Titanium Molybdenum Research Articles

Unraveling the effects of strain‒induced precipitation on continuous cooling ferrite transformation in titanium‒molybdenum microalloyed steel

Strain‒induced precipitation is a characteristic physical‒metallurgical phenomenon during hot‒rolling in microalloyed steel production that strongly affects the overallthermomechanical control process. In this study, the strain‒induced precipitation behavior in titanium‒molybdenum microalloyed steel was comprehensively investigated, and its complex effects on the austenite/ferrite transformation during continuous cooling were analyzed for the first time, based on stress relaxation and multi‒aspect characterization methods. The stress relaxation results revealed that the fastest strain‒induced precipitation occurred at 900 °C. The precipitates were identified as FCC structured (Ti, Mo)C particles with a coherent or semi‒coherent cubic‒cubic orientation relationship to the austenite matrix. The strain‒induced precipitation proved to increase the ferrite transformation temperature and proportion, significantly refine and homogenize the transformed grains. The intermittent quenching at 0.5 C/s further revealed that the (Ti, Mo)C particles with cubic‒cubic orientation relationship to austenite matrix exerted a dual pinning effect: by pinning dislocations, these particles facilitated diffusion‒controlled ferrite nucleation and growth both at austenite grain boundaries and within grains; by pinning migrating phase interfaces, the particles inhibited the coarsening of ferrite grains. Coupled with compressive testing and strengthening contribution analysis, the strain‒induced precipitation was shown to weaken precipitation strengthening but enhance grain refinement strengthening, thereby providing a novel approach to achieving an optimal balance between microstructural homogeneity and mechanical properties.

Microbial adhesion on different types of orthodontic brackets and wires: An in vitro study

ObjectiveThe objective of this study was to compare the microbial adhesion of different oral pathogens on different wires used in orthodontic treatment and to evaluate the potential of these pathogens to form biofilms on different types of orthodontic wires and brackets. MethodsIn this in vitro investigation, we calculated that the sample size for each group (i.e., those with brackets [metal braces, ceramic braces, and self-ligating braces] and wires [nickel titanium, titanium molybdenum, and stainless steel]) should be 15 individuals. Five types of microbes (Streptococcus mutans, Escherichia coli, Enterococcus faecalis, Staphylococcus aureus, and Candida albicans) were used. Three types of brackets and three types of wires were used with five types of bacteria, and the process was repeated three times to collect the average. ResultsNo significant differences were observed in the mean concentrations of bacteria in the different brackets (p > 0.05) or in the mean concentrations in the different orthodontic materials used in these brackets. In contrast, there were considerable differences between the concentrations of bacteria in the wires and those in the brackets (p < 0.05). ConclusionDifferent wires and brackets have different associations with bacterial adhesion and concentration. The wires exhibited more substantial biofilm absorbance and concentrations than the brackets. The adhesion of biofilm may be a decisive factor when choosing a type of orthodontic wire, particularly for individuals at high risk of developing bacterial oral diseases, such as periodontal diseases and dental caries.

Position and root resorption of the incisors following anterior segment retraction using friction versus frictionless mechanics: A randomised controlled trial.

To evaluate the three-dimensional position and root resorption of incisors after anterior segment retraction (ASR) using friction versus frictionless mechanics. Thirty female patients (13-18 years) with bimaxillary protrusion were randomly allocated into two groups. In the intervention group, ASR was undertaken using an elastomeric chain rendering 160 g/side extending between mini-screw implant and a hook crimped on 0.017 × 0.025-inch stainless-steel wire distal to the lateral incisor. In the comparison group, ASR was undertaken using closing T-loops fabricated from 0.017 × 0.025-inch titanium molybdenum alloy (TMA) wire rendering comparable retraction force. In both groups, the canine brackets were ligated after retraction to the mini-screw implants that were inserted in both the upper and lower arches bilaterally. The primary outcome was the three-dimensional changes in the position of the incisors. The secondary outcome was root resorption. These were measured from cone-beam computed tomography scans. Statistically significant decreases in the upper (UI) and lower incisors (LI) crown torque were seen in both groups; however, the difference between groups was not statistically or clinically significant (UI MD -2.04°; 95% confidence interval [CI] = -8.02-3.95; LI MD -0.49°; 95% CI = -7.06-6.08). Significant tipping of upper (MD -1.17°; 95% CI = -2.06--0.27) and lower (MD -1.13°; 95% CI = -1.66--0.60) incisors was found in the friction, but not the frictionless group after retraction; however, the changes were not clinically significant. Significant lower incisor intrusion was found in both groups after retraction; however, the difference between groups was not statistically or clinically significant (MD -0.61°; 95% CI = -1.99-0.77). Statistically significant decreases in the UI and LI root length were seen in both groups. The difference between groups for UI changes was statistically significant (MD 0.54 mm; 95% CI = -0.02-1.07) but probably not clinically significant. Considering the limitations in the current study, there was no advantage of either mechanics over the other regarding the final position of incisors. The likelihood of root resorption should be considered when frictionless mechanics are used for retraction of incisors. Clinicaltrials.gov (NCT04878939).

Torque moments and stress analysis in two passive self-ligating brackets across different incisor inclinations: A 3-dimensional finite element study

ObjectiveTo compare torque expression characteristics between rectangular slot (0.022″ x 0.028″) Damon Q passive self-ligating brackets (Ormco, Glendora, Calif) and square slot (0.021″ x 0.021″) Pitts 21 brackets (OC Orthodontics) using 0.019″ x 0.025″ Stainless Steel and 0.020″ x 0.020” Titanium Molybdenum alloy wires at various incisal inclinations using finite element analysis. The null hypothesis was that there were no differences in torque expression in both tested groups. MethodsReporting guidelines for in-silico studies using finite element analysis in medicine (RIFEM) were used. Damon Q and Pitts 21 brackets were scanned and 3D models generated. Brackets were placed on a 3-D model of a maxillary central incisor with its long axis inclined at 0⁰,5⁰,10⁰,15⁰ and 20⁰ to the occlusal plane. Final 0.019″ x 0.025″ SS and 0.020″ x 0.020” TMA archwires were inserted into slots of both tested brackets. Geometric models were converted into finite element models. Material properties were assigned for involved structures with automatic meshing performed by software. Torque movements were simulated with the FE program Ansys Space claim R 22. ResultsTorque moment values, torque expression and Von - Mises stress was higher in Pitts 21 than Damon Q at all inclination angles. There was a gradual increase in the magnitude of values with decrease in incisal inclination. ConclusionSquare slot passive self-ligating brackets show superior torque expression characteristics as compared to rectangular wire-rectangular slot combinations. The FEM results should be validated with in-vivo studies in order to confirm the findings.

A comprehensive study on the surface property changes of antibodies on interacting with Ti3C2Tx, V2CTx, or Mo2TiC2Tx MXenes

MXenes are nanomaterials composed of layered transition metal carbides and nitridesand are considered to have considerable potential in the biomedical translation field. However, the biological and toxicological behaviours of nanomaterials (NMs) are regulated by protein-corona formation, which leads to conformational changes in proteins and impacts their biological functions. Thus, in this work, we synthesized four different MXenes (multi-layered titanium carbide (Ti3C2Tx-ML); single-layered titanium carbide (Ti3C2Tx-SL); single-layered molybdenum titanium carbide (Mo2TiC2Tx-SL); and multi-layered vanadium carbide (V2CTx-ML)) and studied their physicochemical interactions with a model protein immunoglobin G (IgG) from human serum. The conformational, thermal, and colloidal stabilities of IgG were investigated after exposing IgG to MXenes for 15 min at IgG/MXene ratios of 40:1 and 20:1. Circular dichroism (CD) spectroscopy revealed that the secondary structure of IgG underwent a concentration-dependent conformational change after exposure to all four MXenes. ζ-potential studies showed that Ti3C2Tx-ML MXene had the highest negative surface charge due to the presence of abundant fluorine (F) surface groups. However, this increased the hydrophilicity of IgG/MXene solution and eventually caused IgG aggregation and destabilization. Furthermore, Ti3C2Tx-ML MXene had a greater tendency to produce protein coronas than the other MXenes. This study describes a versatile means of examining the properties of MXenes responsible for protein coronas and lays a foundation for establishing the connection between protein corona formation and the biological functions of MXenes.

Electrochemical determination of fenitrothion pesticide based on ultrathin manganese oxide nanowires/molybdenum titanium carbide MXene ionic nanocomposite and molecularly imprinting polymer

A novel molecularly imprinted electrochemical sensor is presented based on one-dimensional ultrathin manganese oxide nanowires/two-dimensional molybdenum titanium carbide MXene (MnO2NWs@Mo2TiC2 MXene) for fenitrothion (FEN) determination. After the synthesis of MnO2NWs@Mo2TiC2 MXene ionic nanocomposite was successfully completed with a facile hydrothermal and the pillaring methods, a new type molecular imprinted electrochemical sensor based on MnO2NWs@Mo2TiC2 MXene was constructed with cyclic voltammetry (CV) polymerization including pyrrole monomer and FEN target molecule. After the characterization studies including spectroscopic, electrochemical and microscopic methods, the analytical applications of the prepared sensor were performed. A linearity of 1.0×10−9–2.0×10−8 mol L−1 was obtained and the values of the quantification limit (LOQ) and the detection limit (LOD) were 1.0×10−9 mol L−1 and 3.0×10−10 mol L−1, respectively. The studies of selectivity, stability and reproducibility of the constructed sensor based on MnO2NWs@Mo2TiC2 nanocomposite and molecularly imprinting polymer (MIP) were carried out in detail. Finally, the developed sensor was applied to white flour samples with the values close to 100%.Graphical

Evaluation of Efficacy of MV Loop for En masse Anterior Retraction as Compared to Opus and Snail Loop Using Finite Element Method and Clinical Intervention: A Research Protocol

Abstract Background: In orthodontics, space closure after extraction is crucial. Frictionless mechanics in preadjusted “edgewise appliance” treatment in orthodontics are better alternatives to friction mechanics. The major benefit is dissipation of force, a high M: F ratio and a low load-deflection rate which is not there in friction mechanics. The retraction loops are Snail loop, Opus loop, K Sir loop, L loop etc. which are used as force system in frictionless mechanics. Objectives: To evaluate and compare the efficacy of Multiple Variability (MV) loop for qualitative and quantitative en masse anterior retraction as compared to Opus and Snail loop. Materials and Methods: The study will be carried out in the Department of Orthodontics and Dentofacial Orthopaedics, Sharad Pawar Dental College, Sawangi (M), Wardha with the technical assistance from NIT Engineering College, Pune. MV loop, Opus loop and Snail loop will be fabricated in “0.019 × 0.025, 0.017 × 0.025 inch Titanium Molybdenum alloy (TMA) and 0.017 × 0.025 inch Stainless Steel (SS) wire” with 1 and 2 mm preactivation bends will be analysed on Finite element method (FEM) Software. Then clinical trials will be carried out based on qualitative and quantitative assessment of records for evaluation of MV loop, opus loop and Snail loop. Expected Results: The FEM analysis and clinical trials will predict the perfect design of loop with adequate preactivation bends. Mainly on data access layer (DHAL) analysis MV loop showed 10:1 Moment to Force (M:F). Similar results are expected on FEM analysis and clinical trials. MV loop will show superior results as compared to Opus and Snail loop. Conclusion: Loop mechanics provide efficient intrusion and retraction in extraction cases. A loop to be effective and efficient needs to clinically as well as mechanically evaluated. MV loop was fabricated to fulfill all the requirements of loop. Clinical evaluation of loop will provide complete effectiveness of loop.

In Vitro Comparison to Evaluate Metal Ion Release: Nickel-Titanium vs. Titanium-Molybdenum Orthodontic Archwires.

Background When metals used in orthodontic materials are exposed to the oral environment, teeth, and gingivae over an extended period of time, they may gradually deteriorate. As a result, the patient is exposed to higher concentrations of metals and metal ions than what they would be exposed to through food and other sources. The goal of the current in vitro experiment was to evaluate and contrast the metal ion release from orthodontic archwires made of titanium-molybdenum alloy (TMA) and nickel-titanium (NiTi). Methods For 90 days, 20 orthodontic archwires in each group were immersed in 50 milliliters of simulated saliva using different containers. Atomic Absorption Spectrometry (AAS) (Shimadzu Corporation, Kyoto, Japan) was used to assess and compare metal ion emission. The unit of measurement is parts per million (PPM). Results The findings indicated that the discharge of nickel metal from the NiTi archwire (Group A) was much higher than that from the TMA archwire (Group B), with a statistical significance level of p < 0.001. It was discovered that Group B's release of titanium was statistically significantly (p < 0.05) higher than Group A's titanium release, which did not include the release of any other metals. Conclusion The study findings indicated that the amounts of metal ions released from the orthodontic archwires made of titanium molybdenum and nickel-titanium alloy were within safety limits.

Corrosion-induced changes in surface properties and roughness of orthodontic wires

This study aimed to investigate the surface free energy and surface roughness (SR) of metallic alloys under the influence of acid solutions. The experiment involved the use of 270 rectangular wire samples measuring 0.019 × 0.025-in. These samples were sourced from 3 different commercial brands: Dentsply GAC, American Orthodontics, and Orthoclassic. This invitro study categorized the samples into 3 groups based on the solutions employed: deionized water, citric acid, and phosphoric acid. Each group consisted of 90 samples, with 30 samples representing each type of alloy-stainless steel, nickel-titanium, and titanium molybdenum alloy (TMA). The wire segments were immersed in their respective solutions for 72 hours at a controlled temperature of 37°C, with continuous orbital agitation at 130 rpm. After the immersion period, the study analyzed both surface free energy and SR. The mean values obtained were subjected to an analysis of variance at a significance level of 5%. All alloys displayed hydrophobic behavior, as indicated by interaction free energy values<0. In acidic environments (phosphoric acid and citric acid), significant differences were observed among different brands and alloys, affecting surface energy and interaction free energy. Variations in SR among metallic alloys included steel with the lowest SR variations, followed by nickel-titanium and TMA. Notably, the TMA alloy stood out with significantly higher surface energy compared with that of the other alloys (P<0.001). In this study, all examined alloys demonstrated a hydrophobic nature, suggesting a limited attraction to water. Notably, TMA exhibited the least hydrophobic behavior among the alloys studied. However, when exposed to citric acid, TMA displayed the most substantial alterations in its surface properties. These results underscored the significance of accounting for the distinctive properties of each alloy and their responses to diverse challenges, such as exposure to acidic solutions, during the selection of orthodontic wires for orthodontics treatment.

Incisor torque expression characteristics in two passive self-ligating brackets placed at different heights. A finite element investigation

ObjectiveThis study investigated torque expression in maxillary incisors using two passive self-ligating bracket types (Damon Q and Pitts 21) placed at different heights using the Finite element method. Materials and methodsTwo passive self-ligating brackets, Damon Q (Ormco, USA) and Pitts 21 (OC Orthodontics, USA) were 3D modeled using micro-computed tomography. Damon Q (0.022ˮ x 0.028″ slot size) and Pitts 21 (0.021ˮ x 0.021″ slot size) brackets were placed on a maxillary central incisor at predetermined vertical heights. Arch wires of size 0.019ˮ x 0.025″ stainless steel (Damon Q) and 0.020ˮ x 0.020” Titanium Molybdenum (Pitts 21) were placed in the bracket slots. ResultsPitts 21 brackets showed higher torquing moments at all bonding heights as compared to Damon Q brackets. The minimum torquing moment was 9.03Nmm at 5 mm for Damon Q and the maximum torquing moment was 14.92Nmm for Pitts 21 at a bracket bonding height of 8 mm. Total deformation for Pitts 21 at a height of 5 mm from the incisal edge was 0.61 × 10−6mm as compared to that of Damon Q which was 0.41 × 10−6mm. Lowest Von Mises stress values were at 27.07 MPa in Damon Q brackets at a bracket height of 5 mm from the incisal edge. Highest Von Mises stress values were 36.80 MPa for Pitts 21 brackets at a bracket height of 8 mm from the incisal edge. ConclusionPitts 21 brackets exhibited superior torquing characteristics compared to Damon Q. Total deformation in Pitts 21 was higher than Damon Q at all tested bracket bonding heights.

Adaptability evaluation of anti-corrosion oil pipe materials for water injection wells

The study considers the characteristics of complex working conditions of water injection wells in Shengli Oil Field, high salinity and hardness of water injection, corrosive gases, sulfate-reducing bacteria, and other corrosion and scaling factors. By comparing N80, the corrosion performance of four commonly used anti-corrosion tubing in Shengli Oil Field, namely, nitriding, tungsten plating, titanium nano, and titanium molybdenum, was systematically evaluated. Key factors affecting oil pipe corrosion were summarized through the grey correlation statistical analysis method. Corrosive gas is the key factor affecting N80, tungsten plating, and nitriding test pieces. Mineralization is the key factor affecting titanium nano and titanium molybdenum-coated oil pipes. Using N80 as a comparison, the scale formation on the surface of four types of anti-corrosion test pieces was evaluated. The surface of the four types of anti-corrosion test pieces was mainly composed of calcium carbonate scale. Among these, the scale crystal density of nitrided and titanium molybdenum test pieces was high, and the scale adhesion was relatively tight. The density of scale crystals on the surface of titanium nano and tungsten-plated specimens is sparse, and the adhesion is weak. On the surface of N80, there are both calcium carbonate and many corrosion products.

Passive Q-switched fiber laser with MAX phase molybdenum titanium aluminum carbide film

Passive Q-switched fiber laser with MAX phase molybdenum titanium aluminum carbide film

Elaboration and characterization of molybdenum titanium tungsto-phosphate towards the decontamination of radioactive liquid waste from 137 Cs and 85Sr

The crystalline phase of molybdenum titanium tungsto-phosphate (MoTiWPO4) as an inorganic sorbent material was synthesized via the sol–gel method. The physicochemical characteristics of MoTiWPO4 were evaluated by using Fourier transform infrared (FT-IR), scanning electron microscope (SEM), energy dispersive X-ray (EDX), thermal analysis (TGA-DTA), and X-ray diffraction (XRD). MoTiWPO4 sorbent material exhibits a high chemical resistance to HNO3, HCl, and alkaline media. MoTiWPO4 has good thermal stability as it retained about 75.63% of its saturation capacity upon heating at 500 °C. The sorption studies for several metal ions revealed marked high sorption efficiency of MoTiWPO4 towards Cs+ and Sr2+ ions which reached 99% and 95%, respectively. The saturation capacity of MoTiWPO4 for Cs+ and Sr2+ is 113 and 109 mg/g, respectively. MoTiWPO4 is approved to be successfully eliminating both 137Cs and 85Sr from liquid radioactive waste streams by %eff. of 92.5 and 90.3, respectively, in the presence of competing ions from 60Co(divalent) and 152Eu (trivalent), confirming the batch experiment results for the removal of Cs+ and Sr2+ metal ions. Furthermore, the decontamination factor exceeds 13.3 in the case of 137Cs and 10.3 for 85Sr.

Generation of dual-wavelength Q-switched laser pulses by employing Mo2Ti2AlC3 MAX phase film

In this paper, we experimentally generate dual-wavelength laser pulses from a Q-switched erbium-doped fiber laser (QS-EDFL) by utilizing molybdenum titanium aluminum carbide (Mo2Ti2AlC3) MAX Phase film. The Mo2Ti2AlC3-SA film, which belongs to the MAX phase compound, is prepared using the mechanical exfoliation. The optical and physical properties of Mo2Ti2AlC3-SA are investigated. The fabricated film has a linear absorption of 8 dB and modulation depth of 17 % at 1.55 mm region. A steady dual-wavelength Q-switched laser pulses are achieved with 1531.6 nm and 1557 nm peaks and a free spectral range (FSR) of 25.4 nm. By increasing the input pump power from 131.87 mW to 167 mW, the repetition rate of generated pulses is varied over 104 kHz to 126 kHz. At the highest input power (167 mW), the energy and output power of the obtained pulses are 87.30 nJ and 11 mW, respectively. The results reveal that the exfoliated Mo2Ti2AlC3-SA can be operated inside EDFL to produce stable pulses with dual wavelengths.

Comparing the Efficiency of a Newly Designed Spring With the T Loop for Buccal Canine Disimpaction: A Finite Element Study.

Disimpacting a buccally impacted canine precisely using frictionless mechanics is a challenge in orthodontics. Various mechanics can be used for aligning an impacted canine and a spring is one of the most versatile methods of accomplishing it. The present study describes a newly designed spring for canine disimpaction using the finite element method (FEM) model. In the present study, the efficiency of the newly designed spring was compared with the T loop. The FEM model of the maxilla was prepared. Harsha's Canine Disimpaction (HCD) spring and T loop with no pre-activation bends were utilized to disimpact the left maxillary canine usinga 0.017 x 0.025 inch titanium molybdenum alloywire. Efficiency of both springs in all dimensions (sagittal, vertical and transverse) was compared. Stressacting on the bone and teeth and number of activations needed for disimpaction were evaluated when the spring was activated by 3 mm. A movement/displacement of 0.8, 0.4and 0.1 mm was seen in the sagittal (X), transverse (Y) and vertical (Z) planes, respectively, with the HCD spring, and 0.4, 0.1and 0.1 mm seen in the X, Y and Z planes, respectively, with the T loop. A total of 12-13 and 80 activations were required as per the FEM simulation for disimpaction using the HCD spring and T loop, respectively. Stress concentration in the disto-cervical region was observed during disimpaction with both HCD spring and T loop. Within the constraints and limitations of the present study, it can be concluded that the HCD spring requires lesser activation and brings about greater control of canine disimpaction in all three dimensions when compared to the T loop.

Comparative Assessment of the Efficacy of Newly Designed Multiple Variability Loop and Opus Loop for Anterior en Masse Retraction in Orthodontics: A Finite Element Study.

Introduction Two different mechanisms are used to close the space after extractions, i.e., friction/sliding mechanics and frictionless/loop mechanics. The focus of this study is on space closure using frictionless or loop mechanics, which utilize loops to achieve the desired tooth movement. Loops are designed to increase the resiliency of the archwire so that the ideal moment-to-force ratio (M/F) of 8:1 to 10:1 for bodily tooth movement can be obtained. By incorporating various loop designs, the resiliency of archwires may be increased, and an ideal M/F ratio can be obtained. Method Different pre-activation bends were incorporated in the titanium molybdenum alloy (TMA) wire at alpha (canine side) and beta (premolar side), respectively. A total of 36 finite element method (FEM) models were prepared with and without pre-activation bends to evaluate the moment-to-force ratio. Result The results obtained from the finite element method (FEM) analysis provided valuable insights into the force and moment generated during activation while retracting the tooth. Specifically, the alpha bend at 15 degrees and the beta bend at 20 degrees produced the most desirable results for generating moments on the anterior and posterior teeth, respectively. Conclusion To ensure the proper utilization of the multiple variability (MV) loop, we recommend its preparation using a 0.019 x 0.025-inch TMA wire. This selection will maximize the loop's capabilities and enhance its performance in achieving the desired tooth movement.

Ti-Mo-O Nanotube Arrays Grown by Anodization of Magnetron Sputtered Films

In this study, we introduced the method for the growth of titanium molybdenum oxide (TMO) nanotubes directly from metallic precursor solid state solution and provided their structural and chemical characterization. Precursor films with content of molybdenum from 32 to 82 at% were prepared using co-deposition magnetron sputtering. The optimization of deposition parameters allowed for the growth of a continuous nanotube array with a length up to 700 nm ± 10% by anodic oxidation. Scanning electron microscopy (SEM) combined with energy-dispersive spectroscopy (EDS) revealed nanotube formation with Ti1−xMoxO2 composition, where x can reach the value of 0.5. Scanning transmission electron microscopy combined with EDS (STEM-EDS) confirmed the incorporation of Mo into the TiO2 lattice and uniform elemental distribution across the nanotube at the submicron level. The nanobeam electron diffraction (NBD) and X-ray diffraction analyses (XRD) did not show any notable crystal phase formation for the titanium molybdenum oxide phase.

Effect of Mo content on the properties of graphite–MoC composites sintered by spark plasma sintering

Graphite–molybdenum–titanium powders prepared by colloidal processing technique were sintered by Spark Plasma Sintering (SPS). This material is proposed in this manuscript due to its potential interest as heat sink. The influence of the molybdenum content (2.5, 5.0 and 10.0vol.%) on the thermal, electrical, and mechanical properties of the composite are studied to define the composite with the best properties. Thermal, electrical, and mechanical properties of the composite graphite–10vol.% Mo–1vol.% Ti (that are composites of graphite with molybdenum and titanium carbides after sintering) are significantly better than those of the composites with lower molybdenum contents (2.5vol.% and 5vol.%). This way, flexural strength, electrical conductivity, and thermal conductivity are 1.5, 7.8 and 18 times greater, respectively, than in the composite graphite–2.5vol.% Mo–1vol.% Ti. In the case of comparing with the composite graphite–5vol.% Mo–1vol.% Ti, flexural strength, electrical conductivity, and thermal conductivity are 1.2, 5.1 and 3.2 greater in the composite graphite–10vol.% Mo–1vol.% Ti, respectively.

Evaluation and Comparison of Momentto-Force Ratio of a New “PRP Loop” with that of Opus Loop and L LoopA Finite Element Method Study

Introduction: Extraction space closure is the foremost challenging procedure in the field of orthodontics which needs a robust understanding of biomechanics. There are two commonly used methods of space closure, one which involves friction, also called sliding mechanics, and the other is frictionless. The advantages of frictionless mechanics are there is no force loss due to friction and low anchorage taxing. The preferred method for the retraction of teeth is loop mechanics and which ensures controlled tooth movement. Aim: To evaluate and compare the Moment-to-Force (M/F) ratio of PRP loop with that of Opus loop and L loop by Finite Element Method (FEM). Materials and Methods: An in-vitro study was conducted by using FEM analysis in DMIHER University with technical assistance from the Department of Mechanical Engineering VNIT Nagpur. Computer models of Loops design were prepared on Analysis of Systems (ANSYS) version 10 (V10) software. Opus loop, L loop and Platelet-Rich Plasma (PRP) loop were modelled as SOLID 64 beam elements. Different pre-activation bends were given to the models in α and β nodes of the loop. Statistical analysis was done with Statistical Package for Social Sciences (SPSS) version 27.0 software to compare the mean of all three loops. Results: Total 36 FEM models were studied. PRP loop showed greater M/F ratio than Opus and L loop with 15ºα and 25ºβ pre-activation bends in both 0.017×0.025 and 0.019×0.025- inch Titanium Molybdenum Alloy (TMA) wire i.e., 9.09 and 9.12, respectively. On comparison of M/F ratio of PRP loop, Opus loop and L loop prepared with 0.017×0.025 and 0.019×0.025 TMA wire, at 15ºα and 25ºβ pre-activation bend in 0.019×0.025 TMA, PRP loop showed highest M/F ratio of 9.12 as compared to 0.017×0.025 TMA wire. Conclusion: The study concluded that PRP loop is an efficient retraction loop with ideal moment force ratio for translatory movement of tooth. PRP loops had highest M/F ratio than Opus loop and L loop, indicating that PRP can be used for translatory movement of tooth in wires of different materials. Therefore, for proper utilisation of PRP loop, it must be prepared with either 0.017×0.025 inch TMA or 0.019×0.025 inch TMA wire.

Humidity-driven degradation of sputtered molybdenum oxide and molybdenum–titanium-oxide thin films

IR measurements reveal the enhanced hydrolysis resistance of molybdenum titanium oxide compared to molybdenum oxide when exposed to controlled humidity conditions.