The steady thermocapillary migration of a drop, in the presence of a stagnant cap of an insoluble nondiffusing surfactant, is treated theoretically. Gravitational effects are included for completeness, and analytical solutions are obtained under conditions of negligible convective transport of momentum and energy in the bulk phases. The migration velocity of the drop is calculated, and is found to reduce to the proper asymptotes in limiting cases. Typical streamline plots as well as interfacial velocity distributions are displayed. The distribution of surfactant concentration in the cap region is obtained using an ideal film model, and the conditions for the existence of the cap are discussed.
Read full abstract