Thickness Fraction Research Articles

Effect of final rolling temperature on microstructure and intergranular corrosion resistance of an Al–Cu–Mg–Ag alloy

Connection of microstructure with corrosion properties of an Al-3.62Cu-0.9Mg-0.45Ag alloy in natural aging (NA) state and peak aging (PA) state at different final rolling temperatures (20 °C, 180 °C and 280 °C) are studied by scanning electron microscopy (SEM), electron backscatter diffraction (EBSD), transmission electron microscopy (TEM), X-ray diffraction (XRD), texture and electrochemical analysis. The results show that the deformation texture and recrystallization texture of T280-NA alloy account for the largest percentage with the largest degree of recrystallization. With the increase of final rolling temperature, the proportion of low angle grain boundaries (LAGBs) of NA alloy increases, the diameter, thickness and volume fraction of Ω phase in PA alloy decrease, and the grain boundary precipitates (GBPs) are gradually transformed from discontinuous distribution to continuous distribution. The grain boundary precipitates are also found to be consist of alternating S and θ phases and the width of precipitation free zones (PFZs) is essentially independent of final rolling temperature. The intergranular corrosion (IGC) resistance of T280-NA alloy and T20-PA alloy is the best, which is a result of the combined effect of GBPs, texture and grain boundary properties. In addition, this result is verified in this paper by studying the electrochemical properties of the alloy.

Testing the effect of UHPFRC jacket thickness and steel fiber volume fraction on NSC‐UHPFRC column compressive behavior

AbstractSeveral efficient applications of ultrahigh‐performance fiber‐reinforced concrete (UHPFRC). Among them are UHPFRC jackets utilized for strengthening or permanent formworks of the steel reinforcing normal strength concrete (NSC) columns since UHPFRC jackets could enhance the compressive strength and other properties of the NSC column. However, the efficiency of a UHPFRC jacket simultaneously depends on its thickness and the added steel fiber volume fraction. The paper aims to explore the interaction effect of UHPFRC jacket thickness and steel fiber volume fraction on the behavior of UHPFRC jackets confining the NSC core under compressive load. The circular ultrahigh performance concrete jacket filled inside with the normal strength concrete, named NSC‐UHPFRC column specimen, is tested under loading on the NSC core. UHPFRC jacket thickness of 18‐49 mm with three adding steel fiber volume fractions was conducted for the experimental study. The investigation and analysis of the effect of the UHPFRC jacket and the steel fiber volume fraction on compression behaviors of NSC‐UHPFRC columns proceeded after the compressive strength test results were validated using Richart's model. This comprised a review of various parameters such as specimen failure pattern, stress–strain relationship, and ductile indices. The Weibull distribution was employed to explain the interaction effect on the variation in the experimental results. Finally, an interaction model was proposed and used to discuss the interaction effect of UHPFRC jacket thickness and steel fiber volume fraction and the optimum condition of the compressive strength of the NSC‐UHPFRC columns.

Parasternal Intercostal Muscle Thickness Fraction (PICTF%): Ultrasound a New Tool for Weaning Prediction?

How to cite this article: Bhattacharya D, Esquinas AM, Mandal M. Parasternal Intercostal Muscle Thickness Fraction (PICTF%): Ultrasound a New Tool for Weaning Prediction? Indian J Crit Care Med 2024;28(4):404.

Lung and diaphragm ultrasound as predictors of successful weaning from nasal continuous positive airway pressure in preterm infants.

Assessment of the utility of lung and diaphragm ultrasound in the prediction of successful weaning from nasal continuous positive airway pressure (NCPAP) in preterm infants. This prospective cohort study was conducted on preterm infants who were considered ready for weaning off NCPAP. Lung and diaphragm ultrasound were performed just before and 3 h after weaning off NCPAP. The primary outcome was to evaluate the accuracy of lung ultrasound (LUS) in predicting successful weaning from NCPAP. Out of 65 enrolled preterm infants, 30 (46.2%) were successfully weaned from NCPAP to room air. The successful weaning group had higher gestational ages, lower incidences of previous invasive mechanical ventilation, and treated hemodynamically significant patent ductus arteriosus before the trial weaning. A LUS score of ≤6, measured before discontinuation of NCPAP, exhibited a predictive sensitivity of 80% and specificity of 75% for successful weaning (Area under the curve (AUC) = 0.865, ≤.001). When the LUS score was assessed 3 h after weaning from NCPAP, a cutoff point of ≤7 predicted successful weaning with a sensitivity and specificity of 90% and 60% respectively (AUC = 0.838, p ≤ .001). The diaphragmatic thickness fraction (DTF) was significantly lower in the successful weaning group. After adjustment for various factors, LUS score remained the only independent predictor of successful weaning. LUS score before weaning from NCPAP has a good sensitivity and specificity for predicting successful weaning from NCPAP in preterm infants. Diaphragmatic excursion and DTF were not good predictors.

Modeling of multi-fractional suspended particle pathways in a shallow water basin under influence of strong winds

In this study, we investigate the complex dynamics of multi-fractional suspended particle transport in a shallow water basin subjected to strong wind conditions. Our research focuses on understanding the interplay between wind-induced advection and particle settlement, and its implications for sediment redistribution.Through our analysis, we reveal the distinct behaviors of different sediment fractions. Clay particles, constituting the lowest fraction in sediment cores, remain suspended throughout the simulation due to their low settlement velocity, with relatively stable concentrations. Conversely, the dominant fraction, medium silt, is suspended during intense wind events but quickly settles to the bed due to its higher settling velocity. Wind stress exceeding 0.05 Pa triggers particulate matter erosion, leading to its presence in the water column.Additionally, we explore the 2D distribution of sediment characteristics, including thickness, dry density, and mud fraction, to identify areas prone to erosion and deposition. Our findings demonstrate that coastal areas of the Taganrog Bay experienced significant erosion following strong wind events, exhibiting the thinnest sediment thickness and the highest dry bulk density. Deposition areas, characterized by thicker sediment layers and lower dry density, were often found in proximity to erosion zones, indicating the influence of particle resuspension and settlement processes.Furthermore, we analyze the implications of our findings on the vulnerability of specific regions to erosion and deposition. The central part of the sea contains moderately thicker sediment layers with a moderately high mud fraction, representing a zone of fine sediment accumulation. These fine sediments, including fine silt and clay, remain suspended for longer durations and are redistributed over greater distances by currents.Overall, our study provides valuable understanding into the multi-fractional suspended particle pathways and their interaction with strong winds in shallow water basins. The results contribute to a better understanding of sediment dynamics, which has implications for coastal management, environmental monitoring, and the preservation of benthic ecosystems.

Sonographic assessment of hemi-diaphragmatic palsy post brachial plexus blocks

Background and Aim: Brachial plexus blocks (BPB) are indispensable in providing surgical anaesthesia and postoperative analgesia. Although Hemi-diaphragmatic palsy (HDP) after BPB is clinically insignificant in the majority, it can cause significant physiological impairment in patients with reduced pulmonary function. Sonographic assessment of diaphragmatic function using the ABCDE approach provides accurate and quantitative information on HDP. This can be performed bedside before and after administration of the nerve block to quantify HDP. This was a prospective observational study comparing ultrasound-guided diaphragmatic thickness in two approaches of ultrasound-guided BPB. Methodology: Eighty participants receiving eitherinterscalene/supraclavicular BPB were included in this observational study. Baseline vitals, NRS score for pain and ultrasound-guided diaphragm thickness at inspiration and expiration using the ABCDE approach were noted. After 20 minutes of BPB administration, the diaphragm thickness was remeasured. Results: Eighty participants completed the study, forty from either group. Average volume of the total local anaesthetic drug mixture used was noted to be 30ml. The diaphragmatic thickness ratio in the supraclavicular group was found to decrease by 2.34% as compared to 2.39% in the interscalene group. (p-value 0.256 baseline values,0.292 for post block values) The thickness fraction was found to decrease by 9.21% in Group A as compared to 9.04% in Group B (P value 0.248 baseline values and 0.292 post-block values). There was no statistically significant difference between the diaphragm thickness in both the group'spre- and post-block, irrespective of the approach used. Conclusion: The ABCDE approach to measure diaphragm thickness can be used as a simple bedside modality to quantify the amount of HDP occurring after ultrasound-guided BPB. It is easy to learn & a non-invasive modality which can be used to improve patient safety during BPB Bangladesh Journal of Medical Science Vol.23 (Special Issue) 2024 p.S101-S106

Modeling wax deposition in pipes: Developing a closure relationship for improving the prediction accuracy

Wax deposition remains one of the most challenging flow assurance issues faced by the oil and gas industry. The first cases of paraffin deposition problems in pipelines started to draw attention more than 50 years ago. However, no unequivocal model for its prediction has yet been proposed and accepted. The most used models for paraffin phenomenon prediction usually return over or under-predictions up to 100% in relative errors. Accurate prediction of this phenomenon will lead to proper flowline sizing, insulation requirements, pigging strategies, chemical treatments, etc. With the recent improvements in mechanistic understanding of wax deposition mechanisms based on in-situ microscopic visualization, it became clear that precipitated wax crystals occur within the boundary layer. Therefore, more than one mechanism governs the deposition process. These observations are the core for proposing a new estimation model that accounts for wax crystal precipitation. The model determines the concentration of precipitated crystals of wax through a material balance involving the soluble amount of wax in the system, the degree of supersaturation, and the precipitation rate constant (kp). Deposition data obtained from a laboratory-scale flow loop was used to validate the proposed model, resulting in great improvement in the relative errors between estimated and measured values for deposit thickness and wax fraction. Comparatively, the SD (Santos-Daraboina) Model resulted in predictions with relative errors as low as 12.8% against experimental data, while the FMT model, in some cases, resulted in overpredictions up to 299%.

Sex-Based Differences in the Sonographic Characterization of Diaphragm Thickness in Preterm Infants With Bronchopulmonary Dysplasia at Term Corrected Age: A Secondary Analysis of a Prospective Study.

To determine the sex-specific diaphragm thickness in infants with bronchopulmonary dysplasia (BPD) as well as in healthy term and near-term infants. We performed a secondary analysis of an observational study to compare the sonographic diaphragm thickness at end expiration (DTexp) in female and male infants. The study included infants with BPD and healthy near-term and term infants. To account for differences in anthropometric measurements, we calculated the DTexp as a ratio of body surface area (BSA). Statistical analysis was performed using R statistical software. Of the 111 infants included, 54 (48.6%) were female. There were no significant differences in mean (SD) birth gestation [26.2 (2.1) vs 26.3 (2.1) weeks] and mean study age [38.0 (2.0) vs 37.4 (1.1) weeks] of male vs female infants with BPD. The mean (SD) DTexp [1.5 (0.4) mm vs 1.2 (0.3) mm, P = .02] and DTexp/BSA [8.3 (2.3) mm/m2 vs 6.7 (1.6) mm/m2, P < .01] were significantly thicker in female than male infants with BPD. In contrast, there were no significant differences in DTexp between sexes [1.5 (0.4) mm vs 1.5 (0.3) mm, P = .89] within the healthy control group. Moreover, there were no differences in inspiratory diaphragm thickness, diaphragm thickness fraction, or excursion between males and females in the BPD or healthy groups. Male infants with BPD exhibit thinner diaphragm thickness compared with female infants. Its implication on higher rates of BPD in preterm males is unclear, but this finding highlights the need for further investigation.

Effects of non-uniformity in thickness and volume fraction of agglomerated CNTs on the dynamics of a spinning CNT-reinforced nanocomposite truncated conical shell

In the presented work, the free vibration analysis of a rotating truncated conical shell whose thickness varies in the meridional direction is examined. The material that the shell is made of is a polymeric matrix (epoxy) enriched with carbon nanotubes (CNTs) whose volume fraction varies in the meridional direction. CNTs agglomeration is considered and the density and elastic constants of such a two-phase nanocomposite are calculated sequentially based on the Eshelby–Mori–Tanaka approach alongside the rule of mixture. The conical shell is modeled using the first-order shear deformation theory (FSDT) including the relative acceleration, Coriolis acceleration, and centrifugal acceleration along with the initial hoop tension, and the governing equations are obtained utilizing Hamilton’s principle. The solution of governing equations is performed via the combination of an analytical solution in the circumferential direction and a numerical one in the meridional direction via the differential quadrature method (DQM). The impacts of several parameters on the forward and backward natural frequencies of such a rotating shell are studied such as chirality, mass fraction and dispersion pattern of the CNTs, thickness variation parameters, and boundary conditions. It is observed that higher natural frequencies and critical rotational speeds can be achieved for CNT-reinforced conical shells when the volume fraction of the CNTs and the thickness of the shell increase from its small radius to the large one.

A novel prediction method for nanoplatelets content dependent yield strength of graphene nanoplatelets reinforced metal matrix composites at different temperatures

Especially, the quantitative relationship between the thickness and volume fraction of graphene and the grain size of graphene nanoplatelets reinforced metal matrix composites was revealed, based on which the influence of grain refinement, load transfer and dislocation strengthening on the yield strength of composites and their evolution with temperature was quantitatively characterized. Furthermore, by introducing the weakening effect of graphene agglomeration on associated control mechanism of yield strength, a prediction model of temperature dependent yield strength of graphene nanoplatelets reinforced metal matrix composites was established. The proposed prediction approach is verified by comparing the predictions with the experimental data in other literature. Moreover, using the established model, the quantitative effects of length and thickness of nanoplatelets on the yield strength of composites and their evolution with temperature were carried out. This research also provides an effective method for investigating the optimal volume fraction and failure volume fraction of added graphene.

Impact of Kernel Thickness on Germination and Vigor of Seed Rice

Highlights The impact of kernel thickness grading on seed germination and vigor was explored in medium and low moisture content seeds using two hybrid rice cultivars (RTv7303 &amp;amp; RT7301). Rough rice samples were size fractionated into two thickness fractions (thick &amp;gt;2.03 mm and thin 1.91&amp;gt;&amp;gt;2.03 mm) and dried to 12.5% moisture content (MC) at temperatures of 40°C and 60°C and 25% relative humidity (RH). It was discovered that harvested rice seeds at a medium MC (19% to 21%) and a temperature of 60°C increased seed germination and vigor. Thick kernels outperformed thin kernels in terms of seed germination but were not statistically different when compared to unsorted kernels. ABSTRACT. Rough rice lots harvested on the field contain varying kernel thicknesses within the panicles. These variations influence the drying characteristics of seeds and, thus, the seed germination and vigor. In this study, two hybrid long-grain rice cultivars (RTv 7303 &amp;amp; RT 7301) with harvest moisture contents (HMC) ranging from 19% to 21% and 15% to 17% wet basis (w.b.) for medium and low MC seeds were used, respectively. These rough rice samples were size fractionated into two thickness fractions (thick &amp;gt;2.03 mm and thin 1.91&amp;gt;&amp;gt;2.03 mm), with non-fractionated samples labeled as unsorted or control samples. Kernels from each sub-lot were dried to 12.5% MC at 40°C and 60°C air temperatures and 25% constant relative humidity (RH). Immediately after drying, samples were selected for seed germination and vigor assessments. RTv 7303 had higher seed germination compared to RT 7301, indicating that the two cultivars were genetically different from each other. Thick kernels had significantly higher seed germination (SG) than thin kernels, but there was no significant difference compared to unsorted kernels. Additionally, the percentage points difference between the thick versus unsorted and thin kernels varies from ˜1-pp to 8-pp for low MC seeds and from 2.5-pp to 6-pp for medium MC seeds. The seed vigor index (SVI) difference between the two cultivars is around 3.0 m.% and 1.5 m.% for medium and low MC, respectively. Harvested rice seeds with a medium MC (19% to 21%) and dried at a temperature of 60°C resulted in greater seed germination and vigor. Ultimately, these findings highlight the role of thickness grading in seed assessments. Thus, it was concluded that if the thin kernels could be screened out from the harvested rice lots, seed germination and vigor would increase significantly. Keywords: Rice drying, Rice seed, Seed germination, Seed vigor, Thickness grading.

Correlation Between Diaphragmatic Excursion and Exercise Tolerance Improvement Following Pulmonary Rehabilitation in Patients with Chronic Obstructive Pulmonary Disease-Obstructive Sleep Apnea Overlap Syndrome.

We assess the predictive value of diaphragm excursion (DE) in enhancing exercise tolerance following pulmonary rehabilitation (PR) among patients with COPD-OSA overlap syndrome. This prospective cohort study enrolled 63 patients diagnosed with COPD-OSA overlap syndrome who actively participated in a PR program from January 2021 to May 2023. Among these, 58 patients successfully completed the 20-week PR program, with exercise tolerance assessed through the measurement of six-minute walk distance (6MWD), and DE evaluated by ultrasonography. The responder to PR in terms of exercise ability was defined as a patient who showed an increase of >30m in 6MWD. The cutoff value for predicting PR response based on DE was determined using receiver operating characteristic (ROC) curves. Following the PR program, significant improvements were observed in mMRC, 6MWD, DE during deep breathing, and diaphragm thickness fraction (DTF). Of the participants, 33 patients (57%) were classified as responders, while 25 patients (43%) were considered non-responders. Baseline values of FEV1% predicted, 6MWD, DE during deep breathing, DTF, and PaO2 exhibited a significant elevation in responders as compared to non-responders. The changes of 6MWD were positively associated with the baseline values of DTF and DE during deep breathing, FEV1% predicted and PaO2, while negatively correlated with baseline value of mMRC. The predictive performance in terms of the area under the ROC curve for determining responder's DTF was found to be 0.769, accompanied by a sensitivity of 85% and specificity of 68%, using a cutoff value at 17.26%. Moreover, it was observed that DE during deep breathing could predict the area under the ROC curve for responders to be 0.753, with a sensitivity of 91% and specificity of 56% at a cutoff value of 3.61cm. Diaphragm excursion serves as a valuable predictor for determining the enhancement of exercise tolerance following PR in patients with COPD-OSA overlap syndrome. ChiCTR1800020257, www.chictr.org.cn/index.aspx.

Modelling the damage evolution in unidirectional all-carbon hybrid laminates

Hybrid reinforcements for composites have been extensively studied and adopted to overcome the lack of ductility via pseudo-ductility. Thin-ply all-carbon interlayer hybrid laminates have attracted attention for their peculiar pseudo-ductile tensile response. At the same time, conventional thick plies have been barely considered. This work developed a finite element model to simulate the complex tensile damage scenario of unidirectional thin- and thick-ply all-carbon interlayer hybrid laminates. The damage modes intended in the numerical model were fragmentation in the low-elongation (LE) plies, and delamination of LE and high-elongation (HE) ply interfaces. Thin- and thick-ply hybrid laminates were modelled and compared to available experiments. The numerical model was also adopted to simulate different layups to predict the effect of LE thickness fraction on the pseudo-ductile tensile behaviour and the evolution of damage modes. As suggested in the literature, the results allowed us to depict the damage mode map of the considered hybrid laminates. The map distinguishes the all-carbon hybrid laminate configurations with pseudo-ductile and brittle tensile responses.

Multi-objective optimization of hollow fiber membrane-based water cooler for enhanced cooling performance and energy efficiency

Water-mediated evaporative cooling systems often suffer from cross-contamination, droplet carryover, and high maintenance costs. This study proposes a novel liquid cooling solution, the hollow fiber membrane-based water cooler (HFMWC), to address these issues. The primary innovation of this study lies in the optimization of key design parameters of the countercurrent HFMWC, aligning them with stringent engineering requirements. Two standard working conditions for wet cooling towers are considered. Numerical modeling and response surface methodology are used to develop regression models correlating six key parameters (water velocity, air/water ratio, fiber length, fiber inner diameter, membrane thickness, and packing fraction) with two performance evaluation indexes (outlet water temperature and consumptive electric power ratio). A genetic algorithm-based multi-objective optimization is employed to obtain Pareto fronts, representing optimal trade-offs between the two indexes. Using the ideal point method, relative optimal solutions are identified, resulting in water temperature drops of 7.56 °C and 13.07 °C, with consumptive electric power ratios of 0.0128 kW h/m3 and 0.0138 kW h/m3 for conditions Ⅰ and Ⅱ, respectively. Most solutions achieve the highest energy efficiency rating while satisfying the design temperature difference. The average deviations between optimized and simulated data for the two indexes are 0.88 % and 3.88 %, demonstrating the reliability of the derived optimal solutions for engineering design. These findings not only offer a promising way to overcome the limitations of traditional evaporative cooling systems, but also contribute to the broader field of sustainable and efficient thermal management technologies.

Adaptational Response of Individual Trabeculae Morphology to Loading at Different Directions

Trabecular bone undergoes changes in its morphology when subjected to external loading. This paper analyses changes in morphological parameters of individual trabeculae (trabecular thickness and bone volume fraction) in response to loadings at different directions: 0°, 20°, 45°, 70° and 90°. It was found that increase in the load incline caused increase in trabecular thickness and bone volume fraction. In addition, the equilibrium-state trabeculae obtained from adaptation to load at 90° (shear loading) had the highest axial and lateral stiffnesses, as compared to trabecular geometries obtained from other loading scenarios.

Experimental and numerical investigation of adhesively bonded kfrp/steel double strap joints incorporating eggshell powder-toughened epoxy adhesive

Due to the environmental concerns, the application of natural FRPs to replace synthetic fibre as a strengthening material has increased. Kenaf fibre-reinforced polymer (KFRP) has comparable specific strength with glass fibre-reinforced polymer (GFRP). Moreover, epoxy resin is widely used as a matrix of composites and adhesives; however, it has low shear strength. Improvement of epoxy properties is therefore required, for example, by incorporating biofiller such as eggshells from household waste, which contain calcite, to improve its shear strength. Testing series includes variations of KFRP bond length, KFRP thickness and eggshell filler volume fractions. All the DSJ specimens underwent a two-stage testing process, experimentally and numerically. In Stage 1, experimental work was performed on the specimens through quasi-static tensile tests, following the ASTM D3528–96. In Stage 2, numerical studies were conducted to predict the strength using the extended finite element method (XFEM) within ABAQUS CAE. Subsequently, the strength prediction from developed 2-D FEA models was validated by the experimental datasets. All testing specimens exhibited KFRP rupture mode. For all the studied overlap lengths, the joint strength increased with the increase of the studied composite's adherend thickness (1 - 4 mm); however, the overlap length reached the optimum at the overlap length of 80 mm, where beyond that overlap length, the joint strength tended to decrease. The maximum joint strength is achieved with a combination of 80 mm bond length and 4 mm KFRP thickness, resulting in a 226.5% enhancement compared to the baseline (composite thickness of 1 mm, with adhesive without filler). Moreover, it was found that volume fraction of 5% eggshell was the optimum. The strength prediction was performed using an extended finite element method (XFEM), In general, there were good agreements in both experimental datasets and XFEM models, with discrepancies of less than 16.1% (averaging less than 8%). The FEA modelling approaches are promising for predicting the joint strength of KFRP/steel DSJ.

High‐velocity ballistic response of AA 1100‐H14 based carbon‐fiber metal laminates: An experimental investigation

AbstractA detailed experimental investigation was carried out for the high‐velocity ballistic response of AA 1100‐H14 based carbon‐fiber metal laminates (FMLs). FMLs with different metal volume fractions and the same thickness of carbon‐epoxy fiber laminates were tested to examine the surface and internal damage. The ballistic performance parameters, namely % escalation in absorbed energy, specific energy absorbed, ballistic limit, specific perforation energy, first cracking energy, and global deformation profile, were studied and a comparison was drawn with pure carbons fiber reinforced epoxy composite laminates. Despite having greater thickness, pure carbon fiber‐reinforced epoxy composite laminates absorbed less impact energy than FMLs and failed catastrophically. For FMLs, the % escalation in the absorbed energy and the specific energy absorption kept increasing with the increasing impact velocity until the onset of perforation. Once the perforation started, both these parameters showed a decreasing trend. Thick FMLs absorbed a good amount of energy, leading to projectile recoil suffering minimal damage. The ballistic velocity, specific perforation energy, and first cracking energy on the front and rear face of FMLs layers showed an increasing trend. The minimum for the thinner and maximum for the thicker FMLs attributed to the large thickness and more metal volume fraction. Contrary to the large deformation of the impacting points, pure carbon fiber‐reinforced epoxy composite laminates showed very minimal deformation as compared to FMLs. The brittle nature of the epoxy resin resisted the deformation to a large extent leading to less energy absorption.Highlights High‐velocity ballistic response of AA 1100‐H14 based carbon‐FMLs was investigated. Ballistic performance parameters of FMLs were studied and was compared with carbons fiber reinforced composite laminates. The ballistic limit of FMLs showed a direct dependence its thickness and metal volume fraction. In the absence of any metallic layer, pure carbons fiber reinforced composite laminates absorbed less impact energy.

Controlling adhesion and thermal stability of tetrahedral amorphous carbon coatings with intermediate sp3C fraction

Tetrahedral amorphous carbon (ta-C) coatings with an intermediate sp3C fraction were deposited on single-crystal silicon wafer substrates via intermittent filtered cathode vacuum arc (FCVA) deposition. The ta-C layer thickness and sp3C fraction in the coatings were adjusted using the deposition duration and bias voltage applied to the substrate, respectively. Some of the coated specimens were annealed at 300 and 600 °C for 4 h in a 5-Pa vacuum. The morphologies and microstructures of the specimens were characterized using scanning electron microscopy and transmission electron microscopy. The hybridization of carbon atoms was analyzed using X-ray photoelectron spectroscopy and micro-Raman spectroscopy. The mechanical characteristics of the coatings, including the critical adhesion load between the coatings and substrates, residual stress in the coatings, and hardness, were characterized. For the specimens deposited by the same bias voltage, even their top ta-C layer thickness ranged from approximately 500 nm to 1500 nm, their residual compressive stress in the coatings was maintained at a low value by the intermittent deposition of FCVA, which varied slightly with the coating thickness. The adhesion strength was improved by increasing the thickness of the as-deposited coating from approximately 12 to 40 N. The residual compressive stress of the post-annealing specimens with sp3C fraction of 45–53.8 % exhibited monotonously increasing or V-shaped variation with increasing annealing temperature. Herein, the underlying mechanisms are discussed in detail.

Prognostic Value of Diaphragmatic Ultrasound in Patients Admitted for COVID-19 Pneumonia

IntroductionCOVID-19 pneumonia results in an impairment of the diaphragmatic musculature that influences the development of respiratory failure during the patient's hospitalization. Diaphragmatic ultrasound is a useful, non-invasive, and accessible tool for measuring the function of this muscle. ObjectiveAssessing the morphological and functional ultrasound status of the diaphragm in patients admitted within the first 24h for COVID-related pneumonia and its association with hospital morbidity and mortality (NCT05805579). Material and methodsObservational, prospective cohort study that included 68 patients admitted for COVID-19 pneumonia with respiratory failure. Diaphragmatic ultrasound was performed within the first 24h of admission to the pulmonology ward. Clinical, analytical, and ultrasound variables were collected: excursion, thickness, and diaphragmatic shortening fraction (DSF). DSF<20% was used to define diaphragmatic dysfunction (DD). Patients who showed favorable progression and were managed on the ward (HCONV) were compared to those who required admission to the respiratory monitoring unit (RMU). ResultsA total of 68 patients were included, of which 22 (32.35%) were admitted to the RMU. Diaphragmatic excursion at maximum volume was higher in the HCONV group compared to the RMU group (58.41±17.83 vs. 50.03±16.23; p=0.123). Diaphragmatic dysfunction (DD) was observed in 21 (30.88%) patients, with a higher prevalence in the RMU group than in the HCONV group (15 (68.18%) vs. 6 (13.04%); p=0.0001). In the multivariate analysis, age and DSF at admission were the best predictors of failure to discharge. ConclusionsPerforming diaphragmatic ultrasound to assess mobility and DSF within the first 24h of admission for COVID-19 pneumonia proves valuable in determining short-term progression and the need for admission to a respiratory monitoring unit.

The evolution of deep convective systems and their associated cirrus outflows

Abstract. Tropical deep convective clouds, particularly their large cirrus outflows, play an important role in modulating the energy balance of the Earth's atmosphere. Whilst the cores of these deep convective clouds have a significant short-wave (SW) cooling effect, they dissipate quickly. Conversely, the thin cirrus that flow from these cores can persist for days after the core has dissipated, reaching hundreds of kilometres in extent. These thin cirrus have a potential for large warming in the tropics. Understanding the evolution of air parcels from deep convection, clouds along these trajectories, and how they change in response to anthropogenic emissions is therefore important to understand past and future climate change. This work uses a novel approach to investigate the evolution of tropical convective clouds by introducing the concept of “time since convection” (TSC). This is used to build a composite picture of the lifecycle of air parcels from deep convection. Cloud properties are a strong function of TSC, showing decreases in the optical thickness, cloud-top height, and cloud fraction over time, thereby driving the latitudinal structure of cloudiness. After an initial dissipation of the convective core, changes in thin cirrus cloud amount were seen beyond 200 h from convection. Changes in cloud are shown to be a strong function of TSC and not simply reflective of latitudinal changes as air moves from the tropics to the extratropics. Finally, in the initial stages of convection there was a large net negative cloud radiative effect (CRE). However, once the convective core had dissipated, the sign of the CRE flipped and there was a sustained net warming CRE beyond 120 h from the convective event. Changes are present in the cloud properties long after the main convective activities have dissipated, signalling the need to continue further analysis at longer timescales than previously studied.