Summary Toroidal molecular magnets represent promising candidates for next-generation ultra-dense information storage. These wheel-like molecules are able to store one bit per molecule because of their insensitivity to homogeneous magnetic fields—one of the main sources of magnetic perturbations. However, synthesis of molecules possessing a well-defined and stable vortex arrangement of the on-site magnetic moments in the ground state represents a challenge. Here, we show that 16 magnetic metal ions can be alternately arranged into a macrocycle named {Fe8Dy8}. The net toroidal moment can be experimentally determined at 0.23 Tesla. Moreover, ab initio calculations were performed to reveal that ferromagnetic exchange interactions between the FeIII and DyIII metal centers are the key to generate this toroidal moment. This feature is significantly distinguished from the previously described dipole-dipole interaction-based single-molecule toroics (SMTs), showing the importance of exchange-coupling interactions in the design of next-generation SMTs.