This paper aims to examine dynamic connectedness and hedging opportunities between the realized volatilities of clean energy ETFs and energy implied volatilities through Time-Varying Parameter Vector Autoregression Model (TVP-VAR) and Asymmetric Dynamic Conditional Correlation (ADCC) GARCH models. TVP-VAR analysis results show that dynamic connectedness increases during turbulence periods. We also determine that clean energy ETFs such as PBW, QCLN, SMOG, and TAN are net volatility transmitters. Surprisingly, OVX is a net volatility receiver, especially with the developments after the Paris Agreement in 2016.As a result of the ADCC GARCH analysis, we determine that the conditional correlation between clean energy ETFs and implied volatility ETFs is asymmetric, and negative information shocks increase the conditional correlation. Although OVX is a cheap alternative for hedging long position risks in clean energy ETFs, VXXLE is more effective than OVX in terms of hedging effectiveness. These findings provide insight for individual and institutional investors, and portfolio managers on how negative and positive shocks change the conditional correlation between assets at different levels.