Thermodynamic Performance Research Articles

Optimization study of a high-proportion of solar tower aided coal-fired power generation system integrated with thermal energy storage

Solar aided coal-fired power generation technologies have proven to be effective in reducing fossil fuel consumption and greenhouse gas emission. In this research, a high-proportion solar tower aided coal-fired power generation system integrated with thermal energy storage system is proposed. According to the constraint conditions, the integration scheme with the highest solar coupling capacity is obtained, and its thermodynamic, economic and environmental performances are researched. The results indicate that the solar coupling capacity that can be accommodated by the 660 MW coal-fired unit after parameter optimization is 339.532 MWth. As the load rate decreases, the power generated from solar and solar to electricity efficiency gradually decreases while the proportion of power from solar increases. The proportion of power from solar reaches a maximum of 24.28 % at 50 % load rate. The effects of different thermal energy storage hours on the levelized cost of electricity are investigated, and the results show that the lowest levelized cost of electricity is only 41.62 $/MWh in the high-level direct normal irradiance area. The new system can reduce about 272,921 tons of CO2 emissions in a year at 100 % load rate. This study contributes to further promoting the development of a high-proportion solar aided coal-fired power generation system and realizing the low-carbon transition of coal-fired power generation industry.

Dimensionless thermal performance analysis of a closed isothermal compressed air energy storage system with spray-enhanced heat transfer

The isothermal compressed air energy storage (I-CAES) technology boasts the advantages of high theoretical round-trip efficiency and zero carbon emissions. In order to rapidly and efficiently assess the thermodynamic performance of I-CAES, and addressing the limitations of the overly complex thermodynamic model for spray heat exchanged closed-loop I-CAES (CI-CAES), this paper establishes a dimensionless evaluation model related to container size and initial state a*, spray water quantity b*, start or end spraying time c*, and the ratio of liquid level to droplet velocity u*. The expressions for evaluation indicators such as round-trip efficiency, indicated efficiency, compression exergy efficiency, and expansion exergy efficiency are summarized, revealing the impact patterns of dimensionless numbers on the thermodynamic performance of CI-CAES. The results show that the relative difference in the percentage of air enthalpy change calculated using the real gas model versus the ideal gas model during the expansion stage is 88.26 %. The indicated efficiency and round-trip efficiency of CI-CAES simulated by the real gas model were 88.18 % and 60.51 %, respectively, for the design parameters, and the variable condition operation of the hydrodynamic machinery was the main reason for the lower round-trip efficiency. The larger the values of a* and b*, the closer to the isothermal process, and the greater the effect of b* on the performance of the CI-CAES system compared to the two. When b* is 50, the polytropic indices of the compression and expansion stages reach 1.03 and 1.01, respectively. The round-trip, compression exergy efficiency and expansion exergy efficiency all vary parabolically with c*, suggesting that there is an optimal c* that optimizes the system performance. The change in pressure ratio has a greater effect on round-trip efficiency and on the percentage change in air enthalpy during compression and expansion, and u* has a lesser effect on system performance. The results of the research can provide theoretical guidance for the efficient operation of CI-CAES.

Emergoenvironmental analysis and sustainable flexible peaking of a novel solar-assisted solid oxide fuel cell cogeneration system

The development of green and sustainable conversion technologies is imperative to alleviate the current severe energy and environmental crises and to achieve the goal of carbon neutrality. This project presents a novel cogeneration system that integrates a solid oxide fuel cell afterburning system, an energy recovery system, and a parallel heating system equipped with multistage utilization, solar-assisted, and flexible peaking technologies. Following the establishment and validation of the system, power source analysis, parameter sensitivity studies, three-objective optimization, and internal exergy flow investigation are carried out. Subsequently, the positive impacts of multistage utilization, solar-assisted, and flexible peaking technologies, as well as the thermoeconomic and emergoenvironmental operating characteristics of the system, are discussed. The numerical results demonstrate that the emergoenvironmental factor and emergy environmental impact difference of the system are 70.15 % and 82.52 %, and the energy efficiency is improved by 1.41 %∼19.09 %, respectively, compared with similar solid oxide fuel cell systems, confirming its favorable thermodynamic performance and emergoenvironmental impact. The system achieves daily heating savings of 3302 kWh and life cycle economic benefits of $19,310,524, with a repayment of the investment cost in 4.17 years, reflecting considerable economic benefits. This project also demonstrates exergy flow, module defects, and improvement mechanisms from the perspective of emergoenvironmental, providing a valuable reference for the promotion of green energy.

Design, analysis and optimisation of a novel adiabatic-isothermal CAES system with coupled stepped phase change energy storage unit

Compressed air energy storage (CAES) technology is one of the important technologies to address the instability of renewable energy sources. To further make full use of the system heat of compression and reduce the problem of energy grade dissipation inside the accumulator, this paper proposes a novel CAES system coupled with a graded phase change thermal energy storage unit (SP-TES) and near isothermal compression of a liquid piston. A combination of adiabatic compression and near-isothermal compression is used to reduce the generation of compression heat, while the graded storage of compression heat through SP-TES reduces the reduction of energy grade. The design of the proposed SP-TES is carried out through the binary eutectic theory, and a one-dimensional transient entransy dissipation model, a thermodynamic model and an economic model are developed to analyze the 4E performance (energy, exergy, entransy, and exergoeconomic) of the proposed SP-TES. Further, the effect patterns of key node parameters on the proposed system are investigated by developing system related models and the system is optimized with multiple objectives from the point of view of economic and thermodynamic performances. The results show that the 4E performance of SP-TES is in between that of high and low temperature single-stage accumulators, and that SP-TES combines the advantages of higher economic performance of single-stage low-temperature accumulators and higher thermal performance of single-stage high-temperature accumulators. The SP-TES with a temperature range of 350 K-451 K is gradually stabilized with the number of charging and discharging, and the efficiency of the system in the stabilization stage is 73.24 %. The SP-TES with a temperature range of 407 K-440 K has the best economic performance with exergoeconomic parameter of 360.05 kJ/USD. The thermal storage performance and power output of the SP-TES decreases with the increase in the number of stages. The multi-objective optimization results show that the new CAES system efficiency is 63.03 % and the design is optimal when the unit energy cost is 0.2217 $/kWh.

Thermodynamic and parametric analyses of a zero-carbon emission SOFC-based CCHP system using LNG cold energy

A novel zero-carbon emission combined cooling, heating and power (CCHP) system is currently proposed. The thermal energy of the solid oxide fuel cell (SOFC) exhaust is recovered in a transcritical CO2 (T- CO2) power cycle. Relying on the efficient utilization of liquefied natural gas (LNG) cold energy, CO2 capture has been achieved at low energy consumption. The thermodynamic performance is evaluated by using energy and exergy analysis methods for this hybrid process. The electrical, exergy, and CCHP efficiencies are obtained as 60.37 %, 62.83 %, and 79.09 %, respectively. The CO2 condenser, with the largest exergy destruction ratio (18.60 %) and a low exergy efficiency (37.16 %), is regarded as the weakest point in terms of thermodynamic perfectibility. In addition, the influences of the current density, stack temperature and pressure, and fuel utilization rate have also been studied from different aspects of system performance. The current density, stack temperature, stack pressure, and fuel utilization rate are recommended as 0.3 A/cm2∼0.4 A/cm2, 900 °C, 5 bar, and 85 %, respectively. This research provides practical reference and pragmatic guidance for the integration, analysis, and optimization of SOFC-based CCHP systems.

Enhancing thermodynamic performance with an advanced combined power and refrigeration cycle with dual LNG cold energy utilization

Utilizing waste heat to drive thermodynamic systems is imperative for improving energy efficiency, thereby improving sustainability. A combined cooling and power systems (CCP) utilizes heat from a temperature source to deliver both power and cooling. However, CCP systems utilizing LNG cold energy suffers from low second law efficiency due to significant temperature differences. To address this, an “Advanced Power and Cooling with LNG Utilization (ACPLU)” system is proposed, integrating a cascaded transcritical carbon dioxide (TCO2)-LNG cycle with an Organic Rankine cycle (ORC) for improved power generation and an absorption refrigeration system (ARS) for simultaneous cooling. This study evaluates the second law efficiency, net work output, and exergy destruction performance through a sensitivity analysis, optimizing variables such as heat source temperature, superheater temperature difference, ORC and CO2 turbine inlet and condenser pressures, evaporator temperature, and pinch point temperatures of heat exchangers and generator. Compared to previous studies on CCP systems, the ACPLU shows a superior performance, with a second law efficiency of 27.3 % and a net work output of 11.76 MW. Cyclopentane as an ORC working fluid resulted in the highest second law efficiency of 29.06 % and net work output of 12.27 MW. Parametric analysis suggested that heat source temperature significantly impacts net power output. The exergy analysis concluded that a high-pressure ratio and good thermal match between the heat exchangers enhance overall performance. Utilizing artificial neural network (ANN) to produce a multiple-input-multiple-output (MIMO) objective function and performing multi-objective optimization (MOO) using genetic algorithm (GA), an improved second law efficiency and net power output by 28.11 % and 14.16 MW respectively, with pentane as the working fluid, is demonstrated. An average cost rate of 9.121 $/GJ was observed through a thermo-economic analysis. The ACPLU system is promising for medium temperature waste heat recovery, such as, pharmaceutical manufacturing plants.

Performance comparison of two ORC-VCR system configurations using pure/mixture working fluids based on multi-objective optimization

The organic Rankine cycle-vapor compression refrigeration combined system is an effective way to sufficiently utilize low-grade heat energy and achieve refrigeration without electricity consumption. The combined system typically includes single-fluid configuration with a common condenser and double-fluid configuration with two condensers. In order to determine the optimal configuration of the combined system, the performance comparison of two system configurations using pure/mixture working fluids is carried out. The main innovations of this paper different from the previous literature are as follows: the performance comparison is based on the results of multi-objective optimization. Moreover, the working fluids are selected as the decision variables of multi-objective optimization. In order to provide theoretical guidance for the determination of the optimal system under different performance preferences, single-objective optimization is also conducted. The optimal system is determined under comprehensive performance and different performance preferences. The results indicate that the double-fluid system configuration has better thermodynamic performance than the single-fluid system configuration. Moreover, the performance of the systems using mixture working fluids is greatly improved compared with that of the system using pure working fluids. When users’ performance preference is coefficient of performance, system exergy efficiency or comprehensive performance, the optimal system is the double-fluid system using mixture working fluids with system coefficient of performance of 0.23, system exergy efficiency of 43%, and grey relational degree of 0.96, respectively. When users’ performance preference is levelized cost of cooling, the optimal system is the single-fluid system using mixture working fluids with levelized cost of cooling of 0.027$/kWh.

Thermodynamic and Kinetic Regulation for Mg‐Based Hydrogen Storage Materials: Challenges, Strategies, and Perspectives

AbstractMg‐based hydrogen storage materials have drawn considerable attention as the solution for hydrogen storage and transportation due to their high hydrogen storage density, low cost, and high safety characteristics. However, their practical applications are hindered by the high dehydrogenation temperatures, low equilibrium pressure, and sluggish hydrogenation and dehydrogenation (de/hydrogenation) rates. These functionalities are typically determined by the thermodynamic and kinetic properties of de/hydrogenation reactions. This review comprehensively discusses how the compositeization, catalysts, alloying, and nanofabrication strategies can improve the thermodynamic and kinetic performances of Mg‐based hydrogen storage materials. Since the introduction of various additives leads the samples being a multiple‐phases and elements system, prediction methods of hydrogen storage properties are simultaneously introduced. In the last part of this review, the advantages and disadvantages of each approach are discussed and a summary of the emergence of new materials and potential strategies for realizing lower‐cost preparation, lower operation temperature, and long‐cycle properties is provided.

Developing Lead Compounds of eEF2K Inhibitors Using Ligand–Receptor Complex Structures

The eEF2K, a member of the α-kinase family, plays a crucial role in cellular differentiation and the stability of the nervous system. The development of eEF2K inhibitors has proven to be significantly important in the treatment of diseases such as cancer and Alzheimer’s. With the advancement of big data in pharmaceuticals and the evolution of molecular generation technologies, leveraging artificial intelligence to expedite research on eEF2K inhibitors shows great potential. Based on the recently published structure of eEF2K and known inhibitor molecular structures, a generative model was used to create 1094 candidate inhibitor molecules. Analysis indicates that the model-generated molecules can comprehend the principles of molecular docking. Moreover, some of these molecules can modify the original molecular frameworks. A molecular screening strategy was devised, leading to the identification of five promising eEF2K inhibitor lead compounds. These five compound molecules demonstrated excellent thermodynamic performance when docked with eEF2K, with Vina scores of −12.12, −16.67, −15.07, −15.99, and −10.55 kcal/mol, respectively, showing a 24.27% improvement over known active inhibitor molecules. Additionally, they exhibited favorable drug-likeness. This study used deep generative models to develop eEF2K inhibitors, enabling the treatment of cancer and neurological disorders.

EXPLORACIÓN DE LA MEZCLA RE170/R600: MEJORA DE LA EFICIENCIA COMO ALTERNATIVA AL R600a

The utilization of alternative mixtures to R600a has been extensively explored across various applications, showcasing their potential to enhance the energy efficiency of isobutane in domestic refrigerators and standalone commercial appliances while maintaining comparable thermodynamic characteristics and operational performance parameters. Among these mixtures, those composed of a significant proportion of R600 (butane) and a small portion of secondary refrigerant have emerged as the most promising. However, many secondary refrigerants in these blends are synthetic. RE170 (dimethyl ether or DME), a non-fluorinated and natural refrigerant, has emerged as a particularly promising candidate for blending with R600. This paper presents an experimental analysis of the RE170/R600 refrigerant mixture as an alternative to R600a. For that purpose, a simple compressor highly equipper test bench was used, in which the mixture was analyzed at a composition range varying from 2.5/97.5%w to 27.5/72.5%w at steps of 2.5%. Results show COP increments up to 19.3% respect R-600a and VCC and that low required DME matches the one obtained by R600a. RE170/R600 has been demonstrated to be a long-term superior efficiency mixture.

Evaluating the Impact of CO2 Capture on the Operation of Combined Cycles with Different Configurations

In order to reduce greenhouse gas emissions associated with power generation, the replacement of fossil fuels with renewables must be accompanied by the availability of dispatchable sources needed to balance electricity demand and production. Combined cycle (CC) power plants adopting post-combustion capture (PCC) can serve this purpose, ensuring near-zero CO2 emissions at the stack, as well as high efficiency and load flexibility. In particular, the chemical absorption process is the most established approach for industrial-scale applications, although widespread implementation is lacking. In this study, different natural gas combined cycle (NGCC) configurations were modeled to estimate the burden of retrofitting the capture process to existing power plants on thermodynamic performance. Simulations under steady-state conditions covered the widest possible load range, depending on the gas turbine (GT) model. Attention was paid to the net power loss and net efficiency penalty attributable to PCC. The former can be mitigated by lowering the GT air–fuel ratio to increase the CO2 concentration (XCO2) in the exhaust, thus decreasing the regeneration energy. The latter is reduced when the topping cycle is more efficient than the bottoming cycle for a given GT load. This is likely to be the case in the less-complex heat recovery units.

Integrating solar-driven biomass gasification and PV-electrolysis for sustainable fuel production: Thermodynamic performance, economic assessment, and CO2 emission analysis

Biomass gasification provides a promising pathway for sustainable fuel production. Nevertheless, its development is hindered by lower efficiencies in biomass–to–fuel energy conversion and carbon utilization, along with restricted scale due to economic collection radius. To tackle these challenges, a solar–biomass hybrid gasification system is proposed for sustainable fuel production. The system employs parabolic trough and tower concentrators to generate solar heat, driving the biomass pyrolysis and pyrolysis products gasification reactions to produce bio–solar syngas. The high–density bio–oil and char produced in distributed pyrolysis units can be economically transported to the centralized gasification plant. Moreover, PV–electrolysis water is utilized to generate H2 and O2, which are used to adjust syngas composition and substitute for air separation O2, respectively. Consequently, the energy consumption for water–gas shift, CO2 separation, and air separation units can be reduced. Thermodynamic, economic, and CO2 emission performance are analyzed for a typical case of methanol production using corn residue. The total energy conversion efficiency of the hybrid system can reach 65.01 %, representing an improvement of 6.57 % compared to the conventional biomass gasification system. The fuel production cost is estimated to be $354.1 per ton, falling within the market price range. Additionally, the greenhouse gas emissions to produce unit kg methanol can be reduced by 0.63 kg CO2eq. Furthermore, we analyzed the performance of six representative fuel production scenarios involving different types of biomass feedstocks. Finally, the limitations of this work and the feasibility of its practical applications are discussed. This study offers an innovative approach to bio-solar fuel production, promoting the development of circular bio-economy and the application of sustainable fuel.

Thermodynamic performances of a novel multi-mode solar-thermal-assisted liquid carbon dioxide energy storage system

Liquid carbon dioxide energy storage is an efficient and environmentally friendly emerging technology with significant potential for integration with renewable energy sources. However, the heat recovery and utilization during compression and expansion are not implemented well. This paper proposes a multi-mode solar-thermal-assisted liquid carbon dioxide energy storage system integrated with the organic Rankine cycle. Three operation modes of normal operation mode, heat distribution operation mode, and solar thermal power generation mode are developed to achieve flexible control of the system under both normal and extreme environmental conditions. Thermodynamic performance analysis of the system under normal operation mode shows that compared to traditional system with energy storage density of 8.55 kWh/m3, the overall efficiency of the coupled system increases from 49.5 % to 62.1 %, with an energy storage density reaching 21.74 kWh/m3. The impact of key parameters such as temperature and pressure on system performance is discussed. Furthermore, an analysis of the heat flow distribution ratio under the heat distribution mode was conducted, indicating optimal system performance at a heat flow ratio of 6:4. Comparative analysis of the system performance under various operating conditions for the three operation modes was performed, elucidating the operational strategies of each mode.

Thermodynamic performance evaluation and optimization of a hybrid system integrating vacuum graphene-anode thermionic converters with direct carbon fuel cells

An efficient hybrid system integrating a direct carbon fuel cell (DCFC) with a vacuum graphene-anode thermionic converter (VGTC) is proposed for cogeneration. The VGTC efficiently recycles waste heat released from the DCFC and generate additional electricity, significantly improving energy utilization efficiency and economic performance. A comprehensive mathematical model is developed to quantitatively assess the thermodynamic performance of the hybrid system, taking into account the overpotential losses of the DCFC and the irreversible energy losses occurring within the system. The results show that at an operating temperature of 923 K, the hybrid system can achieve a maximum power density of 466 W/m2, which is approximately 1.34 times that of a single DCFC, indicating a significant improvement in output performance. Besides, the optimal operating region and parameter selection criteria for the hybrid system are determined using finite-time thermodynamic optimization theory. Furthermore, the effects of essential parameters on the output performance of the hybrid system, such as the operating temperature of the DCFC, the heat transfer coefficient, the Fermi level of graphene, the work function of the cathode, the thermal emissivity, and the reflectivity of the back mirror, are investigated. Finally, the comparative study shows that the proposed hybrid system outperforms other previously reported hybrid systems regarding output electric power and conversion efficiency due to the efficient high-grade waste heat recovery and energy conversion by the VGTC.

Hydrogen storage solutions for residential heating: A thermodynamic and economic analysis with scale-up potential

The study presents a thermodynamic and economic assessment of different hydrogen storage solutions for heating purposes, powered by PV panels, of a 10-apartment residential building in Milan, and it focuses on compressed hydrogen, liquid hydrogen, and metal hydride. The technical assessment involves using Python to code thermodynamic models to address technical and thermodynamic performances. The economic analysis evaluates the CAPEX, the ROI, and the cost per unit of stored hydrogen and energy. The study aims to provide an accurate assessment of the thermodynamic and economic indicators of three of the storage methods introduced in the literature review, pointing out the one with the best techno-economic performance for further development and research. The performed analysis shows that compressed hydrogen represents the best alternative but its cost is still too high for small residential applications. Applying the technology to a big system case would enable the solution making it economically feasible.

Proposal and performance analysis of a novel hydrogen and power cogeneration system with CO2 capture based on coal supercritical water gasification

To establish a sustainable energy system, it is essential to achieve low-carbon and clean utilization of coal. In this study, a novel hydrogen and power cogeneration system with full CO2 capture that based on coal supercritical water gasification (SCWG) is proposed. Hydrogen is separated from syngas produced by coal SCWG, and the remaining combustible gas is burned to generate power. Moreover, supercritical CO2 cycle is integrated within the cogeneration system to recover the waste heat with high exergy efficiency. Thermodynamic performances, effects of key operation parameters and off-design performances under part-load conditions of the cogeneration system are analyzed. Under the design condition, the cogeneration system produces 20.26 mol kg−1 hydrogen and generates 8746 kJ kg−1 net power, achieving the high energy efficiency and exergy efficiency of 54.77 % and 52.54 %. The exergy efficiency of cogeneration system can be enhanced by optimizing the operation parameters, which is increased by 0.42 %, 4.03 % and 1.10 % with the optimal coal water slurry concentration (17.5 %), higher gasification temperature (750 °C) and higher gas turbine inlet parameters (1500 °C/3 MPa), respectively. The cogeneration system performance decreases with the power load, and the exergy efficiency decreases by 9.61 % when the system power load reduces from 100 % to 30 %.

Thermodynamic performance assessment of a solar-driven desiccant evaporative air cooling system (SDEAC) for outdoor environments- a dynamic study

In this work, a novel dynamic model of a solar-driven desiccant evaporative air cooling system for outdoor environments is proposed, namely the SDEAC system. The effects of operating and designing parameters on the performance of the SDEAC system are analyzed. The results indicate that the sensible cooling capacity, the latent cooling capacity, and the COP decrease monotonically as the rotational speed of the desiccant wheel increases. When the ratio of dehumidification area to total area (r1) is 0.5, the performance of the SDEAC system is optimal under the condition of sufficient solar radiation. The ratio of the dehumidified air flowrate to the regenerated air flowrate has a small effect on the cooling capacity but has a large effect on the COP. The SDEAC system has a higher sensible cooling capacity and total cooling capacity compared to the EAC system. Moreover, although the COP of the SDEAC is lower than that of the EAC system, it is still maintained at a relatively high level. The SDEAC system with a supply air flowrate of 670 m3/h to cool the outdoor air saves about 1283∼1617 kWh of electricity and 788 kg–1139 kg of carbon emission reduction compared to a conventional vapor compression air conditioning system in different cities during the period of June to August.

Proposal of a novel multi-generation system based on dual-loop absorption power and compression refrigeration cycle

One of the promising approaches to compensate for imminent depletion of fossil energy resources and their adverse global impacts is enhancing the efficiency of systems utilizing low-temperature heat sources. The initial target of the research is to present a promising system for simultaneous production of power, refrigeration, heat, and hydrogen utilizing a combination of the absorption power cycle, the vapor compression refrigeration cycle, and a proton exchange membrane electrolyzer. On this subject, a comprehensive modeling of the energy and exergy of the proposed set-up is presented, and its thermodynamic performance is scrutinized. Furthermore, a comprehensive study of various parameters is performed to evaluate their impacts on system performance. The research aims to enhance and optimize the use of energy and various resources, contributing to the development of more sustainable efficient energy systems. Thermodynamic analysis of the multiple generation system shows that under baseline conditions and initial design, the system has the capability to produce net electrical power of approximately 17.12 kW, cooling power of about 201.5 kW, heating power of around 697.1 kW, and produce pure hydrogen at a rate of 0.153 kilograms per hour. The system exhibits an energy efficiency ratio of 1.364 and an exergy efficiency of 36.58 %. Moreover, optimization with single and multiple objectives with different weighting coefficients reveals that higher values of these parameters can be obtained. In other words, in the MOOM optimization mode, exergy efficiency increases to 7.16 %, and the energy performance ratio rises to 85.73 % compared to the BM mode. Additionally, through a parametric assessment to define the effect of input parameters on system performance, it demonstrates that increasing the temperature of the heat source may simultaneously increase the exergy efficiency and energy performance ratio of the system. The Grassmann diagram also indicates that the total exergy of the input fuel is about 196.9 kW. From this amount, approximately 121.5 kW are destroyed through the components of the system. Furthermore, about 3.39 kW are lost through the absorber coolant and waste from the hydrogen production unit. About 72.4 kW are attributed to products.

Numerical simulation and thermodynamic test analysis of plate heat exchanger based on topology optimization

Efficient heat transfer in PHEs relies on optimizing flow distribution to minimize thermal dead zones. Existing studies have predominantly focused on single-phase fluids as working media and employed density-based methods for structural optimization of microchannel heat exchangers at small scales. In this study, the Brinkman term from the porous media flow model is introduced in an innovative manner, along with the utilization of a material density interpolation model, which builds upon the density-based approach. A novel two-phase fluid topology optimization method is proposed, specifically tailored for large-scale PHE operating conditions, resulting in the successful design of a new PHE topology. To compare the performance of the two heat exchangers, finite element simulation, visualization experiments, and thermodynamic performance testing are conducted. The simulation results reveal that the heat transfer capacity of the topological PHE is 810 W with pressure drops of 18.8 kPa, while the dimple PHE exhibits heat transfer capacity of 652 W with pressure drops of 25.9 kPa. Compared to the dimple PHE, the topological PHE demonstrates 24.2 % improvement in heat transfer performance and 27.8 % reduction in pressure drop. The dimensionless comprehensive heat transfer coefficient (j/f) indicates that the overall performance of the topological PHE significantly surpasses that of the traditional PHE. Furthermore, the visualization experiment results demonstrate that the complex texture structure of the topological PHE effectively induces fluid motion, compelling the fluid to flow along the texture direction. This significantly mitigates the issue of uneven flow within the PHE, thus enhancing heat transfer efficiency. Specifically, the topological PHE exhibits inlet–outlet temperature difference of 10.3 °C and pressure drops of 11.2 kPa, while the dimple PHE shows inlet–outlet temperature difference of 6 °C and pressure drops of 12.9 kPa. The findings of this study provide guidance for future research endeavors aimed at evaluating potential solutions to advance heat transfer in PHEs and facilitate the implementation of thermal management strategies.

Performance of a high-temperature transcritical pumped thermal energy storage system based on CO2 binary mixtures

Pumped thermal energy storage is a novel energy storage technology with features of high efficiency, geographical independence and suitable for bulk capacity energy storage. As a subset of pump thermal energy storage system, the transcritical CO2 arrangements have received widespread attention due to their excellent thermodynamic performance. However, the high cost and low efficiency of heat exchange progress caused by CO2 phase transition hinder the transformation of this system from scientific theory to practical application. CO2 binary mixtures is innovatively employed as working fluid in proposed system. The temperature of mixture is variable rather than remaining constant during the evaporation and condensation progresses. R134a, R290, R600 and R601 are selected respectively to mix with CO2 to form the new working fluids. Advanced thermodynamic and economic models are established to investigate the performance of novel systems. Results indicate that the system driven by CO2/R134a with a refrigerant mass fraction of 0.15 exhibits the optimal overall performance. At the optimal point of the 10 MW/8h system, the round trip efficiency and levelized cost of storage are 66.18 % and 0.146 $/kWh, respectively. Moreover, the investigation of system performance with various energy storage capacities is put forward. It is shown that when the energy system capacity reaches 300 MW, the levelized cost of storage can be reduced to 0.122 $/kWh. To adapt to different peak and valley periods in different regions, systems with different charge and discharge times are investigated and it is found that the charge duration should better be equal to the discharge duration.