Thermal Storage Research Articles

A Novel Liquid–Solid Fluidized Bed of Large-Scale Phase-Changing Sphere for Thermal Energy Storage

The storage of thermal energy has been hindered by the low heat-transfer rate of the solid phase of the phase-changing materiel. With water being the heat-transfer fluid as well as the liquid phase in the liquid–solid two-phase system, a novel type of fluidized bed is designed in this study. Numerous hollow spheres are fabricated with phase-changing materiel encapsulated. Adding the solid–liquid phase-change material capsules to the flowing fluid, the capsules are dispersed suspended in the carrier. The large spheres, 25 mm in present experiment, possess the merits of guaranteeing energy-storage density and tolerating internal interface chaotic motion. Both the fluidization status and phase-changing process are recorded by photography combined with image-processing technology. It is found that the large spheres, with density less than water, can be fluidized by the downward flowing fluid. As the flow rate increases, the expansion ratio of the solid phase increases and the regimes of incipient fluidization and bubbling fluidization can be observed. In comparison to the fixed bed, the oscillation of pressure drop across a fluidized bed is more severe, but the averaged value is less than the fixed bed. The melting and solidifying can be accelerated by 22.6% and 50%, respectively, thus proving the superiority of the fluidized bed in improving the heat-transfer rate while charging/discharging the thermal energy. Three types of basic movement of the spheres are shown to contribute to the enhanced phase-changing rate, which are shifting, colliding and rotating.

Asymmetric Aramid Aerogel Composite with Durable and Covert Thermal Management via Janus Heat Transfer Structure.

Warmth preservation in cold climates requires a long-term heat supply. Conventional thermal devices usually deliver excessive heat and have difficulty preventing heat loss. Herein, to achieve durable thermal comfort, an asymmetric composite (AAAC) is devised through vacuum-filtrating silver nanowires (AgNWs) onto the surface of a poly(ethylene glycol) (PEG)-infiltrated aramid nanofiber aerogel. AgNW e-skin can transfer strong Joule heat to the back side of the AAAC, where the infused PEG further stores thermal energy by phase transition and then releases it to the body constantly after the power is off. Base on the Janus structure, the AAAC can provide thermotherapy for human waists and knees, holding a suitable temperature range of 37-39 °C for 5-8 min without a heat source. In addition, low infrared emissivity (0.064-0.315) of e-skin allows the AAAC to conceal thermal targets while producing Joule heat, which achieves comfortable and safe thermal management in multiple occasions including daily life and military warfare.

Experimental and Simulation Study on Enhancing Thermal Energy Storage and Heat Transfer Performance of Ternary Chloride Eutectic Salt by Doping MgO Nanoparticles

Experimental and Simulation Study on Enhancing Thermal Energy Storage and Heat Transfer Performance of Ternary Chloride Eutectic Salt by Doping MgO Nanoparticles

A Review on the Effective Utilization of Organic Phase Change Materials for Energy Efficiency in Buildings

Energy efficiency is critical for achieving building sustainability because it means that fewer resources are consumed. In this context, the advancement of phase-changing materials has attracted attention with regard to the integration and management of energy efficiency in construction projects. Buildings consume 40% of the global energy output annually, accounting for one-third of the global greenhouse gas emissions. For hot weather-prone construction, PCMs should have a melting temperature of 25–50 °C. For more than 30 years, researchers worldwide have experimented with PCMs at various temperatures, but few studies have been conducted in hot or harsh environments. According to recent studies, the amount of PCMs in construction materials has been limited to 20%, and exceeding this ratio was shown to significantly affect the compressive strength of concrete specimens. In this study, various phase-changing concrete materials were investigated to reduce the thermal energy consumption of buildings. This paper aims to provide an overview of the current state-of-the-art phase change materials for constructing thermal energy storage building materials. It also includes a brief review of the most recent developments in phase change technologies and their encapsulation techniques based on thermophysical properties. Implementing PCM technology in buildings will also maintain good indoor air quality. These materials are widely used in various real-time applications to significantly enhance thermal comfort in buildings.

Optimisation of Integrated Heat Pump and Thermal Energy Storage Systems in Active Buildings for Community Heat Decarbonisation

The electrification of residential heating systems, crucial for achieving net-zero emissions, poses significant challenges for low-voltage distribution networks. This study develops a simulation model to explore the integration of heat pumps within active building systems for community heating decarbonisation. The model optimises heat pump operations in conjunction with thermal energy storage units to reduce peak demand on low-voltage networks by using real-time measured electricity demand data and modelled heat demand data for 76 houses. The study employs an algorithm that adjusts thermal storage charging and discharging cycles to align with off-peak periods. Three scenarios were simulated: a baseline with unoptimised heat pumps, a fixed threshold model, and an active building model with daily optimised thresholds. The results demonstrate that the active building model achieves a 21% reduction in peak demand on the low-voltage substation compared to the baseline scenario; it also reduces the total electrical energy consumption by 12% and carbon emissions by 17%. The fixed threshold scenario shows a 16% improvement in peak demand reduction, but it also shows an increase in energy consumption and emissions. These findings highlight the potential of active buildings to enhance the efficiency and sustainability of residential energy systems, marking a significant step toward decarbonising residential heating while maintaining grid stability.

Improving the charging performance of latent heat thermal energy storage systems using triply periodic minimal surface (TPMS) structures

The utilization of latent heat thermal energy storage (LHTES) using phase change materials (PCM) has attracted considerable attention due to their high energy density and thermal regulation. However, the inferior thermal conductivity of PCM has hindered their widespread implementation, triply periodic minimal surface (TPMS) structures could considerably ameliorate the energy storage utilization. TPMS structures offer escalated surface area and pore interconnectivity, which can enhance the apparent thermal conductivity and improve the performance of LHTES systems. This study focuses on investigating the performance and storage capabilities of three unique TPMS structures, namely Gyroid, IWP, and Primitive, at different relative densities and charging temperatures. The computational model is developed, verified, and validated with the relevant experiment results. A comparative analysis of the temperature distribution and liquid fraction evolution in TPMS LHTES units is carried out and compared to pure PCM LHTES. At a charging temperature of 80 °C, compared to the complete melting time of 7206 s for the pure PCM LHTES, the results demonstrate that the G10, IWP10, and P10-PCM LHTES achieve complete melting at 344 s, 276 s, and 368 s, respectively. This affirms the superiority of IWP structures in improving the melting rates due to their escalated surface areas and tortuous paths. The use of TPMS structures improves the total heat storage, heat storage rate, and volumetric heat storage density, while reducing the gravimetric heat storage density, compared to the pure PCM LHTES. The G10-PCM LHTES attains total heat storage, heat storage rate, volumetric, and gravimetric heat storage density of 2120 J, 6.16 W, 63.6 kWh/m3, and 227 kJ/kg, compared to 1910 J, 0.27 W, 57.3 kWh/m3, and 250 kJ/kg for pure PCM LHTES, respectively. Moreover, increasing the relative density of TPMS structures adversely reduces the total heat storage, heat storage rate, and volumetric heat storage density, and significantly increases the heat storage rates. As the charging temperature increases, the complete melting time is reduced and the charging performance indicators are improved, for the pure PCM and TPMS-PCM LHTES units.

Melting and solidification in periodically modulated thermal convection

Melting and solidification in periodically time-modulated thermal convection are relevant for numerous natural and engineering systems, for example, glacial melting under periodic sun radiation and latent thermal energy storage under periodically pulsating heating. It is highly relevant for the estimation of melt rate and melt efficiency management. However, even the dynamics of a solid–liquid interface shape subjected to a simple sinusoidal heating has not yet been investigated in detail. In this paper, we offer a better understanding of the modulation frequency dependence of the melting and solidification front. We numerically investigate periodic melting and solidification in turbulent convective flow with the solid above and the melted liquid below, and sinusoidal heating at the bottom plate with the mean temperature equal to the melting temperature. We investigate how the periodic heating can prevent the full solidification, and the resulting flow structures and the quasi-equilibrium interface height. We further study the dependence on the heating modulation frequency. As the frequency decreases, we found two distinct regimes, which are ‘partially solid’ and ‘fully solid’. In the fully solid regime, the liquid freezes completely, and the effect of the modulation is limited. In the partially solid regime, the solid partially melts, and a steady or unsteady solid–liquid interface forms depending on the frequency. The interface height can be derived based on the energy balance through the interface. In the partially solid regime, the interface height oscillates periodically, following the frequency of modulation. Here, we propose a perturbation approach that can predict the dependency of the oscillation amplitude on the modulation frequency.

The Regulation of Temperature Fluctuations and Energy Consumption in Buildings Using Phase Change Material–Gypsum Boards in Summer

This study examined the thermal performance of Comfortboard23, a commercial gypsum board from Knauf infused with phase change material (PCM). Structural characterization using XRD and SEM confirmed the presence of microencapsulated PCM within the gypsum matrix. The study does not provide a direct comparison between Comfortboard23 and other PCM-integrated gypsum boards on the market. This is a limitation of the research. A comprehensive comparison would involve testing multiple products under identical conditions, and evaluating factors such as thermal performance, cost-effectiveness, durability, and ease of installation. Thermal characterization involved a novel low-scale thermal chamber to measure U-value, thermal conductivity, heat storage capacity, and dynamic thermal response. Results showed incorporating PCM decreased the U-value by 2% compared to standard gypsum boards. Additionally, PCM inclusion increased heat storage capacity by around 45% and improved dynamic thermal characteristics by decreasing thermal stability coefficient from 0.92 to 0.76 and increasing thermal lag from 0.27 to 0.49 h. The 45% increase in heat storage capacity of Comfortboard23 could lead to a 10–20% reduction in heating and cooling energy consumption, improved thermal comfort, and potential HVAC downsizing. Exact benefits depend on climate, building design, and occupancy patterns, necessitating further research in diverse real-world settings. The findings demonstrate Comfortboard23’s potential for enhancing thermal energy storage in buildings, contributing to energy savings, improved thermal comfort, and reduced temperature fluctuations across varying daily temperatures. Overall, the study highlights the promise of Comfortboard23 as an energy-efficient PCM-integrated building material.

Research on performance and potential of distributed heating system for peak shaving with multi-energy resource

Climate change and its negative effects are driving the global shift from fossil fuels to renewable energy sources. To tackle the dependency on traditional energy sources in harsh winter regions and improve heating quality during periods of thermal demand fluctuations, this paper proposes a new distributed heating peak shaving system (DHPS). The system combines municipal heat and clean energy within the secondary network while reducing the return water temperature in the primary network. It comprises solar collectors, electric thermal storage tanks (ETST), and absorption heat pump (AHP) units, integrated into conventional heat exchange stations. The system operates in two modes to manage peak and off-peak loads respectively, with TRNSYS simulation used to evaluate performance across a range of peak-shaving gradients. A multidimensional comprehensive assessment is conducted between the DHPS under optimal peak shaving coefficient (θ) conditions and conventional peak clipping boiler (PCB). Results indicate that DHPS achieves a high primary energy ratio (PER) of 1.251 at θ = 0.5, reducing combustion emissions by nearly 40%. The static payback period (PBP) of the system is 3.5 years. When the electricity price drops to 0.275 CNY, its operational costs are comparable to PCB. DHPS caters to the energy characteristics of cold regions where electricity supply exceeds demand. It enables flexible peak shaving while ensuring the complete utilization of clean energy and effectively utilizing waste heat from power plants.

Study on the thermal storage properties of a spiral tube heat storage tank based on numerical analysis

IntroductionThe spiral tube heat storage tank is a highly efficient device designed for storing and releasing heat, utilizing a spiral tube structure. Its key advantages include efficiency, reliability, and flexibility, making it suitable for a wide range of conditions, from high temperatures and pressures to low temperatures and high vacuums.MethodsThis study aims to analyze phase change heat storage in spiral tube heat storage tanks using numerical simulation.ResultsIt explores the impact of varying water supply temperatures on heat transfer efficiency and the melting behavior of phase change materials within the tanks. Proposed enhancements, informed by numerical simulation results, seek to improve heat transfer efficiency. Simulation findings indicate that charging efficiency rises with increased temperature differentials, akin to sleeve-type heat exchangers.DiscussionCalculations suggest faster melting of phase change materials at the central position of the tank’s spiral tube, with slower melting near the vessel wall. Consequently, reducing the number of spiral tubes in the middle is suggested for future structural optimization.

Experimental and numerical investigations on phase change thermal storage foam concrete based on CaCl2∙6H2O/silica aerogel composite phase change material

A new type of phase change thermal storage foam concrete was developed by effectively incorporating a composite phase change material (CPCM) into foam concrete. The CPCM was obtained by using 75 wt% CaCl2∙6H2O as PCM and 25 wt% silica aerogel as carrier, with a phase change temperature of 27.0 °C and an enthalpy value of 110.9 J/g. The mechanical and thermal properties of the obtained phase change thermal storage foam concrete blocks were investigated experimentally, along with a numerical analysis of their heat transfer characteristics. The experimental results demonstrated that after adding CPCM, the thermal performances of foam concrete blocks significantly increased, under the condition of their dry densities and compressive strengths met the specification requirements. Adding 20 wt% CPCM, the enthalpy value, specific heat capacity, thermal conductivity and thermal inertia of foam concrete block respectively reached 37.0 J/g, 1782.0 J/(kg∙K), 0.131 W/(m·K) and 770.9, with appropriate phase change temperature (27.2 °C). Numerical analysis for the heat transfer characteristics of the phase change thermal storage foam concrete wall revealed that optimal thermal insulation and thermal storage performances were achieved when the wall contained 20 wt% CPCM and thickness of 80 mm. In this case, the model exhibited a temperature wave attenuation factor of 6.66, the temperature amplitude of 5.84 K and a decline of 9.87 K for the highest temperature of the wall as well as delay time of 198,000 s, effectively regulating indoor temperature and saving energy. Therefore, the as-prepared phase change thermal storage foam concrete had great potential for application in building energy conservation.

Investigating the Effects of PCM-Integrated Walls on Thermal Performance for UK Residential Buildings of Different Typologies

Phase change materials (PCMs) can improve the thermal performance of building facades. The integration position of a PCM in the facades is influenced by multiple factors including the material properties of the PCM, building types, and the internal and external conditions of a building. However, this has not been a focus within the UK dwelling stock, where many dwellings are not thermally protected. This paper, therefore, presents a numerical study with the aid of building simulation that comparatively analysed the thermal performance between four typical UK dwelling types (semi-detached house, terraced house, detached house, and apartment) situated in North East England. The PCM was implemented into the external wall of the dwellings with the positions altered to determine the most effective position. It was determined that the PCM positioned internally was the most effective for all the dwelling types. These results demonstrated that the PCM being implemented in the apartment, semi-detached, and terraced houses had only marginal heat loss reductions (by 8%, 14%, and 8%, respectively) in comparison with that of the detached house (by 30%). It was also found that the large external wall area of the detached house acted as significant thermal energy storage, which was capable of offsetting heat transmission and stabilising indoor thermal conditions. In summary, this paper contributes to the matters concerning the effect of PCMs on indoor thermal performance in dwellings of different typologies in the UK.

Recent Progress on Thermal Energy Storage for Coal-Fired Power Plant

Recent Progress on Thermal Energy Storage for Coal-Fired Power Plant

Understanding photo-thermal and melting mechanisms in optical charging of nano and micro particles laden organic PCMs

Engineering efficient optical charging process necessitates efficient photo-thermal energy conversion, transfer, as well as storage of the incident solar radiant energy. The present work is a determining step in deciphering, quantifying, and understanding the aforementioned steps involved in the optical charging of PCMs. Herein, the effect of particle size, concentration and thermochromism have been critically investigated. In particular, detailed optical characterization and photo-thermal experimentation pertinent to non-thermochromic nanoparticles laden PCM (referred to as NP-PCM) and thermochromic micro capsules laden PCM (referred to as TMCP-PCM) has been undertaken. Detailed optical analysis points out that opposed to NP-PCM, TMCP-PCM significantly scatter the incident radiations – the diffuse transmittance (at room temperature) in the two cases being approximately 2 % and 39 % respectively. Furthermore, whereas, optical properties of non-thermochromic nanoparticles are nearly invariant to temperature changes; in the case of thermochromic microcapsules, the magnitude of scattering further increases and diffuse transmittance reaches as high as 51 % at elevated temperatures. Although, thermochromism helps in enhancing the penetration depth at elevated temperatures, but, due to significant fraction of scattering, the photo-thermal energy conversion is not that effective. In terms of temperature field, spatial-temporal temperature distribution curves reveal that temperature spread (in the liquid phase) in case of optical charging of non-thermochromic particles (carbon soot nanoparticles) laden PCMs is significantly high (as high as approximately 24 °C) relative to that observed in case of thermochromic particles (microcapsules) laden PCMs (approximately, 4 °C). The magnitude of the temperature spread (being representative of the deviation from thermostatic optical charging) clearly points out that opposed to non-thermochromic laden PCMs, nearly thermostatic optical charging can be achieved in case of thermochromic particles laden PCMs.Furthermore, in case of optical charging without thermochromic assistance, the temperature spread, peak temperatures and the melting rates increase with increase in particles concentration. Whereas, in the latter case, although the temperature spread and peak temperatures are nearly independent; the melting rates do depend on the particles’ concentration. Overall, the present work is a significant step towards accelerated-thermostatic thermal energy storage.

Techno-Economic Comparative Assessment of High Temperature Heat Pump Architectures for Industrial Pumped Thermal Energy Storage

Abstract The industrial sector is a key global source of wealth, but it is also recognized as a major challenge toward worldwide decarbonization. Today the industrial sector requires more than 22 % of the global energy demand as thermal energy and produces for this about 40 % of the total CO2 emissions. Solutions to efficiently decarbonize the industrial sector are deemed. This work presents a comparative techno-economic performance assessment of a high temperature heat pump integration within a molten salts based power to heat system for industrial heat flexible generation. The main system performance is reported in terms of required working conditions and temperature for the heat pump and thermal demand size as well as reduction of the attainable levelized cost of heat (LCoH) against non-flexible electric boiler based systems. The impact of different industrial load profiles, electricity prices, heat pump capital cost and heat pump real to Carnot efficiency ratio are also presented. The results highlight that the proposed system can be cost-competitive, particularly for thermal demand around 10 MW and waste heat temperatures above 80°C. Under these conditions LCoH reductions higher than 15 %, with respect to the considered non-flexible electric boiler alternative, are attainable. These LCoH reductions are primarily driven by savings in electrical consumption as high as 30 %. This study sets the ground for further power-to-heat techno-economic investigations addressing different industrial sectors and identifies main system and components design strategies, integrations, and targets.

Solar-enhanced DCMD: dual-tank system for superior efficiency and viability

ABSTRACT This study investigates a novel solar-powered direct contact membrane distillation (DCMD) system designed to significantly enhance desalination efficiency and economic feasibility. The system features a dual-tank configuration integrated with a solar collector, which optimizes thermal energy storage and ensures consistent feedwater temperatures. Therefore, continuous operation is possible despite fluctuations in solar radiation. An assessment of the system's performance under various solar radiation conditions predicted an average daily permeate flux of 14.4 kg/m2 and a specific energy consumption of 1810 kJ/kg, indicating superior thermal efficiency. The economic analysis revealed a competitive levelized water cost of $25.75 per cubic meter, highlighting the system's potential as a viable alternative to conventional desalination technologies. These findings suggest that the proposed DCMD system is a leading technology in the pursuit of sustainable desalination. Considering its thermal management and cost-effectiveness, the system presents a transformative solution for sustainable freshwater production in regions with abundant solar resources.

Solutions and case studies for thermally driven reactive transport and porosity evolution in geothermal systems (reactive Lauwerier problem)

Abstract. Subsurface non-isothermal fluid injection is a ubiquitous scenario in energy and water resource applications, which can lead to geochemical disequilibrium and thermally driven solubility changes and reactions. Depending on the nature of the solubility of a mineral, the thermal change can lead to either mineral dissolution or precipitation (due to undersaturation or supersaturation conditions). Here, by considering this thermo-hydro-chemical (THC) scenario and by calculating the temperature-dependent solubility using a non-isothermal solution (the so-called Lauwerier solution), thermally driven reactive transport solutions are derived for a confined aquifer. The coupled solutions, hereafter termed the “reactive Lauwerier problem”, are developed for axisymmetric and Cartesian symmetries and additionally provide the porosity evolution in the aquifer. The solutions are then used to study two common cases: (I) hot CO2-rich water injection into a carbonate aquifer and (II) hot silica-rich water injection into a sandstone aquifer, leading to mineral dissolution and precipitation, respectively. We discuss the timescales of such fluid–rock interactions and the changes in hydraulic system properties. The solutions and findings contribute to the understanding and management of subsurface energy and water resources, such as aquifer thermal energy storage, aquifer storage and recovery and reinjection of used geothermal water. The solutions are also useful for developing and benchmarking complex coupled numerical codes.

Study on Phase Change Materials’ Heat Transfer Characteristics of Medium Temperature Solar Energy Collection System

Within the next five years, renewable energy is expected to account for approximately 80% of the new global power generation capacity, with solar power contributing to more than half of this growth. However, the intermittent nature of solar energy remains a significant challenge to fully realizing its potential. Thus, efficient energy storage is crucial for optimizing the effectiveness and dependability of renewable energy. Phase-change materials (PCMs) can play an important role in solar energy storage due to their low cost and high volumetric energy storage density. The low thermal conductivity of PCMs restricts their use for energy storage, despite their immense potential. Hence, the primary goal of this study is to experimentally investigate the energy storage capacity of two blended phase-change materials (paraffin and barium hydroxide octahydrate) through integration with a medium-temperature solar heat collection system. The experimental findings reveal that the blended PCMs possess the highest cumulative charge fraction (0.59), energy capacity, and low energy loss compared to each PCM alone. Furthermore, the phase change storage tank achieves higher heat storage (27%) and exergy storage efficiency (18%) compared to the stored tank water without any PCMs. The blended PCMs enhanced their performance, exhibiting improved interaction and excellent thermal storage properties across a range of temperatures, offering an opportunity for the design of an energy-efficient, low-cost storage system.

Study on the heat transfer performance of coaxial casing heat exchanger for medium and deep geothermal energy in cold regions

To accurately assess the heat transfer performance of a medium-depth coaxial casing heat exchanger, this study introduced the concepts of the annual stabilized mining stage and the effective thermal influence distance for each layer of non-homogeneous thermal storage. The study area was stratified into six layers based on the geothermal temperature gradient fitting results. The findings revealed that the maximum injected circulating fluid temperature for the mid-depth coaxial casing geothermal system was 37 °C, with a maximum mass flow rate of 16.67 kg/s. When the injected circulating fluid temperature increased from 2 °C to 25 °C, the duration of the annual stabilized exploitation stage extended from 23 to 26 years. Similarly, increasing the injected circulating fluid mass flow rate from 2.78 kg/s to 16.67 kg/s prolonged the maintenance period in the annual stable mining stage from 22 to 28 years. The study further indicated that the effective thermal influence distance for each layer of thermal storage was significantly impacted by varying injection circulating fluid temperatures. These results offered theoretical insights into the heat transfer performance of medium-depth coaxial casing geothermal systems under both short- and long-term operational conditions.

Numerical Investigation of Solar Collector Performance with Encapsulated PCM: A Transient, 3D Approach

This study presents a comprehensive numerical investigation into the thermal performance of solar collectors integrated with encapsulated phase change materials (PCMs) using a transient three-dimensional (3D) approach. The performance of two distinct PCMs—paraffin wax and RT60—was evaluated under varying operational conditions, including seasonal variations, inlet pipe velocities, and inlet temperatures. The results indicate that paraffin wax exhibits a higher peak temperature, reaching approximately 360 K, compared to RT60’s peak of 345 K, making paraffin wax more effective for consistent thermal energy storage. Paraffin wax also maintained higher fluid fractions, with a maximum of 0.9 in summer, indicating superior heat absorption and retention capabilities. In contrast, RT60 demonstrated a quicker phase transition, fully liquefying at a lower fluid fraction, which is advantageous for rapid heat release. Seasonal variations significantly impacted system efficiency, with the highest efficiency observed in June at 365 K and the lowest in December at 340 K. The study also found that lower inlet velocities (e.g., 0.25 L/s) significantly improved heat retention, resulting in higher outlet temperatures, while increasing the inlet temperature from 290 K to 310 K led to a marked increase in outlet temperatures throughout the day. These findings underscore the importance of optimizing PCM selection, inlet velocity, and temperature in enhancing the performance of solar thermal systems, offering quantitative insights that contribute to the development of more efficient and reliable renewable energy solutions.