Revealing the tool wear mechanisms of machining Zr-based bulk metallic glasses (BMGs) is important for the processing of BMGs in engineering applications. The tool wear mechanisms of machining BMGs with PCBN tools under varying corner radii were investigated, and the results shown that the adhesive and oxidation wear were the main wear mechanisms. The low thermal conductivity of the BMG workpiece material increased the cutting temperature. The effect of corner radius on tool wear mechanism was characterized by the normal stress fields. It indicated that the extremely high maximum normal stress was the main reason for edge chipping. Finally, the influence of tool wear state on machined surface quality was related to the machined surface morphology. The findings have shown that the edge chipping and adhesive wear produced feed marks, material side flow and adhensions on the machined surface, leading to the increase of surface roughness.
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