Thermodynamics Of Mass Transfer Research Articles

Mass Transfer Thermodynamics through a Gas-Liquid Interface.

Molecular level information about thermodynamic variations (enthalpy, entropy, and free energy) of a gas molecule as it crosses a gas-liquid interface is strongly lacking from an experimental perspective under equilibrium conditions. Herein, we perform in situ measurements of water interacting with the ionic liquid (IL) 1-butyl-3-methylimidazolium acetate, [C4mim][Ace], using ambient pressure X-ray photoelectron spectroscopy in order to assess the interfacial uptake of water quantitatively as a function of temperature, pressure, and water mole fraction ( xw). The surface spectroscopy results are compared to existing bulk water absorption experiments, showing that the amount of water in the interfacial region is consistently greater than that in the bulk. The enthalpy and entropy of water sorption vary significantly between the gas-liquid interface and the bulk as a function of xw, with a crossover that occurs near xw = 0.6 where the water-IL mixture converts from being homogeneous ( xw < 0.6) to nanostructured ( xw > 0.6). Free energy results reveal that water at the gas-IL interface is thermodynamically more favorable than that in the bulk, consistent with the enhanced water concentration in the interfacial region. The results herein show that the efficacy for an ionic liquid to absorb a gas phase molecule is not merely a function of bulk solvation parameters but also is significantly influenced by the thermodynamics occurring across the gas-IL interface during the mass transfer process.

Исследование термодинамики тепло- и массообмена среды в грунтах при термомеханическом способе бурения шурфов на магистральных газопроводах

Исследование термодинамики тепло- и массообмена среды в грунтах при термомеханическом способе бурения шурфов на магистральных газопроводах

Water and Salt Migration with Phase Change in Saline Soil during Freezing and Thawing Processes.

Water and salt transfer coupled with phase change may cause serious damage to engineering structures in saline soil regions. In this study, the migration of water and salt in silty clay collected from the Qinghai-Tibet Plateau is explored experimentally and numerically during freezing and thawing processes. The results revealed that there are significant differences in the variations of liquid water content and solution concentration for different initial salt contents, due to salt crystallization and dissolution. The temperature-induced water migration is determined by the soil properties, which can be well explained by the thermodynamics of mass transfer. The amount of salt migrated upward during cooling is slightly larger than that transported downward in the warming period, implying that salt may be accumulated in the surface soil after a large number of circulations and finally result in soil salinization.