw materials and the use of chemical additives during the manufacturing process. Relative to other skin-contacted products, the sanitary napkin contributed more to women's total metal exposure, although the exposure was lower than that of dietary intake. The summed non-carcinogenic risks from six metals and the carcinogenic risks from Pb were acceptable. However, more research is required to investigate metals in sanitary napkins and the associated health risks to women, owing to the variability in the metal concentrations and the complexity of actual exposure.

Performance of wood waste biochar and food waste compost in a pilot-scale sustainable drainage system for stormwater treatment

Sustainable drainage system (SuDS) for stormwater reclamation has the potential to alleviate the water scarcity and environmental pollution issues. Laboratory studies have demonstrated that the capacity of SuDS to treat stormwater can be improved by integrating biochar and compost in the filter media, whereas their performance in scaled-up applications is less reported. This study examines the effectiveness of a pilot-scale SuDS, bioswale followed by bioretention, amended with wood waste biochar (1, 2, and 4 wt.%) and food waste compost (2 and 4 wt.%) to simultaneously remove multiple pollutants including nutrients, heavy metals, and trace organics from the simulated stormwater. Our results confirmed that SuDS modified with both biochar (2 wt.%) and compost (2 wt.%) displayed superior water quality improvement. The system exhibited high removal efficiency (> 70%) for total phosphorus and major metal species including Ni, Pb, Cd, Cr, Cu, and Zn. Total suspended solids concentration was approaching the detection limit in the effluent, thereby confirming its capability to reduce turbidity and particle-associated pollutants from stormwater. Co-application of biochar and compost also moderately immobilized trace organic contaminants such as 2,4-dichlorophenoxyacetic acid, diuron, and atrazine at field-relevant concentrations. Moreover, the soil amendments amplified the activities of enzymes including β-D-cellobiosidase and urease, suggesting that the improved soil conditions and health of microbial communities could possibly increase phyto and bioremediation of contaminants accumulated in the filter media. Overall, our pilot-scale demonstration confirmed that the co-application of biochar and compost in SuDS can provide a variety of benefits for soil/plant health and water quality.

Exploring optimal total metal loading of Ni3Fe/Al2O3 catalyst for CO2 methanation and its kinetic model

A series of Al2O3-supported bimetallic Ni-Fe catalyst with Ni/Fe = 3 are prepared, characterized, and examined for CO2 methanation to identify the total metal loading (Ni+Fe) that yields the maximum activity. The XRD patterns of all catalysts exhibit a noticeable peak shift, which suggests alloy formation and XPS studies reveal that the near-surface concentration of the reduced catalysts possess Ni/Fe ratios similar to those targeted. Analysis of the particle size distribution from TEM and degree of reduction from TPR clearly shows that an increase in metal loading results in a gradual decrease in effective dispersion. However, the catalyst with 55% total metal loading of Ni+Fe, 55Ni3FeAl, possessed the maximum surface metal sites and effective surface metal area, which is reflected in the highest activity of this catalyst during CO2 methanation. Kinetic measurements of the CO2 methanation reaction are obtained on 55Ni3FeAl at temperatures ranging from 513 to 533 K and ambient pressure under differential reactor conditions and in the absence of heat and mass transfer resistance. Several kinetic models are then considered to fit the reaction data for CO2 methanation. The parameters of the models are determined by non-linear regression and analyzed for their thermodynamic consistency and statistical validity (R2, R2adj, NRMSE and F - test). The kinetic data of CO2 methanation on 55Ni3FeAl is adequately represented by a reaction model, where the surface reaction between molecularly adsorbed CO2 and adsorbed H2 appears to be the rate-determining step. The activation energy of this rate determining step was 136 kJ/mol. This kinetic model can then be used to design, analyze, and control different reactors where the most active Al2O3 supported Ni-Fe catalyst with Ni/Fe = 3, 55Ni3FeAl, is used for the CO2 methanation reaction.

Direct elemental analysis of plant oils by inductively coupled plasma mass spectrometry: Simple sample dilution combined with oxygen introduction into the plasma

Assessment of trace metal concentrations in plant oils has been considered a crucial quality control marker for potential health risks, oil flavour, and oxidative stability. A straightforward inductively coupled plasma mass spectrometry (ICP-MS) methodology was developed and validated through introduction of argon:oxygen gas mixture into plasma, allowing for a direct elemental analysis of organic matrices. This approach offers the advantage of a simple one-step preparation of plant oil samples with negligible contamination risks. The complete solubilization of the oil matrix enables the determination of total metal content from a single test tube with low dilution factor of 5. The modified plasma conditions resulted in the development of a robust and accurate ICP-MS method providing limits of detection at sub ng·g−1 levels. The ICP-MS method allowed the determination of trace levels of Ba, Cd, Cu, Fe, Mn, Pb, Sn, V, and Zn in olive, sunflower and rapeseed oils.

Gravimetric, morphological, and chemical characterization of fine and ultrafine particulate matter inside fire stations

Poor air quality inside buildings has direct implications for human health. The activity of firefighters causes cancer and promotes the development/aggravation of cardio-respiratory diseases. The indoor air quality inside fire stations remains poorly characterized. This work assesses firefighters’ daily exposure to fine (PM2.5, PM156nm) and ultrafine (PM50.4nm, PM30.8nm) particulate matter (PM) inside three microenvironments of fire stations, and, for the first time, characterizes the morphology and elemental content of collected PM. Fine PM fractions were predominant in all microenvironments. Fine and ultrafine PM concentrations were increased in the personal protective equipment (PPE) storage room than in the common area and garage [11.84–103.5 μg/m3versus 18.67–51.89 μg/m3 and 22.57–70.69 μg/m3; p > 0.05 and 4.78–46.02 μg/m3versus 3.03–40.99 μg/m3 and 5.55–23.30 μg/m3; p > 0.05]; values were below the guideline proposed for occupational exposure to respirable dust (5.0 mg/m3). The morphological analysis revealed the presence of organic matter, microorganisms, crystals, minerals, metals, and other unidentified substances in fine/ultrafine PM. Exposure to total PM-bound metals was increased in the garage comparatively to the common area and the PPE storage room (2765.0–46586.0 pg/m3versus 2414.2–4568.6 pg/m3; p > 0.5). Cu, Zn, and Cr were the predominant PM-bound metals while Sb, Cd, and Tl were the less abundant. Exposure to PM-bound possible/probable carcinogenic metals (Ni, Cd, Sb, and Pb) accounted for 7.81–10.72% and 0.342–13.07% of fine and ultrafine PM, respectively. The data generated can support regulatory agencies in proposing air quality guidelines that promote occupational safety and health.

Pd-Based Bimetallic Electrocatalysts for Hydrogen Oxidation Reaction in 0.1 M KOH Solution.

A series of carbon black-supported 7.5 wt.% Pd-2.5 wt.% M/C (M: Ag, Ca, Co, Cu, Fe, Ni, Ru, Sn, Zn) electrocatalysts, synthesized via the wet impregnation method, and reduced at 300 °C, were compared in terms of their hydrogen oxidation reaction (HOR) activity in a 0.1 M KOH solution using the thin-film rotating-disk electrode technique. Moreover, 10 wt.% Pd/C and 10 wt.% Pt/C electrocatalysts were prepared in the same manner and used as references. The 7.5 wt.% Pd-2.5 wt.% Ni/C electrocatalyst exhibited the highest HOR activity among the Pd-based electrocatalysts, although it was lower than that of the 10 wt.% Pt/C. Its activity was also found to be higher than that of Pd-Ni electrocatalysts of the same total metal loading (10 wt.%) and reduction temperature (300 °C) but of different Pd to Ni atomic ratio. It was also higher than that of 7.5 wt.% Pd-2.5 wt.% Ni/C electrocatalysts that were reduced at temperatures other than 300 °C. The superior activity of this electrocatalyst was attributed to an optimum value of the hydrogen binding energy of Pd, which was induced by the presence of Ni (electronic effect), as well as to the oxophilic character of Ni, which favors adsorption on the Ni surface of hydroxyl species that readily react with adsorbed hydrogen atoms on neighboring Pd sites in the rate-determining step.

Effects of mild acid pre-treatment on the co-pyrolysis behaviour of biosolids and wheat straw

Co-pyrolysis of biosolids (BS) and wheat straw (WS), as well as their treated variants, was performed in a fluidised bed reactor at 500 ℃. Under mild acid pre-treatment conditions (3% H2SO4 and 25 ℃), demineralisation was the dominating effect of pre-treatment on BS, while it was hemicellulose hydrolysis for WS. Consequently, the co-pyrolysis of raw biosolids (RBS) or treated biosolids (TBS) with raw wheat straw (RWS) or treated wheat straw (TWS) had varying effects on product distribution and product compositions. The co-pyrolysis of RBS+RWS gave the lowest bio-oil yield (36.3 wt%) and highest gas yield (23.1 wt%). In contrast, the highest bio-oil yield (45.8 wt%) and lowest gas yield (14.4 wt%) occurred during the co-pyrolysis of TBS+TWS. The degree of synergy in product distribution was strongest in TBS+RWS followed by RBS+RWS and was weakest in TBS+TWS, demonstrating the catalytic effect of inherent minerals on organic matter devolatilisation and char cracking reactions during co-pyrolysis. Biosolids pre-treatment alone performed competitively with BS co-pyrolysis alone with respect to enhancement in biochar properties producing biochar having 15–18 MJ/kg calorific value, 43–51 wt% carbon content, 0.7–1.0 fuel ratio, ⁓30% organic matter retention, and 27–41 wt% ash content. However, combining BS co-pyrolysis and pre-treatment gave the lowest reduction in biochar total heavy metal concentration. Furthermore, bio-oil compositions were influenced by pre-treatment and/or co-pyrolysis, increasing the yield (area%) of phenols to 25.4%, furans to 24.8%, anhydrosugars to 7.8%, and aromatic hydrocarbons to 20.6%. Lastly, pre-treatment alone weakened gas production while co-pyrolysis combined with pre-treatment impacted the pyrolysis gas profile, switching between light hydrocarbons and carbon oxides (CO and CO2). Overall, co-pyrolysis and pre-treatment can each be a standalone strategy for enhancing BS pyrolysis; however, their combination produced greater synergy for generating high value products.

Effects of land use/cover change on heavy metal distribution of soils in wetlands and ecological risk assessment

This study aimed to determine the impact of land use/cover changes on the heavy metal content in the Sultan Marshland and surrounding area and assess the pollution status. 54 topsoil samples (0–20 cm) were collected from the Rangeland, Farmland, Scrubland, Southern Marshland, Northern Marshland, and Dry Lake areas. The heavy metal contents of the soil samples (Cr, Pb, Fe, Zn, Cu, Co, Mn, Cd, Mo, As, and Ni) were determined using ICP-MS and ICP-OES devices. The impact of land use/cover change on soil heavy metal content was evaluated using variance analysis, while differences between groups were identified using the Duncan test. Principal Component Analysis (PCA) was conducted to identify potential sources of heavy metals. The contamination status of the soils was evaluated based on land use/cover using the Contamination Factor (Cf), Pollution Load Index (PLI), Ecological Risk Factor (Er), and Potential Ecological Risk Index (PERI).Changes in land use/cover around the Sultan Marshlands affected heavy metal distribution of the soils except for Cd. Among all land use/cover types, Fe concentration was the highest in the soils, while Cd concentration was the lowest. Soils in Southern Marshland exhibited higher average concentrations of Cr, Fe, Zn, Co, Cu, and Ni compared to other land uses/covers. Farmlands and rangelands had higher concentrations of Cd, As and Pb. Land use/cover was ranked based on the total heavy metal load in the following order in terms of average values: Southern Marshland > Scrubland > Farmland > Rangeland > Northern Marshland > Dry Lake. According to Cf, the soils in the Dry Lake were exposed to considerable levels of As contamination. Based on PLI, half of the soil sampling points in the Southern Marshland soils showed a degradation in environmental quality. Er indicated that all land uses moderately polluted with Cd. According to the average PERI, all soils under different land use/cover types were categorized as having a low ecological risk. It was believed that heavy metals originated from both natural and human activities. To ensure the sustainability of the ecosystem and to mitigate the risk of heavy metal pollution entering the food chain, it is recommended to manage farming and mining activities and land use habits.

Phytoremediation of pollutants in oil-contaminated soils by Alhagi camelorum: evaluation and modeling

Phytoremediation is a cost-effective and environmentally friendly method, offering a suitable alternative to chemical and physical approaches for the removal of pollutants from soil. This research explored the phytoremediation potential of Alhagi camelorum, a plant species, for total petroleum hydrocarbons (TPHs) and heavy metals (HMs), specifically lead (Pb), chromium (Cr), nickel (Ni), and cadmium (Cd), in oil-contaminated soil. A field-scale study spanning six months was conducted, involving the cultivation of A. camelorum seeds in a nursery and subsequent transplantation of seedlings onto prepared soil plots. Control plots, devoid of any plants, were also incorporated for comparison. Soil samples were analyzed throughout the study period using inductively coupled plasma-optical emission spectroscopy (ICP‒OES) for HMs and gas chromatography‒mass spectrometry (GC‒MS) for TPHs. The results showed that after six months, the average removal percentage was 53.6 ± 2.8% for TPHs and varying percentages observed for the HMs (Pb: 50 ± 2.1%, Cr: 47.6 ± 2.5%, Ni: 48.1 ± 1.6%, and Cd: 45.4 ± 3.5%). The upward trajectory in the population of heterotrophic bacteria and the level of microbial respiration, in contrast to the control plots, suggests that the presence of the plant plays a significant role in promoting soil microbial growth (P < 0.05). Moreover, kinetic rate models were examined to assess the rate of pollutant removal. The coefficient of determination consistently aligned with the first-order kinetic rate model for all the mentioned pollutants (R2 > 0.8). These results collectively suggest that phytoremediation employing A. camelorum can effectively reduce pollutants in oil-contaminated soils.

Pore structure characteristics and leaching mechanism of Cu and Cr in sustainable porous ceramisite produced from contaminated soil and biomass waste

Contaminated soil (CS) and biomass waste are potential resources. Their secure, scale, resource, and high-value utilization will bring significant socio-economic benefits. In present work, the basic properties, crystalline phases, microstructure and leaching behavior of porous ceramisite (PC) via CS and biomass waste were investigated systematically. The link of pore structure characteristics with leaching behavior of Cu and Cr was revealed. The environmental and economic benefits were also assessed. The results showed that the addition of 5∼15% pore-forming agent (carbon powder or biomass waste) made the matrix looser and the leaching amounts of heavy metals increased. However, the heavy metals leaching amounts was still lower than the critical limits of nonhazardous materials with immobilization rates higher than 97.5%. The leaching mechanism of Cu in the PC was controlled by initial wash-off, diffusion and depletion. The time period of the depletion dominated leaching is prolonged with increasing porosity. The leaching mechanism of Cr in the PC was mainly initial wash-off and depletion. The wash-off dominated the total heavy metal leaching amount, accounted for more than 80% of the total leaching amount. The leaching of Cu and Cr showed a positive correlation with (effective) pore volume of pores large than 1 μm, while demonstrating a negative correlation with the fractal dimension. The economic benefits of PC throughout the production process were analyzed, which showed that the production of PC using CS and biomass waste could eliminate raw material costs and could be subsidized by the government. This study provides an idea for the 100% utilization of CS and biomass waste as well as theoretical support for the disposal of solid waste.

α-element enhancements in the ISM of the LMC and SMC: Evidence of recent star formation

Context. Important questions regarding the chemical composition of the neutral interstellar medium (ISM) in the Large Magellanic Cloud (LMC) and Small Magellanic Cloud (SMC) are still open. It is usually assumed that their metallicity is uniform and equal to that measured in hot stars and H II regions, but direct measurements of the neutral ISM metallicity had not been performed until now. Deriving the metallicity from the observed metal abundances is not straightforward because the abundances depend on the depletion of metals into dust and on nucleosynthesis effects such as α-element enhancement. Aims. Our aim is to measure the metallicity of the neutral ISM in the LMC and SMC, dust depletion, and any nucleosynthesis effects. Methods. We collected literature column densities of Ti II, Ni II, Cr II, Fe II, Mn II, Si II, Cu II, Mg II, S II, P II, Zn II, and O I in the neutral ISM towards 32 hot stars in the LMC and 22 in the SMC. We determined dust depletion from the relative abundances of different metals because they deplete with different strengths. This includes a ‘golden sample’ of sightlines where Ti and other α-elements are available. We fit linear relations to the observed abundance patterns so that the slopes determined the strengths of dust depletion and the normalizations determined the metallicities. We investigated α-element enhancements in the gas from the deviations from the linear fits and compared them with stars. Results. In our golden sample we find α-element enhancement in the neutral ISM in most systems, on average 0.26 dex (0.35 dex) for the LMC (SMC), and an Mn underabundance in the SMC (on average −0.35 dex). Measurements of Mn II are not available for the LMC. These are higher than for stars at similar metallicities. We find total neutral ISM metallicities that are mostly consistent with hot star metallicity values, on average [M/H]tot = −0.33 (−0.83), with standard deviations of 0.30 (0.30), in the LMC (the SMC). In six systems, however, we find significantly lower metallicities, 2 out of 32 in the LMC (with ~16% solar) and 4 out of 22 in the SMC (3 and 10% solar), two of which are in the outskirts of the SMC near the Magellanic Bridge, a region known for having a lower metallicity. Conclusions. The observed a-element enhancements and Mn underabundance are likely due to bursts of star formation, more recently than ~1 Gyr ago, that enriched the ISM from core-collapse supernovae. With the exception of lines of sight towards the Magellanic Bridge, the neutral gas in the LMC and SMC appears fairly well mixed in terms of metallicity.

Comprehensive environmental impact assessment and irrigation wastewater suitability of the Arab El-Madabegh wastewater treatment plant, ASSIUT CITY, EGYPT.

The presence of a wastewater treatment plant in the Arab El-Madabegh region, which discharges excessive amounts of raw effluent toward the nearby farming fields, is the area's main issue. Examining the harmful implications of raw effluent releases on groundwater quality, determining if treated wastewater effluent complies with regulations for discharge into the aquatic environment, and assessing irrigation appropriateness by the effluent are the main goals of this work. In order to accomplish these targets, twelve treated effluent samples from the Arab El-Madabegh wastewater treatment plant were gathered every two weeks starting in January 2012 and finishing in June 2012. They were tested to determine pH, Total Dissolved Solids (TDS), Total Suspended Solids (TSS), Temperature (Temp), Conductivity (EC), Turbidity (Turb.), Chemical Oxygen Demand (COD), Biological Oxygen Demand (BOD), Total Organic Carbon (TOC), NO3-, SO42-, Cl-, Ca2+, PO43-, HCO3-, Na+, Mg2+, and heavy metals such as (Fe, Mn, K+, Cr, Pb, Zn, Ni, Cu, and Cd). The outcomes revealed that all Egyptian and Food and Agricultural Organization (FAO) standards for unrestricted irrigation were met by the treated effluents, except for COD, which exceeded than the Egyptian allowed limit. The evaluation indices of the effluent's EC, SAR, PI, MR, and MH were in the low-risk category according to indicators of water quality for irrigation, nevertheless, The SSP and RSC both showed slightly higher values (67.9% and 2.76, respectively). As well, The average values of heavy metals in treated wastewater effluent were found to be below permitted limits, with the exception of lead and phosphate, which exceeded permissible limits in Egypt. The environmental sustainability (ecological friendliness) of reusing and recycling tertiary treated wastewater can be achieved in agriculture to reduce the adverse impacts on the aquatic environment.