Thickness Of TiO2 Thin Film Research Articles

Surface and interface properties of TiO2/CuO thin film bilayers deposited by rf reactive magnetron sputtering

Thin film bilayers of TiO2/CuO with intentionally varied thickness of the top layer of TiO2(25–150 nm) were grown by means of sequential rf magnetron reactive sputtering from Cu and Ti metallic targets in a flow rate-controlled Ar + O2 gas mixture. XRD diffraction in GID configuration, SEM top and cross-sectional images, EDS combined with SEM, XRR profiles, UV–VIS-NIR spectrophotometry and synchrotron soft radiation XAS in TEY mode were used to characterize crystal structure, morphology, the mode of growth, chemical composition, density and roughness as well as the optical and electronic properties of the synthesized thin film bilayers. CuO bottom layer turned out to crystallize in a monoclinic structure while TiO2 top layer remained amorphous. Film roughness of CuO decreased from about 12 nm with the increasing thickness of TiO2 thin film to about 1–2 nm. X-ray absorption spectroscopy demonstrated a presence of Cu+ and Cu2+ in TiO2 top layer of TiO2/CuO heterostructure. The photoelectrochemical measurements revealed that thin film bilayers of TiO2/CuO behaved as photocathodes in the process of water splitting. The photocurrent density was found to be an increasing function of the top TiO2 layer thickness.

Evaluation of the difference in multilayer thickness of TiO2 thin film by laser speckle photography

TiO2 thin film thickness is measured after each layer of coatings by laser speckle photography. TiO2 thin film coatings are carried out on the steel substrate in a periodical way by the spin coating method. At the time t1, the first layer coating scatters the coherent laser and develops the self-interference pattern of an image called speckle, which is captured and auto-correlated. After time t2, the speckle image is recorded by CCD and cross-correlated with the previous one. There is pixel distance movement and it is computed by image processing. This speckle imaging practice gives 8 µm as the thickness of the second layer of Tio2 film coating. Hence, the shift of pixel distance gives the thickness of the multilayer sample coatings in a satisfactory manner.

Effect of TiO2 thin film thickness and dye characterization using Binahong leaf (Anredera cordifolia) as photosensitizer in dye-sensitized solar cell

Abstrak. Dye pada sel surya jenis DSSC merupakan bahan utama yang digunakan sebagai fotosensitizer yang dapat menyerap spektrum warna serta sangat berpengaruh bagi efisiensi sel. Pada penelitian ini, dye yang digunakan adalah pigmen klorofil. Binahong (Anredera Cordifolia) merupakan tanaman yang dapat tumbuh di dataran rendah maupun dataran tinggi dan dapat tumbuh dengan mudah, sehingga daun ini banyak dan mudah ditemukan. Parameter yang menentukan baik atau tidaknya suatu TiO2 digunakan sebagai lapisan semikonduktor pada DSSC selain dari ukuran partikelnya yang kecil, serta ketebalan dari lapisan TiO2 yang meliputi suatu ketebalan lapisan TiO2 dengan struktur permukaan serta diameter pori antar partikel TiO2 sebagai diffusor dye. Hasil penelitian menunjukkan bahwa cell memiliki efisiensi tertinggi 7.24%, rekor efisiensi tertinggi dalam capaian efisiensi dye berbasis klorofil. Abstract. Dye in DSSC solar cells is the primary pigment used as a photosensitizer. It can absorb the color spectrum and is very influential on cell efficiency. In this research, the dye used is chlorophyll pigment. Binahong (Anredera cordifolia) is a plant that can grow in the lowlands and highlands and can grow easily, so the leaves are abundant and easy to find. Parameters that determine whether or not a TiO2 is used as a semiconductor layer in DSSC apart from its small particle size and the thickness of the TiO2 layer which includes a TiO2 layer thickness which includes surface structure and pore diameter between TiO2 particles as an absorber layer. The results showed that the cell had the highest efficiency of 7.24%, the highest efficiency in achieving the efficiency of chlorophyll-based dyes.

TiO2 Antireflection Coating Deposited by Electro-Beam Evaporation: Thin Film Thickness Effect on Weighted Reflectance and Surface Passivation of Silicon Solar Cells

Titanium dioxide was extensively used in solar cell industry and currently has been studied to produce passivated contacts in PERC/PERT and TOPCon solar cells. The aim of this paper was to analyze the impact of the thickness of TiO2 thin films deposited by electro-beam evaporation on the weighted reflectance and the surface passivation on silicon solar cells. Thin films with different thicknesses were deposited to produce PERT solar cells, varying from 50 to 90 nm. The surface passivation was enhanced as the thickness was increased. For instance, at 400 nm, the internal quantum efficiency increased from 71% to 76% when the thickness of the TiO2 was augmented from 50 nm to 90 nm. The lowest weighted reflectance was obtained in samples with 80 nm thick TiO2 films. Considering the compromise between antireflection properties and surface passivation, the highest efficiency solar cells were produced with 80 nm thick TiO2.

A hybrid system consisting of dye-sensitized solar cell and absorption heat transformer for electricity production and heat upgrading

A new hybrid system mainly composed of a dye-sensitized solar cell (DSSC), a solar selective absorber (SSA) and an absorption heat transformer (AHT) is theoretically put forward to harness the long wavelength sunlight transmitted through the DSSC. The models of both DSSC and AHT are adopted from the current literature and the condition enables the AHT to involve in heat upgrading is obtained. The model validations of DSSC and AHT are conducted using experimental data. Mathematical expressions of power output and efficiency for the hybrid system are formulated by taking a variety of irreversible losses into account. The effectiveness of the hybrid system is justified and evaluated. Maximum power density (MPD) and maximum energy efficiency (MEE) of the integrated system are, respectively, 158.2 W m−2 and 16.3 %, having evidently improvement compared to that of a single DSSC. A variety of operating conditions and design parameters affecting the hybrid system performance are studied. Numerical calculation results show that the working temperature, photoelectron absorption coefficient of DSSC and total heat-transfer area of the AHT have positive effects on the hybrid system performance. There exists an optimum TiO2 thin film thickness to optimize the hybrid system performance. However, a greater Schottky barrier has negative influence on the hybrid system performance. The results obtained here may provide some guidance for designing such a practical hybrid system.

TiO2 waveguides thin films prepared by sol-gel method on glass substrates with and without ZnO underlayer

Abstract TiO2 thin films have been deposited on glass substrates with and without ZnO underlayer by sol-gel dip coating process. XRD patterns show the formation of anatase phase with the diffraction lines (1 0 1) and (2 0 0) in TiO2/glass sample. In TiO2/(ZnO/glass) sample, TiO2 is composed of anatase phase with the diffraction line (2 0 0) but the diffraction peaks of ZnO wurtzite are also well-defined. The determination of the refractive index and the thickness of the waveguiding layers has been performed by m-lines spectroscopy. The thickness of TiO2 thin films deduced by Rutheford Backscattering Geometry (RBS) agrees well with that obtained by m-lines spectroscopy. TiO2/glass sample exhibits one guided TE0 and TM0 polarized modes. In TiO2/(ZnO/glass) sample, only, TE0 single mode has been excited due to cutoff condition.

Plasmon-induced electron injection into the large negative potential conduction band of Ga2O3for coupling with water oxidation

In this study, an interfacial modification layer was applied to improve the plasmon-induced light energy conversion of a gallium(iii) oxide (Ga2O3) photoelectrode, which possesses a much more negative conduction band potential compared with the reduction potential of photons to hydrogen. The plasmon-induced photocurrent generation under visible light irradiation was observed with Au nanoparticle-loaded Ga2O3 (Au-NPs/Ga2O3). An interfacial modification was carried out by depositing a titanium dioxide (TiO2) thin-film layer on Au-NPs/Ga2O3via atomic layer deposition. Since the surface states of TiO2 possess excellent hole-trapping ability, this interfacial modification remarkably improved the generation of plasmon-induced photocurrent in the visible region. The photoelectric conversion efficiency of interfacially modified Au-NPs/Ga2O3 showed a TiO2 thin-film thickness dependence because the migration of hot carriers was suppressed with increasing TiO2 thickness. The Au-NPs/Ga2O3 photoelectrode modified with 2 nm-thick TiO2 showed the best photoelectric conversion performance, and the thermodynamic energy conversion efficiency under irradiation with 600 nm light was approximately two times larger than that of the Au-NPs/TiO2-thin film due to the extremely negative onset potential of Au-NPs/Ga2O3 with TiO2. Therefore, the plasmonic Ga2O3 photoanode with the interfacial TiO2 modification could provide both a high reduction ability for H2 evolution and an oxidation ability for water oxidation, because of the negative conduction band of Ga2O3 and the hole-trapping property from TiO2, respectively.

Investigations of structure and electrical properties of TiO2/CuO thin film heterostructures

Three sets of TiO2/CuO thin-film heterostructures with various thickness of TiO2 layer equal to 35 nm, 70 nm and 90 nm were deposited using reactive magnetron sputtering method. Morphology, structural, optical and electrical properties of as-prepared thin-film heterostructures were investigated. Structural investigations showed that thin film based on copper oxides was nanocrystalline and had monoclinic CuO structure. The crystallite size was equal to 11.8 nm. In the case of TiO2 film amorphous nature was observed. All prepared TiO2/CuO heterostructures were well transparent (above 80%) and exhibit the p-type of electrical conduction. Moreover, it was found that the thickness of the top TiO2 film had an effect on the resistance and value of the Seebeck coefficient of prepared oxide heterostructures. Performed measurements of electrical properties revealed that the resistance of as-deposited thin-film structures was increasing with an increase in the TiO2 thin film thickness in the range from 16 MΩ to 25 MΩ. Simultaneously an abnormal decrease in the value of the Seebeck coefficient has been observed.

Low cost and efficient hetero-anthracene based small organic hole transporting materials for solid state photoelectrochemical cells

A series of low cost phenothiazine (PTZ) based small organic hole transporting materials (OHTMs) with high conductivity, hole mobility and low crystallinity were synthesized and systematically investigated for solid state photoelectrochemical cells/dye sensitized solar cells (DSSCs). Thermal, optical, photoelectrical and electrochemical properties of all OHTMs were evaluated using thermal techniques, cyclic voltammetry (CV), UV–vis absorption and other techniques. Density functional theory (DFT) was used to calculate optical and electrochemical properties of OHTMs and compared with experimental data. Role of these OHTMs in solid state photoelectrochemical cells with metal-free carbazole dye, SK3 in presence of additives like lithium bis(trifluoromethyl sulfonyl)imide salt (LiTFSI) and tert-butyl pyridine (TBP) are discussed along with the thickness of photoanode. In order to take an insight into photovoltaic performance, electron transfer kinetics and electron recombination in the OHTMs with different thickness of TiO2 thin film based ss-DSSCs were characterized by I–V, electrochemical impedance spectroscopy (EIS) and open circuit voltage decay (OCVD). The hole mobility, conductivity and photovoltaic performance of OHTMs are comparable with commercially available Spiro-OMeTAD. The highest power conversion efficiency (PCE), 4.91% is achieved from thiophene substituted (at 3,6 positions) phenothiazine based SJH-11, is comparable with reference device incorporating Spiro-OMeTAD as HTM with SK3 sensitizer. All the ss-DSSCs with OHTMs exhibit good long-term stability under 1 sun illumination and ambient humidity conditions. The results are promising and have scope for improvement upon optimization of substitution at 3 and 6 positions of PTZ central/core moiety.

Optimization of TiO2 thin film thickness for dye sensitized solar cell applications

Dye sensitized solar cells (DSSCs) rely on the absorption of photons by the dye molecules which are transported to the conduction band of the TiO2 electrode. The microstructure, energy gap and the absorption spectra of the TiO2 electrodes highly affects the efficiency of the cell. In this paper, the absorption spectra and energy gap has been studied by varying the thickness of the TiO2 paste. Nanocrystalline TiO2 thin films were deposited on ITO glass substrate with three different thickness (4.54μm, 7.12μm and 12.3μm) by using doctor blade method. After deposition all the samples were sintered at 450°C after deposition to enhance the particle bonding and for achieving better adhesion. The samples were characterized by UV-VIS spectra for determining the absorption spectra and Scanning Electron Microscopy (SEM) for investigating the thickness and the surface morphology. Fabricating the electrodes with different thickness showed significant changes in the energy gap and from the results it can be concluded that the energy gap increases with the increased thickness. The highest energy gap of 2.25ev and absorption 3.791 was achieved by 12.3μm thick sample. The absorption spectra also shows better absorption throughout the whole visible light range but the SEM images suggests that 12.3μm thick sample shows cracks all over the deposited region which will cause current leakage when the cell is assembled. Therefore, the optimum result was achieved by 7.12μm thick sample providing 1.9 ev energy gap and 3.91 absorption peak.

Inverted organic solar cells with solvothermal synthesized vanadium-doped TiO2 thin films as efficient electron transport layer

We investigated the effects of using different thicknesses of pure and vanadium-doped thin films of TiO2 as the electron transport layer in the inverted configuration of organic photovoltaic cells based on poly (3-hexylthiophene) P3HT: [6-6] phenyl-(6) butyric acid methyl ester (PCBM). 1% vanadium-doped TiO2 nanoparticles were synthesized via the solvothermal method. Crystalline structure, morphology, and optical properties of pure and vanadium-doped TiO2 thin films were studied by different techniques such as x-ray diffraction, scanning electron microscopy, transmittance electron microscopy, and UV–visible transmission spectrum. The doctor blade method which is compatible with roll-2-roll printing was used for deposition of pure and vanadium-doped TiO2 thin films with thicknesses of 30 nm and 60 nm. The final results revealed that the best thickness of TiO2 thin films for our fabricated cells was 30 nm. The cell with vanadium-doped TiO2 thin film showed slightly higher power conversion efficiency and great Jsc of 10.7 mA/cm2 compared with its pure counterpart. In the cells using 60 nm pure and vanadium-doped TiO2 layers, the cell using the doped layer showed much higher efficiency. It is remarkable that the external quantum efficiency of vanadium-doped TiO2 thin film was better in all wavelengths

Thickness effect on the optical properties of TiO2-anatase thin films prepared by ultrasonic spray pyrolysis: Experimental and ab initio study

TiO2 thin films with different thicknesses were deposited on glass substrates by using the Ion Layer Gas Reaction (Spray-ILGAR) technique at a substrate temperature of 460°. The effects of deposition time on the morphology and the optical properties of deposited anatase TiO2 thin films are studied. A wide range of characterization techniques such as X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Scanning electron microscopy (SEM), Atomic Force Microscopy (AFM) and Ultraviolet–Visible-Near Infrared spectrum were used to characterize prepared TiO2 thin films. The experimental results show that the morphology of deposited thin film changes from sheet like to pyramid like morphology and the optical band gap decreases with increasing the thickness of TiO2 thin films from 3.41 eV to 2.97 eV for thicknesses ranging respectively from 48 nm to 510 nm. XPS measurements revealed oxygen excess, which can be ascribed to the appearance of oxygen vacancy point defects and/or surface adsorption of different species with oxygen element. The ab initio calculations were conducted based on the full-potential linearized augmented plane wave (FP-LAPW) method, to calculate the indirect band gap of different TiO2 thin film thicknesses. The band gap energy calculated using the modified Becker Johnson (mBJ) potential was 3.19 eV for pure bulk TiO2 and 2.98 eV for bulk TiO2 with 8% oxygen vacancy, which is closer to the experimental band gap value of 2.97 eV measured for 510 nm film thickness.

Structural colors of fabric from Ag/TiO2 composite films prepared by magnetron sputtering deposition

PurposeStructural color is more brilliant in color, more resistant to sunshine and will not fade away with time, and more environmental friendly than traditional dyes and pigments. The purpose of this paper is to prepare structural colors of fabrics coated with Ag/TiO2 composite films by magnetron sputtering, and analyze the relationship between the colors and the thicknesses of TiO2 films in Ag/TiO2 composite films.Design/methodology/approachPreparation of Ag/TiO2 composite films by magnetron sputtering and their deposition on textiles were investigated. The chemical compositions and surface morphology of Ag/TiO2 composite films were examined by X-ray photoelectron spectroscopy and scanning electron microscopy, and the structural color of fabric coated with Ag/TiO2 composite film was also analyzed.FindingsAg/TiO2 composite films deposited on textile substrate exhibited structural colors, and the bright colors could be adjusted and controlled by the thickness of TiO2 thin films in Ag/TiO2 composite films without any dyes or pigments. By comparing the results of theoretical calculation and experimental results, it was found that the creation of structural colors by the experiment was coincident to the colors by theoretical calculation according to the film interference principle. There was a linear relationship between the thickness of TiO2 film and the wavelength of the structural color.Originality/valueCompared to traditional coloration by dyes or pigments, the coloration of textile by structural color from Ag/TiO2 composite films prepared by magnetron sputtering was very environmental friendly and simple without water consuming, time consuming and tedious work. Structural colors have great potential applications in textiles in place of traditional dyes and pigments. Furthermore, the textiles coated with Ag/TiO2 composite films have good electrical, optical and magnetic properties, and can be used in apparel, home furnishings and industrial fabrics.

The effect of TiO2 thin film thickness on self-cleaning glass properties

TiO2 is one of semiconductor materials which are widely used as photocatalyst in the form of a thin film. The TiO2 thin film is prepared by using the spin coating sol-gel method. The researcher prepared TiO2 thin film with 3 coating variations and X-Ray Diffraction characterization, UV-Vis Spectrophotometer, Electron Microscopy Scanning, and examined its hydrophilic and anti-fogging properties. The result of X-Ray Diffraction showed that the phase formed is the anatase on 101crystal field. The Electron Microscopy Scanning images showed that TiO2 thin films had a homogeneous surface with the particle sizes as big as 235 nm, 179 nm, and 137 nm. The thickness of each thin film was 2.06μm, 3.33μm, and 5.20μm. The characterization of UV-Vis Spectrophotometer showed that the greatest absorption to the wavelength of visible light was in the thin film’s thickness of 3 coatings with the band-gap determined by using 3.30 eV, 3.33 eV, and 3.33 eV Plot Tuoc. These results indicated that the rate of absorption would be increased by increasing the thickness of film. The increasing thickness of the thin film makes the film hydrophilic able to be used as an anti-fogging substance.

EFFECTS OF TiO2 FILM THICKNESS AND ELECTROLYTE CONCENTRATION ON PHOTOVOLTAIC PERFORMANCE OF DYE-SENSITIZED SOLAR CELL

Effects of film thickness and electrolyte concentration on the photovoltaic performance of TiO2-based dye-sensitized solar cell (DSSC) were studied. Nanocrystalline anatase TiO2 thin films with varying thicknesses (3.2–18.9[Formula: see text][Formula: see text]m) have been deposited on FTO/glass substrates by screen printing method as work electrodes for DSSC. The prepared samples were characterized by UV-Vis spectroscopy, Atomic Force Microscopy/Scanning Tunneling Microscopy (AFM/STM) and X-ray diffraction (XRD). The optimal thickness of the TiO2 photoanode is 13.5[Formula: see text][Formula: see text]m. Short-circuit photocurrent density ([Formula: see text]) increases with film thickness due to enlargement of surface area whereas open-circuit voltage decreases with increase in thickness due to increase in electron diffusion length to the electrode. However, the [Formula: see text] and [Formula: see text] of DSSC with a film thickness of 18.9[Formula: see text][Formula: see text]m (7.5[Formula: see text]mA/cm2 and 0.687[Formula: see text]V) are smaller than those of DSSC with a TiO2 film thickness of 13.5[Formula: see text][Formula: see text]m (9.9[Formula: see text]mA/cm2 and 0.734[Formula: see text]V). This is because the increased thickness of TiO2 thin film resulted in the decrease in the transmittance of TiO2 thin films hence reducing the incident light intensity on the N719 dye. Photovoltaic performance also depends greatly on the redox couple concentration in iodide[Formula: see text]triiodide. [Formula: see text] decreases as the redox concentration increases as a result of increased viscosity of the solution which lowers ion mobility. Similarly, [Formula: see text] decreases as the electrolyte concentration increases due to enhanced back electron transfer reaction. An optimum power conversion efficiency of 4.3% was obtained in a DSSC with the TiO2 film thickness of 13.5[Formula: see text][Formula: see text]m and redox concentration of 0.03[Formula: see text]mol dm[Formula: see text] under AM 1.5G illumination at 100[Formula: see text]mW/cm2.

Enhanced refractive index sensing characteristics of optical fibre long period grating coated with titanium dioxide thin films

A new type of fibre-optic refractive index sensor based on a long period fibre grating (LPFG) coated with a titanium dioxide (TiO2) thin film was demonstrated.The wavelength shift of the attenuation bands of this LPFG sensor to changes in the refractive index of the external media from 1.30 to 1.64RIU was investigated. In order to optimize the sensor the TiO2 thin film thickness deposited around the LPFGs was varied from 10 to 80nm.It was found that the TiO2 thin film increases the wavelength sensitivity of the LPFG to changes in the surrounding refractive index for values lower and higher than the cladding refractive index. As opposed to the bare LPFG it was shown the possibility to monitor refractive indices lower and higher than cladding refractive index tailoring the TiO2 thickness.An average wavelength sensitivity of 5250nm/RIU was achieved in the range 1.444 to 1.456RIU for a TiO2 thickness of 50nm. In the region between 1.46 and 1.48RIU the average sensitivity of about 825nm/RIU was measured for a 40nm thick film.

Application of monodisperse TiO2 nanoparticles with the size of 8–10 nm in dye-sensitized solar cells

In this paper, the commercial monodisperse TiO2 nanoparticles with the size of 8–10 nm were successfully applied to the photoelectrode for dye-sensitized solar cells (DSCs) and the influence of the thickness of the TiO2 thin films on the photovoltaic performance of the DSCs was investigated. The result revealed that the DSCs with the TiO2 thin film thickness of 3.6, 8.0, 11.6 and 20.0 μm gave the photoelectric conversion efficiency of 3.67%, 5.92%, 6.71% and 7.03%, respectively, under the illumination of simulated AM 1.5 sunlight (100 mW cm−2).

Love Wave Ultraviolet Photodetector Fabricated on a TiO2/ST-Cut Quartz Structure

A TiO2thin film deposited on a 90° rotated 42°45′ ST-cut quartz substrate was applied to fabricate a Love wave ultraviolet photodetector. TiO2thin films were grown by radio frequency magnetron sputtering. The crystalline structure and surface morphology of TiO2thin films were examined using X-ray diffraction, scanning electron microscope, and atomic force microscope. The effect of TiO2thin film thickness on the phase velocity, electromechanical coupling coefficient, temperature coefficient of frequency, and sensitivity of ultraviolet of devices was investigated. TiO2thin film increases the electromechanical coupling coefficient but decreases the temperature coefficient of frequency for Love wave propagation on the 90° rotated 42°45′ ST-cut quartz. For Love wave ultraviolet photodetector application, the maximum insertion loss shift and phase shift are 2.81 dB and 3.55 degree at the 1.35-μm-thick TiO2film.

Adsorption and electrochemical properties of photoelectrodes depending on TiO2 film thickness for dye-sensitized solar cells

Dye-sensitized solar cells (DSSCs) consist of a photoelectrode, electrolytes, and a counter electrode. In this work, we prepared the photo electrode using a commercial paste coated on F-doped SnO2 (FTO) glass substrates by the screen printing method; the thicknesses of the coated layers were 5, 9, and 14μm. We developed an adsorption apparatus to understand the adsorption mechanism of dye molecules depending on TiO2 thin film thickness and to obtain precise adsorption amounts without involving a desorption step. Commercial N719 dye was employed to measure the adsorption data, which were then analyzed using the pseudo-first-order and pseudo-second-order models. The diffusion coefficient of the electrolyte containing the iodide/triiodide redox couple was determined by polarization measurements. Electrochemical properties in terms of electron harvesting and electron transport depending on film thickness were evaluated based on incident photon to current conversion efficiency, intensity-modulated photocurrent spectroscopy, and intensity-modulated photovoltage spectroscopy.

Inverted polymer solar cells with TiO2 electron extraction layers prepared by magnetron sputtering

TiO2 thin films deposited by magnetron sputtering possess excellent optical transmittance, high refractive index, good adhesion and chemical stability. In this manuscript, TiO2 thin films deposited by magnetron sputtering was used for the first time as an electron extraction layer in inverted polymer solar cells (IPSCs), and the effect of the TiO2 thickness on the photovoltaic performance of P3HT:PC61BM IPSCs was investigated. The highest PCE value of 3.75% was obtained when the thickness of TiO2 thin films was in the range between 42 nm and 73 nm. The absorption properties, morphology and structure of the TiO2 films were characterized by UV-Vis spectroscopy, SEM and Raman spectroscopy, and were related to the device performance of P3HT:PC61BM IPSCs. The results indicate that TiO2 films deposited by magnetron sputtering are an excellent electron extraction layer for IPSCs.