This paper proposed an innovative hybrid system to generate electricity and fresh water with higher energy efficiency. A subsystem is employed by integrating DCMD and heat pump to recover waste heat of PEMFC to produce fresh water. The thermodynamic and exergoeconomic models are established to evaluate the system comprehensive performance. Compared with the PEMFC alone, the results demonstrated that the proposed hybrid system achieves a 42.07 % increase in energy efficiency and provides 177.86 kg/h of fresh water. The components with high exergy destruction are PEMFC, Relief value, Inverter, Separator 2 and DCMD with the exergy destruction rate of PEMFC stack accounting for 54.55 %. The parametric analysis results indicate that the variation of the membrane filament number, feed and permeate flow rates all have evident impacts on the thermodynamic and economic performances of the hybrid system. The multi-objective optimization is conducted by adopting NSGA-II and three decision-making methods. The optimal solution obtained by AHP-entropy-TOPSIS approach for the net power out, exergy efficiency, WPC, and total exergy cost rate are 96059W, 0.5293, 0.2995 $/m3, and 14.27 $/h, respectively. In addition, the obtained results shown that the simulation times of NSGA-II are significantly reduced from 89.30 to 11.20 h by introducing BP-ANN to improve the simulation efficiency.
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