The uniform layer with thickness at least 50–100μm was found on the CFC tiles from the inboard midplane after more than four years of tokamak operation. The upper part of the uniform layer was amorphous, but at the depth of ∼5μm a structure consisting of micro-size regions with aromatic chains located parallel to the surface was found. Gradual transition from uniform layer to underlying CFC structure was observed. The reciprocating material probe was used for installation of CFC samples in the Tore Supra deuterium plasma. The thermal desorptional spectra of these samples are compared with the spectra of the samples irradiated in the laboratory stand and with the spectra of hydrogenated carbon film. The peculiarities of hydrogen isotope trapping under plasma irradiation and at the atmosphere are presented and discussed.