Thermal Response Research Articles

The Effects of Microcrystalline Cellulose Addition on the Properties of Wood-PLA Filaments for 3D Printing.

This paper describes the use of microcrystalline cellulose (MCC) as an additive in wood-polylactic acid (PLA) filaments suitable for 3D printing. Filaments prepared with PLA, thermally modified (TM) wood, and three different MCC loadings (1, 3, and 5 wt%) by two-step melt blending in the extruder were characterized with respect to their rheological, thermal, and mechanical response. The analyses demonstrate that a low MCC content (1%) improves the mobility of the polymer chains and contributes to a higher elasticity of the matrix chain, a higher crystallinity, a lower glass transition temperature (by 1.66 °C), and a lower melting temperature (by 1.31 °C) and leads to a higher tensile strength (1.2%) and a higher modulus of elasticity (12.1%). Higher MCC loading hinders the mobility of the polymer matrix and leads to a rearrangement of the crystal lattice structure, resulting in a decrease in crystallinity. Scanning electron micrographs show that the cellulose is well distributed and dispersed in the PLA matrix, with some agglomeration occurring at higher MCC levels. The main objective of this study was to develop and evaluate a filament containing an optimal amount of MCC to improve compatibility between wood and PLA, optimize melt processability, and improve mechanical properties. It can be concluded that a 1% addition of MCC favorably changes the properties of the wood-PLA filaments, while a higher MCC content does not have this effect.

Modelling and onsite testing on dynamic thermal responses of built environment in passive solar rooms on Tibetan plateau

It of great importance in assessing built thermal environment level and evaluating corresponding indoor air conditioning demand for energy conservation in construction sectors. Nevertheless, because of the unique meteorological features in plateau area, classical building performance simulation approach contributes to thermal performance evaluation errors since most design codes or standards relies on low attitude regions. In this paper, a modified and improved dynamic thermal design model is put forward for built environment and energy consumption estimation for passive buildings for plateau buildings. Moreover, the simplified experiment is set up to monitor dynamic thermal responses for modelling building. The testing validation illustrate that the onsite measurement accuracy level is quite acceptable for engineering applications with less than 30% relative change range coefficient. Besides, the experiment data demonstrates that window-to-wall ratios, architectural orientation, thermal insulation coefficients, have substantial impacts for solar heat gains in plateau buildings. The study renders building design guidance for energy conservation in high altitude plateau areas.

Impact of 3D air gap eccentricity on winding insulation temperature characteristic in PMSG

The static air gap eccentricity is one of the prevalent faults in permanent magnet synchronous generators. In previous studies, the variation of magnetic flux density, stator current and vibration have been studied mostly. However, the temperature characteristic of winding insulation under 3D static air gap eccentricity fault is rarely investigated. As a supplement, this paper comprehensively analyzes the influence of radial static air gap eccentricity, axial static air gap eccentricity and the combined static air gap eccentricity (radial static air gap eccentricity and axial static air gap eccentricity) fault on the winding insulation thermal response. The whole work is based on not only the loss of core and windings but also the temperature rise of the winding insulation, which is carried out through theoretical analysis, finite element calculation, and experiment verification. It is shown that radial static air gap eccentricity will increase the winding insulation temperature whatever in singe radial static air gap eccentricity or combined static air gap eccentricity, while axial static air gap eccentricity has the opposite effect. Specifically, the winding insulation temperature in radial static air gap eccentricity 0.1 mm, 0.2 mm and 0.3 mm cases are 57.18℃, 59.10℃ and 61.04℃, respectively, which is 3.29℃, 5.21℃ and 7.15℃ higher than that under normal condition. However, under axial static air gap eccentricity, winding insulation temperature will decrease by 1.84℃, 4.11℃ and 5.9℃, respectively. When axial static air gap eccentricity is unchanged and radial static air gap eccentricity is increased, the winding insulation temperature will increase by 1.5℃ and 3.23℃, respectively. On the contrary, when radial static air gap eccentricity is unchanged and axial static air gap eccentricity increases, the winding insulation temperature decreases by 2.54℃ and 5.66℃, respectively. The end part and the join between the end and line parts of the winding insulation are the most dangerous positions to suffer from static thermal wear.

Adaptive responses of erythritol-producing Yarrowia lipolytica to thermal stress after evolution

Elucidation of the thermotolerance mechanism of erythritol-producing Yarrowia lipolytica is of great significance to breed robust industrial strains and reduce cost. This study aimed to breed thermotolerant Y. lipolytica and investigate the mechanism underlying the thermotolerant phenotype. Yarrowia lipolytica HT34, Yarrowia lipolytica HT36, and Yarrowia lipolytica HT385 that were capable of growing at 34 °C, 36 °C, and 38.5 °C, respectively, were obtained within 150 days (352 generations) by adaptive laboratory evolution (ALE) integrated with 60Co-γ radiation and ultraviolet ray radiation. Comparative genomics analysis showed that genes involved in signal transduction, transcription, and translation regulation were mutated during adaptive evolution. Further, we demonstrated that thermal stress increased the expression of genes related to DNA replication and repair, ceramide and steroid synthesis, and the degradation of branched amino acid (BCAA) and free fatty acid (FFA), while inhibiting the expression of genes involved in glycolysis and the citrate cycle. Erythritol production in thermotolerant strains was remarkably inhibited, which might result from the differential expression of genes involved in erythritol metabolism. Exogenous addition of BCAA and soybean oil promoted the growth of HT385, highlighting the importance of BCAA and FFA in thermal stress response. Additionally, overexpression of 11 out of the 18 upregulated genes individually enabled Yarrowia lipolytica CA20 to grow at 34 °C, of which genes A000121, A003183, and A005690 had a better effect. Collectively, this study provides novel insights into the adaptation mechanism of Y. lipolytica to thermal stress, which will be conducive to the construction of thermotolerant erythritol-producing strains.Key points• ALE combined with mutagenesis is efficient for breeding thermotolerant Y. lipolytica• Genes encoding global regulators are mutated during thermal adaptive evolution• Ceramide and BCAA are critical molecules for cells to tolerate thermal stress

Estimation of Heat Production Rate using Thermal Data During Exercise in Indoor Environments: A Study of Heat Storage Rate in Male Athletes.

The increasing preference for indoor exercise spaces highlights the relationship between indoor thermal environments and physiological responses, particularly concerning thermal comfort during physical activity. Determining the metabolic heat production rate during exercise is essential for optimizing the thermal comfort, well-being, and performance of individuals engaged in physical activities. This value can be determined during the activity using several methods, including direct calorimetry measurement, indirect calorimetry that uses analysis of respiratory gases, or approximations using collected data such as speed, body mass, and heart rate. The study aimed to calculate the metabolic heat production rate by infrared thermal evaluation (ITE) based on the body's thermal balance approach and compare it with the values determined by indirect calorimetry (IC). Fourteen participants volunteered for the study, using a cycling ergometer in a controlled climatic chamber. After the familiarization sessions, maximal O2 intake levels (VO2max) were determined through maximal graded exercise tests. Subsequently, constant work rate exercise tests were performed at 60% of VO2max for 20min. The metabolic heat production rates were calculated by IC and ITE for each athlete individually. Respiratory gases were used to determine IC, while body skin and core temperatures, along with physical environmental data, were applied to calculate ITE using the human body thermal balance approximation of ASHRAE. According to the results, heat storage rates were misleading among the body's heat transfer modes, particularly during the first 8min of the exercise. ITE showed a moderate level of correlation with IC (r: 0.03-0.86) with a higher level of dispersion relative to the mean (CV%: 12-84%). Therefore, a new equation (ITEnew) for the heat storage rates was proposed using the experimental data from this study. The results showed that ITEnew provided more precise estimations for the entire exercise period (p > 0.05). Correlations between ITEnew and IC values were consistently strong throughout the exercise period (r: 0.62-0.85). It can be suggested that ITEnew values can predict IC during the constant work rate steady-state exercise.

Hall and viscous dissipation effects on mixed convective MHD heat absorbing flow due to an impulsively moving vertical porous plate with ramped surface temperature and concentration

AbstractThe current investigation is purported on viscous heating dissipation and Hall consequences on mixed convection magneto‐hydrodynamic heat captivating fluid transmitting from an impulsively starting vertical porous plate with ramp surface temperature and concentration in the existence of chemical reaction and radiation. The dimensional flow dominating partial differential equations is translated into a non‐dimensional partial differential form by adopting appropriate variables and parameters. A finite element approach is driven to simplify the resulting dimensionless nonlinear linked partial differential equations with initial and boundary stipulates. The after‐effects of flow commanding parameters on the velocity components, temperature and concentration are broadly analysed graphically, whereas both primary and secondary shear stresses, heat and mass transferral rates close to the surface area of the plate are discussed in tables. The ultimate results of this research revealed that viscous heating dissipation, Hall current, and thermal and mass buoyancy responses intensify both velocity components, whereas the efficacy of magnetic fields and radiation degrade both velocity components. The temperature distribution devalues with increasing heat absorption and Prandtl number, but a contrary impulse was noted with viscous heating dissipation. Likewise, concentration distribution expands with time progress but decays with chemical reaction parameters. A comparative analysis among the current results and certain research studies in the literature manifests the results’ precision and correctness.

Thermal Impedance Measurement of Thick-Film Resistor in High-Frequency Range Using Single-Detector IR System

This paper presents an innovative and simple method of high-frequency thermal impedance measurement using infrared (IR) technique. The method is based on the Fourier transformation of the input power signal and the thermal response of the object after supplying the heat source with square-wave current of different frequencies. The experiment was carried out using a single-detector, low-cost infrared system equipped with a photovoltaic detector module to measure the thermal impedance of an SMD thick-film resistor. Both the simulation using a compact thermal model and the measurement results are discussed.

How Elite Athletes with a Spinal Cord Injury Sweat during Exercise-An Exploratory Study.

Sweat and thermal responses in individuals with spinal cord injury (SCI) are impaired depending on lesion characteristics. This is particularly problematic for athletes and may ultimately lead to reduced performance. This exploratory study investigated the feasibility of field-usable methods to objectively collect data relevant to sweat response in elite athletes with SCI. Differences in sweat response were also evaluated for different athlete characteristics. Measurements were performed during exercise and included core temperature (Tc), heart rate, urine specific gravity, fluid intake, sweat rate, and sweat electrolyte concentration. Differences for sex, lesion level (tetraplegia versus paraplegia), motor impairment (complete versus incomplete), and sport type (endurance versus team/skill) were evaluated. Fifteen athletes (median (Q1-Q3) age, 30 (28-36) years; three females; 11 with complete lesions) were included. Endurance athletes were measured during indoor performance tests (n = 10), whereas team/skill athletes were measured during training sessions (n = 5). In the mixed exercise intensities, the average Tc was 37.7 (37.3-37.8) °C and the average heart rate was 126 (100-146) bpm. Dehydration, defined as a urine specific gravity > 1.020 ng/mL, was prevalent in six athletes before exercise and in five athletes after exercise. The sweat rate was lower in athletes with tetraplegia (p = 0.02) and in team/skill athletes (p = 0.008). Collecting sweat and thermal response data from athletes with SCI in the field is feasible. Given the suboptimal hydration status of many athletes, raising awareness of the importance of hydration seems valuable.

Thermometric properties of SrMoO4:Tb3+ phosphor based on redshift of charge transfer band edge

In this study, SrMoO4:Tb3+ phosphors were successfully synthesized for a single-band ratiometric (SBR) thermometry utilizing the redshift of CTB. The SrMoO4:Tb3+ phosphors have a tetragonal system owing to I41/a space group and irregular microparticles possessing a mean size of 20 μm. The incorporation of Tb3+ ions into the SrMoO4 matrix lattice leads to a reduction in the bandgap energy owing to occurrence of defects level in gap-band. Thermal quenching concentration of Tb3+ is 1%, due to the dipole-dipole interaction between Tb3+ and Tb3+ ions. This study observed an interesting redshift in the edge of the CTB with increasing temperature, which can be explained using the configurational coordinate diagram. This phenomenon can be utilized to construct this SBR temperature measurement strategy by selecting appropriate excitation peaks or bands with different thermal responses. The study also demonstrated that SrMoO4: 1%Tb3+ has higher Sa value of 13.31 × 10−2 K−1 @573 K and Sr value of 3.54 K-1@298 K in optical thermometry, making it a suitable candidate for optical temperature measurement.

Investigation of heat transfer in cracked gun barrels

Heat transfer process significantly affects the life span of gun barrels as it directly associates to the thermoelastic dynamic responses, erosion, and wears of gun barrels. The previous studies regarding the heat transfer in gun barrels were developed in the realm of local theory that is expressed by partial differential equations with the condition of smoothly distributed physical fields, and have rarely studied the cracked gun barrels. However, on one hand, due to manufacturing errors, there inherently exists fractures in realistic gun barrels; on the other hand, the inner wall of the gun barrel wears due to the high-temperature and -speed burning gas generated during the interior ballistic process, as well as the high-speed friction from projectile’s movement, which severely lead more cracks and damages. Therefore, it is of great importance to investigate the heat transfer in cracked gun barrels. In this paper, a non-local heat transfer model for cracked gun barrels is formulated via the bond-based peridynamics. The governing equation is presented in the manner of integration, such that the heat process with the influence of cracks can be readily captured. Numerical results show that the heat energy severely accumulates on the crack surface and as the size of horizon increases, the non-local characteristics of the heat transfer appear to be more pronounced, resulting in a stiffer thermal response.

Mechanical and thermal response of XFe2O4 (X = Zn, Ag and Co) spinel ferrites via IR-spectroscopy and first-principles calculations

The lack of comprehensive literature on the all-important aspect of the elasticity of spinel ferrites led to the hydrothermal synthesis of different (Co, Zn, Ag) spinel ferrites. IR spectroscopy revealed the characteristic absorption bands of metal-oxygen in all three compositions. The shifting of tetrahedral and octahedral bending vibrations towards higher frequencies owes to changes in inter-atomic and inter-ionic distances. Elastic parameters, wave velocities, and Debye temperature have been calculated using IR spectroscopy data. Elastic parameters have been higher for Co ferrites than Zn and Ag ferrites. The Poisson ratio seems to be consistent for different spinel ferrites. Shear wave velocity has been found to be higher than longitudinal wave velocity because perpendicular particle vibrations take higher energy than parallel vibrations. Wave velocities have been found to be higher in Ag ferrites than in the other two compositions. Debye temperature follows the same trend as elastic parameters. Additionally, we have confirmed the mechanical stability of the Co, Zn, and Ag ferrites using the first-principles calculations in the density functional theory (DFT) approach framework. Interestingly, the Co/Zn/Ag ferrites exhibit semiconducting nature with a band gap of 3.96/3.66/0.71 ev. Our study could pave the way for next-generation spintronic devices.

The Application of Bilayer Heterogeneous MOFs in pH and Heat-Triggered Systems for Controllable Fragrance Release.

To facilitate the integration of a fragrance encapsulation system into different products to achieve effective releases, a dual-responsive release system with pH and thermal trigger control is designed in this work. A series of ZIF-8 (M) and bilayer ZIF-8-on-ZIF-8 (MM) materials are synthesized by a solvent method at room temperature. The fragrance is encapsulated into the ZIFs by dynamic adsorption or in situ encapsulation combined dynamic adsorption. The fragrance loading contributed by dynamic adsorption was as high as 80%. The fragrance loaded in the double-layer MM host was almost twice that of the monolayer host M due to the stronger electrostatic interaction between MM and vanillin. In the pH and thermal trigger response release experiments, the second MOF layer in the MM host, as a controlled entity, greatly improved the load and kinetic equilibrium time of vanillin, and realized the controlled release of guest molecules. The developed dual-responsive release system in this work exhibits great potential in daily chemical products.

On the dynamic thermal conductivity and diffusivity observed in heat pulse experiments

Abstract Determining the thermal properties of materials with complex structures is still a major engineering challenge today. The well-known heat pulse experiment can be used to determine the thermal diffusivity by measuring the temperature history as a thermal response for a fast excitation. However, the evaluation of the measurements can be challenging, especially when dealing with non-homogeneous samples. The thermal behavior of such heterogeneous materials may exhibit a response including two-time scales. Therefore, the Fourier equation is not necessarily applicable. The simplest possible alternatives are the 2-temperature models the Guyer–Krumhansl and Jeffreys heat equations. In the present paper, we focus on the interpretation of the Jeffreys heat equation; studying its analytical solution, we present a fitting method for determining the unknown parameters. We also discuss its relation with the other two heat equations, and we offer an interpretation of how to characterize the transient response of heterogeneous materials.

Cell harvesting on robust smart thermosensitive pseudo-double networks prepared by one-step procedure

In this work, pseudo-double networks (pseudo-DN) based on N-vinyl caprolactam (VCL, major component, precursor of thermosensitive chains) and hexyl methacrylate (HMA, minor component, hydrophobic) have been prepared by using single step approach. The adjective pseudo refers to the fact that through the simultaneous copolymerization of VCL and HMA with different relative reaction kinetics, in the presence of an appropriate mixture of crosslinkers, networks with complex structures that tend towards DN-type structures are obtained. Hydrogels have been prepared with HMA/VCL molar ratios from 0 to 23.2 mol %. The series of hydrogels prepared show a composition-dependent behaviour in terms of thermosensitivity, swelling at temperatures below the Volume Phase Transition Temperature (VPTT) value, mechanical properties and performance during the cell culture experiments. More precisely, hydrogels with low percentages of HMA show elastic moduli under compression tests slightly lower than 1 MPa and presented a high thermal response (high swelling below the VPTT) allowing in addition the non-aggressive detachment of cell monolayer by controlled decrease of temperature. As the percentage of HMA increases, the elastic modulus increases, obtaining improved mechanical properties (reaching values in the range 1–3 MPa), thermosensitivity decreases (low swelling below VPTT) and a progressive delay in cell proliferation is also observed, being still cytocompatible. In this sense, hydrogels with low percentages of HMA (up 2.7 mol %) allow cell proliferation and transplantation similar to the control sample.

Feedforward decoupling control of indoor temperature and humidity using a single direct expansion air conditioning unit

Achieving simultaneous control over temperature and humidity through a single direct expansion air conditioner would be advantageous, especially considering its widespread use in residential buildings. Traditional control strategies fail to achieve satisfactory control performance due to the nature of complexity and cross-decoupling of the system. Therefore, this research paper presents the advancement of a feedforward decoupling control scheme designed for a direct expansion air conditioning unit to effectively control both temperature and humidity. To facilitate the controller design, a dynamic model considering both sensible and latent heat transfers was developed and verified. The thermal responses of the coupled system were analyzed and their correlation coefficients also examined. Through identifying the transfer function model of the coupled system, a feedforward decoupling controller with two compensators was designed. The proposed decoupling control scheme was tested using the developed model as the plant to be controlled. Test results showed that, in comparison to the transitional PID based dual single-input and single-output controller, the proposed decoupling control scheme was capable of eliminating the interactions between indoor air temperature and humidity under variable speed operation, and realizing the simultaneous control over indoor air temperature and humidity with a desirable control performance.

Stable self-crosslinking phase change composites with vertically aligned boron nitride for high thermal conductivity thermal interface materials

Thermal interface materials (TIMs) must have a high through-plane thermal conductivity in order to efficiently transfer the heat generated by electronic components to heat sinks. Nevertheless, the achievement of high through-plane thermal conductivity is still a great challenge due to the inadequate thermal conductivity network as well as the lack of thermal response from the polymer matrix. Herein, we have developed a solid-solid phase change polymer matrix achieved through self-crosslinking polyethylene glycol (SCPEG). Subsequently, high-performance TIMs based on the SCPEG matrix and vertically aligned boron nitride (BN) nanosheets are obtained by bidirectional freezing, hot pressing, and longitudinal slicing. The prepared BN/SCPEG composites (BN content of 80 vol%) with a vertically oriented network achieved a through-plane thermal conductivity of 23.03 W m-1 K-1. More importantly, the vertically aligned BN nanosheets improve the thermal conductivity of composites, while the SCPEG matrix can reduce the hardness of composites by absorbing the heat, thus decreasing the contact thermal resistance.

Development of Injectable Thermosensitive Nanocomposite Hydrogel for Ratiometric Drug Delivery to Treat Drug Resistant Chondrosarcoma In Vivo.

Chondrosarcoma(CS), a prevalent primary malignant bone tumor, frequently exhibits chemotherapy resistance attributed to upregulated anti-apoptosis pathways such as the Bcl-2 family. In this manuscript, a new strategy is presented to augment chemosensitivity and mitigate systemic toxicity by harnessing a nano-enabled drug delivery hydrogel platform. The platform utilizes "PLGA-PEG-PLGA", an amphiphilic triblock copolymer combining hydrophilic polyethylene glycol (PEG) and hydrophobic polylactide glycolide (PLGA) blocks, renowned for its properties conducive to crafting a biodegradable, temperature-sensitive hydrogel. This platform is tailored to encapsulate a ratiometrically designed dual-loaded liposomes containing a first-line chemo option for CS, Doxorubicin (Dox), plus a calculated amount of small molecule inhibitor for anti-apoptotic Bcl-2 pathway, ABT-737. In vitro and in vivo evaluations demonstrate successful Bcl-2 suppression, resulting in the restoration of Dox sensitivity, evident through impeded tumor growth and amplified necrosis rates at the tumor site. This delivery system showcases remarkable thermal responsiveness, injectability, and biodegradability, all finely aligned with the clinical demands of CS treatment. Collectively, this study introduces a transformative avenue for tackling drug resistance in CS chemotherapy, offering significant clinical potential.

Study on thermal storage performance of a novel conical spiral tube heat storage system

Due to the structural advantage of the conical spiral tube, which is narrow at the top and wide at the bottom, it helps to improve the thermal response rate of the heat storage system. Therefore, this study proposes a novel conical spiral tube heat storage system. The software Fluent is used to conduct three-dimensional unsteady state calculations and investigate the effects of the conical ratio, taper, and length-to-diameter ratio on the phase change material (PCM) thermal storage performance. The results indicate that when the conical ratio is increased from 1.0 to 3.0, the PCM heat storage capacity is reduced by 1.05%, the melting time is shortened by 17.60%, the average heat storage rate is increased by 20.10%, and the heat storage efficiency is reduced by 0.10%. Continuing to increase the conical ratio, the optimization of the performance is not obvious. Subsequently, a conical ratio of 3.0 heat storage tank is used as the reference unit. When the tank taper is increased from 0 to 0.22 and the length-to-diameter ratio is increased from 1.44 to 1.85, the melting time is shortened by 7.59% and 32.62 %, the heat storage capacity is reduced by 3.45% and 9.24%, the average heat storage rate is increased by 4.47% and 34.69%, and the heat storage efficiency is reduced by 0.02% and increased by 7.99%, respectively. Continuing to increase the taper from 0.22 to 0.32 does not result in an effective improvement of the performance. This study is a good guide for the optimization of the thermal storage performance of spiral tube heat storage systems and the efficient use of solar energy.

Out-of-equilibrium voltage and thermal bias response of a quantum dot hybrid system coupled to topological superconductor

We investigate theoretically the out-of-equilibrium transport properties of a single-level quantum dot coupled to a normal metal electrode and attached to a topological superconductor. Both voltage and thermal bias responses of the system in the nonequilibrium regime are studied. To obtain transport characteristics we used the nonequilibrium Green’s function approach. Particularly, we calculated the current and the corresponding differential conductance in two distinct cases. In the former situation, the charge current is induced by applying a bias voltage, whereas in the latter case it is generated by setting a temperature difference between the leads with no bias voltage. Moreover, strong diode effect in thermally generated current is found and non-equilibrium thermopower is analyzed.

A Near-Infrared Photothermal-Responsive Underwater Adhesive with Tough Adhesion and Antibacterial Properties.

Developing tunable underwater adhesives that possess tough adhesion in service and easy detachment when required remains challenging. Herein, a strategy is proposed to design a near infrared (NIR) photothermal-responsive underwater adhesive by incorporating MXene (Ti3 C2 Tx )-based nanoparticles within isocyanate-modified polydimethylsiloxane (PDMS) polymer chains. The developed adhesive exhibits long-term and tough adhesion with an underwater adhesion strength reaching 5.478MPa. Such strong adhesion is mainly attributed to the covalent bonds and hydrogen bonds at the adhesive-substrate interface. By making use of the photothermal-response of MXene-based nanoparticles and the thermal response of PDMS-based chains, the adhesive possesses photothermal-responsive performance, exhibiting sharply diminished adhesion under NIR irradiation. Such NIR-triggered tunable adhesion allows for easy and active detachment of the adhesive when needed. Moreover, the underwater adhesive exhibits photothermal antibacterial property, making it highly desirable for underwater applications. This work enhances the understanding of photothermal-responsive underwater adhesion, enabling the design of tunable underwater adhesives for biomedical and engineering applications.