Thermodynamic Effects Research Articles

Remote dynamic and thermodynamic effects of typhoons on Meiyu–Baiu precipitation in Japan assessed with bogus typhoon experiments

To advance comprehensive knowledge of typhoon-induced remote precipitation and anomalous atmospheric circulations during the early summer rainy season (Meiyu-Baiu), we performed numerical simulations in which different bogus typhoons are imbedded in the July climatological mean field as ideal initial and lateral boundary conditions using a regional atmospheric model, and we compared experiments with and without the bogus typhoon. The dominance of an anomalous local high (ALH) remotely induced by a typhoon leads to a poleward shift of the primary Meiyu–Baiu frontal zone in the form of the enhancement of the North Pacific subtropical high (NPSH). Typhoon-induced negative potential vorticity advection plays a dominant role in forming the ALH around Japan. Despite the shift of the frontal zone, heavy precipitation in excess of 100 mm per day occurs along the Pacific coast of western Japan, which is triggered by two primary moisture inflows. One is the low-level moisture inflow along the moisture conveyor belt (MCB), which is an appreciable low-level moisture flux zone stretching from the Indian Ocean to a typhoon over the western North Pacific, due to the intensified horizontal pressure gradient between the typhoon and the NPSH. The MCB is more robust in the experiment in which the typhoon is close to the South China Sea where the monsoon westerlies prevail. The parcels along the MCB bring moisture into western Japan even though moisture losses due to condensation occur on the way, to some degree. The other is the moisture inflow through the atmospheric boundary layer along the southwestern periphery of the NPSH. The parcels along the NPSH periphery easily receive moisture from the underlying ocean as they approach western Japan. Both inflows are enhanced by the ALH formation over Japan. The combined effect of the typhoon and its induced ALH is responsible for the prominence of the two major moisture inflows into western Japan, leading to local heavy precipitation in that region.

Temperature response mechanism of methane hydrate decomposition coupled with icing and melting under variational thermodynamic conditions

High-efficient decomposition is the precondition of commercial production of methane hydrates. Under variational thermodynamic conditions, icing and melting may occur during hydrate decomposition, inducing complex heat and mass transfer. In this study, hydrates formed under temperature gradient of 0.012, 0.020 and 0.026 °C/mm in a 2 L reactor, decomposed by long depressurization to 1.0 MPa at constant exhaust rate from 0.11 to 1.07 ln/min. Temperature of hydrate-bearing area was in a specific relationship called thermodynamic non-equilibrium effect with pressure, controlled by hydrate decomposition. When pressure reached around 2.1–2.3 MPa, instant icing caused rapid temperature rise, and accelerated hydrate decomposition generating pressure rise of 2.36 MPa at most coordinated by limited exhaust rate. Isothermy stage occurred in double phase transition system with hydrate decomposition and ice melting, temperature slightly raised after most hydrates had decomposed. Temperature gradient only worked on non-hydrate/ice area because the temperature response of hydrate decomposition couple with icing and melting is first dominated by thermodynamics and then affected by heat and mass transfer. The control effect of ice melting in thermodynamic is stronger than hydrate decomposition. These results are significant for systematic analysis among gas production, hydrate decomposition, temperature gradient and ice behavior of actual hydrate exploitation.

Two modes of fusogenic action for influenza virus fusion peptide.

The entry of influenza virus into the host cell requires fusion of its lipid envelope with the host membrane. It is catalysed by viral hemagglutinin protein, whose fragments called fusion peptides become inserted into the target bilayer and initiate its merging with the viral membrane. Isolated fusion peptides are already capable of inducing lipid mixing between liposomes. Years of studies indicate that upon membrane binding they form bend helical structure whose degree of opening fluctuates between tightly closed hairpin and an extended boomerang. The actual way in which they initiate fusion remains elusive. In this work we employ atomistic simulations of wild type and fusion inactive W14A mutant of influenza fusion peptides confined between two closely apposed lipid bilayers. We characterise peptide induced membrane perturbation and determine the potential of mean force for the formation of the first fusion intermediate, an interbilayer lipid bridge called stalk. Our results demonstrate two routes through which the peptides can lower free energy barrier towards fusion. The first one assumes peptides capability to adopt transmembrane configuration which subsequently promotes the creation of a stalk-hole complex. The second involves surface bound peptide configuration and proceeds owing to its ability to stabilise stalk by fitting into the region of extreme negative membrane curvature resulting from its formation. In both cases, the active peptide conformation corresponds to tight helical hairpin, whereas extended boomerang geometry appears to be unable to provide favourable thermodynamic effect. The latter observation offers plausible explanation for long known inactivity of boomerang-stabilising W14A mutation.

Phase Shift of the Winter South China Sea Western Boundary Current Over the Past Two Decades and Its Drivers

AbstractThe winter South China Sea (SCS) western boundary current (WBC) has presented a significant weak–strong–weak phase shift in the last two decades, as revealed by observations and model products. Its phase shift has mainly been attributed to the joint effect of wind stress curl over the SCS and Luzon Strait transport (LST). Changes in the wind stress curl and planetary vorticity input through the Luzon Strait are the two major sources maintaining the winter SCS WBC state in different phases. The LST is closely related to the Kuroshio strength and thus the Pacific North Equatorial Current (NEC) bifurcation. Therefore, the winter SCS WBC phase shift is attributed to phase shifts of the winter monsoon and the NEC bifurcation, which are mostly related to those of the Indian Ocean Dipole Mode and Atlantic Multidecadal Oscillation, respectively. Understanding the SCS circulation low‐frequency variability is essential to forecast its thermodynamic state and regional climate effect.

Thermodynamic effect on attached cavitation and cavitation-turbulence interaction around a hydrofoil

This paper aims to numerically investigate the thermodynamic effect on attached cavitation and cavitation-vortex interaction around a NACA0015 hydrofoil. Based on the isothermal cavitation model, the compressibility and thermodynamic effect are considered by adding the state equation and modifying the evaporation and condensation source term in the mass transport equation. The thermodynamic effect on the hydrodynamic performance and the cavity volume fluctuations, the temporal evolution of the unsteady cavitation, the temporal evolution of vortex structures in the hydrofoil wake, and the cavitation-vortex interaction are presented. The main features of the unsteady quasi-periodic cavitation behavior are illustrated for the isothermal and non-isothermal conditions. The new omega vortex identification method depicts the influence of the thermodynamic effect on the shedding structure around the wake of a hydrofoil. Furthermore, the cavitation-vortex interaction is examined to show the relationship.

Anthropogenic forcing and Pacific internal variability-determined decadal increase in summer precipitation over the Asian water tower

The increased precipitation in the Asian water tower has prompted the abrupt lake expansion and increased runoff, significantly reshaping the water resource redistribution in the Inner Tibetan Plateau (ITP). However, the dynamic attribution behind this decadal increment remains unclear. Here, analysis of observations, large ensemble simulations, and pacemaker experiments indicates that this decadal increase was mainly attributed to the synergistic effects of the external forcing (anthropogenic greenhouse and aerosol emissions) and the Pacific internal variability, while the Atlantic and the Indian Ocean play a secondary role. Observations and simulations show that thermodynamic and dynamic effects work collaboratively to this increase. Remarkably, the upper-level dynamic convergence over the ITP would be enhanced through teleconnection and atmospheric dynamic feedback when involving the Pacific internal variability, resulting in more precipitation occurrence. Further analyses show that the enhanced stationary Rossby wave propagation over Eurasia and strengthened transient eddy activity over North Pacific could contribute to the anomalous cyclone over the ITP and weakened East Asian westerly jet, which built a pathway for the external forcing and Pacific internal variability collaboratively impacting the decadal increase in precipitation in the ITP. These results can improve our understanding of ITP summer precipitation attribution and can be applied to emergent constraints on future decadal precipitation prediction.

大西洋经向翻转环流的演变特征及其对北半球地表气温的热动力影响

大西洋经向翻转环流的演变特征及其对北半球地表气温的热动力影响

Evolution characteristics of the Atlantic Meridional Overturning Circulation and its thermodynamic and dynamic effects on surface air temperature in the Northern Hemisphere

Evolution characteristics of the Atlantic Meridional Overturning Circulation and its thermodynamic and dynamic effects on surface air temperature in the Northern Hemisphere

Influence of Stationary Waves on Precipitation Change in North American Summer during the Last Glacial Maximum

Abstract Paleo-proxy reconstructions reveal a moistening of the American Southwest during the Last Glacial Maximum (LGM; 21 ka). However, the primary mechanisms driving the moistening trend are still debated, with relatively few studies focused on hypotheses related to synoptic changes in precipitation. Analysis of the Paleoclimate Intercomparison Model Project (PMIP3) simulations shows enhancement of precipitation in the southwest and south-central United States during the winter and summer. Here, we suggest that summertime eastward phase shifting of stationary waves at the LGM enhanced precipitation in the south-central United States and dried the southeastern United States. Mechanism denial experiments performed with version 3 of the Hadley Centre Coupled Model (HadCM3) indicate that the thermodynamic effect of the Laurentide Ice Sheet forced eastward phase shifting of stationary waves. By comparing a synthesis of LGM proxies to the PMIP3 ensemble, we find models that compare more favorably to the reconstructions simulate a weaker Laurentide ice thermodynamic effect, smaller eastward phase shifting of stationary waves, and weaker jet stream anomalies. Significance Statement Our study is motivated by the impact of climate change on hydroclimate in North America, especially in the semiarid areas near the southwestern United States, and the persistent problem of significant disagreements among CMIP model projections. Yet modern models and observations alone cannot tell us the likeliest climate change outcome in this region. Here we analyze precipitation during the LGM reconstructed from proxies and as simulated by the PMIP3, which reveal a precipitation trend with wetting in the southwestern United States and drying in the southeastern United States. Our interpretation of the PMIP3 simulations involves application of simple theories for midlatitude stationary waves, and indicates that the LGM precipitation is generated by the phase shift of stationary waves from the enhancement of jet speeds. Our model–data comparison also suggests that in the PMIP3 simulations, weak LGM jet stream anomalies, due to weak polar amplification, compare more favorably to the proxies.

Prolonged South Asian Monsoon variability and weakened denitrification during Mid-Pleistocene Transition

During Mid-Pleistocene Transition (MPT, 0.68 to 1.16 million years ago, Ma), the earth's climate cycle shifted from 41 kyr (thousand years) to quasi-100 kyr cyclicity. The South Asian Monsoon (SAM) variability and its forcing factors during MPT are not fully understood. We present a multiproxy record of productivity and denitrification related to SAM variability from the eastern Arabian Sea (IODP Expedition 355, Site 1457) during MPT. The denitrification and productivity vary distinctly during the early (1.19 Ma to 0.95 Ma), mid (0.95 Ma to 0.79 Ma), and late (0.79 Ma to 0.68 Ma) MPT. The long-term SAM variability followed the prolonged glacial-interglacial cycle as it shifted to quasi-100 kyr periodicity at 0.95 Ma. The SAM was strong (weak) during the interglacials (glacials) of MPT. During early MPT, the SAM intensity was high during one of the glacial periods (MIS 30) due to precessional and CO2 forcing. At mid-MPT, the denitrification anomalously decreases, possibly, due to enhanced oxygen solubility during the extended glacial period. During the various phases of MPT, both the dynamic (precession, interhemispheric insolation gradient) and the thermodynamic (CO2 variability) effects govern the SAM.

Correlation of Extractables Transfer from Low-Density Polyethylene into Extraction Solvents with Abraham Solvation Parameter Model and Assessment of Thermodynamic and Kinetic Effects in Achieving Exhaustive Extractions in Chemical Characterization of Medical Devices

Correlation of Extractables Transfer from Low-Density Polyethylene into Extraction Solvents with Abraham Solvation Parameter Model and Assessment of Thermodynamic and Kinetic Effects in Achieving Exhaustive Extractions in Chemical Characterization of Medical Devices

Enhancement of formic acid production from carbon dioxide hydrogenation using metal-organic frameworks: Monte Carlo simulation study

Formic acid production from CO2 allows the reduction of carbon dioxide emissions while synthesizing a product with a wide range of applications. CO2 hydrogenation is challenging due to the cost of transition metal catalysts and the toxicity of the transition elements. In this work, the thermodynamic confinement effects of the metal–organic framework UiO-66 on the CO2 hydrogenation to formic acid were studied by force field-based molecular simulations. The confinement effects of UiO-66 and the metal–organic frameworks Cu-BTC, and IRMOF-1 were compared, to assess the impact of different pore size and metal centers on the production of HCOOH. Monte Carlo simulations in the grand-canonical ensemble were performed in the frameworks, using gas phase mole fractions of CO2, H2, and HCOOH at chemical equilibrium, obtained from Continuous Fractional Component Monte Carlo simulations in the Reaction Ensemble. The adsorption isobars of the components in metal–organic frameworks were computed at 298.15 – 800 K, 1 – 60 bar. The enhancement of HCOOH production due to preferential adsorption of HCOOH in metal–organic frameworks was calculated for all studied conditions. UiO-66, Cu-BTC, and IRMOF-1 affect CO2 hydrogenation reaction, shifting the thermodynamical equilibrium toward HCOOH formation. The prevailing factor is the type of metal center in the metal–organic framework. The confinement effect of Cu-BTC turns out to exceed the enhancement caused by UiO-66, and IRMOF-1. The resulting mole fraction of HCOOH increased by ca. 2000 times compared to the gas phase at 298.15 K, 60 bar. Cu-BTC can be considered as an alternative to improve the production of HCOOH due to elimination of the high-cost temperature elevation, cost reduction of downstream processing methods, and comparable final concentration of HCOOH to the reported concentrations of formate obtained using transition metal catalysts.

Study on thermodynamics and flow characteristics of jet condensate in subcooled flowing liquid

Steam jet condensation in flow water under different conditions was investigated numerically. A cavitation model considering thermodynamic effects was proposed to study the flow and interfacial heat transfer characteristics. The distribution of thermodynamic parameters and the influence of different incident angles on the jet state were studied. The decrease in steam pressure and water subcooling would have a negative impact on the heat transfer coefficient of the interface and the length of plume. Furthermore, with increased water flow, the steam plume was tapered and its length was gradually shortened. Additionally, the turbulent kinetic energy is the maximum at the outlet of the nozzle and decreases with increasing flow distance. The distribution characteristic of the heat transfer coefficient is similar to and turbulence kinetic energy, which increases with the water mass flux, and reaches the maximum at both sides of the axis. Gradually increases in the middle of the axis. Therefore, the improvement of jet condensation should be achieved by adjusting the incidence angle and the water flow velocity.

An Axially Compressed Moving Nanobeam Based on the Nonlocal Couple Stress Theory and the Thermoelastic DPL Model

This article introduces a new model that can be used to describe elastic thermal vibrations caused by changes in temperature in elastic nanobeams in response to transverse external excitations. Using the idea of nonlocal elasticity and the dual-phase lagging thermoelastic model (DPL), the coupled equations of motion and heat transfer were derived to explain small-scale effects. Additionally, modified couple stress theory (MCST) and Euler–Bernoulli (EB) beam assumptions were considered. The proposed theory was verified by considering the thermodynamic response of nanobeams moving horizontally at a constant speed while one end is subjected to a periodic thermal load. The system of governing equations has been solved numerically with the help of Laplace transforms and one of the tested evolutionary algorithms. The effects of changing the nonlocal modulus, the magnitude of the external force, and the length scale parameter on the system fields were investigated. It is also shown how the behavior of the thermal nanobeam changes depending on the phase delay factors in addition to the horizontal velocity of the beam. To determine this model’s accuracy, its results were compared with the results of the classical continuity model and thermoelastic concepts. The numerical results show that when the nanobeam moves, the length scale can change the studied thermal and mechanical vibration wave patterns and physical fields. Additionally, during thermally stimulated vibrations, thermodynamic effects that have implications for the dynamic design and performance improvement of nanostructures must be considered.

Feasibility Study of Scheme and Regenerator Parameters for Trinary Power Cycles

Natural gas-fired combined cycle plants are nowadays one of the most efficient and environmentally friendly energy complexes. High energy efficiency and low specific emissions are achieved primarily due to the high average integral temperature of heat supply in the Brayton–Rankine cycle. In this case, the main sources of energy losses are heat losses in the condenser of the steam turbine plant and heat losses with the exhaust gases of the waste heat boiler. This work is related to the analysis of the thermodynamic and economic effects in the transition from binary to trinary cycles, in which, in addition to the gas and steam–water cycles, there is an additional cycle with a low-boiling coolant. A method for the feasibility study of a waste heat recovery unit for trinary plants is proposed. The schematic and design solutions described will ensure the increased energy and economic performance of combined cycle power plants. Based on the results of the thermodynamic optimization of the structure and parameters of thermal schemes, it was found that the use of the organic Rankine cycle with R236ea freon for the utilization of the low-grade heat of a trinary plant’s exhaust gases operating from a GTE-160 gas turbine makes it possible to achieve a net electrical efficiency of 51.3%, which is a 0.4% higher efficiency for a double-circuit combined cycle gas turbine plant and a 2.1% higher efficiency for a single-circuit cycle with similar initial parameters. On the basis of the conducted feasibility study, the parameters and characteristics of the heat exchangers of the regenerative system of the waste heat recovery unit are substantiated. The use of plain fin-and-tube heat exchangers in the regenerative system of the utilization cycle is the most promising solution. It was found that the level of allowable pressure loss in the regenerator of 10 kPa and the degree of regeneration of 80% allow for maximum economic efficiency of the waste heat recovery unit.

Effects of Pre-spark Heat Release of Ethanol-Blended Gasoline Surrogate Fuels on Engine Combustion Behavior

<div>Regulations limiting greenhouse gas (GHG) emissions in the transport sector have become more restrictive in recent years, drawing interest to synthetic fuels such as e-fuels and biofuels that could “decarbonize” existing vehicles. This study focuses on the potential to increase the thermal efficiency of spark-ignition (SI) engines using ethanol as a renewable fuel, which requires a deep understanding of the effects of ethanol on combustion behavior with high compression ratios (CRs). An important phenomenon in this condition is pre-spark heat release (PSHR), which occurs in engines with high CRs in boosted conditions and changes the fuel reactivity, leading to changes in the burning velocity. Fuel blends containing ethanol display high octane sensitivity (OS) and limited low-temperature heat release (LTHR). Consequently, their burning velocities with PSHR may differ from that of gasoline. This study therefore aimed to clarify the effects of ethanol on SI combustion behavior under PSHR conditions. Combustion behavior was studied by performing single-cylinder engine experiments and chemical kinetics simulations. The experimental measurements were performed to characterize the relationship between the occurrence of PSHR and the main combustion duration. Analysis of this relationship showed that the ethanol-blended fuel has a lesser PSHR and a longer combustion duration than the non-ethanol fuel by approximately 5% in high engine load conditions. Simulations using input data from the experiments revealed that the ethanol-blended fuel has a lower laminar burning velocity due to the lower temperature in the unburned mixture caused by its PSHR. Additional simulations examining the chemical effect of partially oxidized reactants caused by PSHR on the laminar burning velocity showed that partially oxidized reactants increase the laminar burning velocity of the ethanol-blended fuel but decrease that of a reference fuel without ethanol. A large number of fuel radicals and oxides of the ethanol-blended fuel enhances chain-branching reactions in the pre-flame zone and possibly increases its laminar burning velocity. However, the thermodynamic effect of PSHR on laminar burning velocity exceeds the chemical effect, and thus the ethanol-blended fuel has a lower turbulent burning velocity in the PSHR conditions.</div>

Thermodynamic irreversibility effects with Marangoni convection for third grade nanofluid flow

In this study, an analysis was performed to investigate the thermal and mass transport of radiative flow of a third-grade nanofluid with magnetohydrodynamic. The analysis concerns two-dimensional flow around an infinite disk. Heat transport is studied via heat generation/absorption, thermal radiation and Joule heating. Chemical reaction with activation energy is also considered. The nanofluid characteristics, including Brownian motion and thermophoretic diffusion, are explored via the Buongiorno model. Entropy analysis is also conducted. Moreover, the surface tension is assumed to be a linear function of concentration and temperature. Through adequate dimensionless variables, governed PDEs are non-dimensionlized and then tackled by ND-solve (a numerical method in Mathematica) for solutions purposes. Entropy generation, concentration, velocity, Bejan number and temperature are plotted as functions of the involved physical parameters. It is noticed that higher Marangoni number intensify velocity however it causes a decrease in the temperature. Entropy rate and Bejan number boost for large value of diffusion parameter.

Temperature variability and metabolic adaptation in terrestrial and aquatic ectotherms

Thermodynamics is a major factor determining rates of energy expenditure, rates of biochemical dynamics, and ultimately the biological and ecological processes linked with resilience to global warming in ectothermic organisms. Nonetheless, whether ectothermic organisms exhibit general adaptive metabolic responses to cope with worldwide variation in thermal conditions has remained as an open question. Here we combine a model comparison approach with a global dataset of standard metabolic rates (SMR), including 1,160 measurements across 788 species of aquatic invertebrates, insects, fishes, amphibians and reptiles, to investigate the association between metabolic rates and environmental temperatures in their respective habitats. Our analyses suggest that variation in SMR after removing allometric and thermodynamic effects is best explained by the temperature range encountered across seasons, which always provided a better fit than the average temperature for the hottest and coldest month and mean annual temperatures. This pattern was consistent across taxonomic groups and robust to sensitivity analyses. Nonetheless, aquatic and terrestrial lineages responded differently to seasonality, with SMR declining – 6.8% °C−1 of thermal range across seasons in aquatic organisms and increasing 2.8% °C−1 in terrestrial organisms. These responses may reflect alternative strategies to mitigate the impact of increments in warmer temperatures on energy expenditure, either by means of metabolic reduction in thermally homogeneous water bodies or effective behavioral thermoregulation to exploit temperature heterogeneity on land.

Dynamically screened strongly quantized electron transport in binary neutron-star merger

We examine electron-transport coefficients in magnetized hot and dense electron-ion plasma relevant in binary neutron star merger simulation. We calculate electrical and thermal conductivities in low density, high temperature, highly magnetized plasma of binary neutron star mergers where quantum oscillatory behavior of electrons emerge. For pronounced thermodynamic effects, we consider zeroth Landau level population of electrons for the calculation of conductivity. We solve Boltzmann equation in presence of magnetic field to obtain the dissipative components of electrical and thermal conductivities. The dissipative coefficients are formulated considering frequency dependent dynamical screening in the quantized electron-ion scattering rate. Numerical estimations show that the effect of dynamical screening of photon propagator on electrical and thermal conductivities is pronounced. We observe that dynamical screening reduces the maxima of both the electrical and thermal conductivities by factors of thirty one and twenty respectively leading to a reduction in the corresponding time scales of these coefficients. The common scaling factor between electrical and thermal conductivity is also observed to follow cubic relationship with temperature violating Wiedemann–Franz law.

Balanced mitochondrial function at low temperature is linked to cold adaptation in Drosophila species.

The ability of ectothermic animals to live in different thermal environments is closely associated with their capacity to maintain physiological homeostasis across diurnal and seasonal temperature fluctuations. For chill-susceptible insects, such as Drosophila, cold tolerance is tightly linked to ion and water homeostasis obtained through a regulated balance of active and passive transport. Active transport at low temperature requires a constant delivery of ATP and we therefore hypothesize that cold-adapted Drosophila are characterized by superior mitochondrial capacity at low temperature relative to cold-sensitive species. To address this, we investigated how experimental temperatures from 1 to 19 °C affected mitochondrial substrate oxidation in flight muscle of seven Drosophila species and compared it to a measure of species cold tolerance (CTmin, the temperature inducing cold coma). Mitochondrial oxygen consumption rates measured using a substrate-uncoupler-inhibitor-titration (SUIT) protocol showed that cooling generally reduced oxygen consumption of the electron transport system across species, as was expected due to thermodynamic effects. Complex I is the primary consumer of oxygen at non-stressful temperatures, but low temperature decreases complex I respiration to a much greater extent in cold-sensitive species than in cold-adapted species. Accordingly, cold-induced reduction of complex I correlates strongly with CTmin. The relative contribution of other substrates (proline, succinate and glycerol-3-phosphate) increased as temperature decreased, particularly in the cold-sensitive species. At present, it is unclear whether the oxidation of alternative substrates can be used to offset the effects of the temperature-sensitive complex I, and the potential functional consequences of such a substrate switch are discussed.