In order to evaluate the overtaking risk level of intelligent connected vehicles when providing different connected information, and to make up for the neglect of driver factors in traditional risk assessment and the inadequate evaluation of complex traffic scenarios by a single traffic conflict indicator, this paper introduces the Block maxima (BM) and Peak over threshold (POT) methods to fit the extreme value distribution for two conflict scenarios involved in overtaking events (following vehicle conflict and frontal vehicle conflict), so as to evaluate the risk of following vehicle accidents and frontal collision accidents during overtaking. In each conflict scenario, a non-stationary extreme value model considering driver factors and a binary extreme value model considering different traffic conflict indicators are constructed, and the model is verified by the overtaking test data of intelligent connected vehicles in a two-way two-lane vehicle. Overtaking events were extracted from the original test data and conflict indicators were calculated: including the collision time GAP with the front vehicle at the beginning of the overtaking event, the collision time TTC_t1 with the oncoming vehicle, the deceleration DRAC, and the collision time TTC with the oncoming vehicle and the headway time THW with the front vehicle at the end of the overtaking event. The probability of the event with a negative time conflict indicator or DRAC greater than MADR was used to characterize the degree of collision risk. The results show that in the following vehicle conflict scenario, the binary extreme value model constructed with different conflict indicators has different error results, among which the binary extreme value model constructed with THW&DRAC has the most accurate evaluation result (standard error MAE = 0.00028); in the front vehicle conflict scenario, the binary extreme value model constructed with TTC&DRAC has the most accurate evaluation result ( MAE = 0.006 ). In different conflict scenarios, the non- stationary extreme value model considering the driver factor significantly improves the risk assessment accuracy compared with the model without considering the driver factor (small AIC and BIC values). In addition, different intelligent network information (real-time distance, overtaking advice, speed advice) brings different overtaking risks, and when the intelligent network information is speed advice, the vehicle's overtaking risk is the lowest. Therefore, the non- stationary extreme value model and binary extreme value model considering driver factors proposed in this paper can effectively evaluate driving risks through traffic conflict indicators. Secondly, the experimental data of intelligent networked vehicles show that the extreme value theory model proposed in this paper can accurately evaluate the overtaking risk level of intelligent networked vehicles when providing different network information.