Combustion of single boron particles, about 75 microns in diameter, from a crystalline powder sample has been studied. Particles were, ignited by being dropped through a focused laser beam in several oxidizing gases over a range of pressures In pure oxygen, in air, and in O2/Ar (20/80), particles were merely preheated to a temperature about 2000°K; ignition took place spontaneously after a measurable induction period. Quantitative values of both the induction period and the subsequent self-sustained combustion period are listed. In air and in the O2/Ar mixture, the burning times decrease from about 45 msec to about 20 msec as the pressure is increased from 1 to 35 atm. In pure O2 at atmospheric pressure, the total burning time is only 6.8 msec. In pure CO2 and in O2/N2 (7/93), there is no induction period, no selfignition, and no steady-state combustion; particles must be brought to a burning regime by an external energy flux, and they are able to maintain that regime for only a limited time before extinguishment. It is shown that the classical theory of ignition and combustion can account for all three observed burning modes: metastable surface reaction during the pre-ignition period rapid self-sustained diffusion combustion, and decaying combustion. Previously reported reaction-rate and ignition-limit data are used for quantitative estimates of parameters pertaining to the three regimes.
Read full abstract