A Thurston map is a branched covering map from \(\mathbb {S}^2\) to \(\mathbb {S}^2\) with a finite postcritical set. We associate a natural Gromov hyperbolic graph \(\mathcal {G}=\mathcal {G}(f,{\mathcal {C}})\) with an expanding Thurston map \(f\) and a Jordan curve \({\mathcal {C}}\) on \(\mathbb {S}^2\) containing \({{\mathrm{post}}}(f)\). The boundary at infinity of \(\mathcal {G}\) with associated visual metrics can be identified with \(\mathbb {S}^2\) equipped with the visual metric induced by the expanding Thurston map \(f\). We define asymptotic upper curvature of an expanding Thurston map \(f\) to be the asymptotic upper curvature of the associated Gromov hyperbolic graph, and establish a connection between the asymptotic upper curvature of \(f\) and the entropy of \(f\).