Bridge Bonds Research Articles

Green Synthesis and Theoretical Study of New Imidazopyrimidine Derivatives via One‐Pot Multicomponent Reactions

AbstractAg/Fe3O4/SiO2@MWCNTs MNCs magnetic nanocomposites as an effective catalyst was employed for generating of imidazopyrimidine derivatives in high yields. The structure of synthesized nanoatalyst was confirmed by SEM, XRD, TEM, VSM, EDX and XPS analysis. These new compounds were synthesized by using multicomponent reaction of cyclic guanidine derivatives, electron deficient acetylenic compounds, tert‐butyl isocyanide, ethyl bromopyruvate and synthesized nanocatalyst in aqueous media at room temperature. It should be mentioned that the high performance of nanocatalyat was synthesized by using water extract of Petasits hybridus leaves, which was utilized in these reactions for many times to confirm the reusability of nanocatalyst. The antioxidant property of new synthesized imidazopyrimidine was evaluated by two procedures and compound 5 b have the high property relative to other compounds. Also, the antimicrobial activity of new generated imidazopyrimidine was evaluated by disk distribution process utilizing two kinds of Gram‐negative bacteria and Gram‐positive bacteria; proving bacterial growth was stopped by using of these compounds. Also, to better understanding reaction mechanism density functional theory (DFT) based quantum chemical methods have been applied. Applied to the preparation of imidazopyrimidine derivatives, this method has short reaction times, high product yields, and the ability to separate catalyst and product using simple procedures.

Covalently bridge metals to biomass carbon for sensing DA and FA with high specificity and sensitivity

Due to the high catalytic activity and electrical conductivity, “transition metal-nonmetal” compounds have broad application prospects in the construction of electrochemical sensors. However, it is still a challenge to solve the problem of catalyst deactivation and slow electron transfer due to nanoparticle agglomeration's blockage of active sites. Here, we prepare a series of covalently bonded “C-M-O” bridge bonds on biomass carbon for the first time. The bridge bonds have a straight-like “electron path”, which shortens the electron transfer path and improves the electrical conductivity, and catalytic activity. The bridge bonds exhibit excellent catalytic activity even after being subjected to prolonged mechanical external forces. Besides, the bridge bonds can integrate a biosensor with MIP and exhibit excellent electrocatalytic performance, including high sensitivity, low detection limit, excellent stability, superior interference immunity, and the ability to accurately monitor DA and FA released from real samples and live cells in real time. The strategy of forming “C-M-O” bridge bonds based on covalently bonded supports provides a new perspective for solving the agglomeration of nanocatalysts blocking active site deactivation and improving electron transfer rate.

Antcin-B, a phytosterol-like compound from Taiwanofungus camphoratus inhibits SARS-CoV-2 3-chymotrypsin-like protease (3CLPro) activity in silico and in vitro

Despite the remarkable development of highly effective vaccines, including mRNA-based vaccines, within a limited timeframe, coronavirus disease 2019 (COVID-19) caused by severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) is not been entirely eradicated. Thus, it is crucial to identify new effective anti-3CLPro compounds, pivotal for the replication of SARS-CoV-2. Here, we identified an antcin-B phytosterol-like compound from Taiwanofungus camphoratus that targets 3CLPro activity. MTT assay and ADMET prediction are employed for assessing potential cytotoxicity. Computational molecular modeling was used to screen various antcins and non-antcins for binding affinity and interaction type with 3CLPro. Further, these compounds were subjected to study their inhibitory effects on 3CLPro activity in vitro. Our results indicate that antcin-B has the best binding affinity by contacting residues like Leu141, Asn142, Glu166, and His163 via hydrogen bond and salt bridge and significantly inhibits 3CLPro activity, surpassing the positive control compound (GC376). The 100 ns molecular dynamics simulation studies showed that antcin-B formed consistent, long-lasting water bridges with Glu166 for their inhibitory activity. In summary, antcin-B could be useful to develop therapeutically viable drugs to inhibit SARS-CoV-2 replication alone or in combination with medications specific to other SARS-CoV-2 viral targets.

Manipulating the ESPT process and photophysical properties of HQCT by water-based hydrogen bond bridge

The 8-hydroxyquinoline-2-carboxaldehyde thiosemicarbazone (HQCT) is sensitive to water molecules in dimethyl sulfoxide according to the experimental phenomenon description, with a sensory performance that is dependent on the water-based hydrogen bond bridge as mediator. Here the excited state intramolecular (ESAPT) and intermolecular (ESEPT) proton transfer mechanism involved by water solvent and the optical properties associated with them are clarified in details. Along the minimum energy pathways in the scanned potential energy surfaces (PESs), we find that the ESEPT reaction induced by water molecule is a synergistic double-proton transfer process. And the results indicate that trace water molecules can promote the reaction effectively. In addition, we also investigate the photophysical properties involved with the excited state proton transfer (ESPT) reaction with the increase of water fraction in the solvent. The results show that the fluorescent oscillator strength (f) and radiative rates (kr) decrease with the increase of water fraction, which are consistent with the experimental phenomenon. We attribute the phenomenon of fluorescence quenching to the increasing transition dipole moment (μ) which accelerates the intramolecular charge transfer (ICT) process. Our work not only explain the water-detection mechanism in the organic solvent before water-sensitive reactions essentially, but also provide a theoretical basis for the synthesis of new Schiff base fluorescent chromophores for the water detection in organic solvents.

Covalently bridged bond assembly of MoS2 lamellae onto a graphene sheet: an outstanding electrode for high rate and long-life lithium/sodium-ion batteries

The practical application of Molybdenum sulphide (MoS2) electrodes has been hindered by its structural instability, and poor electrical conductivity. To enhance the cycle stability and rate performance of MoS2 in lithium/sodium-ion batteries (LIBs/SIBs), we synthesized a graphene-supported MoS2 composite (MoS2@rGO) with affluent covalent bridged bonds through a facile and scalable hydrothermal and annealing process. The covalent bridged bonds of Mo–S–C, Mo–O–C and C–O–S provide an effective charge transfer path between MoS2 and graphene, facilitating fast charge hopping and improving rate performance. As anode materials for LIBs, the MoS2@rGO exhibited exceptional long-term cycle life (906 mAh g−1 at 1.0 A g−1 after 400 cycles) and outstanding rate capability (1267.7/314.7 mAh g−1 at 0.1/6.5 A g−1). Additionally, the MoS2@rGO electrode demonstrated a stable reversible capacity of 521.7 mAh g−1 at 1.0 A g−1 after 700 cycles and excellent rate capabilities of 665.1 and 326.3 mAh g−1 at 0.1 and 10.0 A g−1 in SIBs. The edge Mo of MoS2 is directly coupled with the oxygen of the functional group on rGO, achieved by adjusting the pH value of the solution to tune the surface charge feature, can effectively enhance the structural stability of electrode even under higher current density.

Tribological behavior of polycrystalline diamond based on photo-Fenton reaction

Polycrystalline diamonds (PCD) has high thermal conductivity and as heat sinks in semiconductor power devices. However, PCD exhibits high hardness and strong chemical inertness lead to lower processing efficiency and increase processing costs. Hence, achieving efficiently obtain high-quality PCD surfaces is crucial. In this study, we investigated the tribological behavior of PCD in different environments (deionized water, H2O2 + UV, Fenton, and photo-Fenton) and under different photo-Fenton conditions (pH, light intensity, Fe3O4 concentration, and H2O2 concentration) via Si3N4 ball-disk friction and wear experiments. The photo-Fenton reaction improved the material removal rate of PCD, which was the highest (285.4 μm3/min) under optimized conditions of pH = 3, 100 mW/cm2 light intensity, 2 wt% Fe3O4 concentration, and 10 wt% H2O2 concentration. Based on the friction and wear experimental results and X-ray photoelectron spectroscopy, we propose a material removal mechanism for PCD. The hydroxyl radical (·OH) produced by the photo-Fenton reaction oxidize the PCD surface to form CO, CO, and C–OH groups, which are converted into C–O–Si bridge bonds on the PCD surface, resulting in material removal. Our study findings provide theoretical support for the photo-Fenton reaction -assisted CMP of PCD.

TaBOX: A water-soluble tetraanionic rectangular molecular container for conjugated molecules and taste masking for berberine and palmatine

A water-soluble macrocycle that bears four carboxylate anions has been designed and prepared, which forms a rectangular cavity that can efficiently encapsulate discrete electron-deficient aromatic compounds, including berberine and palmatine. This macrocycle is revealed to be highly biocompatible and able to inhibit the bitter taste of the two drugs.

Condensation of residue during direct liquefaction of a high-vitrinite coal

To understand the formation of residues and its relation with the vitrinite structure and the products yield in direct coal liquefaction (DCL), a high vitrinite low-rank coal, Naomaohu (NMH), is studied at 380–460 °C in the presence of tetrahydronaphthalene and absence of a catalyst. The structures of coal and residues are characterized by the proximate and ultimate analyses, 13C nuclear magnetic resonance, and the electron spin resonance. Beside the frequently seen coal conversion and products yield at various temperatures and time, the products yield and the residues structure parameters are correlated with the residues yield (YRes) and the quantity of hydrogen donated from tetrahydronaphthalene (QH). It is found that the DCL can be roughly defined into two regions demarcated by 420 °C, with limited condensation at 380–400 °C and intensive condensation at 440–460 °C, for example. These two-region behaviors can be clearly evidenced by the different trends in products yield and the residues parameters, such as those relevant to the cleavage of bridge bonds (fal, Cn, δ-C and δ-O) and those relevant to the residues’ condensation (far, Xb, RD and H/C), against YRes and QH. The two-region behavior is important for optimization of DCL conditions and its processing scheme.

The competition between radical copolymerization and charge separation of cyclic ketene acetals and electron‐deficient olefins

AbstractCyclic ketene acetals (CKAs) possess unique features in two aspects. On one hand, after the addition of a radical on the alkene, CKAs can undergo ring‐opening via radical rearrangement, enabling polyester preparation based on chain‐growth polymerization. On the other hand, the alkene connected with two electron‐donating oxygens in a strained form exhibit unique reactivities, resulting in complex reactions in the presence of electron deficient compounds. In this investigation, fundamental studies on CKA radical ring‐opening polymerization and charge‐mediated reactions were performed. Alternating copolymers of CKA and maleimides, or maleates, were prepared and characterized. Quantum chemistry modeling from the perspectives of reaction kinetics and thermodynamics enabled an in‐depth mechanistic study on the side reactions between CKA and maleic anhydride or itaconic anhydride, inspiring the techniques to minimize those side reactions in competition with radical copolymerization. After purifying the anhydride monomers with sublimation, the copolymerization with CKA successfully occurred. The anhydride containing polyester structures with an alternating sequence were confirmed with comprehensive characterizations. Facile post‐functionalization with an alcohol was performed, resulting in carboxylate containing polyesters.

Self-Assembly of an Anionic [Cu5I8]3- Supramolecular Cluster Driven by Ion-Pair Interaction and Catalytic Properties.

The rational design and controlling synthesis of an anionic cuprous iodide supramolecular cluster with high nuclearity through noncovalent interactions remains a significant challenge. Herein, a cationic organic ligand (L1)3+ was driven by anion-cation ion-pair electrostatic interaction to induce free cuprous iodide to aggregate into an anionic supramolecular cluster, [(Cu5I8)3-(L1)3+] (C1). Moreover, five copper(I) atoms bind with eight iodides through multiply bridged Cu-I bonds associated with intramolecular cuprophilic interactions in this butterfly-shaped cluster core. Supramolecular cluster C1 exhibited a solid-state emission at 380 nm and an emission at 405 nm in acetonitrile at room temperature, respectively. Interestingly, this unprecedented cuprous iodide cluster demonstrated a good catalytic performance for azide-alkyne cycloaddition reaction (CuAAC) and the catalytic yield can be up to 80% for eight different substrates at 80 °C. Furthermore, the density functional theory (DFT) calculation revealed that the thermodynamic-dependent cycloaddition reaction underwent a four-step pathway with an overall energy barrier of -43.6 kcal mol-1 on the basis of intermediates monitored by mass spectrum.

Phase evolution and mechanical-hydroscopic properties of alkali-silica reaction gels modified by magnesium nitrate

Alkali-silica reaction (ASR)'s destructiveness is governed by the compositions and properties of ASR products, while methods of converting these hygroscopic-expansive gel-like products into innocuous phases remain unexploited. In this study, the influence of magnesium nitrate on the evolutions of phase, molecular structure, hydroscopic and mechanical properties of ASR gels with varying Mg/Si ratios from 0.1 to 1.1 was investigated. The results indicate that the primary phases of ASR products, tobermorite-type calcium silicate hydrate (C–S–H) and alkali kanemites, can be suppressed into brucite and eventually converted into magnesium-silicate-hydrate (M-S-H) in the presence of increasing Mg/Si ratios and the consequent decreasing pH. The Si–O–Si bridging bonds and Si–O symmetric stretching in the Q3 sites of ASR products can be suppressed. The phase and structure modifications resulted in a 93.5% reduction in hydroscopic swelling, a 94.7% decrease in strength, and a 152.3% drop in modulus of elasticity rendering the ASR products less destructive.

New MCRs: Preparation of Novel Derivatives of Pyrazoloazepines in Ionic Liquid and Study of Biological Activity

In the present investigation, we have effectively synthesized innovative pyrazoloazepine derivatives with notable yields. The synthesis was successfully accomplished by means of a multicomponent reaction that was carried out in an ionic liquid at ambient temperature conditions. The constituents implicated in this procedure consisted of NH-acids such as isatins, α-halo ketones, electron deficient acetylenic compounds, hydrazine, and hydrazonoyl chlorides. Significantly, the inclusion of an NH group appeared as a crucial characteristic in the resultant compounds. Our investigation encompassed the examination of the antioxidant capabilities exhibited by these substances. The study utilized various assays, including ferric reduction capacity and diphenyl-picrylhydrazine (DPPH) radical trapping, to investigate the possible antioxidant benefits of the substances. The antioxidative capacity of the produced pyrazoloazepine compounds was evaluated by various evaluations. The synthetic approach we employ offers numerous advantages. To begin with, the prompt response time enables the expedited generation of complex compounds. Furthermore, the significant outputs of the specific items highlight the effectiveness of our approach. The ease with which the catalyst and products can be separated enhances the efficiency of the purification procedure.

Novel Isomer of Volleyballene Sc20C60.

The Stone-Wales defect is a well-known and significant defective structure in carbon materials, impacting their mechanical, chemical, and electronic properties. Recently, a novel metal-carbon nanomaterial named Volleyballene was discovered, characterized by a C-C bond bridging two carbon pentagons. Using first-principles calculations, a stable Stone-Wales-defective counterpart of Volleyballene, exhibiting Th symmetry, has been proposed by rotating the C-C bond by 90°. Although its binding energy per atom is slightly higher than that of Volleyballene (ΔEb = 0.009 eV/atom), implying marginally lower structural stability, it can maintain its bond structure until the effective temperature reaches about 1500 K, indicating greater thermodynamic stability. Additionally, its highest vibration frequency is 1346.2 cm-1, indicating a strong chemical bond strength. A theoretical analysis of the Sc20C60 + Sc20C60 binary systems highlights that the stable building block may be applied in potential nanoassemblies.

Green Synthesis and Biological Study of New Imidazothiazines Using New MCRs: A Combined Experimental and Theoretical Investigation

For the performing this research multicomponent reaction of isatin, electron-deficient acetylenic compounds, α-haloketones, ammonium acetate, isothiocyanates and methyl aziridine in aqueous at room temperature was investigated for the production of novel derivatives of azepinothiazine in excellent yields. The synthesized azepinothiazines have OH, NH2 and NH functional groups that have acidic hydrogen and show high antioxidant activity. These synthesized compounds also displayed antimicrobial activity by using the disk diffusion procedure and two Gram-positive and Gram-negative bacteria. Also, to better understanding reaction mechanism density functional theory-based quantum chemical methods have been applied. The employed process for the production of azepinothiazine has some benefits such as short time of reactions, excellent efficiency of the product, easy separation of products.

A novel zinc‐chelating peptide identified from rapeseed (Brassica napus) protein hydrolysate: insights into its zinc‐binding sites by density functional theory

SummaryThe binding sites between zinc chelating peptide (ZCP) and zinc have not been clearly understood at the quantum chemistry level. Ala‐Ser‐His (ASH), a new ZCP located in the cruciferin precursor, was identified from in vitro digestion hydrolysate of rapeseed (Brassica napus) protein. Also, ASH exerted the concentration value of 114.09 ± 0.98 mM showing 50% zinc chelating activity. The prepared ASH–Zn (ZCP‐zinc chelate), displayed varying characteristics from ASH on surface microstructures, X‐ray photon energies, and infrared spectrum. The geometric structure of ASH–Zn with minimum free energy was obtained using density functional theory, producing a bridge bond of O21–Zn41–O32 between Ser and His residues. Based on the basic set of 6–311++G (d, p), O21–Zn 41 and O32–Zn41, respectively, had bond lengths of 1.96503 Å and 1.94515 Å, while O21–Zn41–O32 displayed a bond angle of 136.41069°. These findings further promote research on rapeseed proteins providing new possibilities for studying peptide‐metal chelates.

A preliminary study on the quality evaluation of coking coal from its structure thermal transformation: Applications of fluidity and swelling indices

Evaluating the coking coal quality from coal structure thermal transformation was crucial to control the coking process. The coal quality indices of ash composition, volatile matter, element distribution and caking indices were redefined based on the coal structural characteristics. Five structure parameters derived from volatile matter and element distribution, including carbon aromaticity (fa), average number of condensation rings (NCR), ring condensation index (2(NCR −1)/C), aliphatic hydrogen content (AlH) and number of bridge bonds (AlB), were proposed to evaluate the comprehensive structure properties of coals. The rationality of these parameters was verified through 13C NMR analysis. The superiority of fluidity and swelling indices in reflecting the structure transformation of individual and blended coals was clarified. In addition, a novel mothed for measuring swelling pressure was developed, taking into account the impact of heat and mass transfer on the coking process. The results show that the bridge bonds content (AlB) affects the coal particle softening which attributes to the thermal cleavage of Cal-Cal/O and Car-O. The high aliphatic hydrogen content (AlH) relating to the stabilization of pyrolytic fragments decreases maximum fluidity temperature. The formula of F(MD) captures the relevance among maximum dilatation, volatile matter, caking and plastic layer indices, which aids in comprehending the swelling mechanism based on the balance between gas release and permeability evolution. The fluidity and swelling indices serve as indicators of the structural transformation during individual coal coking, contributing to the quality evaluation of blended coals with similar coke performance. The self-designed device provides a more accurate prediction of pushing current based on the maximum swelling pressure, compared to the Audibert-Arnu dilatation. This work contributes to the scientific evaluation of coking coals and the precise control of the coking process.

Chemical bonding and facet modulating of p-n heterojunction enable vectorial charge transfer for enhanced photocatalysis

Heterojunctions have been proved to be the promising photocatalysts for hazardous contaminants removal, but the inferior interfacial contact, low carrier mobility and random carrier diffusion seriously hamper the photoactivity improvement of the conventional heterojunctions. Herein, SO chemically bonded p-n oriented heterostructure is fabricated via selectively anchoring of p-type Ag2S nanoparticles on the lateral facet of n-type Bi4TaO8Cl nanosheet. Such a p-n heterojunction engineering on specific facet of Bi4TaO8Cl semiconductor derives ingenious double internal electric field (IEF), which not only effectively creates the spatially separated oxidation and reduction sites, but also delivers the powerful driving forces for impactful spatial directed photocarrier transfer along the cascade path. Additionally, our experimental and theoretical analyses jointly signify that the interfacial SO bond could serve as an efficient atomic-level interfacial channel, which is conducive to encouraging the vectorial charge separation and migration kinetic. As a result, the Ag2S/Bi4TaO8Cl oriented heterojunction exhibits significantly enhanced visible light driven photocatalytic redox ability for tetracycline oxidation and hexavalent chromium reduction than those of single component and the traditional random/mixed heterojunctions. This study could provide a deeper insight into the synergistic effects of multi-IEF modulation and interfacial chemical bond bridging on optimizing the photogenerated carrier behaviors.

Glycerol-based H3PO4-activated carbon as a versatile adsorbent for removal of pollutants from wastewater: A novel synthesis protocol

Aiming at revaluing oversupplied glycerol as a result of biodiesel production, this approach introduces an authentic synthesis protocol for producing glycerol-based activated carbons holding suitable textural/surface properties for an efficient application in the methylene blue and Pb2+ adsorption processes. Typically, glycerol and phosphoric acid were submitted to a polycondensation reaction in order to insert manipulable fractions of C-O-P bridge bonds throughout the whole polymer chain in the form of mono, di and triesters before the traditional carbonization and activation steps. The physicochemical and surface chemistry properties of the ACPs were characterized by means of N2 adsorption/desorption isotherms, thermal analysis, elemental analysis, surface functional groups titration and pHpzc, X-rays diffraction, FTIR spectroscopy and scanning electron microscopy. Indeed, such strategy gave rise to a set of micro/mesoporous activated carbons (ACP) with surface area of up to 1056 m2/g and total acidity, constituted by thermally insensitive carbonyls-/phosphorus-containing functional groups, ranging from 1.63 to 2.32 mmol g−1. Adsorptive features of the obtained series of activated carbons were validated in the methylene blue and Pb2+ removal processes reaching out adsorption capacity of up to 543.3 and 26.5 mg g−1 at 298 K, respectively. Additionally, after confronting experimental data with several isothermal and kinetic theoretical models, it was demonstrated that the adsorption mechanism of both pollutants onto the ACPs is driven by chemisorption up to the monolayer coverage. The thermodynamic study indicated spontaneity of the adsorption processes and suggested a relation between the textural properties and surface functionalities of the ACPs with the enthalpic nature of the adsorbent-adsorbate interactions.

Effect of extracts of petroleum ether, dichloromethane and methanol on thiophenic sulfur release during coal pyrolysis

The existing forms and thermal transformation of sulfur in high sulfur coal directly influence the efficiency of coal clean utilization by the staged pyrolysis conversion. Low molecular compounds distributed in coal are very different from the macromolecular structure of coal and play an important role during coal pyrolysis. In order to investigate the effects of low molecular compounds on the release of typical thiophenic sulfur species during coal pyrolysis by Py-GC/MS, petroleum ether, dichloromethane, and methanol were used for sequential ultrasonic extraction of Linfen coal (LFC). The compositions of extracts were detected by GC×GC/MS. Results show that three primary kinds of thiophenic sulfur species (2-methyl thiophene, benzothiophene, and dibenzothiophene) were released during coal pyrolysis and they are mainly derived from the cracking of macromolecular skeleton containing thiophenic sulfur in coal. The amounts of thiophenic sulfur released during raw coal and residues pyrolysis both increase with temperature. Besides, extracts with different compositions have different effects on the release of thiophenic sulfur during pyrolysis. In detail, the cyclization of aliphatic compounds could provide active hydrogen. On the one hand, the active hydrogen promotes the break of bridge bonds around thiophenic sulfur. On the other hand, active hydrogen may attack sulfur atoms of thiophenic sulfur, reducing the energy barriers of thiophenic sulfur decomposition. Aromatic compounds polymerize with sulfur-containing groups converting to benzothiophene and dibenzothiophene with larger molecular weight. In addition, thiophenic sulfur may be oxidized by esters to sulfones or sulfoxides, which further decompose, resulting in the inhibition effect on thiophenic sulfur formation during coal pyrolysis.

Effect of SrTiO3 amount and ultrasonic disperse on the thickness of Bi2O3 nanosheets and the photocatalytic performance of the composite α-Bi2O3/SrTiO3

Due to the correlation between structure and activity, even the photoelectric performance of simple materials can be improved by designing component structures reasonably. Taking α-Bi2O3/SrTiO3 as an example, this article reports a novel ultrasound assisted synthesis method for adjusting the thickness of α-Bi2O3 nanosheets (NSs) in heterojunctions. The continuous variation from ∼200 to ∼10 nm confirms that the thickness of NSs is limited by the amount of SrTiO3 added, and ultrasonic dispersion before calcination is a key initiative. Systematic tests indicate that the opto-electronic properties of the heterojunctions are highly thickness-dependent. The heterojunction with a thickness of ∼20 nm α-Bi2O3 NSs has a wider light absorption range (>550 nm), higher photocurrent response (52.8 μA cm−2), lower charge transfer resistance, and efficient catalytic ability for organic degradation (0.071 min−1 for 0.1 g·L−1 RhB). Various spectroscopic evidences display that Bi-O-Ti oxygen bridge bonds provides an efficient transport channel for photogenerated carriers. Furthermore, large specific surface area, and the built-in electric field of heterojunctions jointly accelerate the oxidation degree of pollutants. As high as 98.9% (0.1 g·L−1) and 55.9% (0.5 g·L−1) degradation efficiencies in 1 h, importantly, documented that the α-Bi2O3/SrTiO3 heterojunctions was competitive for the dispose of high-concentration [RhB] outlet water.