To explore the fracture morphology and acoustic emission characteristics of thermally damaged granite under mixed mode I/III loading, a series of heat treatment and mixed mode I/III loading tests were conducted on edge-notched disc bend (ENDB) granite samples. First, the thermal damage samples’ strength and crack opening displacement were analyzed. Subsequently, based on 3D laser scanning technology, the fracture morphology of the sample was studied, and the fractal dimension was calculated. Then, the samples’ acoustic emission characteristics were discussed, including the ringing count, b value, spectrum signature, and AF-RA. Finally, an acoustic early warning index was proposed based on the critical slowing down theory, and the influence of temperature on the early warning effect was analyzed. The results show that under mixed mode I/III loading, the samples formed an antisymmetric curved surface with out-of-plane torsion. As the thermal damage effect is enhanced, the peak strength decreases linearly, and the fractal dimension increases linearly. The failure mode changes from sudden instability to progressive instability. Shear cracks gradually dominate the sample failure. The peak frequency signal of the sample is mainly distributed between 80 kHz and 400 kHz. The appearance of the sudden drop in the b value and a zero-frequency signal has an early warning effect. The quadratic function can describe the relationship between warning time and temperature. As the temperature increases, the deterioration effect of historical loading on the sample is enhanced, the development time of sample failure is prolonged, and the early warning effect is better.