In recent years, laser-driven neutron sources have attracted attention for their applications such as nondestructive analysis and the production of medical radioisotopes. One of the efficient neutron production methods is the use of the 9Be(d, n)10B reaction on a beryllium target with deuterons accelerated by laser–plasma interactions, since this is an exothermic reaction. For efficient deuteron acceleration, we have developed a formation system for solid deuterium targets. A millimeter thick solid deuterium target can be formed with the system. Before the laser shot, the solid deuterium target in the laser chamber can be mechanically moved to the laser irradiation point. We have demonstrated deuteron acceleration by the LFEX laser, and a highly pure deuteron pulse with energies of up to 6.2 MeV was measured with a Thomson parabola ion spectrometer.