Titanium Cathode Research Articles

Electro-phytoremediation of polluted soil at pilot level using maize

This article presents the imposition of a direct current electric field in the presence of seeds and plants of Zea mays L., to rehabilitate soils contaminated with hydrocarbons at a pilot level, and its influence on some physical and chemical properties of the soil, such as pH, electrical conductivity, organic matter content in the soil, enzymatic activity, bulk density, apparent density, porosity, cation exchange capacity, and soluble cations such as potassium, sodium, and calcium. For this reason, the edaphological characterization was carried out before and after an electro-phytoremediation process of soils contaminated with hydrocarbons, using an IrO2-Ta2O5|Ti anode and a titanium cathode, applying a constant electric field of 0.2 V/cm for 4 h to maize seeds and stimulating their germination. After one week, an electric field of 0.1 V/cm for 8 h was applied to the maize seeds every day for 42 days to stimulate the growth of maize plants. This study demonstrated the removal of hydrocarbons by electro-phytoremediation. The applied electric field increases seed germination and plant growth of Zea mays L. These results were obtained with the different transport phenomena that develop when using the electric field in the soil Vertisol pelic understudy at a pilot level.

Performance Effects of Different Shutdown Methods on Three Electrode Materials for Electromethanogenesis

AbstractIndustrial applications of microbial electrochemical systems will require regular maintenance shutdowns, involving inspections and component replacements to extend the lifespan of the system. Here, we examined the impact of such shutdowns on the performance of three electrode materials (i. e., platinized titanium, graphite, and nickel) as cathodes in a microbial electrochemical system that would be used for electromethanogenesis in power‐to‐gas applications. We focused on methane (CH4) production from hydrogen (H2) and carbon dioxide (CO2) using Methanothermobacter thermautotrophicus. We showed that the platinized titanium cathode resulted in high volumetric CH4 production rates and Coulombic efficiencies. Using a graphite cathode would be more cost‐effective than using the platinized titanium cathode in microbial electrochemical systems, but showed an inferior performance. The microbial electrochemical system with the nickel cathode showed improvements compared to the graphite cathode. Additionally, this system with a nickel cathode demonstrated the fastest recovery during a shutdown experiment compared to the other two cathodes. Fluctuations in pH and nickel concentrations in the catholyte during power interruptions affected CH4 production recovery in the system with the nickel cathode. This research enhances understanding of the integration of biological and electrochemical processes in microbial electrochemical systems, providing insights into electrode selection and operating strategies for effective and sustainable CH4 production.

Effect of rare earth yttrium and the deformation process on the thermal deformation behavior and microstructure of pure titanium for cathode rolls

This study explores the challenges associated with microstructural refinement and homogenization control for large titanium cathode rolls utilized in electrolytic copper foil production. An innovative deformation control strategy was developed by incorporating yttrium microalloying within the β→α dual-phase region to refine the hot-deformed microstructure of pure titanium. Gleeble thermal simulation tests were performed to assess the impact of rare earth Y, deformation temperatures (700–900 °C), and interpass cooling rates (5 °C/s, 25 °C/s, and 50 °C/s) on the hot deformation behavior and microstructural evolution of pure titanium. The results reveal that Y2O3 particles generated by the addition of rare earth Y enhance dynamic recrystallization through the particle-stimulated nucleation (PSN) mechanism, effectively pinning grain boundaries and impeding recrystallized grain growth. Increased interpass cooling rates lead to finer grains and higher stored energy. The mechanism for grain refinement during dual-phase deformation is described as follows: β-phase nonrecrystallization temperature deformation → rapid cooling control → α-phase recrystallization deformation control, energy storage, strain-induced dynamic phase transformation (SIDT, α→β), and dynamic recrystallization (DRX). Under experimental conditions of β-phase region deformation at 980 °C → inter-pass cooling rate of 50 °C/s → α-phase region deformation at 750 °C, the addition of rare earth yttrium achieved the most effective grain refinement, reducing the average grain size to 2.56 μm.

Electrochemically assisted sol-gel deposition of bioactive gels for biomedical applications

So far, the sol-gel process has been available to prepare precursor gels of bioactive glasses with various compositions. In this report, we described a novel coating method of bioactive gels on a titanium substrate where the sol-gel transition is controlled by applying external electric fields. The application of a constant current of 10 mA/cm2 in an acidic sol containing pre-hydrolyzed tetraethoxysilane, calcium nitrate, and ammonium dihydrogen phosphate led to the deposition of gels on the titanium cathodes due to the generation of OH– by water electrolysis as a catalyst of the sol-gel transition. The obtained gels, which were characterized to be amorphous and consisted of Si, Ca, and P, covered the titanium substrates as a coating. The bioactivity of the gels deposited was confirmed by soaking in a simulated body fluid (SBF) up to 7 days, suggesting that the electrochemically assisted sol-gel process is promising for providing bioactive coatings on metallic implants.Graphical

Effects of post-deposition annealing on structure and mechanical properties of multilayer Ti/DLC films

The multilayer (Ti/DLC) × 3 films were deposited using a DC arc evaporator with a titanium cathode and a pulsed cathode-spark evaporator with a graphite cathode. Following the deposition of the films, a heat treatment process was performed in air and Ar atmosphere at temperatures of 200 °C and 400 °C. The investigation of the films involved the examination of their structure, surface morphology, and chemical composition using AFM, SEM, XPS and Raman. Additionally, the mechanical properties of the films were assessed by nanoindentation, sclerometry and wear test. Changes in the structure, RMS roughness, С-sp2/С-sp3 ratio of carbon atoms in the film and the formation of Ti-C carbide were determined in relation to the heat treatment conditions. Studies have demonstrated that subjecting materials to heat treatment at temperatures of 400 °C results in a decrease in friction coefficient and an increase in hardness. The deposition of films on the working surfaces of microdrills with subsequent heat treatment leads to a reduction in wear, an extension of their service life, and an improvement in drilling accuracy as compared to microdrills without films. Furthermore, microdrills with (Ti/DLC) × 3 films annealed in air at 400 °C exhibit negligible size reduction and better drilling accuracy.

Improved chloralkaline reversible electrochemical cells featuring a catalytic-coating-free 3-D printed titanium gas diffusion electrode

This study presents a novel resin 3-D printed chloralkaline reversible electrochemical cell featuring a 3-D printed titanium (3DP-Ti) cathode and a mixed-metal oxide anode. It evaluates the capability of this cell for electricity production (using hydrogen and bleach as fuel and comburent, respectively) and electrolysis of NaCl brine (producing hydrogen, chlorine, and retaining carbon dioxide). Parameters including NaCl concentration, bleach pH, and temperature were varied for examination. Despite the assembled 3DP-Ti does not contain any cathodic catalytic layer, the cell shows outstanding performance and it reaches maximum power densities of 7.38 mWcm−2 and maximum current densities of 12.7 mAcm−2. Hydrogen is flowed through small pores and electricity production dependence on feeding solution pH, electrolyte concentration, and temperature are observed. The system proved as a reversible chloralkaline electrochemical cell by confirming its good performance as an electrolyzer, with faradic efficiencies of 100 % for hydrogen production and 70 % for chlorine production. Energy efficiencies reached 196.54 mg Cl2/Wh and 7.48 mg H2/Wh. During operation as an electrolyzer (stream feeding to the gas diffusion cathode), it also demonstrated the capacity to fix carbon dioxide contained in gaseous streams by reacting with hydroxyl ions produced during the electrochemical hydrogen production. The fixation efficiency was 220.0 mg CO2 fixed/Wh. These findings demonstrate progress in electrochemical cell technology, highlighting its potential for various electrochemical applications.

Anodic oxidation of esomeprazole in water by carbon coated titanium (C/Ti) electrode: Optimization and degradation analysis

AbstractEsomeprazole (ESO) is one of the proton pump inhibitors (PPIs) that is commonly used to treat extreme acidity and gastrointestinal irritation. Since it is used at a high rate, it is now classified as a pollutant of emerging concern (CEC). ESO gravely jeopardizes the health of living beings because it persists in water and wastewater sources even after standard treatment. Studies on the effective removal of PPIs, especially ESO, are scarce. In the current study, esomeprazole is disintegrated in water using electrochemical oxidation (EO). Titanium cathode with sodium sulfate electrolyte and carbon coated titanium (C/Ti) anode were used to apply EO. Through optimization studies utilizing COD measurement, it was discovered that 93% of the COD could be removed at pH 3, 60 mM sodium sulfate concentration, 300 min treatment period, and 115 mA cm−2 current density. Whereas TOC research revealed only 44% mineralization, HPLC‐PDA experiments revealed 100% ESO transformation. High resolution mass spectrometry (HRMS) studies were used to propose a degradation mechanism and pathway. The primary processes of degradation included desulfurization, thioperoxole group formation, sulfinyl benzimidazole group breakage, and demethylation. More than 20 reuses of the anode and cathode materials were possible without significantly lowering their oxidation efficiency.

Gallium recovery by cyclone electrowinning from alkaline electrolyte with titanium cathode

A process for gallium recovery by cyclone electrowinning was proposed to inhibit concentration polarization and improve current efficiency (CE). The diffusion coefficient of GaO2− in 120 g/L NaOH solution was determined to be 1.65×10−7 cm2/s by electrochemical study. The effect of various parameters on gallium electrowinning was investigated, and the optimum conditions were determined as: titanium cathode, current density of 750 A/m2, gallium concentration of 39.9 g/L, NaOH concentration of 120 g/L, and circulation flow of 200 L/h. Under these conditions, the CE and gallium recovery of electrowinning were 47.9% and 90.2%, respectively. The precipitated gallium can be easily separated from the cathode, and the final purity of gallium after washing was 99.993%. The energy consumption (EC) of gallium cyclone electrowinning was about 9048 kW·h/t. Overall, it is suggested that cyclone electrowinning is a promising process for gallium production with high CE and low EC.

Comparison of test methods for crevice corrosion propagation and repassivation potential of stainless steel AISI 316

The crevice corrosion propagation modes and repassivation potential of stainless steel AISI 316 in chloride solution were compared using cyclic potentiodynamic polarization (CPP), potentiodynamic-galvanostatic-potentiodynamic (PD-GS-PD) and Tsujikawa– Hisamatsu electrochemical (THE) methods. The PD-GS-PD method was found to be the most conservative electrochemical technique which delivered the lowest repassivation potential value in a relatively short time. The crevice corrosion propagation modes in these three electrochemical methods were also compared with crevice corrosion propagation mode in galvanically coupled small area stainless steel AISI 316 anode with large area titanium cathode. The crevice corrosion propagation mode achieved in galvanically coupled AISI 316 anode at open circuit potential simulated the crevice corrosion propagation mode in real systems. The crevice corrosion propagation modes achieved in PD-GS-PD and THE methods mimicked the crevice corrosion propagation in real systems.

Microbial Electrosynthesis Using 3D Bioprinting of Sporomusa ovata on Copper, Stainless-Steel, and Titanium Cathodes for CO2 Reduction

Acetate can be produced from carbon dioxide (CO2) and electricity using bacteria at the cathode of microbial electrosynthesis (MES). This process relies on electrolytically-produced hydrogen (H2). However, the low solubility of H2 can limit the process. Using metal cathodes to generate H2 at a high rate can improve MES. Immobilizing bacteria on the metal cathode can further proliferate the H2 availability to the bacteria. In this study, we investigated the performances of 3D bioprinting of Sporomusa ovata on three metal meshes—copper (Cu), stainless steel (SS), and titanium (Ti), when used individually as a cathode in MES. Bacterial cells were immobilized on the metal using a 3D bioprinter with alginate hydrogel ink. The bioprinted Ti mesh exhibited higher acetate production (53 ± 19 g/m2/d) at −0.8 V vs. Ag/AgCl as compared to other metal cathodes. More than 9 g/L of acetate was achieved with bioprinted Ti, and the least amount was obtained with bioprinted Cu. Although all three metals are known for catalyzing H2 evolution, the lower biocompatibility and chemical stability of Cu hampered its performance. Stable and biocompatible Ti supported the bioprinted S. ovata effectively. Bioprinting of synthetic biofilm on H2-evolving metal cathodes can provide high-performing and robust biocathodes for further application of MES.

The effect of cathode arc current on the structures of TiN thin films prepared by cathodic arc deposition

The titanium nitride (TiN) thin films were fabricated by the cathodic arc deposition technique. The effect of titanium cathode arc current on structural, chemical, and morphological properties of thin films was investigated by X-ray diffraction(XRD), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscope (FESEM) and atomic force microscopy (AFM), respectively. The XRD results showed titanium nitride formation with a fcc phase structure for all samples and the preferred orientation changed from (111) to (200) plane with increasing the cathode arc current from 50 to 60 A. The crystallized sizes of the thin films increased as increasing the cathode arc current. In addition, the relationship between the size of the microdroplets on the coating surfaces and the arc current was examined.

Photoelectrocatalytic degradation of pharmaceuticals promoted by a metal-free g‑C3N4 catalyst

Graphitic carbon nitride (g-C3N4) recently emerged as a remarkable photoelectrocatalyst for water treatment. Advanced oxidation processes (AOPs) consisting of photoelectrocatalytic (PEC) systems are being researched towards the development of sustainable strategies for the complete removal of refractory contaminants from effluents of urban wastewater treatment plants (WWTPs). This work consists of the optimisation of a PEC system, composed of a boron-doped diamond (BDD) anode, titanium cathode, and a suspended g-C3N4 photoelectrocatalyst, for the treatment of both synthetic and real urban waste waters spiked with pharmaceutical active compounds (PhACs). Different working parameters were considered and optimised to improve degradation and mineralisation rates, such as the cathode material, anode-to-cathode distance, electrolyte resistivity, and matrix composition. The optimal conditions allowed removals of 100 % diclofenac, 88 % fluoxetine and 77 % ibuprofen in the complex wastewater matrix. Moreover, it was observed that the presence of other refractory organic molecules offered a greater impediment to PEC treatment than residual co-existing substances. The main oxidative agents were investigated by scavenging experiments, showing that generated holes and reactive oxy-species, i.e. hydroxyl and superoxide radicals, take a major role in the degradation of PhACs. The recyclability of the g-C3N4 suspension as photoelectrocatalyst in the PEC process provides a promising perspective for the development of wastewater treatment units.

Improving the protective properties of an artificial joint friction couple by using TiN and DLC films

Artificial joint replacement represents the most effective approach for addressing joint pathologies. However, friction and wear, the production of debris and the release of metal ions reduce the durability of artificial joints and negatively impact human health.This study focuses on a CoCrMo alloy joint femoral head and an ultra-high molecular-weight polyethylene cup, which are commonly used as standard artificial joint friction couples. Two different types of films have been deposited on the surface of the joint femoral head. Multilayer TiN/(Ti/DLC) × 3 films were deposited on the surface of the alloy ball via pulsed cathode-arc discharge, and a friction experiment was carried out by a hip friction simulation tester. As an alternative film for use in medicine, TiN films were deposited by direct current arc evaporation of the titanium cathode in a nitrogen atmosphere at a partial pressure of 1.2 × 10−1 Pa. Prior to conducting the wear test, the film structure was studied through Raman and XPS spectroscopy. The surface morphology and adhesion of the films to the joint femoral head were studied.A change in the mass of the prosthesis has been seen when comparing the presence and absence of deposited films. Inductively coupled plasma mass spectroscopy has shown the effectiveness of protecting the surface of the prosthesis with the deposited TiN/(Ti/DLC) × 3 film. This method successfully reduces the concentration of Co and Cr released during friction. The findings indicate that the TiN/(Ti/DLC) × 3 film deposited on the joint femoral head reduces the wear of the UHMWPE cup and did not degrade over five million cycles, thus significantly exceeding the operating life of the TiN film. The results show that TiN/(Ti/DLC) × 3 film demonstrates a 55 % reduction in the generation of abrasive debris in the UHMUPE cup. Furthermore, it effectively prevents the release of metal ions from the alloy femoral head.

Characterization of Bismuth Composited to Carbon Nanotube-Coated Titanium Cathode in Electro-Fenton System

Bismuth (Bi) is a highly reactive catalyst for the generation of hydroxyl (∙OH) radicals. Cathodes constructed from composites of Bi and carbon nanotube (CNT) exhibit high stability and low resistance, which enhance their electron transfer capability. In this work, a titanium substrate was coated with multi-walled carbon nanotube (MWCNT/Ti) using electrophoretic deposition process, followed by electrodeposition of Bi onto the MWCNT-coated Ti (Bi/MWCNT/Ti). The effects of Bi electrodeposition time on the surface morphology of Bi/MWCNT/Ti cathodes were investigated by scanning electron microscopy and energy-dispersive X-ray spectroscopy, and the electrochemical characteristics of each cathode were identified via a series of electrochemical analyses further. The results demonstrated that electrodeposition at −0.85 V vs. Ag/AgCl for 5 min revealed uniform distribution of dense Bi across the surface of cathode, which provides better hydrophilicity for cathode and promotes highest electron transfer rates, respectively; when the Bi/MWCNT/Ti cathode was used as an electro-Fenton (EF) cathode, the EF system achieved a rhodamine B degradation rate of 80.8% after 30 min, which is a significant increase (83.63%) than the unmodified Ti cathode. The use of Bi in EF cathodes improves the efficiency of the EF process.

Approaches to Enhancing Cathodic Nickel Recovery from Ni-EDTA Containing Synthetic Wastewaters

Ethylenediaminetetraacetic acid (EDTA) is widely employed as a chelating agent in the electroless nickel plating industry to form stable metal–organic complexes (e.g., Ni-EDTA). These metal–organic complexes cannot be removed from plating wastewaters by traditional treatments in a cost-effective way. While electrochemical advanced oxidation processes (EAOPs) have been utilized for the efficient degradation of Ni-EDTA at the anode, challenges remain in the simultaneous and effective recovery of nickel at the cathode. In this study, we investigate the efficacy of five cathode materials [i.e., carbon felt (CF), titanium plate, graphite plate (GP), copper plate, and stainless-steel plate] with respect to Ni recovery. The highest Ni removal efficiency of 81.6 ± 0.1% was achieved with the carbon felt cathode which was 30% higher than that of the titanium cathode (52.1 ± 1.4%) with the improvement in performance attributed to the higher rate of mass transport of Ni ions (CF: 4.3 ± 0.4 × 10–4 s–1 vs Ti: 1.8 ± 0.2 × 10–4 s–1) toward the nanowire structure of carbon felt and to the large surface area of the carbon felt cathode compared with the other cathodes. While the chemical composition of the deposits was independent of the cathodic material or structure, the morphology of deposition varied with the cathode material. The accumulated Ni on the carbon felt surface was successfully recovered either as a nickel salt solution by acid leaching or as high purity NiO by calcinating the Ni-loaded carbon felt cathode at over 800 °C. The performance of the regenerated carbon felt after acid leaching was comparable to that of the fresh cathode even after 10 cycles of use and regeneration via acid leaching with this result confirming the stability and reusability of the carbon felt material.

Microhardness and tensile strength of electrochemically synthesized nickel-cobalt binary alloy sheets exfoliated from a dumbbell-shaped titanium cathode

Nanocrystalline nickel–cobalt (Ni–Co) binary alloy sheets were fabricated through electroforming in an acidic aqueous bath using exfoliation from a metallic titanium cathode. Cobalt content in Ni–Co alloy sheets ranged from 28.8 at% to 72.0 at% depending on experimental parameters, such as cathodic overpotential and bath composition. The surface roughness (R a) of the electroformed alloy sheets significantly decreased down to 1.5 μm as saccharin sodium dihydrate was added as an additive to the acidic aqueous solution bath. X-ray diffraction profiles and transmission electron microscopy images indicated that the electroformed Ni–Co alloy sheets have a nanocrystalline structure (grain size ≈ 30 nm). The lattice constant of the electroformed Ni–Co alloy sheets increased with an increase in cobalt content (i.e. solute atom concentration). The mechanical properties were significantly improved because of the synergistic effects of crystal grain refinement and solid solution strengthening. The microhardness and tensile strength of the electroformed Ni–Co alloy sheets reached 609 kgf mm−2 and 1757 MPa (X Co = 49.9 at%), respectively. The tensile strength of the electroformed Ni–Co alloy sheets in this study significantly exceeded that of solidified Ni–Co alloys (approximately 370 MPa). Therefore, this study offers a technique to enhance the mechanical properties of electroformed Ni–Co alloy sheets.

Improving treatment of VOCs by integration of absorption columns into electrochemical cells using 3-D printing technology

This work is focused on the evaluation of the performance of a novel integrated electrochemically assisted absorption reactor. This reactor combines a PEM cell (equipped with Nafion 117 membranes, boron doped diamond anode and titanium cathode) and a packed absorption column into a one compartment device that helps to maximize the use of electrogenerated oxidants by promoting the oxidation of gaseous pollutants. The device has been made using 3D printing technology with a clear Formlabs resin as printing material. Benzene was used as model of volatile organic compound (VOCs). Results demonstrate that this technology prevents wasting of ozone and obtains high efficiencies in the removal of benzene. As well, it is shed light on the mechanisms of benzene absorption and degradation in the liquid phase and on the effect of the current density on the efficiency of the process. Maximum removal efficiencies of nearly 60% are attained working at 50 mA·cm−2 with a moderate energy consumption. Lower degradation at higher current densities is explained in terms of the benzene desorption from liquid to gas phase provoked by the intense gas generation at the electrochemical cell (mainly H2 and O2). These results demonstrate the viability of this new reactor for the removal of VOC's.

Combined electrocoagulation and electrooxidation treatment system for real effluents from the fishing industry

Fishing industries are characterized by high water consumption and a considerable content of organic matter and salt in their wastewater. In this work, a combined electrochemical process was studied at laboratory scale for the treatment of real wastewater from the processing of mackerel from an industrial facility located in the province of Buenos Aires that discharges to the sewer, which the plant is currently using and does not produce an effluent in discharge conditions. Taking advantage of the high conductivity of these effluents, in the electrocoagulation stage with aluminum anodes, it was possible to remove the coarsest fraction of suspended matter, achieving a Chemical Oxygen Demand (COD) removal of about 60%, at pH 7.5, showing a higher efficiency over the conventional treatment. Despite this superiority, the necessary removal was still not achieved; therefore, the wastewater treated by electrocoagulation was then subjected to electrooxidation, using a graphite anode and a titanium cathode, and with a first-order oxidation kinetics, achieving a final COD value lower than the discharge limit, after 7.5 min of processing at pH 6, obtaining an efficient treatment for removal of high concentrations dissolved organic matter and colloidal/suspended particles in this kind of effluent. All treatments were performed in batches.The removal of pollutants in the wastewater was verified by means of spectroscopic and voltammetric techniques; at the same time, these techniques, together with SEM-EDX analysis, proved the superiority of electrocoagulation over chemical coagulation. This study laid the groundwork for the design of modifications to the plant to achieve discharge parameters in accordance with current legislation.

The Effect of Novel Complex Treatment of Annealing and Sandblasting on the Microstructure and Performance of Welded TA1 Titanium Plate

The welding titanium cathode roller has the obvious advantages of low cost, high efficiency, and no diameter restriction. Unfortunately, the longitudinal weld on the cathode roller adversely impacts the quality of the electrolytic copper foil due to the great difference between the microstructure of the weld zone and the base metal. Thus, it is crucial to reduce their difference by regulating the microstructure of the weld zone. In this study, a novel complex treatment of heat treatment and sandblasting is primarily developed for regulating the microstructure of the weld zone. The results show that the novel complex treatment has an efficient effect on regulating the microstructure of the weld zone and making the microstructure in the weld zone close to that of the base metal. During vacuum annealing, the microstructure of the weld zone is refined to some degree, and 650 °C annealing has the optimal effect, which can effectively reduce the ratio of α phase's length to width and reduce the microstructure difference between the weld zone and the base metal. At the same time, with an increase in the annealing temperature, the tensile strength and yield strength decreased by about 10 MPa; the elongation after fracture increased by 20%; the average microhardness of the WZ and the HAZ decreased by about 10 HV0.10; and that of the BM decreased by about 3 HV0.10. The heat treatment after welding can effectively adjust the properties of the weld zone, reduce the hardness and strength, and improve the toughness. The subsequent sandblasting after annealing can further refine the grain size in the weld zone and make the microstructure in the weld zone close to that of the base metal. Sandblasting after annealing can further refine the grain in the weld zone and make the microstructure in the weld zone close to that of base metal. Meanwhile, an application test confirmed that the adverse impact of a longitudinal weld on the quality of electrolytic copper foil could be resolved by adopting this novel complex treatment. Therefore, this study provides valuable technical support for the "welding" manufacturing of the titanium sleeves of the cathode roller.

Numerical simulation of cathode-spot crater formation and deuterium desorption process on hydrogen titanium cathode with flux boundary conditions and different impregnation degree

In this paper, the crater formation process of single cathode spot on hydrogen titanium electrode is modeled. In this model, combined with the deuterium diffusion equation, the flux boundary condition was considered to calculate the cathode spot desorption rate with different impregnation degree, and the deformation process of the cathode spot crater was simulated by a hydrodynamic model. The simulation results show that the current, size, and depth of a single cathode spot crater tend to decrease with increasing impregnation degree, which is consistent with many related experimental results. The simulation result shows that the desorption of deuterium in a single cathode spot crater mainly occurs in the ignition stage, and the positions of desorption are successively distributed in the liquid metal flow area on the side wall of the crater and the high temperature area in the center of the crater. The desorption rate of deuterium drops rapidly after cathode spot quenching. At the same time, the increase of arc current and impregnation degree can improve the deuterium desorption rate of a single cathode spot.