In vehicular networks, some edge servers may not function properly due to the time-varying load condition and the uneven computing resource distribution, resulting in a low quality of caching services. To overcome this challenge, we develop a Vehicular dew computing (VDC) architecture for the first time by combining dew computing with vehicular networks, which can achieve wireless communication between vehicles in a resource-constrained environment. Consequently, it is crucial to develop an adaptive caching scheme that empowers vehicles to form efficient cooperation in VDC. In this paper, we propose an intelligent caching scheme based on VDC architecture, which includes two parts. First, to meet the dynamic nature of VDC, a spatiotemporal vehicle clustering algorithm is proposed to establish adaptive cooperation to assist content caching for vehicles. Second, the multi-armed bandit algorithm is employed to select suitable content for caching in vehicles based on real-time file popularity, and a model is established to dynamically update each vehicle’s request preferences. Extensive experiments are conducted to demonstrate that the proposed scheme has excellent performance in terms of cluster head stability and cache hit rate.