We studied the signal from a thermionic diode when a femtosecond laser beam was spatially overlapped by an excimer pumped dye laser beam. The nanosecond dye laser was scanned from 435 to 438nm in order to excite the autoionizing levels of barium by two photon absorption. The broadband ultrashort laser light was centered at 427nm, which is also above the first ionization limit of barium. The bias voltage between the cell body and the tungsten rod (set at either 9 or 0V) was used to collect electrons after the barium ions had been created by multiphoton (auto) ionization. The overall background of the thermionic signal was appreciably elevated due to the two photon ionization by the broadband femtosecond laser. We measured the thermionic signal with and without femtosecond laser overlap, and with a biasless and biased thermionic diode. The effect of the femtosecond laser was appreciable enhancement of the background ionization continuum. This was especially visible in the presence of noble gases at pressure of 50mbar. Argon produced the largest and helium produced the smallest enhancement in the background continuum. In addition, we observed a few broad spectral features of a presumably collision induced nature.