Thermometry Technique Research Articles

Luminescence Thermometry with Eu3+-Doped Y2Mo3O12: Comparison of Performance of Intensity Ratio and Machine Learning Temperature Read-Outs.

Accurate temperature measurement is critical across various scientific and industrial applications, necessitating advancements in thermometry techniques. This study explores luminescence thermometry, specifically utilizing machine learning methodologies to enhance temperature sensitivity and accuracy. We investigate the performance of principal component analysis (PCA) on the Eu3+-doped Y2Mo3O12 luminescent probe, contrasting it with the traditional luminescence intensity ratio (LIR) method. By employing PCA to analyze the full emission spectra collected at varying temperatures, we achieve an average accuracy (ΔT) of 0.9 K and a resolution (δT) of 1.0 K, significantly outperforming the LIR method, which yielded an average accuracy of 2.3 K and a resolution of 2.9 K. Our findings demonstrate that while the LIR method offers a maximum sensitivity (Sr) of 5‱ K⁻1 at 472 K, PCA's systematic approach enhances the reliability of temperature measurements, marking a crucial advancement in luminescence thermometry. This innovative approach not only enriches the dataset analysis but also sets a new standard for temperature measurement precision.

Implementation of a high-frequency phosphor thermometry technique to study the heat transfer of a single droplet impingement

Contributing to a better understanding of spray cooling systems, the heat transfer process underlying the event of a droplet impinging onto a uniformly heated stainless steel surface (SS304) was experimentally investigated. Since the heat transfer process is linked to the droplet’s hydrodynamics, high-speed videos were recorded to measure the deformation of the droplet. A series of isothermal and non-isothermal impacts were performed for Weber numbers (We) within the range 17.7≤We≤58.2. A strong relationship between the maximum spreading ratio reached by the droplet and its initial kinetic energy was found. The surface temperature directly affects the droplet hydrodynamic during the impact by promoting an oscillatory behavior of the droplet after the maximum spreading is reached. Given the spatial–temporal resolution of the heat transfer process, a high-frequency phosphor thermometry technique was implemented, finding that the temperature drop upon droplet impact was independent of impact velocity. The sharp temperature drop results in an intense thermal interaction that occurred during the first 10 ms of the impact. The maximum average heat flux registered was 98.56 W/cm2 with a cooling effectiveness of 3.5%.

Temperature measurement in laser–metal processing using optical sensing: Radiometric calibration and validation of a multispectral camera

In laser–metal processing such as Laser-based Powder Bed Fusion of Metals (PBF-LB/M), the quality of the final product is significantly influenced by the thermal behaviour of the melt pool. Accurate temperature measurements are challenging due to high temperature gradients and rapid cooling. This study introduces Multispectral Imaging (MSI) as a highly effective thermometry technique to address these demanding conditions. MSI captures multiple bands of radiation, enabling the simultaneous determination of absolute temperature and surface emissivity. This capability is crucial for ensuring high-quality outcomes in laser–metal processing such as PBF-LB/M, contingent upon robust radiometric calibration.To enhance reliability, two radiometric calibration models were developed: an empirical model based on linear sensor data correlations and an analytical model leveraging sensor behaviour. An efficient calibration was found for both models across a range of signal-to-noise ratios in the black body calibrator, where the analytical model even performs robust under a high noise level.Additionally, the temperature accuracy in the solid-state case was tested with a thermo-mechanical simulator. Results showed that the empirical and analytical models achieved mean relative errors of 2.0% and 1.6%, respectively, outperforming the state-of-the-art. Further, laser irradiation experiments highlighted the analytical model’s ability to accurately determine the emissivity decrease during the solid-to-liquid transition, allowing for accurate melt pool temperature estimations. Conversely, the empirical model struggled to estimate temperature effectively in the liquid phase.This study not only proposed a robust methodology of MSI in temperature measurement but also confirmed the accuracy and reliability of the system, broadening the scope for further investigation into the intricate thermal dynamics involved in laser–metal interactions.

An analytical heat transfer model for transient Raman thermometry analysis.

Transient Raman thermometry improves on its steady-state counterpart by eliminating the error-prone steps of temperature calibration and laser absorption measurement. However, the accompanying complex heat transfer process often requires numerical analysis, such as the finite element method, to decipher the measured data. This step can be time-consuming, inconvenient, and difficult to derive a physical understanding of the heat transfer process involved. In this work, the finite element method is replaced by fitting the measured data to an analytical three-dimensional heat transfer model. This process can be completed in a few seconds. Using this approach, the in-plane thermal conductivity of two bulk layered materials and the interfacial thermal conductance between two-dimensional materials and quartz have been successfully measured. Based on our model, we performed an analytical quantitative sensitivity analysis for transient Raman thermometry to discover new physical insights. The sensitivity of the in-plane thermal conductivity of bulk layered materials is dictated by the ratio between the spot radius and heat spreading distance. The sensitivity of the interfacial thermal conductance between two-dimensional materials and quartz is determined by its conductance value. In addition, the uncertainty of the measured value contributed by the uncertainty of the input parameters can be efficiently estimated using our model. Our model provides an efficient data and sensitivity analysis method for the transient Raman thermometry technique to enable high throughput measurements, facilitate designing experiments, and derive physical interpretations of the heat transfer process.

A composite laser ablation diagnosis method based on multiple spectroscopic and imaging analyses

This study proposes a novel diagnostic approach for target ablation to comprehensively elucidate the physical mechanisms of laser ablation in aluminium alloys and stainless steel, precisely measure sample temperatures, and predict the ablation state. The method utilizes a spatially weighted emissivity model in conjunction with multispectral thermometry techniques to analyze spatial variations in temperature and emissivity distributions, facilitating the evaluation of target ablation status. Through a series of experiments, temperature data obtained using an enhanced weighted radiative spectral inversion technique were compared with temperatures recorded by thermal imaging cameras, confirming the effectiveness and accuracy of the weighted radiative spectral inversion method in multispectral thermometry. Additionally, a detailed examination of laser ablation in aluminium alloys and stainless steel was conducted to elucidate the underlying damage mechanisms. This refined approach establishes a solid groundwork for further investigation into the characteristics and dynamic Evolution of laser-damaged regions.

Effects of typical MH2 (M= Ti, Mg, Zr) on the detonation energy release characteristics of composite charge containing Al/PTFE reactive materials and RDX

To explore the effects of three typical metal hydride powders (TiH2, MgH2, ZrH2) on the detonation energy release characteristics of composite charge containing Al/PTFE reactive materials and RDX, a variety of composite charges containing Al/PTFE/MH2 ternary active materials and RDX were prepared. The effects of metal hydrides on detonation parameters of composite charges were studied by air blast experiments and the temperature distributions of explosion fireball were mapped using colorimetric thermometry technique. The experimental results indicated that the addition of metal hydrides had significantly positive effects on afterburning effect and detonation performance of composite charges, and the enhancement effect of MgH2 was superior to that of TiH2 and ZrH2. The fireball duration, maximum average temperature and shock wave parameters of the composite charges in air blast experiments all changed with the order of Al/PTFE/MgH2+RDX > Al/PTFE/TiH2+RDX > Al/PTFE/ZrH2+RDX > Al/PTFE + RDX. The results could offer theoretical references for the formulation design of high-power explosives.

Nanoscale thermal imaging of hot electrons by cryogenic terahertz scanning noise microscopy.

Nanoscale thermal imaging and temperature detection are of fundamental importance in diverse scientific and technological realms. Most nanoscale thermometry techniques focus on probing the temperature of lattice or phonons and are insensitive to nonequilibrium electrons, commonly referred to as "hot electrons." While terahertz scanning noise microscopy (SNoiM) has been demonstrated to be powerful in the thermal imaging of hot electrons, prior studies have been limited to room temperature. In this work, we report the development of a cryogenic SNoiM (Cryo-SNoiM) tailored for quantitative hot electron temperature detection at low temperatures. The microscope features a special two-chamber design where the sensitive terahertz detector, housed in a vacuum chamber, is efficiently cooled to ∼5K using a pulse tube cryocooler. In a separate chamber, the atomic force microscope and the sample can be maintained at room temperature under ambient/vacuum conditions or cooled to ∼110K via liquid nitrogen. This unique dual-chamber cooling system design enhances the efficacy of SNoiM measurements at low temperatures. It not only facilitates the pre-selection of tips at room temperature before cooling but also enables the quantitative derivation of local electron temperature without reliance on any adjustable parameters. The performance of Cryo-SNoiM is demonstrated through imaging the distribution of hot electrons in a cold, self-heated narrow metal wire. This instrumental innovation holds great promise for applications in imaging low-temperature hot electron dynamics and nonequilibrium transport phenomena across various material systems.

Effects of vacuum degree on the detonation characteristics and energy release laws of RDX explosive

To explore the detonation characteristics and energy release laws of RDX explosives under varying degrees of vacuum, the influence of vacuum degree on the fireball characteristic parameters, shock wave propagation laws and detonation performance of columnar RDX charges were studied using the air-blast experiments and AUTODYN simulations, and the fireball temperature distributions were mapped with the colorimetric thermometry technique. The experimental results indicated that as the degree of vacuum increased, the combustion duration and zone area size of the explosive fireball were both extended, while its temperature decay rate was slowed down, making the afterburning effect more pronounced. Furthermore, the peak overpressure and positive impulse of the explosion shock wave showed a downward trend, with the reductions of 56.1 % and 53.5 %, respectively, with the increasing vacuum degree. Numerical simulation was also used to reveal the energy release laws of RDX explosive, and the comparison between the experimental and numerical results showed a good degree of concordance with an average error of 6.45 %. The results of the study could provide a reference for expanding the explosion theory of explosives in plateau environment and improving the performance of explosion-proof equipment.

Monitoring of the heating rate of a motorized gear system using UV-curable resin containing Y2WO6:Yb3+-Er3+ up-converting nanoparticles as optical temperature sensor

The ability to create various three-dimensional objects and precisely deposited layers has enabled manufacturers using UV-curable resins to produce customized and complex composite parts with greater efficiency and precision. There are many products used in this photo-induced solidification process, and one of them is a mixture of organic compounds forming a resin, which is cured using ultraviolet light to achieve the desired final hardness. In addition, the combination of this resin with innovative materials has led to the creation of interesting elements with a wide variety of applications. For this reason, this work describes the implementation of lanthanide-based luminescent nanoparticles Y2WO6 doped with Yb3+ and Er3+ and admixed in a resin, for deposition on a metallic gear surface via painting and UV curing. The as-prepared luminescent gears start to generate heat due to the occurrence of mechanical friction when they start to work. Analyzing the ratio between the thermalized Er3+ emissions at 525 nm (2H11/2 → 4I15/2) and 550 nm (4S3/2 → 4I15/2) we could remotely detect small temperature variations that gears undergo through friction. This technique is especially useful in monitoring temperature in elements where measurements with thermographic cameras or with direct contact is inaccurate or is not possible. This work can open new horizons in monitoring of heat flow in various scientific and industrial processes, utilizing the benefits of non-invasive temperature detection via luminescence thermometry technique.

Optimizing optical thermometry with tri-doped Ba2GdV3O11 phosphors: Ratiometric and fluorescence lifetime analysis

Optical sensor technology has undergone a transformative evolution with the advent of fluorescence ratio techniques (FIR) and fluorescence lifetime (FL) strategies, revolutionizing precision, performance, and reliability. This study delves into the synthesis of Ba2GdV3O11 phosphors doped with Ho3+/Nd3+, Er3+, and Yb3+, employing the sol-gel method for upconverting material fabrication. A thorough investigation into the structural, morphological, and optical properties of the synthesized phosphors is conducted. Excitation at 980 nm unveils upconversion (UC) emissions across green and red spectra. The intensities of the observed emission bands for Ho3+, Nd3+, and Er3+ demonstrate significant sensitivity to fluctuations in temperature. Temperature sensing relies on the 4S3/2 and 2H11/2 upconversion emissions bands, in addition to the emission lifetimes at 4S3/2. Enhanced thermal sensitivity values are attained, reaching up to 1.03 % K−1 and 1.07 % K−1 using the FIR strategy, and up to 0.146 % K−1 and 0.47 % K−1 with the FL strategy for Ho3+/Er3+/Yb3+ and Nd3+/Er3+/Yb3+ tri-doped Ba2GdV3O11 phosphors, respectively. Furthermore, the studied phosphors exhibit remarkable precision in detecting minute temperature changes (0.3 K), positioning them as promising candidates for precise temperature sensing. This study pioneers innovative methodologies to advance optical thermometry techniques, offering promising prospects for scientific and industrial applications reliant on precise optical temperature sensing.

One-dimensional temperature measurement of gases based on femtosecond laser-extended electrode discharge spectroscopy (FEEDS)

Temperature, and hence thermometry techniques, are critical for characterizing gaseous flows and flames. Therefore, it is always attractive to develop new thermometry techniques to satisfy different demands. Here, we propose a thermometry technique for one-dimensional gas temperature measurements based on femtosecond laser-extended electrode discharge spectroscopy (FEEDS). By FEEDS measurements in gas flows containing hydrogen, we found that the temperature of the gas flow has a strong correlation with the full width at half maximum (FWHM) of the atomic hydrogen line at 656 nm, and this correlation is monotonic in the temperature range we measured, i.e., the temperature of gas flows can be extracted by measuring this FWHM. We applied this technique to methane/air gas mixtures and realized temperature measurements in the range of 300–1806 K with an error of ∼50 K. Also, we found that the technique has the capability to achieve one-dimensional measurements; more importantly, we found that changes in the stoichiometric ratio of the gas mixture do not affect the temperature measurements. Finally, we applied this technique to a premixed methane/air jet flame.

Dual-tracer laser-induced fluorescence thermometry for understanding bubble growth during nucleate boiling on oriented surfaces

Nucleate boiling is perhaps one of the most efficient cooling methodologies due to its large heat flux with a relatively low superheat. Nucleate boiling often occurs on surfaces oriented at different angles; therefore, understanding the behavior of bubble growth on various surface orientations is of importance. Despite significant advancement, numerous questions remain regarding the fundamentals of bubble growth mechanisms on oriented surfaces, a major source of enhanced heat dissipation. This work aims to accurately measure three-dimensional (3D), space- and time-resolved, local liquid temperature distributions surrounding a growing bubble on oriented surfaces that quantify the heat transfer from the superheated liquid layer during bubble growth. The dual tracer laser-induced fluorescence thermometry technique combined with high-speed imaging captures transient 2D temperature distributions within a 0.3 ºC accuracy at a 30 μm resolution. The results show that the temperature close to the heated surface and bubble interface exhibits an acute transient behavior at the time of bubble departure, and the growing bubble works as a pump to remove heat from the surface with a temperature difference of up to 10 °C during its growth and departure. The experimental results are compared with data available in the literature to validate the accuracy of the technique. It was found that the heat transfer coefficient close to the bubble interface and heater is approximately 1.3 times higher than the heat transfer coefficient in the bulk liquid.

Technical advances in motion-robust MR thermometry.

Proton resonance frequency shift (PRFS) MR thermometry is the most common method used in clinical thermal treatments because of its fast acquisition and high sensitivity to temperature. However, motion is the biggest obstacle in PRFS MR thermometry for monitoring thermal treatment in moving organs. This challenge arises because of the introduction of phase errors into the PRFS calculation through multiple methods, such as image misregistration, susceptibility changes in the magnetic field, and intraframe motion during MRI acquisition. Various approaches for motion correction have been developed for real-time, motion-robust, and volumetric MR thermometry. However, current technologies have inherent trade-offs among volume coverage, processing time, and temperature accuracy. These tradeoffs should be considered and chosen according to the thermal treatment application. In hyperthermia treatment, precise temperature measurements are of increased importance rather than the requirement for exceedingly high temporal resolution. In contrast, ablation procedures require robust temporal resolution to accurately capture a rapid temperature rise. This paper presents a comprehensive review of current cutting-edge MRI techniques for motion-robust MR thermometry, and recommends which techniques are better suited for each thermal treatment. We expect that this study will help discern the selection of motion-robust MR thermometry strategies and inspire the development of motion-robust volumetric MR thermometry for practical use in clinics.

Cryogenic to high temperature measurements in gas flows by femtosecond laser-induced CN luminescence

Temperature is a crucial parameter of gas flow fields. Here, we present a novel thermometry technique for gas flow based on femtosecond laser-induced cyano (CN) luminescence. Specifically, a femtosecond laser with a central wavelength of 267 nm is used to induce CN violet emissions in a nitrogen flow seeded with a trace amount of methane. The spectral peak of CN B2Σ+- X2Σ+ (0,0) transitions shift to longer wavelengths with increasing temperatures, and the concentration of methane does not influence this spectral shift. The calibration curve of the spectral peak position and the temperature ranging from 93 to 1028 K is obtained through the experiment, and the curve exhibits a nearly linear trend in the low-temperature regime, and an uncertainty of 3.6 % at 173 K is obtained. The technique's wide temperature measurement capability makes it suitable for gas flow temperature measurements, particularly in environments with significant temperature variations, such as wind tunnels.

Sensitive Luminescence Thermometry through Excitation Intensity Ratio in Eu-Doped BaTiO3.

Optical ratiometric thermometry techniques have gained much attention in recent years due to their reliable and noncontact temperature sensing capability for industrial and biorelated applications. Herein, we exploited the temperature dependence of the absorption band of BaTiO3 (BTO) for novel excitation intensity ratio (EIR) thermometry. Photoluminescence and excitation properties of Eu3+-doped BTO powders were studied as a function of Eu3+ doping concentration. The excitation peak intensities at 397 and 468 nm, corresponding to the 7F0 → 5L6 and 5D2 transitions of Eu3+, were used as EIR parameters. The temperature dependence of the EIR can be explained by the competitive absorption between Eu3+ and the BTO host. The EIR properties were studied in relation to the doping concentration, registering a maximum relative sensitivity (Sr) of 4.89% K-1 in BTO:Eu3+ (0.5%) at 303 K. An amphoteric Eu3+ occupation mode at both Ba2+ and Ti4+ sites was found to interpret the doping concentration dependence of the Sr. The reduced Ba2+ site occupation ratio proved to be responsible for the low Sr values at high Eu3+ doping concentrations. Accordingly, an Eu3+/Ti3+ codoping method was further proposed to improve the Sr by increasing the Ba2+ site occupation ratio. Our result showed that BTO:Eu3+ (0.5%) demonstrated an enhancement of Sr from 4.89 to 6.42% K-1 at 303 K after 2% Ti3+ codoping.

Novel GdAlGe2O7:Bi3+,Eu3+ phosphors with anti-thermal quenching properties for high sensitivity optical temperature measurement

The thermometry technique based on fluorescence intensity ratio has attracted much attention for its advantages of fast response, high accuracy, and non-contact. Here, we report a series of novel GdAlGe2O7:Bi3+,Eu3+ phosphors with anti-thermal quenching properties for high sensitivity optical temperature measurement. By constructing the energy transfer between Bi3+ and Eu3+ ions, the GdAlGe2O7:Bi3+,Eu3+ exhibits a rare anti-thermal quenching performance upon 285 nm excitation due to the redshift of the charge transfer band. Therefore, we designed ratiometric optical thermometers with high sensitivity based on the intense thermal quenching behavior of the Bi3+ ions and the anti-thermal quenching property of the Eu3+ ions with a relative sensitivity of 1.06% K−1 at 483 K and an absolute sensitivity of up to 0.0447 K−1 at 573 K. Our results not only reveal the optical behaviors of the Bi3+ and Eu3+ ions in GdAlGe2O7:Bi3+,Eu3+, but also propose that the synthesized phosphors have significant potential applications in the field of optical temperature measurement.

Ultrasound-switchable fluorescence thermometry with dual detection channels using temperature-sensitive liposomes.

Temperature measurements in biological tissues play a crucial role in studying metabolic activities. In this study, we introduce a noninvasive thermometry technique based on two-color ultrasound-switchable fluorescence (USF). This innovative method allows for a local temperature mapping within a microtube filled with temperature-sensitive liposomes as nano imaging agents. By measuring the temperature-dependent fluorescence emission of the liposomes using a spectrometer, we identify four characteristic temperatures. The local background temperature can be estimated by analyzing the corresponding appearance time of these four characteristic temperatures in the dynamic USF signals captured by a camera-based USF system with two detection channels. Simultaneous measurements with an infrared (IR) camera showed a 0.38°C ± 0.27°C difference between USF thermometry and IR thermography in a physiological temperature range of 36.48°C-40.14°C. This shows that the two-color USF thermometry technique is a reliable, noninvasive tool with excellent spatial and thermal resolution.

A novel laser-induced fluorescence concept for thermometry measurements in machining lubricoolants

This study investigates a two-colour laser-induced fluorescence (LIF) technique for thermometry in cooling lubricants (CL) for machining. The diagnostic technique should enable a simultaneous determination of cooling film thickness and film temperature, which is relevant for typical machining processes like turning and milling processes. The temperature determination is based on a temperature-sensitive fluorescence intensity ratio of a special dye determined in suitable spectral regions representing common band pass filters. For this purpose, two CL emulsions CL6 (6 vol.% CL, 94 vol.% water; normal machining) and CL10 (10 vol.% CL, 90 vol.% water; heavy machining) and its individual components were doped with the fluorescence dye Eosin-Y. Temperature dependent spectral LIF intensities were recorded in the range of 273–313 K, which are relevant for milling and cutting operations. Furthermore, absorption spectra were analysed as well. The temperature-dependent fluorescence measurements revealed a temperature limit for the emulsion stability. The emission peaks of Eosin-Y are shifted with increasing temperature towards longer wavelengths. The sensitivities of CL10 (1.88%/K) and CL6 (1.58%/K) are comparable to or even higher than the sensitivities of other LIF dyes provided in the literature. The literature-based dyes were however not determined in those CL. The measurements showed, that the investigated tracer-CL/water emulsions mixed with the dye enable a reliable temperature determination.

Heat transfer near a growing bubble during nucleate boiling using dual-tracer laser-induced fluorescence thermometry

Boiling heat transfer associated with bubble growth is perhaps one of the most efficient cooling methodologies due to its large latent heat during phase change. Despite the significant advancements, numerous questions remain regarding the fundamentals of bubble growth mechanisms, which is a major source of enhanced heat dissipation. This work aims to accurately measure three-dimensional (3D), space and time-resolved, local liquid temperature distributions surrounding a growing bubble to quantify the heat transfer in the superheated liquid layer during bubble growth. The dual tracer laser-induced fluorescence thermometry technique combined with high-speed imaging captures transient 2D temperature distributions, that will render 3D temperature distributions by combining multiple 2D layers, within a 0.3 °C accuracy at a 30 μm resolution. Two fluorescent dyes, fluorescein and sulforhodamine B, were used to measure transient temperatures, by account of their temperature-sensitive emissions. The results show that the temperature close to the heated surface and bubble interface exhibits an acute transient behavior at the time of bubble departure. The growing bubble works as a pump to remove heat from the surface with a peak temperature difference of up to 10 °C during its growth and departure. The experimental results were compared with previously reported studies to validate the accuracy of the technique. It was found that the heat transfer coefficient close to the bubble interface and heater is approximately 1.3 times higher than the heat transfer coefficient in the bulk liquid.

A new noninvasive technique for heat-flux-based deep body thermometry together with possible estimation of thermal resistance of the skin tissue.

A new noninvasive core-thermometry technique, based on the use of two heat flux sensors with different very low thermal resistances, is proposed. Thermodynamically derived equations, using a pair of skin temperatures and heat fluxes detected from the sensors, can give the estimated deep body temperature (DBT) together with thermal resistance of the skin tissue itself. The validity and accuracy of this method are firstly investigated through in vitro experiments using a tissue phantom model and, secondly, as in vivo comparisons with sublingual (Tsub) or rectal temperature (Trec) measurements in 9 volunteers, attaching the sensors around the upper sternum or the nape. Model experiments showed a good agreement between the measured and estimated temperatures, ranging from approximately 36 to 42 ℃. In vivo experiments demonstrated linear correlations between the estimated DBT and both Tsub and Trec values, though the estimated DBT was 0.13 ℃ higher than Tsub and 0.42 ℃ lower than Trec on average. The results also strongly suggested the possibility to estimate the tissue thermal resistance; this is discussed herein. Although further in vivo experiments under various environmental conditions are necessary, this method appears highly promising as an accurate, useful and convenient core-thermometry system for medical and healthcare settings.