Measurements of the nighttime atmospheric sodium layer have been made over a period of 4 months at São José dos Campos (23°S, 46°W), using the laser radar technique. Peak sodium concentration is found at a height of 95 km and the topside scale height of the layer is usually less than 2 km. On six occasions a secondary peak has been observed at heights between 100 and 105 km. Detailed structure in the layer is frequently conserved from night to night and it is suggested that such structure may be the result of atmospheric tidal oscillations. Comparison with twilight measurements indicates that the average total abundance of sodium shortly after sunset is between 0.38 and 1.25 of the twilight value.