Tray Research Articles

Perovskite polycrystal for optically tuning terahertz interference fringes

We optically tuned the terahertz interference fringe using a perovskite polycrystal. Specifically, we used CH3NH3PbI3 polycrystals with different morphologies that were annealed at different temperatures. The largest modulations depth (23 %) was obtained for the CH3NH3PbI3 polycrystal drop-coated at 130 °C; this was also greater than that of a spin-coated CH3NH3PbI3 thin film. We demonstrated that the combination of a drop-coated CH3NH3PbI3 polycrystal with a metasurface allows modulation of terahertz waves. Using the interference formed by partial-through measurement and the shift of the periodic peak in the terahertz time-domain spectroscopy system, we experimentally verified that the perovskite polycrystal can redshift the terahertz-band interference fringes by 50 GHz by changing the optical power density of the external excitation light source. This provides a new idea and possibility for the development of novel terahertz modulation devices.

High-frequency terahertz stimulation alleviates neuropathic pain by inhibiting the pyramidal neuron activity in the anterior cingulate cortex of mice.

Neuropathic pain (NP) is caused by a lesion or disease of the somatosensory system and is characterized by abnormal hypersensitivity to stimuli and nociceptive responses to non-noxious stimuli, affecting approximately 7-10% of the general population. However, current first-line drugs like non-steroidal anti-inflammatory agents and opioids have limitations, including dose-limiting side effects, dependence, and tolerability issues. Therefore, developing new interventions for the management of NP is urgent. In this study, we discovered that the high-frequency terahertz stimulation (HFTS) at approximately 36 THz effectively alleviates NP symptoms in mice with spared nerve injury. Computational simulation suggests that the frequency resonates with the carbonyl group in the filter region of Kv1.2 channels, facilitating the translocation of potassium ions. In vivo and in vitro results demonstrate that HFTS reduces the excitability of pyramidal neurons in the anterior cingulate cortex likely through enhancing the voltage-gated K+ and also the leak K+ conductance. This research presents a novel optical intervention strategy with terahertz waves for the treatment of NP and holds promising applications in other nervous system diseases.

Optimized graphene metamaterial for dual plasmon-induced transparency in terahertz band with multifunctional applications

Abstract This paper proposes a patterned graphene periodic metamaterial structure, optimized using an improved genetic algorithm to adjust the position and size of each graphene strip, thereby achieving dual plasmon-induced transparency (PIT) effects in the terahertz band, resulting in extraordinary multifunctionality. The finite difference time domain method is employed to obtain the transmission spectrum, and coupled mode theory is used for theoretical analysis and verification of the dual-PIT effect. The structure exhibits multifunctionality: when used as a photoelectric switch, it achieves a modulation depth of up to 99.04% with an insertion loss as low as 0.16 dB by tuning the Fermi level. Additionally, the structure demonstrates excellent sensing performance, with a maximum sensitivity and figure of merit reaching 0.84 THz/RIU and 88.55, respectively. Furthermore, the slow light performance of the structure is investigated, showing a group delay of up to 0.5 picoseconds.

Large Dynamic Range Spectral Measurement in Terahertz Region Based on Frequency Up-Conversion Detection via OH1 Crystal.

Terahertz spectroscopy systems, which integrate terahertz sources and detectors, have important applications in many fields such as materials science and security checking. Based on highly sensitive frequency up-conversion detection, large dynamic range spectral measurements in a terahertz region are reported. Our system realized the detection sensitivity at a 10 aJ level with a 2-(3-(4-hydroxystyryl)-5,5-dime-thylcyclohex-2-enylidene) malononitrile (OH1) crystal and a dynamic range up to seven orders. Based on this system, we verified the validity of the spectral measurement with tests which were conducted on monohydrate glucose, anhydrous glucose and mixed tablet samples with a thickness of 0.8 mm in 1~3 THz, respectively. Also, a mini coppery elbow tube with an inner diameter of 1 mm was used for the transmission of a terahertz wave to simulate some strip biological tissue samples. By allowing terahertz to transmit through this tube filled with 0.5 g glucose powder, we successfully obtained the absorption spectrum with a minimum transmittance at the absorption peak in the order of 10-4.

Generation of optical-terahertz solitons by a few-cycle laser pulse

The generation of broadband terahertz radiation using an extremely short laser pulse of high intensity is considered. Using numerical simulation of the generalized Yajima-Oikawa system, it is shown that in the generation of an optical-terahertz soliton, in contrast to the quasi-monochromatic case, Kerr nonlinearity plays an important role for a low-period pulse, considering its dispersion.

Beam-steering by a phase-transition metal-based 1-bit programmable metasurface

Abstract Here the beam-steering mechanism is demonstrated using a 1 bit coded metasurface at 2.5 THz. Each unit cell of the metasurface is loaded with vanadium dioxide (VO2) which undergoes phase transition upon excitation by an external stimulus. The electrical and magnetic properties of VO2 change as the transition takes place from insulator to metal resulting in a reflection phase change of 180°. When the metasurface is excited by a microstrip patch antenna placed at a focal distance above it, the reflected beam is directed at an angle of 22°, as a result of anomalous reflection. By changing the coding pattern of the metasurface, the reflected beam is redirected at −22°. Four different coding patterns have been proposed to depict beam-steering action by the metasurface. The maximum gain registered by the reflect-array integrated antenna is 21 dBi at 2.5 THz. THz beam steering assists in forming directional beams which can be deployed in wireless transmission of THz waves.

Integrated identification and detection of hydration state and its evolution using terahertz technology

The accurate detection of dehydration processes in hydrated drugs can reveal various intermolecular vibration modes mediated by hydrogen bonds between water molecules and other components, which underpin the further development of pharmaceutical science, food safety and biophysics. Herein, terahertz (THz) technology is utilized to investigate the dehydration state of d(+)-Raffinose pentahydrate (Rf·5H2O), in conjunction with imaging-based point by point scanning data acquisition and barcodes methods, to establish an innovative platform integrated identification, trace detection, and application capabilities. Our study demonstrates that the dehydration process of Rf·5H2O can be dynamically monitored through the evolution of its THz absorption peaks, offering more precise results compared to XRD and Raman spectroscopies. Moreover, the absorbance spectra data collected at each individual pixel is utilized to build visualized THz images, achieving an ultralow minimum content required for detection of 0.032 μg/(50 μm)2. Additionally, we introduce a THz spectra-barcode conversion system that not only ensures efficient electronic recordkeeping but also enhances user readability, thereby facilitating the practical applications of THz technology.

Stretchable MWCNTs-OH/PDMS composite elastomer with hierarchical porous structure for wideband THz absorption

It is important to develop a wideband THz absorber for the prevention of terahertz electromagnetic pollution and information leakage. Some commonly used methods, such as metamaterials or dynamic modulation technology, have played important roles in the study of wideband THz absorbers. However, most of these absorbers are rigid or non-stretchable, which limits the practical applications in large mechanical deformation and non-plane scenarios. In the paper, we proposed a stretchable MWCNTs-OH/PDMS composite elastomer using the sugar template method. A series of characterization methods were carried out to verify the excellent compatibility of PDMS and MWCNTs-OH. Benefiting from its hierarchical porous structure, the draw-length ratio of sample and tensile strength reaches ∼ 190% and ∼ 0.4 MPa, respectively. More THz waves could be trapped inside the sample for conductive loss because of better impedance matching and conductivity loss (the smallest square value is ∼0.4 kΩ/□), which leads to wideband and high absorptivity (over 98% in 0.2∼2.0 THz range). Furthermore, the tested value of EMI SE was over 10 dB in 0.22∼1.82 THz frequency range at transmission mode. Combined with inherent hydrophobicity characteristics, the material also could be used in humid and rainy environments. The systemic study of stretchable MWCNTs-OH/PDMS composite elastomer will provide theoretical and technical support for subsequent THz absorption in practical scenarios.

Research on Drug Efficacy using a Terahertz Metasurface Microfluidic Biosensor Based on Fano Resonance Effect.

Advanced biosensors must exhibit high sensitivity, reliability, and convenience, making them suitable for detecting trace samples in biological or medical applications. Currently, biometric identification is the predominant method in clinical practice, but it is complex and time-consuming. In this study, we propose an optical metasurface utilizing the Fano resonance effect, which exhibits a sharp resonance with a transmittance of 32% at 0.65 THz. The resonance dip has a narrow bandwidth of 0.07 THz and a high Q-factor of 42. This resonance arises from the coupling of bright and dark modes, underpinned by the electromagnetic mechanism of Fano resonance. We integrated the metasurface into a microfluidic platform and fabricated low-temperature gallium arsenide photoconductive antennas (LT-GaAs-PCAs) on both sides of the microfluidics to efficiently generate and detect THz waves, significantly reducing the system's volume. The biosensor's detection limits for Escherichia coli (E. coli) and cefamandole nafate are 5 × 103 cells/mL and 5 μg/mL, respectively. Experimentally, when E. coli and cefamandole nafate solutions were sequentially injected into the microfluidic chip, a blue shift in the spectrum was observed. The sensor measured a 95.2% killing rate of E. coli by 40 μg/mL cefamandole nafate solution, with only a 3% deviation from biological experiments. Additionally, a timed killing experiment using 40 μg/mL cefamandole nafate on E. coli revealed a 93.7% killing rate within 3 min. This research presents a THz microfluidic biosensor with rapid detection, high sensitivity, and enhanced portability and integration, offering a promising approach for biomedical research, including antibiotic efficacy assessment and bacterial concentration monitoring.

Dispersion-free characterization of terahertz slab–waveguide modal confinement based on a metal Bragg grating structure

Photonic waveguide structures that use periodic metal grooves and periodically perforated metal slits (PPMSs) can laterally confine Sommerfeld and Zenneck surface waves of metals with the electric field accumulation among metal interspaces in the terahertz (THz) region, instead of the total internal reflection principle of dielectric slab media. For the efficiency enhancements of THz-wave coupling and slab–waveguide confinement, specific integrators with high refractive indices or specified for input angles of transverse magnetic polarized waves, such as prisms, metal blades, and waveguides, are requested to excite spoof surface plasmons in the THz region. However, the integrator-assembled slab–waveguides encounter challenges of THz pulse-wave communication in compact and low-distortion systems. A resonant waveguide grating structure based on PPMSs is experimentally demonstrated to confine THz lateral waves from the plane-wave radiation in free space. The open frame and periodic metal cavities of PPMSs can work as a slab–waveguide to transmit structural confined waveguide modes with forwarding evanescent waves of Fabry–Pérot resonance. For 0.1–1 THz waves, the short wavelengths that are both less than half the metal slit width and 3.75 times the metal thickness can lead to zero dispersion and the highest confinement factor in a slab–waveguide for PPMS-confined THz waves. This behavior is opposite to the high structural dispersion in confined THz waves of surface plasmonic devices.

Design of a beam splitter based on an adjustable beam-splitting ratio of a hexagonal star-like topological photonic crystal

We propose a new, to the best of our knowledge, mechanism to realize topological phase transition, that is, in a hexagonal star-like honeycomb lattice photonic crystal (PC), the optical quantum spin Hall effect (QSHE) can be realized by changing the materials of the outer or inner ring dielectric rods in the cells. We calculated the energy band and analyzed the topological phase transition law of a hexagonal star-like honeycomb PC. By changing the permittivity of the PC, the disturbance is introduced to the edge state. It is found that with the decrease of the permittivity of the PC, the gap decreases, the lower boundary state gradually redshifts, and the maximum transmittance in the straight waveguide can reach 98.8%. On this basis, a topological beam splitter was designed and analyzed. Results show that the beam splitting ratio obtained by the system is in the wide range of 0.2–3.5. Our research enriches the implementation of topological photonics, provides potential applications for topological boundary states in terahertz technology, and offers a new avenue for the design of current optical integrated devices.

Research on wheat impurity identification method based on terahertz imaging technology

The traditional detection of impurities in wheat has difficulties such as low precision, time-consuming, and cumbersome, therefore, it is important to study the method of rapid and accurate detection of impurities in wheat for correctly assessing the quality grade of wheat. Terahertz (THz) technology has many superior properties such as transient, broadband, low-energy, and penetrating, which can realize rapid and nondestructive detection of wheat quality. In this study, a classification and recognition algorithm AHA-RetinaNet-X for wheat impurity terahertz images based on RetinaNet and Artificial hummingbird algorithm (AHA) is proposed.A THz three-dimensional tomography imaging system is used to image wheat and its impurities, and two THz image datasets, respectively the wheat and impurity dataset for verifying the classification effect of wheat and impurities and the impurity dataset for verifying the classification effect of impurities. The experimental results show that the AHA-RetinaNet-X model outperforms other detection and classification models in terms of accuracy, F1-score, precision, recall, and specificity, and is able to achieve 96.1%, 94.9%, 95.2%, 95.8%, 95.5%, 95.3%, and 93.3% for the wheat and impurity dataset and the impurity dataset, respectively, 95.6%, 96.3%, and 95.2%, and the mAP value of AHA-RetinaNet-X is also higher than the other models and can reach 92.1%. The combination of THz imaging technology and AHA-RetinaNet-X can realize the classification and identification of wheat and impurities, which provides a new method for the non-contact rapid nondestructive detection and identification of wheat and impurities, and also provides a reference for the research of the identification and detection methods of other substances.

A miniaturized dual band terahertz metamaterial based absorber as a biosensor for non-melanoma skin cancer diognostic

Early diagnosis of Non-melanoma skin cancers (NMSCs) is most important for successful treatment of the disease.The detection of NMSCs involves visual inspection or invasive method of detection by skin biopsy. Recently, terahertz spectroscopy has come into limelight for detection of biomarkers in low terahertz (THz) region in between 0.1 – 10 THz which will be in resonance with the biomolecules. This work entails in designing a microscale THz metamaterial absorber for discriminating the attributes between Non-melanoma skin cancerous skin and normal skin. The proposed absorber is composed of space filling curved aluminum layer over a polymide substrate. The absorber culminates its absorbance peak of 99.8 % at 0.503 THz and 99.5 % at 1.076 THz, revealing its dual band trait. Moreover, variation of refractive index of the medium from 1.3 to 1.4 shows shift in absorption peak with a sensitivity of 95.76 GHz/RIU and 100 GHz/RIU for first and second band respectively.

Graphene-based hybrid metasurfaces with quasi-bound states in the continuum for manipulating terahertz absorption

We present a graphene-based hybrid metasurface with quasi-bound states in the continuum (BICs) for manipulating terahertz (THz) wave absorption. By the strategic application of structural perturbations for the THz metasurface, the symmetry-protected BICs transforms into quasi-BICs. The incorporation of graphene adeptly satisfies the critical coupling condition, thereby facilitating the attainment of the theoretical maximum absorption of 0.5 for the quasi-BICs in the THz region. And the Q-factor of the quasi-BIC can be up to 2755. Moreover, the metasurface exhibits a distinctive ability for unique tuning and efficient absorption of terahertz waves by varying the asymmetry parameter and Fermi levels. This work provides promising strategies for manipulating terahertz wave absorption.

Coherent Modulation of Two-Dimensional Moiré States with On-Chip THz Waves.

van der Waals (vdW) structures host a broad range of physical phenomena. New opportunities arise if different functional layers are remotely modulated or coupled in a device structure. Here we demonstrate the in situ coherent modulation of moiré excitons and correlated Mott insulators in transition metal dichalcogenide (TMD) moirés with on-chip terahertz (THz) waves. Using common dual-gated device structures of a TMD moiré bilayer sandwiched between two few-layer graphene (fl-Gr) gates with hexagonal boron nitride (h-BN) spacers, we launch coherent phonon wavepackets at ∼0.4-1 THz from the fl-Gr gates by femtosecond laser excitation. The waves travel through the h-BN spacer, arrive at the TMD bilayer with precise timing, and coherently modulate the moiré excitons or Mott states. These results demonstrate that the fl-Gr gates, often used for electrical control, can serve as on-chip opto-elastic transducers to generate THz waves for coherent control and vibrational entanglement of functional layers in moiré devices.

Terahertz phase imaging of large-aperture liquid crystal modulator with ITO interdigitated electrode

Abstract We have fabricated and characterized a large-aperture electrooptic phase modulation device operating in the terahertz (THz) frequency range. The device consists of a 1.6 mm thick nematic liquid crystal placed between glass plates with a novel interdigitated electrode design. Using THz time-domain spectroscopy (THz-TDS) coupled with raster scanning imaging, we evaluated phase modulation across a 25 mm diameter LC device and mapped the spatial uniformity of phase shift. Our results confirm the functionality of the LC cell as a controllable quarter-wave plate at 0.26 THz and half-wave plate at 0.52 THz. This work contributes to the development of large-aperture and transmissive LC devices as low-cost phase plates for THz waves and paves the way for future applications in THz modulators.

Non-destructive testing for thickness measurement of the adhesive layer and defect detection in ceramic-metal bonded structures using THz waves

Ceramics, owing to their superior thermal barrier properties, are employed by bonding them to primary structures exposed to elevated temperatures, such as the external components of aircraft and spacecraft. However, when these bonded structures are subjected to thermal impact resulting from high-temperature environments or rapid temperature variations, issues such as debonding, crack formation, and degradation may ensue. These issues can significantly undermine the reliability of the structures, necessitating nondestructive testing (NDT) to monitor the condition of the adhesive layer before and after thermal impact. In this article, we evaluated the integrity of adhesive structures before and after thermal impact using Terahertz (THz) waves, which offer exceptional penetration and resolution for NDT of nonmetallic materials without causing damage to the structure. To achieve this, ceramic-metal bonded structures were mounted on a robotic arm, and scanning was performed over a 70 mm area at 1 mm intervals and 0.5° increments. The peak-to-peak time of the THz signal through the adhesive layer was calculated to determine the thickness distribution. Based on experimental results, the average thickness of the ceramic layer before thermal shock was measured at 9.48 mm (standard deviation: 0.03) and the average thickness of the adhesive layer was 0.234 mm (standard deviation: 0.03). Additionally, four suspected defect areas within the adhesive layer were identified. After thermal shock, the ceramic layer’s thickness decreased by an average of 0.02 mm (0.17%), resulting in an average thickness of 9.46 mm, and the adhesive layer’s thickness decreased by an average of 0.002 mm (0.99%), resulting in an average thickness of 0.232 mm. The four suspected defect areas were confirmed to be in the same locations before thermal impact. To validate the NDT method using THz wave, the ceramic-metal bonded structure was cut to identify debonding defects in the suspected areas. The difference between the thickness distribution obtained using the THz wave-based NDT and that measured using optical microscopy after cutting was 4.4%, confirming the accuracy of the THz wave-based method for defect detection and thickness measurement.

Broadband THz Wave Generation and Detection in Organic Crystal PNPA at MHz Repetition Rates

AbstractOrganic nonlinear optical (NLO) crystals have emerged as efficient room‐temperature emitters of broadband THz radiation with high electric field strengths. Although initially confined to high‐pulse‐energy excitation in the millijoule range with kHz rates, recent efforts have focused on tailoring the physical properties of organic NLO materials for compatibility with popular MHz‐rate telecommunication wavelength lasers emitting nanojoule energy pulses. This is motivated by the large potential of such crystals for more portable and user‐safe spectroscopic systems, additionally complemented by their room‐temperature field‐sensitive THz detection capabilities. In this work, the MHz‐rate operation of the organic crystal PNPA ((E)‐4‐((4‐nitrobenzylidene)amino)‐N‐phenylaniline), which was recently discovered through data mining algorithms and reported to surpass the conversion efficiency of rivaling NLO crystals at 1 kHz repetition rate is demonstrated. Using a compact 200 mW Er:fiber laser producing 18 fs pulses at 50 MHz repetition rate, the THz field generation and detection capabilities of PNPA via performing gas phase spectroscopy in the 1.3–8.5 THz range are demonstrated. A dynamic range of 40 dB over 3.6 s and 70 dB over 2 h is obtained. The work extends the family of organic crystals compatible with telecommunication‐wavelength excitation using nJ pulses for spectroscopy beyond 5 THz.

Tunable lattice-induced transparent metasurface for dynamic terahertz wave modulation.

Tunable metasurfaces offer a promising avenue for dynamically modulating terahertz waves. Phase-change materials are crucial in this dynamic modulation, enabling precise and reversible control over the electromagnetic properties of the metasurfaces. In this study, we designed and experimentally fabricated a tunable lattice-induced transparent metasurface. This metasurface comprises two gold rod resonators exhibiting different periodic distributions, each supporting an electric dipole resonance at 2.03 THz and a surface lattice resonance at 1.51 THz, respectively. By combining these structures, we realize lattice-induced transparency. Simulation results show that the phase change of Ge2Sb2Te5 modulates these resonances, with the crystalline state significantly weakening their resonance strength intensity. The maximum modulation depth of the lattice-induced transparency peak can reach 44.4%. Experimental results of laser-induced GST phase changes confirm a modulation depth of 42.4%. This innovative metasurface design holds promise for applications in terahertz communication systems.

Effect of micrometer bubble interfaces on the detection and measurement method of XLPE

Hidden air bubble defects in the XLPE (Cross-Linked Polyethylene) insulation will seriously affect its electrical performance, which needs to be detected timely to ensure the safe and stable operation of the power system, but the interfaces between bubbles and XLPE may affect the detection. This paper proposes a novel method for high-precision detection and measurement method of micron-sized bubbles in XLPE based on THz time-domain reflection technology. To analyze the influencing factors limiting the high-precision detection and measurement of micron-sized defects, firstly, the propagation law of THz wave in XLPE with and without defects is studied, and the unipolar and bipolar pulses reflected at the defects are analyzed by overlap, and then a new method of micron-sized defects detection and measurement is proposed based on the overlap property of the bipolar pulses, and the relationship between the minimum detecting frequency and the size of the defects in the various detecting methods is determined. And the finite element method is used to simulate the THz detection of XLPE samples with defect thicknesses of 100, 7, 5, and 3 μm, respectively, and the proposed method is validated in conjunction with experiments. The results show that micrometer defects can be detected and measured with high precision using this proposed method, and the error can be controlled within 4.39%, which is significantly better than the conventional detection method. The proposed method can provide a new idea for non-destructive testing of insulation defects.