Ti6Al4V Substrates Research Articles

Development of a Cu/MoS2/Ni Self-Lubricating Composite Clad through Laser Additive Approach over a Ti6Al4V Substrate and Its Characterizations.

Solid lubricant coatings play a critical role in enhancing the tribological properties of engineering materials, particularly in aerospace and biomedical applications. Ti6Al4V is widely used in aerospace and defense industries due to its excellent mechanical properties and high strength-to-weight ratio. In this regard, a solid lubricant metal matrix composite (MMC) clad was successfully fabricated over Ti6Al4V. A full factorial (L16) was successfully implemented to investigate the interaction of process parameters for laser power and scanning speed with response outputs, such as the clad layer thickness and microhardness. The microstructural study of the clad confirmed the presence of dark and bright phases of the microstructure with cylindrical, elliptical, and lamellar structures. This showed the presence of molybdenum and sulfide phases (MoS2, TiS, CuS) and the presence of a nickel phase (TiNi, NiS, CuNi), confirmed through X-ray diffraction (XRD) analysis and energy-dispersive X-ray (EDX) spectroscopy; these phases bestowed hardness as well as solid lubricating properties on the clad. The microhardness of the clad was found to be 2-3 times that of the substrate material. The wear behavior of the clad was studied in the load range of 5-15 N; the coefficient of friction (0.33 for clad and 0.5 for base), wear track depth profile, and wear mechanism revealed that the cladded sample has higher wear resistance as compared to the substrate material. The worn morphology showed that microcutting and microplowing are the major phenomena of wear occurrence. Further, X-ray photoelectron spectroscopy (XPS) analysis was performed to determine the binding energy of the compound formed at the clad zone, which can predict the most significant phase for the alteration of the mechanical behavior of the solid lubrication clad.

Ablation resistance of SiC-modified nanocomposite ceramic coating prepared by LPDS method on titanium alloy

To enhance the ablation resistance of Ti6Al4V alloy, a SiC-modified nanocomposite ceramic coating was fabricated by a novel one-step liquid plasma-assisted particle deposition sintering (LPDS) method. A microarc oxidation (MAO) ceramic coating was prepared on the surface of titanium alloy as a comparison. The micromorphologies and formation mechanisms of two ceramic coatings were investigated with the assistance of scanning electron microscopy (SEM), X-ray diffractometer (XRD), and transmission electron microscopy (TEM). The thickness of the SiC nanocomposite coating (about 39 μm) was significantly increased by 129% compared to the MAO coating (about 17 μm). Additionally, ablation tests of Ti6Al4V alloy, MAO coating, and SiC nanocomposite coating were conducted at 1000 °C using a butane gas lance. Then, the variation of microstructure, phases, elemental composition, and thickness before and after ablation was also comparatively analyzed. The results indicate that the SiC nanocomposite coating exhibits the smallest thickening (29 μm) after ablation at 1000 °C for 360 s, which is 39% and 46% compared with the Ti6Al4V substrate and MAO coating, respectively. The nanocomposite coating is intact and cracks-free after the ablation test. SiO2, formed during the ablation of SiC nanocomposite coatings, blocks oxygen diffusion into the substrate, which plays a protective role in the coating. Therefore, the SiC nanocomposite coating by a novel LPDS technique exhibits superior ablation resistance to enhance the thermal protection performance of titanium alloy substrate.

Metal ion reinforced hydrogel/Ti6Al4V bionic composite joint bearing interface with extraordinary mechanical and biotribological properties

Artificial joints are facing challenges of high friction and severe wear, which limits their application in the high stress-loading conditions of joint bearing interfaces. Inspired by the soft/hard structure of articular cartilage/subchondral bone in a natural joint and the presence of lubricating proteoglycan/lubricin on cartilage surface, a polyanionic hydrogel coating rich in carboxylates/sulfonates was constructed on a porous Ti6Al4V substrate through ultraviolet radiation combined with metal ion bridging method. In addition, metal ions were adopted to form ionic coordination bonds with the polyanionic hydrogel layer to enhance its mechanical properties. Characterization results showed that the hydrogel layer was firmly adhered to the porous Ti6Al4V surface, and the as-obtained metal ion reinforced hydrogel/Ti6Al4V joint bearing interfaces displayed improved hydrophilicity and mechanical properties. Notably, compared with Al3+ and Fe3+, Ca2+ reinforced PVA-PAA-PSPMK/DT-Ti6Al4V joint bearing interface in deionized water exhibited a lower friction coefficient (∼0.068), which was similar to that of fresh porcine cartilage, and only slight scratches on the worn surface. Moreover, after 4 h of lubrication in phosphate buffer (PBS) or calf serum, its stable and low friction coefficient further revealed its great application potential in physiological environments. The lubrication mechanisms were also discussed in detail. This work presents a simple and effective method to develop hydrogel/Ti6Al4V bionic composite joint bearing interfaces with advanced performance.

Fabrication and Characterization of a Multifunctional Coating to Promote the Osteogenic Properties of Orthopedic Implants.

Titanium-based alloys are used in orthopedic applications as fixation elements, hard tissue replacements in artificial bones, and dental implants. Despite their wide range of applications, metallic implant defects and failures arise due to inadequate mechanical bonding, postoperative clotting problems, aseptic loosening, and infections. To improve the surface bioactivity and reduce the corrosion rate of the Ti6Al4V alloy, multi-layered coatings (HAp, BG, Cs, and Hep) were applied via electrophoretic deposition (EPD). XRD images showed the presence of HAp within the coating. In vitro investigation: cell line NIH-3T3 fibroblasts were seeded on the non-coated and coated Ti6Al4V substrates, and their cellular behavior was evaluated. The results indicated that the HApBGCsHep coating could enhance the adhesion and proliferation of NIH 3T3 cells. In addition, the potentiodynamic polarization results are compatible with the in vitro outcome.

Effect of GO content on microstructure and mechanical properties of Ti6Al4V coating reinforced artificial joint.

In this study, we have innovatively proposed a method of in-situ synthesized TiC hard phase to improve the surface mechanical properties of artificial joint materials (Ti6Al4V). In order to explore the optimum graphene oxide (GO) addition, GO/Ti6Al4V composite powders with different proportions (0, 0.5, 1.0, and 1.5 wt.%) were prepared. The homogeneously dispersed GO/Ti6Al4V composite powder was prepared on Ti6Al4V substrate by laser cladding technology. The microstructure, phase composition, and mechanical behavior of GO/Ti6Al4V composite coatings were studied by scanning electron microscope (SEM), optical microscope (OM), energy dispersive spectrometer (EDS), tribometer, hardness tester, and surface profiler. The results showed that the addition of GO could significantly improve the mechanical properties of TC4 substrate. During the preparation of the coating, the grain size of in-situ TiC phase was nanoscale and was distributed between acicular martensite, which played a critical role in enhancing the mechanical properties of the coating. The TiC phase distributed between acicular martensite refine the grain size of phase and improve the cutting resistance of the coating. Nevertheless, excessive GO decreased the fluidity of the molten pool, and micro holes tended to generate in the coating, which had a negative impact on the mechanical properties of the coating. At the GO content of 0.5 wt.%, the microhardness of the GO/Ti6Al4V coating was 1.325 times that of pure Ti6Al4V. Under the friction environment of simulated body fluid solution, the average friction coefficient was approximately 0.307 and the wear rate decreased to 3.5 × 10-7 mm3/N · m.

Interfacial microstructure and stress characteristics of laser-directed energy deposited AA2024 on Ti6Al4V substrate

Interfacial microstructure and stress characteristics of laser-directed energy deposited AA2024 on Ti6Al4V substrate

Vancomycin-loaded porous chitosan-pectin-hydroxyapatite nanocomposite coating on Ti6Al4V towards enhancing prosthesis antiinfection performance

Cathodic electrophoretic deposition (EPD) was used to fabricate novel porous chitosan/pectin/hydroxyapatite (CS/P/HA) nanocomposite coatings on Ti6Al4V substrates. Rietveld refinement results revealed variations in peak intensity, position, and width, reflecting structural changes resulting from the reduction of the applied voltage from 30 to 10 V. The deposits obtained at 10 V after 1 h of presedimentation exhibited a denser microstructure with narrow pore size distribution compared to the others. The wettability and adhesion strength of coated Ti6Al4V improved with increasing HA content. Release of antibiotic from the composite coating confirmed 40% initial burst release, 50% semi-steady release and 10% residual release. A thick and uniform porous apatite layer was formed on Ti6Al4V after 21 days of immersion in simulated body fluid (SBF). Therefore, CS/P/HA coated Ti6Al4V has the potential for practical antiinfection performance.

Evading stability-biocompatibility tradeoff in TiNb coatings with armour-like super hydrophilic micro-nano structure surface

Modification of micro-nano structures on the surface of medical implants using a femtosecond laser (FSL) can improve cell behavior, increase tissue and material bonding strength, and promote preferred osseointegration. Nevertheless, the FSL processed micro-nano structures suffer from a compromise between biocompatibility and structural stability. Herein, a Ti32·5Nb alloy laser cladding (LC) coating was initially created on the surface of the Ti6Al4V (TC4) substrate, followed by the construction of an armour-like micro-nano structure with structural stability and biocompatibility on the coating surface. The results show that the microhardness, were resistance and corrosion resistance of the coatings were significantly improved. It efficiently prevents wear damage to the micro-nano structure by modifying the surface armour structure of FSL. In addition, a considerable quantity of hydroxyapatite (HA) is deposited on the surface, resulting in a Ca/P ratio that is closer to that of osteogenesis. Moreover, the surface structure is a periodic micro-nano structure with three-level distribution, which can guide the migration and proliferation of cell nanofiber matrix. Human osteosarcoma cells (MG-63) adhere to the surface and proliferate rapidly along the direction of the micro-nano structure. Hereby, the armoured micro-nano structures developed exhibit sustained wear resistance and great biocompatibility. It offers a wide range of applications in the field of surface modification of orthopedic biomaterials.

Synthesis of TiO2/rGO composite coatings on titanium alloys with enhanced anticorrosion performance in palmitic acid-incorporated physiological solutions

During plasma electrolytic oxidation (PEO) process, molten oxide is rapidly solidified through arc discharges in order to create in-situ ceramic TiO2 coatings on titanium alloy substrates. PEO coatings made on biomedical titanium alloys may have limited protection efficiency in organic acid-containing biological solutions due to their inherent porosity. In order to elevate the anticorrosion performance of these coatings, a second layer can be applied to the top surface of the PEO coatings to seal the cracks and pores by other surface engineering methods. In current work, the reduced graphene oxide (rGO) nanosheets were electrophoretically deposited on the Ti–6Al–4V substrate involving an intermediate TiO2 oxide layer applied PEO process. Electrochemical measurements in palmitic acid-containing biological media showed that the duplex TiO2/rGO coating has higher compactness and better corrosion performance than simple TiO2 coating. Indeed, the synthesis of the TiO2/rGO coating on the Ti alloy results in a decrease in the corrosion current density (2.19 μA‧cm−2) in comparison with the simple TiO2 coating (9.85 μA‧cm−2) in an acidic media.

Elevated temperatures erosion wear behavior of HVOF sprayed WC-Co-Cr/Mo coatings on Ti6Al4V substrate

The present research aims to investigate the effect of different impact angles and temperatures on volumetric erosion loss of WC-Co-Cr coating containing 10 wt% Mo. The composite coating was developed using High-Velocity Oxy Fuel (HVOF) process on a titanium substrate (Ti-31). A solid particle erosion behavior of the coatings is carried out at different impact angles (30°, 60°, and 90°) and temperatures (200 °C, 400 °C,600 °C, and 800 °C). The volumetric erosion loss of the coated samples was measured using an air jet erosion tester at high temperatures using Al2O3 as an erodent. The XRD, SEM/EDS, porosity, density, microhardness, bond strength, and scratch tests characterized the as-sprayed coatings. The 3D optical profilometer was employed to evaluate the volumetric erosion loss and the mode of erosion. The scratch resistance of WC-Co-Cr coating is better than WC-Co-Cr/Mo coating. The WC-Co-Cr coating shows a brittle mode of erosion up to 600 °C and a ductile mode of erosion at 800 °C. In contrast, the WC-Co-Cr/Mo coating shows a brittle mode of erosion at 200 °C and a mixed mode of erosion at 400 °C to 800 °C. The volumetric erosion loss of WC-Co-Cr is less than WC-Co-Cr/Mo for all temperatures and impact angles. The formation of oxide phases on the coating surfaces demonstrates erosion resistance at high temperatures. The results of volumetric erosion loss measured by the weight loss method correlate well with a non-contact type 3D optical profilometer.

Impact of reactive nitrogen flow on morphology, mechanical properties, and biocorrosion behavior of sputtered TiN coatings towards orthopedic applications

This work aimed to investigate the effects of reactive nitrogen flow on the morphology, mechanical properties, and biocorrosion behavior of TiN coatings deposited on Ti6Al4V alloys and Si (100) wafer by direct current (DC) magnetron sputtering technique. From analysis results of x-ray diffraction (XRD) and scanning electron microscope (SEM), it revealed that the preferred orientation of the coatings changed from TiN (111) to TiN (200) plane, and the surface morphology altered from faceted structures to closed sphere structures with the increasing reactive N2 flow. The high density and fine grain size of the coating deposited with a reactive N2 flow of 25 sccm resulted in the highest hardness (24.8 ± 1.8 GPa) and the best corrosion resistance. In addition, the friction coefficient was reduced owing to the decrease in the grain size as reactive N2 flow increased from 10 to 30 sccm. Compared with Ti6Al4V substrate, TiN coatings possess better corrosion resistance, suggesting that the coating is beneficial for improving the performance of the Ti6Al4V alloys.

Formation of highly ordered TiO2 nanotubes on Ti6Al4V alloys manufactured by electron beam powder bed fusion (E-PBF)

Highly ordered TiO2 nanotubes were obtained by anodization on Ti6Al4V substrates manufactured by electron beam powder bed fusion (E-PBF). Effects of anodization parameters such as anodizing time, stirring, fluoride concentration, and water content were analyzed in an organic electrolyte (ethylene glycol) that contains ammonium fluoride. The ordering of the nanotubes was measured by regularity ratio calculations based on fast Fourier transform (FFT) from SEM images. It was found that for the processed specimens, the highest ordering of the TiO2 nanotubes was reached at 30 V for 5000 s with a concentration of 9 vol% H2O and 0.4 wt.% NH4F, exhibiting nanotubes free of delamination, cracks, and coral-like structures with a regularity ratio (RR) of 1.91. This work offers a simple method for creating homogeneous and organized TiO2 nanotubes on Ti6Al4V substrates manufactured by E-PBF which potentially improves its functionality in diverse industrial applications such as nanosensors, controlled-release substances, solar cells, water splitting, electrochromic devices, and Li-ion battery anodes.Graphical

Characteristics and properties of plasma electrolytic nitrocarburizing Ti (C, N) coatings on Ti6Al4V alloy

Titanium carbonitrides Ti(C,N) coatings were prepared by plasma electrolytic nitrocarburizing in an electrolytic solution containing ammonium nitrate, glycerol and ethanol. The coating consists of an outer compound layer and an inner diffusion layer with a total thickness of about 100μm. The compounds consist of Ti(C,N) and amorphous TiO2. The corrosion current density of the coating is almost an order of magnitude lower than that of Ti6Al4V substrate in 3.5% NaCl solution. The hardness of the coating is up to 2200HK0.025, which is 5~6 times greater than that of Ti6Al4V alloy. The coating itself is worn very slightly while the counter ball suffering serious abrasion during sliding against the SAE52100 counter ball. The PEN/C coating enhances the hardness, corrosion and abrasive resistances of Ti6Al4V alloy substantially.

Geometry and Microstructure Control of Remanufactured Metallic Parts by Cold Spray Additive Manufacturing.

Cold Spray Additive Manufacturing (CSAM) is a thermal spray technique that is typically used for the repair of metallic components. One of the challenges of CSAM is to improve the geometrical accuracy of the sprayed parts, along with overcoming the inferiority of the mechanical properties of the deposits by tailoring their microstructure with different deposition strategies. For this, Cu, Al, Ti, and Ti6Al4V substrates were reconstructed by two Cold Spray (CS) methods: Traditional (T) and a novel strategy, Metal Knitting (MK). The final geometry, microstructure, and mechanical properties of the reconstructed parts by these two methods were compared. Additionally, we investigated the effects of annealing on the microstructure of sprayed components and its influence on adhesion, resistance to erosion, and abrasive wear. The results indicate that annealing effectively reduces the microstructure defects of the remanufactured parts (up to 30% porosity reduction) and improves the adhesive strength (i.e., below 30 MPa for as-sprayed deposits, and up to 160 MPa for heat-treated Ti4Al4V deposits). Notably, the abrasive and erosive resistance of the Cu and Al annealed deposits sprayed by MK gave very similar results compared to their bulk counterparts, suggesting that it is an efficient method for the reconstruction of damaged parts.

Microstructure, wear and corrosion behavior of high-entropy alloy coatings: The concentration of Mo element and the dual effect of σ-CrMo phase

In this work, LaB6/FeCoNiCrMoX (X = 0, 0.3, 0.6 and 1) high-entropy alloys coatings with different Mo contents were prepared on the Ti6Al4V substrate by laser cladding technology. The effect of Mo content on the microstructure, microhardness, friction and wear, and electrochemical properties were investigated. The results indicated that the increase of Mo element enhanced the lattice distortion effect, and σ-CrMo phase is generated at X = 0.6 and 1. Benefiting from the strength of σ-CrMo phase, the mechanical properties of the coating have been significantly improved. At X = 1, the microhardness of Mo1.0 coating was the highest (987 HV0.3), and compared to the Mo0 coating, the wear volume of Mo0.3, Mo0.6, and Mo1.0 were lower, with values of 5.01, 1.47, and 0.54 μm3, respectively. The appropriate content of Mo element significantly improved the corrosion resistance of the coating. The corrosion current density of Mo0, Mo0.3, Mo0.6, and Mo1.0 coatings were 2.045 × 10−5, 8.873 × 10−6, 1.641 × 10−6, 2.164 × 10−6, 1.641 × 10−6 A·cm−2, respectively. As the Mo content increased, the thickness of the passivation film increased, reaching the maximum value (6.915 nm) at X = 0.6. However, excessive Mo (X = 1.0) content led to crack initiation, disrupting the stability of the passivation film, and the thickness of the passivation film actually decreases (4.162 nm). The research in this work provided a theoretical basis for the composition design of high entropy alloys regarding Mo content.

Effect of Vacuum Heat Treatment on the Microstructure and Tribological Property of Ti–6Al–4V Alloy with Cu Coating

The effect of vacuum heat treatment on the interface microstructure and tribological property of Cu‐coated Ti–6Al–4V alloy is investigated herein. After the vacuum heat treatment process, a diffusion layer is formed at the interface between the Cu coating and the Ti–6Al–4V substrate. The formed intermetallic compounds at the interface between the Ti–6Al–4V substrate and Cu coating are CuTi2, CuTi, Cu4Ti3, and β‐Cu4Ti. The activation energy of intermetallic compound growth in the diffusion zone of Cu‐coated Ti–6Al–4V is 126.0 kJ mol−1, and the pre‐exponential factor is 0.1 m2 s−1. The tribological properties of the Cu‐coated Ti–6Al–4V alloy are best when subjected to diffusion treatment at 700 °C for 300 min, with weight loss reduced by 58.2% compared to the Ti–6Al–4V alloy. The wear resistance of the Ti–6Al–4V alloy can be enhanced by Cu coating and vacuum diffusion heat treatment, and the formation of the Cu–Ti intermetallic compound contributes to this improvement. These findings offer new insights for further advancements in the tribological properties of titanium alloys.

Study on Zn-doped antibacterial bioactive coatings on Ti6Al4V titanium alloy surfaces by micro-arc oxidation

To enhance the bioactivity and antibacterial activity of titanium alloys, coatings with different content of Zn element were successfully formed on Ti6Al4V substrates by micro-arc oxidation (MAO). The microstructure and composition of the coatings were characterized, and the bioactive and antibacterial activities were evaluated by the contact angle, cell viability and plate colony counting experiments, respectively. The results show that when Zn2+ concentration of the electrolytes rises, the breakdown voltage and the process voltage decrease, while the duration of the micro-arc oxidation stage increases. The products of MAO in the coatings are mainly rutile and anatase phases. As Zn2+ concentration in the electrolyte increases, the content of crystalline phases reduces, the thickness and the surface roughness of coatings increase, and the porosity shows an increase overall. MAO coatings bond tightly to the substrates, forming a thin, dense barrier layer and a thick, porous outer accumulation layer. The increase of Zn content results in an increase of Ca and P content in the coatings and a rise in Ca/P ratio. The concentrations of Ti, O, Ca and Zn elements on the cross-section show a transition distribution. Moreover, the hydrophilicity of all coatings is improved. Zn-doped coatings improve the cell viability of preosteoblast MC3T3-E1 cells and macrophage RAW264.7 cells, and higher cell viability is observed on the coatings with higher Zn concentration. Although the MAO coatings with low Zn content increase bacterial adhesion compared to the substrate, the coatings with high Zn content show adequate antibacterial activity.

Fabrication of a Ag2O/SiO2/Ta2O5 nanocomposite coating for orthopaedic applications: Anticorrosion, photocatalytical and antimicrobial activities

With the considerable growth of the world's elderly population, there is an urgent need to develop bone implants with multifunctional surfaces, including high wear/corrosion resistance, favorable biocompatibility and excellent self-sterilization characteristics. Here, a Ag2O/SiO2/Ta2O5 nanocomposite coating was deposited on a Ti–6Al–4V substrate by double-cathode glow discharge technology. The mechanical characteristics, microstructure, biological corrosion resistance, biocompatibility, visible light catalytic activity and antibacterial properties of the nanocomposite coating were comprehensively evaluated. The Ag2O/SiO2/Ta2O5 coating was composed of crystalline Ta2O5 and Ag2O particles embedded in amorphous SiO2, and showed significantly improved surface hardness relative to the substrate. Further, this coating significantly reduced the corrosion damage from Ringer's solution to the substrate and was conducive to the spreading, adhesion and proliferation of MC3T3-E1 cells. Through investigation of the coating's photocatalytic activity, it was found that the nanocomposite coating solved the limitation that commercial Ta2O5 could not be induced by visible light. Further DFT calculations revealed the orbital occupation of the density of states of the Ag2O/SiO2/Ta2O5 heterojunction and the transfer path of the photogenerated electron-hole pairs. This finding was validated by investigation of antibacterial behaviour under the conditions of dark and visible light. It was shown that the antibacterial rate for the Ag2O/SiO2/Ta2O5 nanocomposite coating against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) under visible-light is close to 100%, which is higher than the single antibacterial rate for Ag+ ions under dark conditions. Thus, the multifunctional Ag2O/SiO2/Ta2O5 nanocomposite coating is expected to become an attractive alternative for the surface modification of the next generation of bone implants.

Adatom controlled emergence of high hardness in biocompatible beta-Ti3Au intermetallic thin film surfaces

There is growing international interest in hard biocompatible thin film surface coatings to extend the lifetime of medical implants. Parameters of the physical vapour deposition technique can be utilized to fine tune the microstructure and resulting properties of the growing thin film surface by modifying the adatom mobility of the incoming species. This work investigates the evolution of high hardness and biocompatibility of sputter deposited beta-Ti3Au intermetallic thin film surfaces as a function of growth temperature and pressure. Titanium and gold are sputtered in an optimised 3:1 ratio over glass and Ti6Al4V substrates at varying pressures of 0.3 to 1.2 Pa and temperatures of 25 to 450°C. The microstructure and crystallinity of the deposited films improved with reduction in pressure from 1.2 to 0.3 Pa but development of the β-Ti3Au intermetallic compound occurred at temperatures above 350˚C. The density of the films also increased with reducing pressure, whereas improvement in their columnar structure was observed with increasing substrate temperature. These microstructural changes caused by adatom mobility variation, led to the emergence of superior mechanical surface hardness, reaching a peak value of 12.5 GPa for films grown at 0.3 Pa and 450°C. All thin film surfaces were highly biocompatible with ion leaching levels below 1 ppm, and films deposited at lower pressure exhibited much safer cytotoxic profiles against L929 mouse fibroblasts. This work demonstrates the emergence of high hardness and biocompatibility in Ti3Au thin film surfaces with potential as next generation medical implant coating materials.

Effect of Si and Nb additions on carbonitride coatings under proton irradiation: A comprehensive analysis of structural, mechanical, corrosion, and neutron activation properties

In the present study, understoichiometric TiZrCN, TiZrNbCN, and TiZrSiCN coatings were produced using the cathodic arc technique with a C/N ratio of approximately 0.5 to investigate their potential use in nuclear technology. The coatings were evaluated for their corrosion resistance in 3.5 % NaCl and neutron activation. The effect of adding Si and Nb to the quaternary TiZrCN system was also investigated. The results showed that the addition of Si (∼4.64 at.%) to the matrix of TiZrCN improved their electrochemical properties in NaCl solution, the protective efficiency was 92%, while the Nb addition (∼5.5 at%) lead to the decrease in corrosion resistance by 1.39 times comparing with TiZrCN. Furthermore, after fast neutron irradiation at a nominal power of 1450 kW, none of the coatings were activated, indicating good radiation resistance. It was determined from the structural analysis that the Ti6Al4V substrate before corrosion consists of hexagonal and cubic space groups with different lattice parameters. By adding Si and Nb, a small amount of ZrO2 and Si3N4 was detected along with the main phases in the TiZrCN structure.