Polycrystalline samples of pure Ti and Ti-V alloys containing 2.8, 7.6, 11.4, 20, 25, 35, 40 and 50 atomic percent V were investigated up to ~ 25 GPa at ambient temperature using a diamond anvil pressure cell and X-ray diffraction techniques. The X-ray data show that for alloys with less than ~ 30% V, the hexagonal ω phase is more stable under high pressure conditions than the h.c.p. α phase and the b.c.c. β phase. For alloys with higher V content (> ~ 30%), however, no ω phase was detected. The transformation pressure for the α → ω + α transition decreases gradually with increasing V content whereas for the β → ω + β transition, it increases exponentially. The pressure-induced ω phase obtained in the Ti-V system has an axial ratio c o a o of 0.6105 ± 0.0015, which is about 0.3% lower than the value (0.612) reported for thermally treated ω phases. The pressure-induced ω phase has a smaller volume than the corresponding β and a phases. Thus the relationships a ω = √2 a β and c ω = ( √3 2 ) a β , which hold very well for thermal ω phases, do not hold for the pressure-induced ω phase.
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